Mineralogical and geochemical constraints on the origin of the Sohland-Rožany Ni-Cu-(PGE) sulfide mineralization (Lausitz Block, Bohemian Massif, Germany/Czech Republic)

The Sohland-Rožany Ni-Cu-(PGE) sulfide mineralization is hosted by a small gabbroic dike that is one of several Ni-Cu sulfide-bearing gabbroic intrusions in the northern Bohemian Massif. The intrusions are associated with a Middle Devonian to Early Carboniferous mafic-ultramafic plumbing system that emplaced within Cadomian granodiorites of the Lausitz Block. The Sohland-Rožany dike comprises varitextured olivine- and hornblende bearing gabbro and hornblende gabbro, with in particular the olivine-bearing lithologies affected by late-stage hydrothermal alteration. The variable lithotypes originated from differently fractionated magma batches. Fractionation likely took place in deeper parts of the magmatic systems, e.g. within staging magma chambers.
Mineralogical features like Ti-rich primary brown hornblende and diopsidic clinopyroxene as well as overall enriched incompatible element contents suggest moderate alkaline basaltic parental magmas with high volatile contents. The magmatic sulfide mineralization is exclusively hosted by the olivine- and hornblende-bearing gabbro and include disseminated, net-textured and massive sulfides. The mineralization types are predominated by pyrrhotitepentlandite-chalcopyrite assemblages accompanied by secondary violarite and pyrite as well as by accessory Pt, Pd, Au and Ag phases. The disseminated and net-textured sulfides have highly variable modal proportions of base metal sulfides with pyrrhotite-dominated beside chalcopyrite-dominated aggregates on the hand specimen scale. The platinum-group mineral (PGM) assemblage includes Pd-Pt-Ni-bearing bismuthotellurides of the melonite– merenskyite and michenerite–testibiopalladite solid solution series as well as sperrylite, of which bismuthian palladian melonite represents the most prominent PGE-bearing phase. The sulfide ores feature evolved Ni and highly variable Cu and Pt, Pd and Au tenors (3.5–7.5 wt.% Ni, 0.1–16.6 wt.% Cu, 80–3080 ppb Pt, 70–5320 ppb Pd and 20–3770 ppb Au). The magmatic sulfides are locally characterized by a late-stage hydrothermal overprint where sulfides were replaced by hydrous secondary phases (e.g. actinolite–tremolite and chlorite). A significant redistribution of the PGE due to hydrothermal alteration is unlikely as the majority of PGM show a close spatial association to the base-metal sulfides.
Textures and chemical compositions of the sulfides suggest that repeated magma batches eroded already fractionated sulfide pools and entrained early crystalized cumulates of monosulfide solid solution (MSS) together with variable fractionated sulfide melts. Sulfide saturation in the Sohland-Rožany magmas was likely controlled by fractional crystallization and assimilation of the granodioritic wall-rock in the course of thermomechanical erosion. The latter process was amplified by high mica contents of the granodiorites. Sulfur isotope signatures (–2.0 to – 1.2 ‰ VCDT) and the S-poor nature of the hosting granodiorites exclude a significant contribution of S from the country rocks.