Investigation for Safer Initiation of Grignard Reactions
Investigation for Safer Initiation of Grignard Reactions
Hessel, G.; Hulzer, G.; Kryk, H.; Schmitt, W.
Due to the spontaneous heat release during the initiation of the strongly exothermic Grignard reaction, these reactions dispose of considerable harzard potentials. Therefore, the knowledge of thermody-namic and thermokinetic parameters is one of the prerequisites for safe formation of Grignard rea-gents in production plants. To obtain more accurate results, these studies on the formation of Grignard reagents were carried out in a closed reaction calorimeter by dosing the pure bromobenzene deriva-tive for the first time. The molar reaction enthalpy per mole bromobenzene derivative was determined with a standard deviation of about 5%.
Keywords: Grignard reaction; Initiation; in-situ FTIR-specrometer
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Lecture (Conference)
Proceedings of the 3rd European Congress of Chemical Engineering, Nuremberg 26-28 June 2001, on ECCE-CD / Contents / 2. Sustainable Development, 2.2 Chemical Risk Management -
Abstract in refereed journal
Chemie Ingenieur Technik 73, 6 (2001) 611 -
Contribution to proceedings
Proceedings of the 3rd European Congress of Chemical Engineering, Nuremberg 26-28 June 2001, on ECCE-CD / Contents / 2. Sustainable Development, 2.2 Chemical Risk Management
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