Self-assembly of [2+2] Co(II) metallomacrocycles and Ni(II) metallogels with novel bis(pyridylimine) ligands

Kelly, Norman; Gloe, Kerstin; Doert, Thomas; Hennersdorf, Felix; Heine, Axel; März, Juliane; Schwarzenbolz, Uwe; Weigand, Jan J.; Gloe, Karsten

doi:10.1016/j.jorganchem.2016.04.021

Self-assembly of [2+2] Co(II) metallomacrocycles and Ni(II) metallogels with novel bis(pyridylimine) ligands

Kelly, N.; Gloe, K.; Doert, T.; Hennersdorf, F.; Heine, A.; März, J.; Schwarzenbolz, U.; Weigand, J. J.; Gloe, K.

Two novel 46-membered Co(II) metallomacrocycles, Co2Cl4(L1)2]∙CH2Cl2 and [Co2(NO3)2(L1)2(H2O)2 ligand L4 was also demonstrated to form metallogels when reacted with NiCl2∙6H2O in tetrahydrofuran under defined conditions.

Keywords: Bispyridylimine ligands; Cobalt(II); Nickel(II); Metallomacrocycles; Metallogel; Self-assembly; Supramolecular chemistry

Journal of Organometallic Chemistry 821(2016), 182-191
Online First (2016) DOI: 10.1016/j.jorganchem.2016.04.021
Cited 18 times in Scopus

Permalink: https://www.hzdr.de/publications/Publ-23493