A monomeric copper-phosphoramide complex: Synthesis, structure, and electronic properties
A monomeric copper-phosphoramide complex: Synthesis, structure, and electronic properties
Henriques, M. S.; Gorbunov, D. I.; Ponomaryov, A. N.; Saneei, A.; Pourayoubi, M.; Dusek, M.; Zvyagin, S.; Uhlarz, M.; Wosnitza, J.
We report on a novel phosphoramide complex with formula Cu(NO3)2([C5H10N]3PO)2. This complex is the first example of a copper monomeric phosphoric triamide having an octahedral Cu[O]6 coordination environment. Cu(NO3)2([C5H10N]3PO)2 crystallizes in the monoclinic space group P21/n with the Cu atom located at an inversion center, as determined by single-crystal X-ray diffraction. Magnetic measurements along the principal crystallographic directions of the single crystal indicate that the complex is a paramagnet with very low magnetic anisotropy. Electron paramagnetic resonance spectra reveal the presence of two Cu2+ sites and make it possible to extract the hyperfine coupling.
Involved research facilities
- High Magnetic Field Laboratory (HLD)
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Polyhedron 118(2016), 154-158
DOI: 10.1016/j.poly.2016.07.042
Cited 3 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-24126
