Personal web page of Christoph Hennig
Scientific career
- Since 1997:Scientist, HZDR, Institute of Resource Ecology, and Rossendorf Beamline at European Synchrotron Radiation Facility
- 1995:Dr. rer.-nat. University of Leipzig
- 1991:Diploma in Crystallography, University of Leipzig
Research work
- operation of two diffractometers at the Rossendorf Beamline (BM20) at ESRF / Grenoble
- coordination chemistry of f-elements (single-crystal diffraction)
- zirconium-based ceramics (powder diffraction)
Publications
2021
ROBL-II at ESRF: A synchrotron toolbox for actinide research
Scheinost, A.; Claußner, J.; Exner, J.; Feig, M.; Findeisen, S.; Hennig, C.; Kvashnina, K.; Naudet, D.; Prieur, D.; Roßberg, A.; Schmidt, M.; Qiu, C.; Colomp, P.; Cohen, C.; Dettona, E.; Dyadkin, V.; Stumpf, T.
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Journal of Synchrotron Radiation 28(2021), 333-349
DOI: 10.1107/S1600577520014265
2020
Ternary MIn₂S₄ (M = Mn, Fe, Co, Ni) Thiospinels - Crystal Structure and Thermoelectric Properties
Wyzga, P.; Veremchuk, I.; Bobnar, M.; Hennig, C.; Leithe-Jasper, A.; Gumeniuk, R.
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Zeitschrift für Anorganische und Allgemeine Chemie 646(2020)14, 1091-1098
DOI: 10.1002/zaac.202000014
Crystal structure, phase transition and properties of indium (III) sulfide
Wyżga, P.; Carrillo-Cabrera, W.; Akselrud, L.; Veremchuk, I.; Wagler, J.; Hennig, C.; Tsirlin, A.; Leithe-Jasper, A.; Kroke, E.; Gumeniuk, R.
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Dalton Transactions 49(2020)44, 15903-15913
DOI: 10.1039/d0dt03302b
Polar structure formation in solid solution of strontium substituted fluorapatite-gelatin composites: from structural and morphogenetic aspects to pyroelectric properties
Knaus, J.; Sommer, M.; Duchstein, P.; Gumeniuk, R.; Akselrud, L. G.; Sturm, S.; Auffermann, G.-D.; Hennig, C.; Zahn, D.; Hulliger, J.; Sturm, E. V.
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Chemistry of Materials 32(2020)19, 8619-8632
DOI: 10.1021/acs.chemmater.0c02993
Understanding the local structure of Eu3+ and Y3+ stabilized zirconia – Insights from luminescence and X–ray absorption spectroscopic investigations
Eibl, M.; Shaw, S.; Prieur, D.; Roßberg, A.; Wilding, M. C.; Hennig, C.; Morris, K.; Rothe, J.; Stumpf, T.; Huittinen, N. M.
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Journal of Materials Science 55(2020), 10095-10120
DOI: 10.1007/s10853-020-04768-3
Ternary MIn2S4 (M = Mn, Fe, Co, Ni) thiospinels - crystal structure and thermoelectric properties
Wyżga, P.; Veremchuk, I.; Bobnar, M.; Hennig, C.; Leithe-Jasper, A.; Gumeniuk, R.
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Zeitschrift für Anorganische und Allgemeine Chemie 646(2020)14, 1091-1098
DOI: 10.1002/zaac.202000014
New tools for calibrating diffraction setups
Kieffer, J.; Vals, V.; Blanc, N.; Hennig, C.
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Journal of Synchrotron Radiation 27(2020), 558-566
DOI: 10.1107/S1600577520000776
The missing pieces of the PuO2 nanoparticles puzzle
Gerber, E.; Romanchuk, A.; Pidchenko, I.; Amidani, L.; Roßberg, A.; Hennig, C.; Vaughan, G.; Trigub, A.; Egorova, T.; Bauters, S.; Plakhova, T.; Hunault, M.; Weiß, S.; Butorin, S.; Scheinost, A.; Kalmykov, S.; Kvashnina, K.
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Nanoscale 12(2020)35, 18039-18048
DOI: 10.1039/d0nr03767b
2019
How do actinyls interact with hyperphosphorylated yolk protein Phosvitin ?
Kumar, S.; Creff, G.; Hennig, C.; Rossberg, A.; Steudtner, R.; Raff, J.; Vidaud, C.; Oberhaensli, F. R.; Bottein, Y.; Den Auwer, C.
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Chemistry - A European Journal 25(2019), 12332-12341
DOI: 10.1002/chem.201902015
Deciphering the Crystal Structure of a Scarce 1D Polymeric Thorium Peroxo Sulfate
Bonato, L.; Virot, M.; Dumas, T.; Mesbah, A.; Lecante, P.; Prieur, D.; Le Goff, X.; Hennig, C.; Dacheux, N.; Moisy, P.; Nikitenko, S.
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Chemistry - A European Journal 25(2019)41, 9580-9585
DOI: 10.1002/chem.201901426
Indium thiospinel In1-xxIn2S4 – structural characterization and thermoelectric properties
Wyżga, P.; Veremchuk, I.; Himcinshi, C.; Burkhardt, U.; Carrillo-Cabrera, W.; Bobnar, M.; Hennig, C.; Leithe-Jasper, A.; Kortus, J.; Gumeniuk, R.
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Dalton Transactions 48(2019), 8350-8360
DOI: 10.1039/c9dt00890j
Structural stability and thermoelectric performance of high quality synthetic and natural pyrites (FeS2)
Zuñiga-Puelles, E.; Cardoso-Gil, R.; Bobnar, M.; Veremchuk, I.; Himcinschi, C.; Hennig, C.; Kortus, J.; Heide, G.; Gumeniuk, R.
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Dalton Transactions 48(2019), 10703-10713
DOI: 10.1039/c9dt01902b
CeMo2B5: a new type of arrangement of puckered boron hexagonal rings
Flipo, S.; Kohut, M.; Roth, F.; Weigel, T.; Schnelle, W.; Bobnar, M.; Ormeci, A.; Burkhardt, U.; Hennig, C.; Leisegang, T.; Meyer, D.-C.; Leithe-Jasper, A.; Gumeniuk, R.
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European Journal of Inorganic Chemistry (2019)31, 3572-3580
DOI: 10.1002/ejic.201900411
Is hydroxypyridonate 3,4,3‐LI(1,2‐HOPO) a good competitor of fetuin for uranyl metabolism?
Younes, A.; Creff, G.; Beccia, M. R.; Moisy, P.; Roques, J.; Aupiais, J.; Hennig, C.; Solari, P. L.; Den Auwer, C.; Vitaud, C.
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Metallomics 11(2019), 496-507
DOI: 10.1039/c8mt00272j
Extreme multi-valence states in mixed actinide oxides
Epifano, E.; Naji, M.; Manara, D.; Scheinost, A. C.; Hennig, C.; Lechelle, J.; Konings, R. J. M.; Gueneau, C.; Prieur, D.; Vitova, T.; Dardenne, K.; Rothe, J.; Martin, P. M.
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Communications Chemistry 2(2019), 59
DOI: 10.1038/s42004-019-0161-0
2018
Polyethyleneimine Methylenecarboxylate: a macromolecular DTPA analogue to chelate plutonium(IV)
Lahrouch, F.; Siberchiot, B.; Leost, L.; Aupiais, J.; Rossberg, A.; Hennig, C.; Den Auwer, C.; Di Giorgio, C.
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Chemical Communications 54(2018)83, 11705-11708
DOI: 10.1039/c8cc05206a
Superconductivity and magnetism in noncentrosymmetric LaPtGe3 and CePtGe3
Feig, M.; Nicklas, M.; Bobnar, M.; Schelle, W.; Schwarz, U.; Leithe-Jasper, A.; Hennig, C.; Gumeniuk, R.
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Physical Review B 98(2018)18, 184516
DOI: 10.1103/PhysRevB.98.184516
Competitive adsorption of ZrO2 nanoparticle and alkali cations (Li+ – Cs+) on muscovite (001)
Qiu, C.; Eng, P. J.; Hennig, C.; Schmidt, M.
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Langmuir 34(2018)41, 12270-12278
DOI: 10.1021/acs.langmuir.8b02277
Peculiar thermal behavior of UO2 local structure
Prieur, D.; Epifano, E.; Dardenne, K.; Rothe, J.; Hennig, C.; Scheinost, A.; Neuville, D.; Martin, P.
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Inorganic Chemistry 57(2018)23, 14890-14894
DOI: 10.1021/acs.inorgchem.8b02657 -
Lecture (Conference)
ATAS 2018 - 4th International Workshop on Advanced Techniques in Actinide Spectroscopy, 06.-09.11.2018, Nice, France
The {Np38} clusters: The missing link in the largest poly-oxo cluster series of tetravalent actinides
Martin, N. P.; Volkringer, C.; Roussel, P.; März, J.; Hennig, C.; Loiseau, T.; Ikeda-Ohno, A.
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Chemical Communications 54(2018)72, 10060-10063
DOI: 10.1039/C8CC03744B
Towards the development of chitosan nanoparticles for plutonium pulmonary decorporation
Léost, L.; Roques, J.; van de Meeren, A.; Vincent, L.; Sbirrazzuoli, N.; Hennig, C.; Rossberg, A.; Aupiais, J.; Pagnotta, S.; Den Auwer, C.; Di Giorgio, C.
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Dalton Transactions 47(2018), 11605-11618
DOI: 10.1039/c8dt02419g
Interaction of Uranium(VI) with α‑Amylase and Its Implication for Enzyme Activity
Barkleit, A.; Hennig, C.; Ikeda-Ohno, A.
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Chemical Research in Toxicology 31(2018), 1032-1041
DOI: 10.1021/acs.chemrestox.8b00106
Cluster Formation in the Superconducting Complex Intermetallic Compound Be21Pt5
Amon, A.; Ormeci, A.; Bobnar, M.; Akselrud, L. G.; Avdeev, M.; Gumeniuk, R.; Burkhardt, U.; Prots, Y.; Hennig, C.; Leithe-Jasper, A.; Grin, Y.
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Accounts of Chemical Research 51(2018)2, 214-222
DOI: 10.1021/acs.accounts.7b00561
Formation and Aggregation of ZrO2 Nanoparticles on Muscovite (001)
Qiu, C.; Eng, P. J.; Hennig, C.; Schmidt, M.
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Journal of Physical Chemistry C 122(2018), 3865-3874
DOI: 10.1021/acs.jpcc.7b10101
Noncentrosymmetric Superconductor BeAu
Amon, A.; Svanidze, E.; Cardoso, R.; Wilson, M. N.; Rosner, H.; Bobnar, M.; Schnelle, W.; Lynn, J. W.; Gumeniuk, R.; Hennig, C.; Luke, G. M.; Borrmann, H.; Leithe-Jasper, A.; Grin, Y.
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Physical Review B 8(2018)97, 014501
DOI: 10.1103/PhysRevB.97.014501
Uniaxial ferromagnetism of local uranium moments in hexagonal UBeGe
Gumeniuk, R.; Yaresko, A. N.; Schnelle, W.; Nicklas, M.; Kvashnina, K. O.; Hennig, C.; Grin, Y.; Leithe-Jasper, A.
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Physical Review B 97(2018), 174405
DOI: 10.1103/PhysRevB.97.174405
2017
Structural and thermodynamic investigation of AnIVLI(O)HOPO(Article)
Aupiais, J.; Younes, A.; Moisy, P.; Hennig, C.; Rossberg, A.; Brunel, B.; Kerbaa, M.; Vidaud, C.; Den Auwer, C.
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New Journal of Chemistry 41(2017)19, 11291-11298
DOI: 10.1039/c7nj02123b
Two-gap superconductivity in Ag1–x Mo6S8 Chevrel phase
Feig, M.; Bobnar, M.; Veremchuk, I.; Hennig, C.; Burkhardt, U.; Starke, R.; Kundys, B.; Leithe-Jasper, A.; Gumeniuk, R.
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Journal of Physics: Condensed Matter 29(2017), 495603
DOI: 10.1088/1361-648X/aa97fd
Polyethyleneimine Methylphosphonate : towards the design of a new class of macromolecular actinide chelating agent in case of human exposition
Lahrouch, F.; Sofronov, O.; Creff, G.; Rossberg, A.; Hennig, C.; Den Auwer, C.; Di Giorgio, C.
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Dalton Transactions 46(2017), 13869-13877
DOI: 10.1039/c7dt02643a
Structural characterization of Am(III) and Pu(III)-DOTA complexes
Audras, M.; Berthon, L.; Berthon, C.; Guillaumont, D.; Dumas, T.; Illy, M. C.; Martin, N.; Zilbermann, I.; Ben-Eliyahu, Y.; Moissev, Y.; Bettelheim, A.; Camelli, S.; Hennig, C.; Moisy, P.
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Inorganic Chemistry 56(2017), 12248-12259
DOI: 10.1021/acs.inorgchem.7b01666
Thermoelectric Properties of Natural Chalcopyrite from Zacatecas, Mexico
Wyżga, P.; Bobnar, M.; Hennig, C.; Leithe-Jasper, A.; Mori, T.; Gumeniuk, R.
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Zeitschrift für Anorganische und Allgemeine Chemie 643(2017)13, 858-863
DOI: 10.1002/zaac.201700074
Coordination of Tetravalent Actinides (An=Th-IV, U-IV, Np-IV, Pu-IV) with DOTA: From Dimers to Hexamers
Tamain, C.; Dumas, T.; Hennig, C.; Guilbaud, P.
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Chemistry - A European Journal 23(2017)28, 6864-6875
DOI: 10.1002/chem.201700493
Insights into the sonochemical synthesis and properties of salt-free intrinsic plutonium colloids
Dalodière, E.; Virot, M.; Morosini, V.; Chave, T.; Dumas, T.; Hennig, C.; Wiss, T.; Blanco, O. D.; Shuh, D. K.; Tyliszcak, T.; Venault, L.; Moisy, P.; Nikitenko, S. I.
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Scientific Reports 7(2017), 43514
DOI: 10.1038/srep43514
A Combined Spectroscopic/Molecular Dynamic Study for Investigating a Methyl Carboxylated PEI as a Potential Uranium Decorporation Agent
Lahrouch, F.; Chamayou, A. C.; Creff, G.; Duvail, M.; Hennig, C.; Lozano Rodriguez, M. J.; Den Auwer, C.; Di Giorgio, C.
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Inorganic Chemistry 56(2017), 1300-1308
DOI: 10.1021/acs.inorgchem.6b02408
Synthesis of coordination polymers of tetravalent actinides (U and Np) with phthalate or mellitate ligand in aqueous medium
Martin, N. P.; März, J.; Volkringer, C.; Henry, N.; Hennig, C.; Ikeda-Ohno, A.; Loiseau, T.
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Inorganic Chemistry 56(2017)5, 2902-2913
DOI: 10.1021/acs.inorgchem.6b02962
Solution species and crystal structure of Zr(IV) acetate
Hennig, C.; Weiss, S.; Kraus, W.; Kretzschmar, J.; Scheinost, A.
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Inorganic Chemistry 56(2017), 2473-2480
DOI: 10.1021/acs.inorgchem.6b01624
The inverse-trans-influence as a general principle of f-block chemistry
Gregson, M.; Lu, E.; Mills, D. P.; Tuna, F.; Mcinnes, E. J. L.; Hennig, C.; Scheinost, A. C.; Mcmaster, J.; Lewis, W.; Blake, A. J.; Kerridge, A.; Liddle, S. T.
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Nature Communications 8(2017), 14137
DOI: 10.1038/ncomms14137
2016
Structures of Plutonium(IV) and Uranium(VI) with N,N‑Dialkyl Amides from Crystallography, X‑ray Absorption Spectra, and Theoretical Calculations
Acher, E.; Cherkaski, Y. H.; Dumas, T.; Tamin, C.; Guillaumont, D.; Boubals, N.; Javierre, G.; Hennig, C.; Solari, P. L.; Charbonnel, M.-C.
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Inorganic Chemistry 55(2016), 5558-5569
DOI: 10.1021/acs.inorgchem.6b00592
Evidence of trivalent Am substitution into U3O8
Caisso, M.; Roussel, P.; Den Auwer, C.; Picart, S.; Hennig, C.; Scheinost, A. C.; Delahaye, T.; Ayral, A.
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Inorganic Chemistry 55(2016), 10438-10444
DOI: 10.1021/acs.inorgchem.6b01672
First evidence of a water soluble Pu(IV) - [Pu6(OH)4O4]12+ - hexanuclear cluster.
Tamain, C.; Dumas, T.; Guillaumont, D.; Hennig, C.; Guilbaud, P.
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European Journal of Inorganic Chemistry 22(2016), 3536-3540
DOI: 10.1002/ejic.201600656
Neptunium characterization in uranium dioxide fuel: Combining a XAFS and a thermodynamic approach
Chollet, M.; Martin, P.; Degueldre, C.; Poonoosamy, J.; Belin, R. C.; Hennig, C.
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Journal of Alloys and Compounds 662(2016), 448-454
DOI: 10.1016/j.jallcom.2015.12.005
Emergence of comparable covalency in isostructural cerium(IV)- and uranium(IV)-carbon multiple bonds
Gregson, M.; Lu, E.; Tuna, F.; Mcinnes, E. J. L.; Hennig, C.; Scheinost, A. C.; Mcmaster, J.; Lewis, W.; Blake, A. J.; Kerridge, A.; Liddle, S. T.
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Chemical Science 7(2016), 3286-3295
DOI: 10.1039/C6SC00278A
Oxyhydroxy silicate colloids: A new type of waterborne actinide(IV) colloids
Zänker, H.; Weiss, S.; Hennig, C.; Brendler, V.; Ikeda-Ohno, A.
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ChemistryOpen 5(2016), 174-182
DOI: 10.1002/open.201500207
2015
Ex-Situ Kinetic Investigations of the Formation of the Poly-Oxo Cluster U38
Falaise, C.; Volkringer, C.; Hennig, C.; Loiseau, T.
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Chemistry - A European Journal 21(2015), 16664-16654
DOI: 10.1002/chem.201502207
Insights into the Mechanism of Extraction of Uranium (VI) from Nitric Acid Solution into an Ionic Liquid by using Tri-n-butyl phosphate
Gaillard, C.; Boltoeva, M.; Billard, I.; Georg, S.; Mazan, V.; Ouadi, A.; Ternova, D.; Hennig, C.
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ChemPhysChem 16(2015), 2653-2662
DOI: 10.1002/cphc.201500283
A new look at the structural properties of trisodium uranate Na3UO4
Smith, A. L.; Raison, P. E.; Martel, L.; Prieur, D.; Charpentier, T.; Wallez, G.; Suard, E.; Scheinost, A. C.; Hennig, C.; Martin, P.; Kvashnina, K. O.; Cheetham, A. K.; Konings, R. J. M.
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Inorganic Chemistry 54(2015)7, 3552-3562
DOI: 10.1021/acs.inorgchem.5b00136
Formation of neptunium(IV)-silica colloids at near-neutral and slightly alkaline pH
Husar, R.; Weiss, S.; Hennig, C.; Hübner, R.; Ikeda-Ohno, A.; Zänker, H.
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Environmental Science & Technology 49(2015)1, 665-671
DOI: 10.1021/es503877b
Intrinsic formation of nanocrystalline neptunium dioxide under neutral aqueous conditions relevant to deep geological repositories
Husar, R.; Hübner, R.; Hennig, C.; Martin, P. M.; Chollet, M.; Weiss, S.; Zänker, H.; Stumpf, T.; Ikeda-Ohno, A.
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Chemical Communications 51(2015), 1301-1304
DOI: 10.1039/C4CC08103J
2014
Recent advances in the study of the UO2–PuO2 phase diagram at high temperatures
Böhler, R.; Welland, M. J.; Prieur, D.; Cakir, P.; Vitova, T.; Pruessmann, T.; Pidchenko, I.; Hennig, C.; Guéneau, C.; Konings, R. J. M.; Manara, D.
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Journal of Nuclear Materials 448(2014), 330-339
DOI: 10.1016/j.jnucmat.2014.02.029
A 23Na Magic Angle Spinning Nuclear Magnetic Resonance, XANES, and High Temperature X-Ray Diffraction Study of NaUO3, Na4UO5, and Na2U2O7
Smith, A. L.; Raison, P. E.; Martel, L.; Charpentier, T.; Farnan, I.; Prieur, D.; Hennig, C.; Scheinost, A. C.; Konings, R. J. M.; Cheetham, A. K.
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Inorganic Chemistry 53(2014)1, 375-382
DOI: 10.1021/ic402306c
Synthesis of coffinite, USiO4, and structural investigations of the UxTh(1-x)SiO4 solid solutions
Labs, S.; Hennig, C.; Weiss, S.; Curtius, H.; Zaenker, H.; Bosbach, D.
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Environmental Science & Technology 48(2014), 854-860
DOI: 10.1021/es403995b
Colloid-borne forms of tetravalent actinides: A brief review
Zänker, H.; Hennig, C.
- Journal of Contaminant Hydrology 157(2014), 87-105
2013
Thermodynamic study of the complexation of protactinium(V) with diethylenetriaminepentaacetic acid
Mendes, M.; Leguay, S.; Le Naour, C.; Hamadi, S.; Roques, J.; Moisy, P.; Guillaumont, D.; Topin, S.; Aupiais, J.; Den Auwer, C.; Hennig, C.
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Inorganic Chemistry 52(2013), 7497-7507
DOI: 10.1021/ic400378t
Short note on the hydrolysis and complexation of neptunium(IV) in HEPES solution
Dahou, S.; Hennig, C.; Moisy, P.; Petit, S.; Scheinost, A. C.; Subra, G.; Vidaud, C.; Den Auwer, C.
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Radiochimica Acta 101(2013), 367-372
DOI: 10.1524/ract.2013.2036
Uranyl-Halide Complexation in N,N-Dimethylformamide: Halide Coordination Trend Manifests Hardness of [UO2]2+
Takao, K.; Takao, S.; Ikeda, Y.; Bernhard, G.; Hennig, C.
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Dalton Transactions 42(2013)36, 13101-13111
DOI: 10.1039/c3dt51191j
Crystal structure and solution species of Ce(III) and Ce(IV) formates-from mononuclear to hexanuclear complexes
Hennig, C.; Ikeda-Ohno, A.; Kraus, W.; Weiss, S.; Pattison, P.; Emerich, H.; Abdala, P.; Scheinost, A.
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Inorganic Chemistry 52(2013)20, 11734-11743
DOI: 10.1021/ic400999j
Hydrolysis of Tetravalent Cerium for a Simple Route to Nanocrystalline Cerium Dioxide: An In Situ Spectroscopic Study of Nanocrystal Evolution
Ikeda-Ohno, A.; Hennig, C.; Weiss, S.; Yaita, T.; Bernhard, G.
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Chemistry - A European Journal 19(2013), 7348-7360
DOI: 10.1002/chem.201204101
Identification of hexanuclear Actinide(IV) carboxylates with Thorium, Uranium and Neptunium by EXAFS spectroscopy
Hennig, C.; Takao, S.; Takao, K.; Weiss, S.; Kraus, W.; Emmerling, F.; Meyer, M.; Scheinost, A. C.
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Journal of Physics: Conference Series 430(2013), 012116
DOI: 10.1088/1742-6596/430/1/012116
Multi edge X-ray absorption spectroscopy of thorium, neptunium and plutonium hexacyanoferrate compounds
Dumas, T.; Charbonnel, M. C.; Charushnikova, I. A.; Conradson, S. D.; Fillaux, C.; Hennig, C.; Moisy, P.; Petit, S.; Scheinost, A. C.; Shuh, D. K.; Tyliszczak, T.; Den Auwer, C.
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New Journal of Chemistry 37(2013), 3003-3016
DOI: 10.1039/c3nj00318c
Solid-state properties and colloidal stability of thorium(IV)-silica nanoparticles
Hennig, C.; Weiss, S.; Banerjee, D.; Brendler, E.; Honkimäki, V.; Cuello, G.; Ikeda-Ohno, A.; Scheinost, A.; Zänker, H.
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Geochimica et Cosmochimica Acta 103(2013), 197-212
DOI: 10.1016/j.gca.2012.10.051
2012
Structure and stability range of a hexanuclear Th(IV) – glycine complex
Hennig, C.; Takao, S.; Takao, K.; Weiss, S.; Kraus, W.; Emmerling, K.; Scheinost, A. C.
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Dalton Transactions 41(2012), 12818-12823
DOI: 10.1039/C2DT31367G
Simplest Homoleptic Metal-Centered Tetrahedrons, [M(OH2)4]2+, in 1- Ethyl-3-methylimidazolium Tetrafluoroborate Ionic Liquid (M = Co, Ni, Cu)
Takao, K.; Tone, Y.; Hennig, C.; Inoue, S.; Tsubomura, T.
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Inorganic Chemistry 51(2012), 4850-4854
DOI: 10.1021/ic3003433
Evidence for the formation of UO2(NO3)42- in an ionic liquid by EXAFS
Gaillard, C.; Klimchuk, O.; Ouadi, A.; Billard, I.; Hennig, C.
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Dalton Transactions 41(2012), 5476-5479
DOI: 10.1039/c2dt30205e
Dinuclear complexes of tetravalent cerium in an aqueous perchloric acid solution
Ikeda-Ohno, A.; Tsushima, S.; Hennig, C.; Yaita, T.; Bernhard, G.
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Dalton Transactions 41(2012)24, 7190-7192
DOI: 10.1039/C2DT12406H
Formation of Soluble Hexanuclear Neptunium(IV) Nano-Clusters in Aqueous Solution: Growth Termination of Actinide(IV) Hydrous Oxides by Carboxylates
Takao, K.; Takao, S.; Scheinost, A.; Bernhard, G.; Hennig, C.
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Inorganic Chemistry 51(2012)3, 1336-1344
DOI: 10.1021/ic201482n
EXAFS and DFT Investigations of Uranyl-Arsenate Complexes in Aqueous Solution
Gezahegne, W. A.; Hennig, C.; Tsushima, S.; Planer-Friedrich, B.; Scheinost, A. C.; Merkel, B. J.
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Environmental Science & Technology 46(2012)4, 2228-2233
DOI: 10.1021/es203284s
Perrhenate Complexation by Uranyl in Traditional Solvents and in Ionic Liquids: A Joined Molecular Dynamics/Spectroscopic Study
Chaumont, A.; Klimchuk, O.; Gaillard, C.; Billard, I.; Ouadi, A.; Hennig, C.; Wipff, G.
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Journal of Physical Chemistry B 116(2012), 3205-3219
DOI: 10.1021/jp209476h
2011
Electrochemical behaviour of tetrachloro and tetrabromo uranyl complexes in room temperature ionic liquids
Sornein, M.-O.; Cannes, C.; Le Naour, C.; Mendes, M.; Hennig, C.
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Journal of Electroanalytical Chemistry 661(2011)1, 49-56
DOI: 10.1016/j.jelechem.2011.07.012
Formation of uranium(IV)-silica colloids at near-neutral pH
Dreissig, I.; Weiss, S.; Hennig, C.; Bernhard, G.; Zänker, H.
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Geochimica et Cosmochimica Acta 75(2011)2, 352-367
DOI: 10.1016/j.gca.2010.10.011
Local structure in americium and californium hexacyanoferrates. Comparison with their lanthanide analogues
Dupouy, G.; Bonhoure, I.; Conradson, S. D.; Dumas, T.; Hennig, C.; Le Naour, C.; Moisy, P.; Scheinost, A. C.; Simoni, E.; Den Auwer, C.
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European Journal of Inorganic Chemistry 10(2011), 1560-1569
DOI: DOI: 10.1002/ejic.201001004
2010
Thermodynamical and Structural Study of Protactinium(V) Oxalate Complexes in Solution
Mendes, M.; Hamadi, S.; Le Naour, C.; Roques, J.; Jeanson, A.; Den Auwer, C.; Moisy, P.; Topin, S.; Aupiais, J.; Hennig, C.; Di Giandomenico, M. V.
- Inorganic Chemistry 49(2010), 9962-9971
Competitive Complexation of Nitrates and Chlorides to Uranyl in a Room Temperature Ionic Liquid
Gaillard, C.; Chaumont, A.; Billard, I.; Hennig, C.; Ouadi, A.; Georg, S.; Wipff, G.
- Inorganic Chemistry 49(2010)14, 6484-6494
The Role of Transferrin in Actinide(IV) Uptake: Comparison with Iron(III)
Jeanson, A.; Ferrand, M.; Funke, H.; Hennig, C.; Moisy, P.; Solari, P. L.; Vidaud, C.; Den Auwer, C.
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Chemistry - A European Journal 16(2010), 1378-1387
DOI: 10.1002/chem.200901209
Molecular Structure and Electrochemical Behavior of Uranyl(VI) Complex with Pentadentate Schiff Base Ligand: Prevention of Uranyl(V) Cation-Cation Interaction by Fully Chelating Equatorial Coordination Sites
Takao, K.; Kato, M.; Takao, S.; Nagasawa, A.; Bernhard, G.; Hennig, C.; Ikeda, Y.
- Inorganic Chemistry 49(2010)5, 2349-2359
In situ Spectroelectrochemical Investigation of Pt(II/IV) Oxidation in Aqueous Solution Using X-ray Absorption Spectroscopy
Takao, K.; Takao, S.; Scheinost, A. C.; Bernhard, G.; Hennig, C.
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Inorganica Chimica Acta 363(2010)4, 802-806
DOI: 10.1016/j.ica.2009.11.032
Comparative investigation of the limiting solution species [U(CO3)5]6- and the crystal structure of Na6[U(CO3)5]12H2O
Hennig, C.; Ikeda-Ohno, A.; Emmerling, F.; Kraus, W.; Bernhard, G.
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Dalton Transactions 39(2010), 3744-3750
DOI: 10.1039/b922624a
Double photoexcitation of 2p and 4f electrons in curium
Hennig, C.; Skanthakumar, S.; Soderholm, L.
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Journal of Electron Spectroscopy and Related Phenomena 180(2010), 17-20
DOI: 10.1016/j.elspec.2010.03.004
2009
Neptunium Carbonato Complexes in Aqueous Solution: An Electrochemical, Spectroscopic, and Quantum Chemical Study
Ikeda-Ohno, A.; Tsushima, S.; Takao, K.; Rossberg, A.; Funke, H.; Scheinost, A.; Bernhard, G.; Yaita, T.; Hennig, C.
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Inorganic Chemistry 48(2009)24, 11779-11787
DOI: 10.1021/ic901838r
Structure of early actinides(V) in acidic solutions
Di Giandomenico, M. V.; Le Naour, C.; Simoni, E.; Gulliaumont, D.; Moisy, P.; Hennig, C.; Conradson, C.; Den Auwer, C.
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Radiochimica Acta 97(2009), 347-353
DOI: 10.1524/ract.2009.1620
First Hexanuclear U(IV) and Th(IV) Formate Complexes - Structure and Stability Range in Aqueous Solution
Takao, S.; Takao, K.; Kraus, W.; Emmerling, F.; Scheinost, A. C.; Bernhard, G.; Hennig, C.
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European Journal of Inorganic Chemistry 32(2009), 4771-4775
DOI: 10.1002/ejic.200900899
Coordination environment of [UO2Br4]2- in ionic liquids and crystal structure of [Bmim]2[UO2Br4]
Sornein, M. O.; Mendes, M.; Cannes, C.; Le Naour, C.; Nockemann, P.; van Hecke, K.; van Meervelt, L.; Berthet, J. C.; Hennig, C.
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Polyhedron 28(2009), 1281-1286
DOI: 10.1016/j.poly.2009.02.027
Sorption of Th(IV) onto Iron Corrosion Products: EXAFS Study
Seco, F.; Hennig, C.; de Pablo, J.; Rovira, M.; Rojo, I.; Marti, V.; Gimenez, J.; Duro, L.; Grive, M.; Bruno, J.
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Environmental Science & Technology 43(2009), 2825-2830
DOI: 10.1021/es803608a
Thermodynamics and Structure of Actinide(IV) Complexes with Nitrilotriacetic Acid
Bonin, L.; Guillaumont, D.; Jeanson, A.; Den Auwer, C.; Grigoriev, M.; Berthet, J.-C.; Hennig, C.; Scheinost, A.; Moisy, P.
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Inorganic Chemistry 48(2009)9, 3943-3953
DOI: 10.1021/ic801453w
Complex Formation and Molecular Structure of Np(VI) and Np(V) Acetates
Takao, K.; Takao, S.; Scheinost, A. C.; Bernhard, G.; Hennig, C.
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Lecture (Conference)
Migration'09, 20.-25.09.2009, Kennewick, Washington, USA -
Inorganic Chemistry 48(2009), 8803-8810
DOI: 10.1021/ic900981q
Speciation of Rare-Earth Metal Complexes in Ionic Liquids: A Multiple-Technique Approach
Nockemann, P.; Thijs, B.; Lunstroot, K.; Parac-Vogt, T. N.; Görller-Walrand, C.; Binnemans, K.; van Hecke, K.; van Meervelt, L.; Nikitenko, S.; Daniels, J.; Hennig, C.; van Deun, R.
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Chemistry - A European Journal 15(2009), 1449-1461
DOI: 10.1002/chem.200801418
Speciation and Structural Study of U(IV) and -(VI) in Perchloric and Nitric Acid Solutions
Ikeda-Ohno, A.; Hennig, C.; Tsushima, S.; Scheinost, A. C.; Bernhard, G.; Yaita, T.
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Inorganic Chemistry 48(2009)15, 7201-7210
DOI: 10.1021/ic9004467
The sulfate coordination of Np(IV), Np(V) and Np(VI) in aqueous solution
Hennig, C.; Ikeda-Ohno, A.; Tsushima, S.; Scheinost, A.
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Inorganic Chemistry 48(2009), 5350-5360
DOI: 10.1021/ic9003005
X-ray absorption fine structures of uranyl(V) complexes in non-aqueous solutions
Takao, K.; Tsushima, S.; Takao, S.; Scheinost, A. C.; Bernhard, G.; Ikeda, Y.; Hennig, C.
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Lecture (Conference)
Actinides 2009, 12.-17.07.2009, San Francisco, USA - Inorganic Chemistry 48(2009)20, 9602-9604
The role of aspartyl-rich pentapeptides in comparative complexation of actinide(IV) and iron(III). Part 1
Jeanson, A.; Berthon, C.; Coantic, S.; Den Auwer, C.; Floquet, N.; Funke, H.; Guillaneux, D.; Hennig, C.; Martinez, J.; Moisy, P.; Petit, S.; Proux, O.; Quemeneur, P.; Solari, P. L.; Subra, G.
- New Journal of Chemistry 33(2009), 976-985
2008
The relationship of monodentate and bidentate coordinated uranium(VI) sulfate in aqueous solution
Hennig, C.; Ikeda, A.; Schmeide, K.; Brendler, V.; Moll, H.; Tsushima, S.; Scheinost, A. C.; Skanthakumar, S.; Wilson, R.; Soderholm, L.; Servaes, K.; Görrler-Walrand, C.; van Deun, R.
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Radiochimica Acta 96(2008), 607-611
DOI: 10.1524/ract.2008.1543
Electrochemical and Complexation Behavior of Neptunium in Aqueous Perchlorate and Nitrate Solutions
Ikeda, A.; Hennig, C.; Rossberg, A.; Funke, H.; Scheinost, A. C.; Bernhard, G.; Yaita, T.
- Inorganic Chemistry 47(2008)18, 8294-8305
Double photoexcitation involving 2p and 4f electrons in L3-edge x-ray absorption spectra of protactinium
Hennig, C.; Le Naour, C.; Den Auwer, C.
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Physical Review B 77(2008), 235102-1-235102-6
DOI: 10.1103/PhysRevB.77.235102
Coordination of a uranium(IV) sulfate monomer in an aqueous solution and in the solid state
Hennig, C.; Kraus, W.; Emmerling, F.; Ikeda, A.; Scheinost, A.
- Inorganic Chemistry 47(2008)5, 1634-1638
Structural Determination of Individual Chemical Species in a Mixed System by Iterative Transformation Factor Analysis (ITFA)-based X-ray Absorption Spectroscopy Combined with UV-Visible Absorption and Quantum Chemical Calculation
Ikeda, A.; Hennig, C.; Rossberg, A.; Tsushima, S.; Scheinost, A. C.; Bernhard, G.
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Analytical Chemistry 80(2008)4, 1102-1110
DOI: 10.1021/ac7021579
Species distribution and coordination of uranyl chloro complexes in acetonitrile
Hennig, C.; Servaes, K.; Nockemann, P.; van Hecke, K.; van Meervelt, L.; Wouters, J.; Görller-Walrand, C.; van Deun, R.
- Inorganic Chemistry 47(2008)8, 2987-2993
2007
Combining theoretical chemistry and XANES multi-edge experiments to probe actinide valence states
Fillaux, C.; Berthet, J.-C.; Conradson, S. D.; Guilbaud, P.; Guillaumont, D.; Hennig, C.; Moisy, P.; Roques, J.; Simoni, E.; Shuh, D. K.; Tyliszczak, T.; Castro-Rodriguez, I.; Den Auwer, C.
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Comptes Rendus Chimie 10(2007), 859-871
DOI: 10.1016/j.crci.2006.12.012
Dissolution of UO2, UO3 and of some lanthanide oxides in BumimTf2N: effect of acid and water and formation of UO2(NO3)3−
Billard, I.; Gaillard, C.; Hennig, C.
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Dalton Transactions 4214(2007), 4214-4221
DOI: DOI: 10.1039/b706355e
XAS study of (U1−yPuy)O2 solid solutions
Martin, P.; Grandjean, S.; Valot, C.; Carlot, G.; Ripert, M.; Blank, P.; Hennig, C.
- Journal of Alloys and Compounds 444-445(2007), 410-414
Structural and spectroscopic studies of the complex [BuMeIm]2[UCl6] in the solid state and in hydrophobic room temperature ionic liquid [BuMeIm][Tf2N]
Nikitenko, S. I.; Hennig, C.; Grigoriev, M. S.; Le Naour, C.; Cannes, C.; Trubert, D.; Bossé, E.; Berton, C.; Moisy, P.
- Polyhedron 26(2007), 3136-3142
A Comparative Study of U(VI) and U(V) Carbonato Complexes in Aqueous Solution
Ikeda, A.; Hennig, C.; Tsushima, S.; Takao, K.; Ikeda, Y.; Scheinost, A.; Bernhard, G.
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Inorganic Chemistry 46(2007)10, 4212-4219
DOI: 10.1021/ic070051y
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