Facile Silylation of Cyclitols using Silyl-bis(triflates)
Facile Silylation of Cyclitols using Silyl-bis(triflates)
Topp, A.; Köckerling, M.; Reinke, H.; Miethchen, R.; Mamat, C.
Novel silylated diols and polyols were prepared using a recently developed synthesis route with bifunctionalized silyl triflates. These silyl derivatives include two triflate functions, which allow a selective protection of two hydroxy groups. Moreover, the conformation of the silyl chain in the silane backbone led to exceptional UV properties.
Keywords: Silyl-bis(triflates); Cyclitols; Silylation; Protecting group; Carbohydrates
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European Journal of Inorganic Chemistry (2018), 1302-1308
DOI: 10.1002/ejic.201701327
Cited 1 times in Scopus
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