Oxyhydroxy silicate colloids: A new type of waterborne actinide(IV) colloids
Oxyhydroxy silicate colloids: A new type of waterborne actinide(IV) colloids
Zänker, H.; Weiss, S.; Hennig, C.; Brendler, V.; Ikeda-Ohno, A.
At the near-neutral and reducing aquatic conditions expected in undisturbed ore deposits or in closed nuclear waste repositories, the actinides Th, U, Np and Pu are primarily tetravalent. These tetravalent actinides (An(IV)) are sparingly soluble in aquatic systems and, hence, are often assumed to be immobile. However, An(IV) could become mobile if they occur as colloids. This mini-review focuses on a new type of An(IV) colloids, oxyhydroxy silicate colloids. We herein discuss the chemical characteristics of these colloids and the potential implication for their environmental behavior. The binary oxyhydroxy silicate colloids of An(IV) could be potentially more mobile as a waterborne species than the well-known mono-component oxyhydrox-ide colloids.
Keywords: Tetravalent actinides; thorium(IV); uranium(IV); neptunium(IV); silica; colloids; colloid stability; nuclear waste repositories
Involved research facilities
- Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265
Related publications
- DOI: 10.1107/S1600577520014265 is cited by this (Id 22532) publication
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ChemistryOpen 5(2016), 174-182
DOI: 10.1002/open.201500207
Cited 14 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-22532