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41688 Publications
Roadmap on Spin-Wave Computing
Chumak, A. V.; Kabos, P.; Wu, M.; et al.; Schultheiß, H.; Schultheiß, K.
Abstract
Magnonics addresses the physical properties of spin waves and utilizes them for data processing. Scalability down to atomic dimensions, operation in the GHz-to-THz frequency range, utilization of nonlinear and nonreciprocal phenomena, and compatibility with CMOS are just a few of many advantages offered by magnons. Although magnonics is still primarily positioned in the academic domain, the scientific and technological challenges of the field are being extensively investigated, and many proof-of-concept prototypes have already been realized in laboratories. This roadmap is a product of the collective work of many authors that covers versatile spin-wave computing approaches, conceptual building blocks, and underlying physical phenomena. In particular, the roadmap discusses the computation operations with Boolean digital data, unconventional approaches like neuromorphic computing, and the progress towards magnon-based quantum computing. The article is organized as a collection of sub-sections grouped into seven large thematic sections. Each sub-section is prepared by one or a group of authors and concludes with a brief description of current challenges and the outlook of further development for each research direction.
Keywords: Spin wave; Magnon; Magnonics; Computing; Data processing
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IEEE Transactions on Magnetics 8(2022)6, 0800172
DOI: 10.1109/TMAG.2022.3149664
Cited 190 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34291
Data publication: Multisite Dopamine Sensing with Femtomolar Resolution Using a CMOS Enabled Aptasensor Chip
Baraban, L.; Seichepine, F.; Sessi, V.; Ibarlucea, B.; Klinghammer, S.; Ibrahim, I.; Heinzig, A.; Szabo, N.; Mikolajick, T.; Reinhold Hierlemann, A.; Frey, U.; Weber, W.; Cuniberti, G.
Abstract
Data describe the graphs summarized into the figures with a possibility of opening the figures and direct data access.
Related publications
- DOI: 10.3389/fnins.2022.875656 references this (Id 34290) publication
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Multisite Dopamine Sensing with Femtomolar Resolution Using a CMOS Enabled …
ROBIS: 34286 has used this (Id 34290) publication of HZDR-primary research data
-
Reseach data in the HZDR data repository RODARE
Publication date: 2022-07-26 Open access
DOI: 10.14278/rodare.1815
Versions: 10.14278/rodare.1816
License: CC-BY-4.0
Downloads
Permalink: https://www.hzdr.de/publications/Publ-34290
Lab Scale Experimental Studies For Modeling Possible Zinc Removal Efforts in LOCA Situations
Harm, U.; Kryk, H.; Hampel, U.; Seeliger, A.; Alt, S.; Kästner, W.
Abstract
During the sump recirculation phase after a postulated LOCA in PWR, the coolant in the reactor sump is recirculated to the reactor core by residual-heat removal pumps as part of the emergency core cooling system. Long-term contact of the boric acid containing coolant with hot-dip galvanized containment internals (e.g. grating treads) is assumed to cause corrosion of corresponding materials with the consequence of rising concentrations of dissolved zinc in coolant. As it was shown in previous research projects, subsequently formed zinc borates may precipitate within hot spots of the reactor core in the late phase of the LOCA causing thermal hydraulic effects. In PWR, ion exchange columns are installed as part of the coolant cleaning system, having potential to be used to remove dissolved zinc ions.
For evaluation of such approach, lab scale investigations with ion exchange resins to remove dissolved zinc ions from the coolant are carried out under typical conditions of the post LOCA phase (sump recirculation). The usability of the coolant cleaning system for this purpose was proven successfully. The further aim is to model the zinc removal process by the coolant cleaning system by means of data of the ion exchange capacity of different ion exchange resins and kinetic data for the zinc removal under LOCA conditions.
The investigations are carried out as joint research project of Helmholtz-Zentrum Dresden - Rossendorf, TU Dresden, and Hochschule Zittau/Goerlitz. The goal is to build up a database for extensions of thermo-hydraulic simulation tools by the project partner GRS.
Keywords: PWR; LOCA; coolant cleaning system; zinc; modeling
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Contribution to proceedings
The 19th International Topical Meeting on Nuclear Reactor Thermal Hydraulics (NURETH-19), 06.-11.03.2022, Brussels, Belgium
Proceedings of NURETH-19 -
Lecture (Conference)
(Online presentation)
The 19th International Topical Meeting on Nuclear Reactor Thermal Hydraulics (NURETH-19), 06.-11.03.2022, Brussels, Belgium
Permalink: https://www.hzdr.de/publications/Publ-34289
Understanding the M4 edge HERFD XANES of U6+
Amidani, L.; Volkova, A.; Retegan, M.; Popa, K.; Martin, P.; Kvashnina, K.
Abstract
Hexavalent uranium is of considerable importance in the actinide field, and its characterization, consequently, of fundamental concern. The application of High-Energy-Resolution Fluorescence-Detected X-ray Absorption Near-Edge Structure (HERFD XANES) spectroscopy at the M4 edge of actinides probes the 5f electronic structure with augmented resolution compared to conventional XANES and is gaining great popularity. If, from one side, the extreme sensitivity of M4 HERFD XANES to actinides’ oxidation state is well-established [1], its sensitivity to the local environment has been less extensively explored [2,3]. The partially filled 5f subshell makes intra-atomic electron interactions the primary force shaping the spectrum, and simulations treating multi-electronic effects can only approximately account for the local environment.
In these regards, U6+, with its empty 5f shell, is a fortunate exceptional case. Simulation approaches based on the one-electron approximation can then be applied, and the dependence on the local environment be carefully investigated. We recently reported a detailed investigation where experimental and simulated M4 HERFD XANES are obtained on a set of U6+ compounds with different local environments [4]. The coordination of U6+ represented by the set of samples comprises an almost perfect UO6 octahedral bipyramid (Sr3UO6), two UO6 featuring the uranyl ion (Cs2UO2Cl4 and SrUO4), and a UO8 distorted hexagonal bipyramid (CaUO4).
Experimental M4 HERFD are shown in Figure 1. The spectral shape has a similar structure, made of three or four peaks of decreasing intensity. At the same time, it presents significant differences indicating the substantial impact on the spectral shape of the local environment. We simulated the set of U6+ compounds with the DFT-based code FDMNES [5]. The good agreement between theory and experiment, see Fig. 1, makes it reasonable to have a closer look at the underlying f-density of states and to assign spectral features to specific f-orbitals.
Simulations allow to rationalize how the local coordination of U6+ affects the M4 HERFD XANES and demonstrate its high sensitivity to the local environment. Simulations based on crystal field theory were also performed. Their comparison to FDMNES results will be discussed.
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Lecture (Conference)
JdA 51 - Journées des Actinides, 10.-14.04.2022, Santa Margherita, Italia
Permalink: https://www.hzdr.de/publications/Publ-34288
State-resolved ultrafast charge and spin dynamics in [Co/Pd] multilayers
Le Guyader, L.; Higley, D. J.; Pancaldi, M.; Liu, T.; Chen, Z.; Chase, T.; Granitzka, P. W.; Coslovich, G.; Lutman, A. A.; Dakovski, G. L.; Schlotter, W. F.; Shafer, P.; Arenholz, E.; Hellwig, O.; Lalieu, M. L. M.; Koopmans, B.; Reid, A. H.; Bonetti, S.; Stöhr, J.; Dürr, H. A.
Abstract
We use transient absorption spectroscopy with circularly polarized x-rays to detect laser-
excited hole states below the Fermi level and compare their dynamics with that of unoc-
cupied states above the Fermi level in ferromagnetic [Co/Pd] multilayers. While below
the Fermi level an instantaneous and significantly stronger demagnetization is observed,
above the Fermi level the demagnetization is delayed by 35 ± 10 fs. This provides a direct
visualization of how ultrafast demagnetization proceeds via initial spin-flip scattering of
laser-excited holes to the subsequent formation of spin waves
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Applied Physics Letters 120(2022), 032401
DOI: 10.1063/5.0076953
Cited 8 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34287
Multisite Dopamine Sensing with Femtomolar Resolution Using a CMOS Enabled Aptasensor Chip
Baraban, L.; Seichepine, F.; Sessi, V.; Ibarlucea, B.; Klinghammer, S.; Ibrahim, I.; Heinzig, A.; Szabo, N.; Mikolajick, T.; Reinhold Hierlemann, A.; Frey, U.; Weber, W.; Cuniberti, G.
Abstract
Many biomarkers including neurotransmitters are found in external body fluids, such as sweat or saliva, but at lower titration levels than they are present in blood. Efficient detection of such biomarkers thus requires, on the one hand, to use techniques offering high sensitivity, and, on the other hand, to use a miniaturized format to carry out diagnostics in a minimally invasive way. Here, we present the hybrid integration of bottom-up silicon-nanowire Schottky-junction FETs (SiNW SJ-FETs) with complementary-metal–oxide–semiconductor (CMOS) readout and amplification electronics to establish a robust biosensing platform with 32 x 32 aptasensor measurement sites at a 100 µm pitch. The applied hetero-junctions yield a selective biomolecular detection down to femtomolar concentrations. Selective and multi-site detection of dopamine is demonstrated at an outstanding sensitivity of ~ 1 V/fM. The integrated platform offers great potential for detecting biomarkers at high dilution levels and could be applied, for example, to diagnosing neurodegenerative diseases or monitoring therapy progress based on patient samples, such as tear liquid, saliva, or eccrine sweat.
Related publications
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Data publication: Multisite Dopamine Sensing with Femtomolar Resolution Using …
ROBIS: 34290 HZDR-primary research data are used by this (Id 34286) publication
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Frontiers in Neuroscience 16(2022), 875656
DOI: 10.3389/fnins.2022.875656
Cited 6 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34286
Design and production of tungsten-carbide rich coating layers
Racz, A. S.; Fogarassy, Z.; Kentsch, U.; Panjan, P.; Menyhard, M.
Abstract
Ion beam induced mixing (IBM) can be used for making protecting coating layers at room temperature. We have studied the production of tungsten-carbide, having high strength and low friction, by IBM since this material is also a candidate for protective coatings. WC rich layers have been produced by irradiating C/W multilayer of various structures (with individual layer thicknesses from 10 to 20 nm) by noble gases using medium energy projectiles. The resulting alterations of the samples have been measured by Auger electron spectroscopy (AES) depth-profiling. TRIDYN simulations, with some parametrization, were applied to determine the elemental in-depth distribution after IBM; the compound formation was calculated by a simple model. The calculated and measured depth profiles were compared and excellent agreement has been found for a rich dataset differing in layer structures, projectiles, ion fluences and energies. The good agreement in a wide parameter range validates our procedure and allows the design of the WC-rich layers and also enables the significant decrease of the experimental work.
Keywords: Tungsten-carbide; WC; Coating; Simulation; Ion irradiation; TRIDYN
Involved research facilities
- Ion Beam Center DOI: 10.17815/jlsrf-3-159
Related publications
- DOI: 10.17815/jlsrf-3-159 is cited by this (Id 34285) publication
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Applied Surface Science 586(2022), 152818
DOI: 10.1016/j.apsusc.2022.152818
Cited 3 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34285
A perfect match between borophene and aluminium in the AlB3heterostructure with covalent Al-B bonds, multiple Dirac points and a high Fermi velocity
Jiao, Y.; Ma, F.; Zhang, X.; Heine, T.
Abstract
By performing a swarm-intelligent global structure search combined with first-principles calculations, a stable twodimensional (2D) AlB3 heterostructure with directed, covalent Al-B bonds forms due to a nearly perfect lattice match between 2D borophene and the Al(111) surface. The AlB3 heterosheet with the P6mm space group is composed of a planar Al(111) layer and a corrugated borophene layer, where the in-plane coordinates of Al covalently link with the corrugated B atoms. The resulting structure shows a similar interlayer interaction energy to that of the Al(111) surface layer to the bulk and high mechanical and thermal stability, possesses multiple Dirac points in the Brillouin zone with a remarkably high Fermi velocity of 1.09 × 106 m s-1, which is comparable to that of graphene. Detailed analysis of the electronic structure employing the electron localisation function and topological analysis of the electron density confirm the covalent Al-B bond with high electron localisation between the Al and B centres and with only little interatomic charge transfer. The combination of
borophene with metal monolayers in 2D heterostructures opens the door to a rich chemistry with potentially unprecedented properties.
Keywords: Calculations; Charge transfer; Electronic structure; Graphene; Topology; Dirac point
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Chemical Science 13(2022), 1016
DOI: 10.1039/d1sc05207a
Cited 6 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34284
Quantifying the Dzyaloshinkii-Moriya Interaction Induced by the Bulk Magnetic Asymmetry
Zhang, Q.; Liang, J.; Bi, K.; Zhao, L.; Bai, H.; Cui, Q.; Zhou, H.-A.; Bai, H.; Feng, H.; Song, W.; Chai, G.; Gladii, O.; Schultheiß, H.; Zhu, T.; Zhang, J.; Peng, Y.; Yang, H.; Jiang, W.
Abstract
A broken interfacial inversion symmetry in ultrathin ferromagnet/heavy metal (FM/HM) bilayers is generally believed to be a prerequisite for accommodating Dzyaloshinskii-Moriya interaction (DMI) and for stabilizing chiral spin textures. By contrast, we present an approach for engineering both the sign and amplitude of DMI in relatively thick films without involving interfacial asymmetry, which is achieved through incorporating the composition gradient-induced bulk magnetic asymmetry (BMA) combined with strong spin-orbit coupling (SOC). The pivotal roles of BMA and SOC are theoretically examined based on the three-site Fert-Lévy model and the first principles calculations. Experimentally, both the sign and amplitude of DMI in films with controllable composition gradients along the growth direction, in the presence/absence of SOC are studied by using a Brillouin light scattering spectroscopy. Our results suggest that the appreciable value of DMI (±0.15 mJ/m2) could be established through combining BMA and SOC into relatively thick films. It is expected that our findings may help to further understand chiral magnetism and to design novel non-collinear spin textures.
Keywords: Dzyaloshinskii-Moriya interaction; Brillouin light scattering; spin-wave non-reciprocity; bulk magnetic asymmetry; spin-orbit coupling
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Physical Review Letters 128(2022), 167202
DOI: 10.1103/PhysRevLett.128.167202
Cited 30 times in Scopus
Downloads
Permalink: https://www.hzdr.de/publications/Publ-34283
Electron-ion temperature relaxation in warm dense hydrogen observed with picosecond resolved X-ray scattering
Fletcher, L. B.; Vorberger, J.; Schumaker, W.; Ruyer, C.; Goede, S.; Galtier, E.; Zastrau, U.; Alves, E. P.; Baalrud, S. D.; Baggott, R. A.; Barbrel, B.; Chen, Z.; Döppner, T.; Gauthier, M.; Granados, E.; Kim, J. B.; Kraus, D.; Lee, H. J.; Macdonald, M. J.; Mishra, R.; Pelka, A.; Ravasio, A.; Roedel, C.; Fry, A. R.; Redmer, R.; Fiuza, F.; Gericke, D. O.; Glenzer, S. H.
Abstract
Angularly resolved X-ray scattering measurements from fs-laser heated hydrogen have been
used to determine the equilibration of electron and ion temperatures in the warm dense matter
regime. The relaxation of rapidly heated cryogenic hydrogen is visualized using 5.5 keV X-ray
pulses from the Linac Coherent Light (LCLS) source in a 1 Hz repetition rate pump-probe setting.
We demonstrate that the electron-ion energy transfer is faster than quasi-classical Landau-Spitzer
models that use ad hoc cutoffs in the Coulomb logarithm.
Keywords: warm dense matter; x-ray scattering; relaxation; femtosecond; hydrogen jet
Related publications
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Data publication: Electron-ion temperature relaxation in warm dense hydrogen …
ROBIS: 35947 HZDR-primary research data are used by this (Id 34282) publication
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Frontiers in Physics 10(2022), 838524
DOI: 10.3389/fphy.2022.838524
Cited 10 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34282
Quantitative assessment of radionuclide production yields in in-beam1 and offline PET measurements at different proton irradiation facilities
Bauer, J.; Hildebrandt, M.; Baumgartl, M.; Fiedler, F.; Robert, C.; Buvat, I.; Enghardt, W.; Parodi, K.
Abstract
Objective: Reliable radionuclide production-yield data are a prerequisite for positron-emission-1
tomography (PET) based in-vivo proton treatment verification. In this context, activation data acquired2
at two different treatment facilities with different imaging systems were analyzed to provide3
experimentally determined radionuclide yields in thick targets and were compared with each other to4
investigate the impact of the respective imaging technique.5
Approach: Homogeneous thick targets (PMMA, gelatine, and graphite) were irradiated with mono-6
energetic proton pencil-beams at two distinct energies. Material activation was measured (i) in-beam7
during and after beam delivery with a double-head prototype PET camera and (ii) offline shortly after8
beam delivery with a commercial full-ring PET/CT scanner. Integral as well as depth-resolved +-9
emitter yields were determined for the dominant positron-emitting radionuclides 11C, 15O, 13N and (in-10
beam only) 10C. In-beam data were used to investigate the qualitative impact of different monitoring11
time schemes on activity depth profiles and their quantitative impact on count rates and total activity.12
Main results: Production yields measured with the in-beam camera were comparable to or higher13
compared to respective offline results. Depth profiles of radionuclide-specific yields obtained from the14
double-head camera showed qualitative differences to data acquired with the full-ring camera with a15
more convex profile shape. Considerable impact of the imaging timing scheme on the activity profile16
was observed for gelatine only with a range variation of up to 3.5 mm. Evaluation of the coincidence17
rate and the total number of observed events in the considered workflows confirmed a strongly18
decreasing rate in targets with a large oxygen fraction.19
Significance: The observed quantitative and qualitative differences between the datasets underline20
the importance of a thorough system commissioning. Due to the lack of reliable cross-section data, in-21
house phantom measurements are still considered a gold standard for careful characterization of the22
system response and to ensure a reliable beam range verification
Keywords: offline PET; positron emitter production yield; in-beam PET; particle therapy; in-vivo range verification
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Physics in Medicine and Biology 67(2022)15, 155001
DOI: 10.1088/1361-6560/ac7a89
Permalink: https://www.hzdr.de/publications/Publ-34281
Scale dependent anisotropy & intermittency in bubble laden turbulent flows
Ma, T.; Hessenkemper, H.; Lucas, D.; Ott, B.; Fröhlich, J.; Bragg, A.
Abstract
-- Anisotropy
DNS data of disperse bubbly flows in a vertical channel are used to study scale-dependent anisotropy for flows dominated by bubble-induced turbulence. We developed a new method, based on an extension of the barycentric map approach, that allows to quantify and visualize the anisotropy and componentiality of the flow at any scale. Using this we found that the bubbles significantly enhance anisotropy in the flow at all scales compared with the unladen case, and that for some bubble cases, very strong anisotropy persists down to the smallest scales of the flow. The strongest anisotropy observed was for the cases involving small bubbles.
-- intermittency
We experimentally explore the properties of bubble-laden turbulent flow at different scales, considering how the bubbles effect the extreme events of the flow. To this end, high-resolution Particle Shadow Velocimetry measurements are carried out in a bubble column in which the flow generated by a homogeneous distributed bubble swarm rising in water for two different bubble diameters (2.7 mm & 3.9 mm) and moderate gas volume fractions (0.26% - 1.31%). We considered the intermittency quantified by the normalized probability density functions of the longitudinal velocity increments. The results reveal that extreme values in the velocity increments become more probable with decreasing Reynolds number, the opposite of the behavior in single-phase turbulence. We visualize those extreme events and find that regions of intense small-scale velocity increments occur near the turbulent/non-turbulent interface at the boundary of the bubble wake.
Keywords: Bubbly flow; Turbulence
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Invited lecture (Conferences)
Special Seminar at Johns Hopkins University Center for Environmental & Applied Fluid Mechanics, 23.02.2022, Baltimore, USA
Permalink: https://www.hzdr.de/publications/Publ-34280
Experimental activation determination in and on components of nuclear power plants and comparison with activity calculations
Barkleit, A.; Rachamin, R.; Yassin, G.; Pönitz, E.; Konheiser, J.
Abstract
Due to the “German Energiewende”, all nuclear power plants (NPPs) in Germany will have been shut down by the end of 2022. Consequently, a safe, economical, and efficient dismantling of the NPPs will be an important challenge for the next decades. This includes to progress with methods for optimal planning and implementation of decommissioning.
Several studies have been conducted to develop a standardized method for evaluating the specific and temporal progression of the activation in the reactor components, near-reactor concrete, and construction elements based on the reactor's power history. This will serve as an early non-destructive tool for the radiological characterization of the NPP's components. Such essential knowledge can significantly minimize the radioactive waste and the radiation exposure of the operating personnel during the NPP's decommissioning.
The studies considered two strategies. In the first one, the radionuclide inventory in the material of an NPP already under dismantling was investigated. Among others, Co-60 and C-14 in steel samples from the reactor pressure vessel and Eu-152 and Ba-133 in concrete drill cores from biological shielding were determined. In the second strategy, the neutron flux in NPPs still under operation was determined with activation monitors (small metal foils, e.g., In, Sn, Zn). The experimental data from both strategies were compared with results from Monte-Carlo simulations.
This work is funded by the German Federal Ministry of Education and Research (BMBF) under grant numbers 15S9412 (WERREBA) and 15S9409A (EMPRADO) and is carried out in cooperation with PreussenElektra GmbH and EWN Greifswald GmbH.
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Contribution to proceedings
19th Radiochemical Conference RadChem, 15.-20.05.2022, Marianske Lazne, Czech Republic -
Lecture (Conference)
19th Radiochemical Conference RadChem, 15.-20.05.2022, Marianske Lazne, Czech Republic
Permalink: https://www.hzdr.de/publications/Publ-34279
Speciation and transfer of radionuclides in the human organism especially taking into account decorporation agents (RADEKOR) – a joint project
Barkleit, A.; Heller, A.; Walther, C.; Walther, D.; Raskob, W.
Abstract
In case radionuclides (RN) enter the food chain and are incorporated by humans, they pose a possible health risk due to their radio- and chemotoxicity. To precisely assess the health risk after oral incorporation of RN with food and beverages and to apply effective decontamination methods, it is mandatory to understand the processes of RN biokinetics on both cellular and molecular scale. Within the joint research project “Speciation and transfer of radionuclides in the human organism especially taking into account decorporation agents (RADEKOR)”, quantitative excretion analysis and biokinetic modeling of orally incorporated RN are performed. Additionally, these macroscopic investigations are combined with molecular speciation studies of RN in artificial fluids of the alimentary tract of humans and cytotoxicity studies with respective human and rat cell lines both in the absence and presence of decorporation agents. Aim of the project is to expand the knowledge of processes underlying RN interactions within the human alimentary tract on a cellular and molecular scale to establish a precise biokinetic model as well as to contribute to the development and improvement of nuclide specific decontamination methods.
This joint project is funded by the German Federal Ministry of Education and Research (grant number 02NUK057). The funding period is from July 2020 to December 2023 and cooperation partners are: Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Technische Universität Dresden (TUD), Leibniz-Universität Hannover (LUH), VKTA - Radiation Protection, Analytics & Disposal (VKTA), and Karlsruhe Institute of Technology (KIT).
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Contribution to proceedings
19th Radiochemical Conference RadChem, 15.-20.05.2022, Marianske Lazne, Czech Republic -
Poster
19th Radiochemical Conference RadChem, 15.-20.05.2022, Marianske Lazne, Czech Republic
Permalink: https://www.hzdr.de/publications/Publ-34278
Strained Ammonium Precursors for Radiofluorinations
Abstract
The increasing application of positron emission tomography (PET) in nuclear medicine has stimulated the extensive development of a multitude of novel and versatile techniques to introduce fluorine-18 especially for the radiolabelling of biologically or pharmacology active molecules. Taking into consideration that the introduction of fluorine-18 (t1/2 = 109.8 min) mostly proceeds under harsh conditions, radiolabelling of such molecules represents a challenge and is of enormous interest. Ideally, it should proceed in a regioselective manner under mild physiological conditions, in an acceptable time span, with high yields and high specific activities. Special attention has been drawn to 2-fluoroethyl and 3-fluoropropyl groups, respectively, which are often the active site of radiofluorinated compounds. Precursors containing an ammonium leaving group which consists of a strained azetidinium or aziridinium moiety can help to overcome these obstacles leading to a mild introduction of [18F]fluoride with high radiochemical yields.
Keywords: strained rings; ring opening; aziridines; azetidinium; fluorination
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ChemistryOpen 11(2022), e202200039
DOI: 10.1002/open.202200039
Cited 2 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34277
CeO2-azacrown conjugate as a nanoplatform for combined radiopharmaceuticals
Khabirova, S. Y.; Aleshin, G. Y.; Plakhova, T. V.; Zubenko, A. D.; Shchukina, A. A.; Fedorova, O. A.; Averin, A. A.; Belova, E. V.; Bazarkina, E. F.; Kvashnina, K. O.; Kalmykov, S. N.
Abstract
This communication is one of the first attempts to assess CeO2 nanoparticles as a nanoplatform for radiopharmaceuticals with radionuclides. The process of functionalization using a bifunctional azacrown ligand is described, and the resulting conjugates are characterized by IR and Raman spectroscopy. Their complexes with 207Bi show a high stability in medically relevant media, thus encouraging the further study of these conjugates in vivo as potential combined radiopharmaceuticals
Involved research facilities
- Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265
Related publications
- DOI: 10.1107/S1600577520014265 is cited by this (Id 34276) publication
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Nanomaterials 12(2022), 4484
DOI: 10.3390/nano12244484
Cited 5 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34276
Data publication: Effects of gravity modulation on the dynamics of a radial A + B → C reaction front
Stergiou, Y.; Hauser, M. J. B.; Comolli, A.; Brau, F.; de Wit, A.; Schuszter, G.; Papp, P.; Horvath, D.; Roux, C.; Pimienta, V.; Eckert, K.; Schwarzenberger, K.
Abstract
Raw image data of the reaction-diffusion-advection front experiments in radial Hele-Shaw cells. Including experiments in ground 1-g conditions and parabolic flight experiments.
Keywords: Reaction-diffusion-advection; reaction front; microgravity; convection; radial Hele-Shaw; parabolic flight
Related publications
- DOI: 10.1016/j.ces.2022.117703 references this (Id 34275) publication
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Effects of gravity modulation on the dynamics of a radial A + B → C reaction …
ROBIS: 34260 has used this (Id 34275) publication of HZDR-primary research data -
Chemical flowers: Buoyancy-driven instabilities under modulated gravity during …
ROBIS: 34848 has used this (Id 34275) publication of HZDR-primary research data
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Reseach data in the HZDR data repository RODARE
Publication date: 2022-03-28 Closed access
DOI: 10.14278/rodare.1502
Versions: 10.14278/rodare.1503
Downloads
Permalink: https://www.hzdr.de/publications/Publ-34275
Cr2+ solid solution in UO2 evidenced by advanced spectroscopy
Smith, H.; Townsend, L. T.; Mohun, R.; Cordara, T.; Stennett, M.; Mosselmans, F.; Kvashnina, K.; Hyatt, N.; Corkhill, C.
Abstract
Advanced Cr-doped UO2 fuels are essential for driving safe and efficient generation of nuclear energy. Although widely deployed, little is known about their fundamental chemistry, which is a critical gap for development of new fuel materials and radioactive waste management strategies. Utilising an original approach, we directly evidence the chemistry of Cr(3+)2O3–doped U(4+)O2. Advanced high-flux, high-spectral purity X-ray absorption spectroscopy (XAS), corroborated by diffraction, Raman spectroscopy and high energy resolved fluorescence detection-XAS, is used to establish that Cr2+ directly substitutes for U4+, accompanied by U5+ and oxygen vacancy charge compensation. Extension of the analysis to heat-treated simulant nuclear fuel reveals a mixed Cr2+/3+ oxidation state, with Cr in more than one physical form, explaining the substantial discrepancies that exist in the literature. Successful demonstration of this analytical advance, and the scientific underpinning it provides, opens opportunities for an expansion in the range of dopants utilised in advanced UO2 fuels.
Involved research facilities
- Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265
Related publications
- DOI: 10.1107/S1600577520014265 is cited by this (Id 34274) publication
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Communications Chemistry 5(2022), 163
DOI: 10.1038/s42004-022-00784-3
Cited 6 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34274
High surface area “3D Graphene Oxide” for enhanced sorption of radionuclides
Boulanger, N.; Kuzenkova, A. S.; Iakunkov, A.; Nordenström, A.; Romanchuk, A. Y.; Trigub, A. L.; Zasimov, P. V.; Podana, M.; Enachescu, M.; Bauters, S.; Amidani, L.; Kvashnina, K. O.; Kalmykov, S. N.; Talyzin, A. V.
Abstract
Earlier studies demonstrated that graphene oxide (GO)
with large number of defects is favorable for the sorption of
radionuclides. Here we report oxidation treatment which converts high
surface area activated reduced graphene oxide (arGO) into a 3D
analogue of defect-rich GO (dGO). Oxidation of arGO using
ammonium persulfate results in oxidation corresponding to carbon to
oxygen ratio C/O=3.3, similar to the oxidation state of graphene oxide
while preserving high BET surface area of about 880 m2/g. Analysis
of surface oxidized arGO shows high abundance of oxygen functional
groups very similar to dGO and hydrophilic properties. The “3D
graphene oxide” showed high sorption capacity for U(VI) removal in
an extraordinary broad interval of pH. Notably, the surface oxidized
carbon material has a rigid 3D structure with micropores accessible
for penetration of radionuclide ions. Therefore, the bulk “3D GO” can
be used as a sorbent directly without dispersing, the step required for
GO to make its surface area accessible for pollutants
Involved research facilities
- Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265
Related publications
- DOI: 10.1107/S1600577520014265 is cited by this (Id 34273) publication
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Advanced Materials Interfaces 9(2022)18, 2200510
DOI: 10.1002/admi.202200510
Cited 8 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34273
Data publication: MOFs with 12-coordinate 5f-block metal centers
Lv, K.; Urbank, C.; Patzschke, M.; März, J.; Kaden, P.; Weiß, S.; Schmidt, M.
Abstract
Autoluminescence CO2 BET Elemental analysis Leaching test results Powder XRD TGA-DSC UV/vis
Keywords: Actinides; Metal-Organic Frameworks; Autoluminescence; Semiconductor
Related publications
- DOI: 10.1021/jacs.1c13127 references this (Id 34272) publication
-
MOFs with 12-coordinate 5f-block metal centers
ROBIS: 34224 has used this (Id 34272) publication of HZDR-primary research data
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Reseach data in the HZDR data repository RODARE
Publication date: 2022-02-17 Open access
DOI: 10.14278/rodare.1439
Versions: 10.14278/rodare.1440
License: CC-BY-4.0
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Permalink: https://www.hzdr.de/publications/Publ-34272
A study on the wettability of metal oxides as cathode active materials to improve lithium-ion battery recycling
Sandbrink, J.; Vanderbruggen, A.; Rudolph, M.
Abstract
One of the main tasks for today’s researchers in order to ensure the supply of critical raw materials is the efficient recovery and recycling of secondary resources. Lithium-ion batteries (LIB) are the key technology to electrify transport, which is one of the multiple measures proposed to prevent global warming. Therefore, the recycling of spent LIBs is of great interest and unvoidable. A major challenge in spent LIBs recycling, is the beneficiation of fine powder resulting from the battery crushing, so-called “black mass”, which contains the valuable lithium metal oxides (from the cathode) and the critical graphite (from the anode). One promising way to separate the graphitic material from the lithium metal oxides is through froth flotation, which separates the particles according to their differences in wettability.
In order to improve the separation process, one must first have a proper understanding of the particle properties. In particular, the lithium metal oxides are rather declared as hydrophilic and should therefore be easily separated from the hydrophobic graphite. Nevertheless, many studies report on their recovery into the froth product, along with the graphite, thus lowering its grade, which is most probably due to the residual hydrophobic binder that causes a change in their wettability.
In this study, different battery materials, including fresh lithium metal oxides and graphite, as well as real spent materials from LIBs were used. The particles were analysed for their wettability and wetting ability using optical contour analysis, inverse gas chromatography, particle attachment to bubbles, analytical particle solvent extraction as well as the Washburn method. These results are set into context with flotation tests and shed light on the particle wettability and its effect on the flotation separation efficiency, as well as the difficulties that arise when it comes to the recycling of spent LIBs.
Keywords: Flotation; lithium-ion batteries; wettability; recycling
-
Lecture (Conference)
(Online presentation)
Jahrestreffen der ProcessNet-Fachgruppen Grenzflächenbestimmte Systeme und Prozesse, Partikelmesstechnik sowie Aerosoltechnik, 16.-17.02.2022, Online, Online
Permalink: https://www.hzdr.de/publications/Publ-34271
Sustainable Bioengineering of Gold Structured Wide-Area Supported Catalysts for Hand-Recyclable Ultra-Efficient Heterogeneous Catalysis
Bhatt, C. S.; Parimi, D. S.; Bollu, T. K.; Madhura, H. U.; Jacob, N.; Korivi, R.; Ponugoti, S. S.; Mannathan, S.; Ojha, S.; Klingner, N.; Motapothula, M.; Suresh, A. K.
Abstract
Metal nanoparticles grafted within inert and porous wide-area supports are emerging as recyclable, sustainable catalysts for modern industry applications. Here, we develop gold nanoparticle-anchored supported catalysts by utilizing the natural metal binding and reductive potential of natural eggshell. Variable hand-recyclable wide-area catalysts between ~(80±7) and (0.5±0.1) cm2 are generated by varying the support dimensions. The catalyst possesses high-porosity (17.1 Å) and stability against high-temperatures (300°C), polar and non-polar solvents, electrolytes, acids and bases, facilitating compatible ultra-efficient catalysis. As validated by large-volume (2.8 liters) sewage-dye detoxification, gram-scale hydrogenation of nitroarenes and synthesis of propargylamine. Moreover, persistent-recyclability, monitoring of reaction kinetics and product intermediates are possible due to retrievability and interchangeability of the catalyst. Finally, the bio-nature of support permits ~76.9% recovery of noble gold simply by immersing in royal solution. Our naturally-created, low-cost, scalable, hand-recyclable and resilient supported mega-catalyst dwarfs most challenges for large-scale metal-based heterogeneous catalysis.
Keywords: supported-catalyst; sustainable; hand-recyclable; gram-scale; large-volume; dye-detoxification; sewa
Involved research facilities
- Ion Beam Center DOI: 10.17815/jlsrf-3-159
Related publications
- DOI: 10.17815/jlsrf-3-159 is cited by this (Id 34270) publication
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ACS Applied Materials and Interfaces 14(2022)46, 51579-52578
DOI: 10.1021/acsami.2c13564
Cited 4 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34270
Perspective paper about the joint EANM/SNMMI/ESTRO practice recommendations for the use of 2-[18F]FDG-PET/CT external beam radiation treatment planning in lung cancer
Vaz, S.; Adam, J.; Bolton Delgado, R.; Vera, P.; van Elmpt, W.; Herrmann, K.; Hicks, R.; Lievens, Y.; Santos, A.; Schöder, H.; Dubray, B.; Visvikis, D.; Troost, E. G. C.; de Geus-Oei, L.
Abstract
In ‘‘Joint EANM/SNMMI/ESTRO Practice Recommendations for the Use of 2-[18F]FDG-PET/CT External Beam Radiation Treatment Planning in Lung Cancer V1.0” clinical indications for PET-CT in (non-)small cell lung cancer are highlighted and selective nodal irradiation is discussed. Additionally, concepts about target definition, target delineation and treatment evaluation are reviewed.
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Radiotherapy and Oncology 168(2022), 37-39
DOI: 10.1016/j.radonc.2021.12.048
Cited 4 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34269
Spinning Particles in Quantum Mechanics and Quantum Field Theory
Corradini, O.; Schubert, C.; Edwards, J. P.; Ahmadiniaz, N.
Abstract
These are notes of lectures on spinning particles and the worldline formalism originally given by Olindo Corradini and Christian Schubert at the School on spinning Particles in Quantum Field Theory: Worldline Formalism, HigherSpins, and Conformal Geometry, held at Morelia, Mexico, from November 19 through November 23, 2012. The lectures were addressed to graduate-level students with a background in relativistic quantum mechanics and at least a rudimentary knowledge of field theory. They have since been up-dated to include a further set of lecture notes on tree level processes from a worldline perspective based on a mini-course by James P. Edwards at the Instituto de Fisica y Matematicas in Morelia, Mexico given to graduatesand visiting professors during July 2017 and in various later classes, com-plemented by a series of three lectures titled New techniques for amplitude calculation in QED given by Naser Ahmadiniaz at the Center for Relativistic Laser Science (CoReLS), Institute for Basic Science (IBS), November 2015, Gwangju, South Korea and as an invited lecturer at the Helmholtz International Summer School (HISS) - Dubna International Advanced School of Theoretical Physics (DIAS-TH): “Quantum Field Theory at the Limits: from strong Fields to Heavy Quarks”, July-August 2019, Dubna, Russia. These additional notes complete the picture of first quantised techniques and bring the worldline description up to date.
Keywords: Worldline formalism; loop-level processes; Tree-level processes
-
Invited lecture (Conferences)
Quantum Field Theory at the Limits: from Strong Fields to Heavy Quarks, 22.07.-02.08.2019, Dubna, Russia
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Permalink: https://www.hzdr.de/publications/Publ-34268
Breakup with benefits - hydrothermal mineral systems related to the disintegration of a supercontinent
Burisch, M.; Markl, G.; Gutzmer, J.
Abstract
Mesozoic hydrothermal systems host the majority of Europe's fluorspar and barite resources as well as significant amounts
of metals such as Ag, Co, Zn, Pb, Ni and Cu. Their genetic link to extensional tectonics in conjunction with the opening of
the North Atlantic has long been suspected, but their spatial and temporal relation to the tectonic evolution of Europe has
remained enigmatic. A thorough evaluation of available geochronological data for fluorite-barite-Pb-Zn, native-metalarsenide-
carbonate and MVT-type mineralization in Continental Europe and North Africa reveals a distinct, as yet
unrecognized, time-space relationship between the distribution of hydrothermal mineral systems and the tectonic evolution
of the Tethys-Atlantic-Caribbean rift system. The observed time-space relationship and ore-forming mechanisms are
evaluated to constrain the underlying driving force for hydrothermal mineralization in the context of the geodynamic evolution
of the European lithosphere. Based on this assessment we propose the first continental-scale model for the genesis of
Mesozoic hydrothermal ore deposits associated to the breakup of the supercontinent Pangea.
Keywords: continental rifting; critical raw materials; hydrothermal ore deposits; North Atlantic; Pangea supercontinent
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Earth and Planetary Science Letters 580(2022), 117373
DOI: 10.1016/j.epsl.2022.117373
Cited 25 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34267
Linking Diffraction Techniques with XRF and XAS Spectroscopy at the German CRG Beamline ROBL / ESRF
Hennig, C.; Svitlyk, V.
Abstract
The recent upgrade of the Rossendorf Beamline at ESRF allows simultaneous collection of diffraction and spectroscopy (XRF and XANES). A 6-circle Huber diffractometer (XRD-1) with Eulerian cradle geometry is used for high-resolution powder diffraction and surface diffraction. The powder diffraction module uses an Eiger CdTe 500k detector, the surface diffraction module is equipped with a Pilatus Si 100k detector. PXRD data suitable for Rietveld refinement can be collected between 10 and 31 keV in an 2θ angular range of 0-65°. The Bragg reflexes in PXRD are extracted by radial integration using a modified pyFAI code. Diffraction measurements can be combined with XRF and XAS spectroscopy using a single-element Si drift detector (Vortex X90 CUBE, 1mm SDD, 25 mm Be window) with a FalconX1 processor.
The second diffractometer (XRD-2) consists of a heavy optical bench with an exchangeable goniometer and a Pilatus3 X 2M detector. It is used for single crystal diffraction and in situ or operando powder diffraction. Devices for non-ambient sample conditions are a hot-air blower (RT-1100K), a heating chamber (RT-1470K), and a LN2 cryostream (90-400K). This diffractometer is controlled with the Pylatus software. The single crystal data extraction is performed with CrysAlisPro. The Si drift detector can be placed in different positions to combine diffraction with XRF and XAS measurements.
Keywords: single-crystal diffraction ScXRD; high resolution powder diffraction HR-PXRD; in situ and perando applications
Involved research facilities
- Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265
Related publications
- DOI: 10.1107/S1600577520014265 is cited by this (Id 34265) publication
-
Lecture (Conference)
(Online presentation)
30th Annual Meeting of the German Crystallographic Society, 14.-17.03.2022, Munich, Germany
Permalink: https://www.hzdr.de/publications/Publ-34265
“X-ray diffraction spectroscopy” – Refinement of dispersion correction parameters for XRD measurements of Mo(CO)6 at the Mo K-edge
Meurer, F.; Dolomanov, O. V.; Hennig, C.; Peyerimhoff, N.; Kleemiss, F.; Puschmann, H.; Bodensteiner, M.
Abstract
Correcting for anomalous dispersion is part of any refinement of an X-ray
diffraction crystal structure determination. The procedure takes the inelastic
scattering in the diffraction experiment into account. This X-ray absorption effect
is specific to each chemical compound and is particularly sensitive to radiation
energies in the region of the absorption edges of the elements in the compound.
Therefore, the widely used tabulated values for these corrections can only be
approximations as they are based on calculations for isolated atoms. Features of
the unique spatial and electronic environment that are directly related to the
anomalous dispersion are ignored, although these can be observed spectroscopically.
This significantly affects the fit between the crystallographic model and
the measured intensities when the excitation wavelength in an X-ray diffraction
experiment is close to an element’s absorption edge. Herein, we report on
synchrotron multi-wavelength single-crystal X-ray diffraction, as well as X-ray
absorption spectroscopy experiments which we performed on the molecular
compound Mo(CO)6 at energies around the molybdenum K edge. The dispersive
(f 0) and absorptive (f 00) terms of the anomalous dispersion can be refined as
independent parameters in the full-matrix least-squares refinement. This procedure
has been implemented as a new feature in the well-established OLEX2 software
suite. These refined parameters are in good agreement with the independently
recorded X-ray absorption spectrum. The resulting crystallographic models show
significant improvement compared to those employing tabulated values.
Keywords: X-ray diffraction; anomalous dispersion; crystal structure determination
Involved research facilities
- Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265
Related publications
- DOI: 10.1107/S1600577520014265 is cited by this (Id 34263) publication
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IUCrJ 9(2022), 604-609
DOI: 10.1107/S2052252522006844
Cited 3 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34263
Improved ⁴¹Ca AMS measurements at DREAMS
Vivo Vilches, C.; Rugel, G.; Lachner, J.; Wallner, A.; Koll, D.; Stübner, K.; Fichter, S.; Winkler, S.
Abstract
Sensitivity of ⁴¹Ca measurements at the 6 MV AMS system at HZDR, DREAMS, using calcium fluoride (CaF₂) targets, is mainly limited by 2 factors: the total efficiency of the measurements; and the fraction of ions of its isobar ⁴¹K which mimic the signal of ⁴¹Ca in the gas ionization chamber detector.
The addition of lead fluoride (PbF₂) to the target mixture has been proven to boost the production of different (MFₙ)- ions. At DREAMS, changing the previously used mixture of CaF₂+Ag (1:4 w/w) by CaF₂+Ag+PbF₂ (1:4:4 w/w), ionization efficiency is increased from ∼0.15% to ∼0.45%.
The ⁴¹K suppression by the detector can also be improved, even without changes in the instrumentation itself. With an optimized analysis of the 4-dimensional signals from the gas ionization chamber detector, the suppression factor can be increased, at least, a factor 2: from 2 × 10⁴ to 4 × 10⁴.
The reported changes improve the total efficiency of ⁴¹Ca detection as well as the suppression of the ⁴¹K isobar and lead to a ⁴¹Ca/⁴⁰Ca sensitivity of 2-3 × 10⁻¹⁵ with an overall efficiency of ∼0.03%.
Involved research facilities
- Ion Beam Center DOI: 10.17815/jlsrf-3-159
Related publications
- DOI: 10.17815/jlsrf-3-159 is cited by this (Id 34262) publication
-
Lecture (Conference)
(Online presentation)
85th Annual Conference of the DPG and DPG Spring Meeting, 14.-18.03.2022, Erlagen, Germany
Permalink: https://www.hzdr.de/publications/Publ-34262
Evaluation of [18F]LU14 and [18F]LU13 in a rat model with a local overexpression of the human cannabinoid receptor 2 in the brain with PET
Gündel, D.; Deuther-Conrad, W.; Ueberham, L.; Teodoro, R.; Bormans, G.; Toussaint, M.; Kopka, K.; Bachmann, M.; Brust, P.; Moldovan, R.-P.
Abstract
Objectives: An upregulation of cannabinoid receptors type 2 (CB2) has been reported in association with inflammation processes, traumatic brain injury, neurodegeneration and cancer.[1] The activation of CB2 leads to an anti-inflammatory action. Therefore, the non-invasive assessment of the CB2 availability with PET could improve the decision-making for CB2-directed therapies. We developed a series of fluorinated naphthyridine-2-one-carboxamides as CB2 ligands, of which [18F]LU14[2] and [18F]LU13 were radiosynthesized and biologically evaluated.
Methods: The two radioligands [18F]LU14[2] and [18F]LU13 were developed starting from appropriate precursor compounds.The fraction of radiometabolites was quantified in isolated plasma and brain samples at 30 min p.i. The CB2 binding affinities selectivities (expressed and determined from KD and Ki values of both radioligands were determined in vitro. PET studies were performed to evaluate the radioligand uptake into the brains of rats overexpressing the hCB2(D80N) in the right striatum[3].
Results: Favourable properties where achieved for [18F]LU14, which could be further improved for [18F]LU13 (AM, affinity, selectivity and metabolic stability). In rats bearing the local overexpression of the hCB2 a target-specific and reversible uptake for both radioligands was demonstrated. [18F]LU14 reached a TAC peak SUV of 3.3 ± 0.6 at 7.4 ± 2.8 min p.i., and the SUVr (target region–to–cerebellum) was stable between 6.6 and 7.0 after 30 min p.i. For [18F]LU13 a stable SUV of 3.6 ± 0.9 after 26 min p.i. was reached and a close to linearly increasing SUVr (target region–to–cerebellum) up to 8.8 ± 4.3 at 60 min p.i. was determined (slope = 0.15 SUV/min; R² =.0.8).
Conclusion: [18F]LU14 and [18F]LU13 showed an excellent ability to image the CB2 receptors in vivo. Additionally, [18F]LU14 revealed a faster washout from the non-target regions in the brain, compared to [18F]LU13.
References: [1] Stasiulewicz et al. IJMS, 2020, 21, 2778; [2] Teodoro et al. IJMS, 2021, 22, 15; [3] Attili et al. BJP, 2019, 176, 1481
Keywords: cannabinoid receptor 2; PET; brain; [18F]LU13; [18F]LU14[2]; CB2
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Lecture (Conference)
Turku PET Symposium 2022, 03.-06.06.2022, Turku, Finland
Permalink: https://www.hzdr.de/publications/Publ-34261
Effects of gravity modulation on the dynamics of a radial A + B → C reaction front
Stergiou, Y.; Hauser, M. J. B.; Comolli, A.; Brau, F.; de Wit, A.; Schuszter, G.; Papp, P.; Horvath, D.; Roux, C.; Pimienta, V.; Eckert, K.; Schwarzenberger, K.
Abstract
The dynamics of radial A + B → C reaction fronts can be affected by buoyancy-driven convection. Motivated by recent advances in reaction-diffusion-advection (RDA) systems theory, we investigated experimentally a radial A + B → C RDA system under modulated gravity, using a Hele-Shaw cell setup onboard a parabolic flight. We evaluated characteristic properties of the RDA models, such as the temporal evolution of the total amount of product C, the width and position of the reaction front and compared them with theoretical predictions. During increased gravity, we observed an increase in the total amount of product C, formed and the front width, compared to the corresponding normal-gravity experiments, caused by the stronger buoyancy-driven convection in the former case. Finally, we report on experiments performed entirely in absence of gravity, eliminating buoyancy-driven convection. Despite the short observation time, comparison with ground experiments showed the effect of buoyant convection on radial RDA fronts, enhancing mixing and increasing product generation.
Keywords: Reaction-diffusion-advection; reaction front; microgravity; convection; radial Hele-Shaw; parabolic flight
Related publications
-
Data publication: Effects of gravity modulation on the dynamics of a radial A …
ROBIS: 34275 HZDR-primary research data are used by this (Id 34260) publication
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Chemical Engineering Science 257(2022), 117703
DOI: 10.1016/j.ces.2022.117703
Cited 8 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34260
Beyond Active Colloids: From Functional Materials to Microscale Robotics
Simmchen, J.; Baraban, L.; Wang, W.
Abstract
Guest editors Juliane Simmchen, Larysa Baraban, and Wei Wang introduce the topics covered in this special collection covering the synthesis, applications, and dynamics of active colloids.
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ChemNanoMat 8(2022)2, e202100504
Online First (2021) DOI: 10.1002/cnma.202100504
Cited 5 times in Scopus
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Permalink: https://www.hzdr.de/publications/Publ-34259
Development of explanatory movies for the delineation of new organs at risk in neuro-oncology
Di Perri, D.; Hofstede, D.; Postma, A.; Zegers, C.; In’T Ven, L.; Hoebers, F.; van Elmpt, W.; Verheesen, L.; Beurskens, H.; Troost, E. G. C.; Compter, I.; Eekers, D.
Abstract
Ten new organs at risk (OARs) were recently introduced in the updated European Particle Therapy Network neurological contouring atlas. Despite the use of the illustrated atlas and descriptive text, interindividual contouring variations may persist. To further facilitate the contouring of these OARs, educational films were developed and published on www.cancerdata.org.
Keywords: atlas for neuro-oncology; brain; organs at risk; film; particle therapy; radiotherapy
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Clinical and Translational Radiation Oncology 33(2022), 112-114
DOI: 10.1016/j.ctro.2022.02.005
Cited 2 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34258
A systematic review of clinical studies on proton Relative Biological Effectiveness (RBE)
Underwood, T.; McNamara, A.; Appelt, A.; Haviland, J.; Sørensen, B.; Troost, E. G. C.
Abstract
Recently, a number of clinical studies have explored links between possible Relative Biological Effectiveness (RBE) elevations and patient toxicities and/or image changes following proton therapy. Our objective was to perform a systematic review of such studies. We applied a "Problem [RBE], Intervention [Protons], Population [Patients], Outcome [Side effect]” search strategy to the PubMed database. From our search, we retrieved studies which: (a) performed novel voxel-wise analyses of patient effects versus dose and LET (n= 13), and (b) compared image changes between proton and photon cohorts with regard to proton RBE (n=9). For each retrieved study, we extracted data regarding: primary tumour type; size of patient cohort; type of image change studied; image-registration method (deformable or rigid); LET calculation method, and statistical methodology. We compared and contrasted their methods in order to discuss the weight of clinical evidence for variable proton RBE. We concluded that clinical evidence for variable proton RBE remains statistically weak at present. Our principal recommendation is that proton centres and clinical trial teams collaborate to standardize follow-up protocols and statistical analysis methods, so that larger patient cohorts can ultimately be considered for RBE analyses.
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Radiotherapy and Oncology 175(2022), 79-92
DOI: 10.1016/j.radonc.2022.08.014
Cited 18 times in Scopus
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Permalink: https://www.hzdr.de/publications/Publ-34256
Optical study of RbV₃Sb₅: Multiple density-wave gaps and phonon anomalies
Wenzel, M.; Ortiz, B. R.; Wilson, S. D.; Dressel, M.; Tsirlin, A. A.; Uykur, E.
Abstract
Temperature-dependent reflectivity studies on the non-magnetic kagome metal RbV₃Sb₅ in a broad energy range (50 cm$^{-1}$ - 20000 cm$^{-1}$, equivalent to 6 meV - 2.5 eV) down to 10 K are reported. Below T_CDW=102 K, the optical spectra demonstrate a prominent spectral-weight transfer from low to higher energies as the fingerprint of the charge-density wave (CDW) formation with the opening of a partial gap. A detailed analysis reveals two energy scales of, respectively, ~800 cm$^{-1}$ (100 meV) and 360 cm$^{-1}$ (45 meV), the latter appearing below 50 K only. Additionally, two modes at, respectively, 160 cm$^{-1}$ (20 meV) and 430 cm$^{-1}$ (53 meV) can be traced both above and below T_CDW. They show strong anomalies already above T_CDW with a further renormalization across the transition, suggesting the importance of the electron-phonon coupling in RbV₃Sb₅ in both normal and CDW states. While the 160 cm$^{-1}$mode can be attributed to the E_1u phonon, the 430 cm$^{-1}$ mode could not be reproduced in our phonon calculations. The antiresonance nature of this mode suggests a nontrivial electron-phonon coupling in RbV₃Sb₅. A distinct localization peak observed at all temperatures signals damped electron dynamics, whereas the reduced Drude spectral weight manifests moderate deviations from the band picture in RbV₃Sb₅.
Related publications
-
(Data set) Optical study of RbV₃Sb₅: Multiple density-wave gaps and phonon …
ROBIS: 34588 is referenced by this (Id 34255) publication -
(Data set) Optical study of RbV₃Sb₅: Multiple density-wave gaps and phonon …
ROBIS: 34588 HZDR-primary research data are used by this (Id 34255) publication
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Physical Review B 105(2022), 245123
DOI: 10.1103/PhysRevB.105.245123
Cited 16 times in Scopus
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- Open Access Version from arxiv.org
- Secondary publication expected
Permalink: https://www.hzdr.de/publications/Publ-34255
Amphiphilic Anionic Oligomer-Stabilized Calcium Phosphate Nanoparticles with Prospects in siRNA Delivery via Convection-Enhanced Delivery
Mitrach, F.; Schmid, M.; Toussaint, M.; Dukic-Stefanovic, S.; Deuther-Conrad, W.; Franke, H.; Ewe, A.; Aigner, A.; Wölk, C.; Brust, P.; Hacker, M. C.; Schulz-Siegmund, M.
Abstract
Convection-enhanced delivery (CED) has been introduced as a concept in cancer treatment to generate high local concentrations of anticancer therapeutics and overcome the limited diffusional distribution, e.g., in the brain. RNA interference provides interesting therapeutic options to fight cancer cells but requires nanoparticulate (NP) carriers with a size below 100 nm as well as a low zeta potential for CED application. In this study, we investigated calcium phosphate NPs (CaP-NPs) as siRNA carriers for CED application. Since CaP-NPs tend to aggregate, we introduced a new terpolymer (o14PEGMA(1:1:2.5) NH3) for stabilization of CaP-NPs intended for delivery of siRNA to brain cancer cells. This small terpolymer provides PEG chains for steric stabilization, and a fat alcohol to improve interfacial activity, as well as maleic anhydrides that allow for both labeling and high affinity to Ca(II) in the hydrolyzed state. In a systematic approach, we varied the Ca/P ratio as well as the terpolymer concentration and successfully stabilized NPs with the desired properties. Labeling
of the terpolymer with the fluorescent dye Cy5 revealed the terpolymer’s high affinity to CaP. Importantly, we also determined a high efficiency of siRNA binding to the NPs that caused very effective survivin siRNA silencing in F98 rat brain cancer cells. Cytotoxicity investigations with a standard cell line resulted in minor and transient effects; no adverse effects were observed in organotypic brain slice cultures. However, more specific cytotoxicity investigations are required. This study provides a systematic and mechanistic analysis characterizing the effects of the first oligomer of a new class of stabilizers for siRNA-loaded CaP-NPs.
Keywords: Calcium phosphate nanoparticles; Cell transfection; Particle characterization; PEGylated terpolymer
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Pharmaceutics 14(2022)2, 326
DOI: 10.3390/pharmaceutics14020326
Cited 7 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34254
Platinum-group elements in Late Quaternary high-Mg basalts of eastern Kamchatka: Evidence for minor cryptic sulfide fractionation in primitive arc magmas
Nekrylov, N.; Kamenetsky, V. S.; Savelyev, D. P.; Gorbach, N. V.; Kontonikas-Charos, A.; Palesskii, S. V.; Shcherbakov, V. D.; Kutyrev, A. V.; Savelyeva, O. L.; Korneeva, A. A.; Kozmenko, O. A.; Zelenski, M. E.
Abstract
The geochemical variations of magmas across and along supra-subduction zones (SSZ) have been commonly attributed to profound changes in the phase and chemical compositions of the mantle source and subduction-derived melt and fluid fluxes, as well as the physical parameters (e.g. depth, temperature, oxygen fugacity etc) of slab dehydration, mineral breakdown and melting. Here we test the variability of the Late Quaternary primitive magmas in the southern and northern parts of the meridionally oriented Eastern Volcanic Belt (EVB) of Kamchatka, with a slab depth varying from 60 to 160 km. Eight high-Mg (Mg# > 60 mol%) basalts were characterized for major, trace and platinum-group element (PGE) abundances, as well as the compositions of olivine phenocrysts and olivine-hosted spinel inclusions. The basalts in our study are geochemically typical of SSZ magmas and contain similar liquidus assemblages of forsteritic olivine (Mg# 78–92 mol%), low-Ti Cr-spinel and clinopyroxene. Although the absolute abundances of major and trace elements, and their ratios, in the basalts fluctuate to some extent, the observed variability cannot be correlated with any of considered parameters in the geometry of the Kamchatka SSZ and conditions of melting. This unexpected result led to the evaluation of the platinumgroup element (PGE) systematics against the lithophile and chalcophile trace element geochemistry and the compositions of phenocrysts. Total whole-rock PGE content varies from 2.3 to 11.7 ppb, whereas the normalized PGE concentration patterns are typical for supra-subduction zones magmas and broadly similar in all studied samples. They are enriched in Rh, Pd and Pt relative to mid-ocean ridge basalts (MORB) and have nearly identical concentrations of Ir-group PGE. The only parameter that correlates well with PGE contents is the average Mg# of olivine phenocrysts from 84 to 90.3 mol%. This is interpreted to result from minor cryptic fractionation of sulfide melt, together with primitive olivine, in low-to-mid crustal conditions. Negative Ru anomalies on chondrite-normalized diagrams correspond to the Fe2+/Fe3+ ratios in spinel (a proxy for magma redox conditions), which reflects a replacement of monosulfide solid solution by laurite in the mantle wedge during oxidation.
Keywords: Kamchatka; Olivine; Laurite; PGE; Sulfide
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Lithos 412-413(2022), 106608
DOI: 10.1016/j.lithos.2022.106608
Cited 8 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34252
Analysis of MRI and CT-based radiomics features for personalized treatment in locally advanced rectal cancer and external validation of published radiomics models
Shahzadi, I.; Zwanenburg, A.; Lattermann, A.; Linge, A.; Baldus, C.; Peeken, J.; Combs, S.; Diefenhardt, M.; Rödel, C.; Kirste, S.; Grosu, A.-L.; Baumann, M.; Krause, M.; Troost, E. G. C.; Löck, S.
Abstract
Radiomics analyses commonly apply imaging features of different complexity for the prediction of the endpoint of interest. However, the prognostic value of each feature class is generally unclear. Furthermore, many radiomics models lack independent external validation that is decisive for their clinical application. Therefore, in this manuscript we present two complementary studies. In our modelling study, we developed and validated different radiomics signatures for outcome prediction after neoadjuvant chemoradiotherapy (nCRT) in patients with locally advanced rectal cancer (LARC) based on computed tomography (CT) and T2-weighted (T2w) magnetic resonance (MR) imaging datasets of 4 independent institutions (training: 122, validation 68 patients). We compared different feature classes extracted from the gross tumour volume for the prognosis of tumour response and freedom from distant metastases (FFDM): morphological and first order (MFO) features, second order texture (SOT) features, and Laplacian of Gaussian (LoG) transformed intensity features. Analyses were performed for CT and MRI separately and combined. Model performance was assessed by the area under the curve (AUC) and the concordance index (CI) for tumour response and FFDM, respectively. Overall, intensity features of LoG transformed CT and MR imaging combined with clinical T stage (cT) showed the best performance for tumour response prediction, while SOT features showed good performance for FFDM in independent validation (AUC = 0.70, CI = 0.69). In our external validation study, we aimed to validate previously published radiomics signatures on our multicentre cohort. We identified relevant publications on comparable patient datasets through a literature search and applied the reported radiomics models to our dataset. Only one of the identified studies could be validated, indicating an overall lack of reproducibility and the need of further standardization of radiomics before clinical application.
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Scientific Reports 12(2022), 10192
DOI: 10.1038/s41598-022-13967-8
Cited 15 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34251
Uptake of Np(V) by zirconia: a combined batch, spectroscopic, and surface complexation modeling study
Jessat, I.; Roßberg, A.; Scheinost, A.; Lützenkirchen, J.; Foerstendorf, H.; Jordan, N.
Abstract
The interactions of long-lived actinides, such as the transuranium element neptunium, with corrosion products in the near-field of a repository are important processes that have to be considered when assessing the safety of a nuclear waste repository. As a main corrosion product of the zircaloy cladding material of spent nuclear fuel rods, zirconia (ZrO₂) constitutes a first possible barrier against the release of radionuclides.
To gain a detailed understanding of the surface processes in the Np(V)−zirconia system, a comprehensive, multi-method approach was applied. The Np(V)−ZrO₂ system has been studied on the macroscopic level by conducting pH-dependent batch sorption experiments under varying conditions (ionic strength, Np(V) concentration, and solid-to-liquid ratio (m/V)). In addition, a Np(V) sorption isotherm at pH 6 was collected. The results revealed that Np(V) sorption onto ZrO₂ was affected by pH, Np(V) concentration, and solid-to-liquid ratio. Uptake of Np(V) increased with pH, starting around pH 3 with maximum sorption reached from pH 6. The shift of the sorption edge towards lower pH with increase of the m/V ratio points to the presence of different kinds of sorption sites. This is supported by the Np(V) sorption isotherm results, where the shape suggests strong and weak binding sites. Furthermore, Np(V) uptake was found to be independent of ionic strength and zeta potential measurements revealed a shift towards higher pH values of the isoelectric point of the neat ZrO₂ in the presence of Np(V). Hence, the formation of Np(V) inner-sphere surface complexes is indicated.
Molecular information about the surface species were obtained by Extended X-ray Absorption Fine Structure Spectroscopy (EXAFS) and in situ Infrared (IR) Spectroscopy, revealing the predominant formation of inner-sphere Np(V) surface complexes. A short Np−Zr distance derived from EXAFS suggests the presence of Np(V) bidentate inner-sphere complexes on the ZrO₂ surface.
These information obtained on a macroscopic and a molecular level can be used to restrict the number of surface species as well as their denticity in a surface complexation model. The thermodynamic surface complexation parameters of the Np(V)−zirconia system derived in this study will help to make more reliable predictions about the fate of Np(V) in the environment.
Keywords: neptunium(V); zirconia; ZrO₂; sorption; spectroscopy; EXAFS; IR
Involved research facilities
- Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265
Related publications
- DOI: 10.1107/S1600577520014265 is cited by this (Id 34249) publication
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Lecture (Conference)
19th Radiochemical Conference (RadChem), 15.-20.05.2022, Mariánské Lázně (Marienbad), Czech Republic
Permalink: https://www.hzdr.de/publications/Publ-34249
Crystal field effects in the zig-zag chain compound SrTm2O4
Kademane, A. B.; Quintero-Castro, D. L.; Siemensmeyer, K.; Salazar Mejia, C.; Gorbunov, D.; Stewart, J. R.; Luetkens, H.; Baines, C.; Li, H.
Abstract
The single ion properties of the zig-zag chain compound SrTm2O4 have been investigated using heat capacity, magnetic susceptibility, magnetization, inelastic neutron scattering, and polarized muon spectroscopy. Two crystal field models are employed to estimate the single ion properties; a Density Function Theory based model and an effective charge model based on the Hutchings point charge model. The latter describes our experimental results well. This model estimates an easy-axis anisotropy for one of the Tm3+ sites and an easyplane anisotropy for the second site. It also predicts a mixed ground state with dominating 𝐽 = 0 characteristics for both sites. Additionally, muon spin rotation/relaxation (𝜇+SR) spectra reveal oscillations, typically a sign of long-range magnetic order. However, the temperature dependence of the precession frequency and the relaxation rates indicate that the system is in an extended critical regime and the observed relaxation is actually dynamic.
Involved research facilities
- High Magnetic Field Laboratory (HLD)
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Journal of Magnetism and Magnetic Materials 551(2022), 169020
DOI: 10.1016/j.jmmm.2022.169020
Cited 2 times in Scopus
Downloads
Permalink: https://www.hzdr.de/publications/Publ-34248
Numerical Simulation of the Two-Phase Flow at a Single Trapezoid Fixed Valve Using a Hybrid CFD Approach
Wiedemann, P.; Kota, S. P.; Weckesser, S.; Schleicher, E.; Schubert, M.; Hampel, U.
Abstract
In the present contribution, we demonstrate the application of a hybrid CFD approach, which allows for simulating dispersed phases as well as resolved interfaces within an Eulerian framework, for the flow on distillation trays for the first time. The morphology adaptive multi-field two-fluid model is exemplified for a generic tray setup with a single trapezoid fixed valve. Instead of fully resolving its geometry in the computational grid, we emulate the gas inlets by implementing local mass and momentum sources. Different source term implementations are tested and compared: continuous gas vs. dispersed gas sources and steady vs. dynamic sources. The simulation results are verified with experimental data from a lab-scale test rig with air-water flow. Local phase fractions were measured using a conductivity sensor array. The comparison of simulated and experimental results reveals that the relevant time-averaged and transient flow characteristics can be predicted satisfactorily when choosing proper source term implementations.
Keywords: fixed valve; morphology adaptive multi-field two-fluid model; local source terms; CFD
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Contribution to proceedings
12th international conference on Distillation & Absorption 2022, 18.-21.09.2022, Toulouse, France -
Lecture (Conference)
12th international conference on Distillation & Absorption 2022, 20.09.2022, Toulouse, France
Permalink: https://www.hzdr.de/publications/Publ-34247
On the agglomeration and breakage of particles in turbulent flows through pipe bends using CFD-PBE
Bilde, K. G.; Hærvig, J.; Lehnigk, R.; Schlegel, F.; Sørensen, K.
Abstract
Particle agglomeration and breakage through pipe bends in turbulent flows are important for a wide range of industries and applications. A computational fluid dynamics (CFD) model is presented where the population balance equation (PBE) is applied to track the particle size distribution for a periodic turbulent pipe flow with 180◦ bends with a fluid Reynolds number in the range 15, 000 < Ref < 35, 000 and for three different pipe bend radii of rB = 1dh, rB = 1.5dh and rB = 2.5dh. The critical parameters in the Eulerian framework are analysed and suitable parameters are chosen to describe the agglomeration of soot-like particles suspended in water based on an experimentally obtained particle size distribution. The experimental particle size distribution of flocculated
soot particles was measured using a Malvern Mastersizer 3000 at the outlet of a static flocculator with a bend radius of rb = 1.5D. It is concluded that for the particle properties applied, the particle Sauter mean diameter converges to a constant value independent of the pipe bend radius when the fluid Reynolds number exceeds Ref = 30, 000. The agglomeration and breakage kernels for solid particles in a turbulent fluid flow are implemented in the open-source CFD library by the OpenFOAM Foundation.
Keywords: Multiphase flows; Population balance equation; Particle agglomeration; Particle breakage; Turbulence
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Chemical Engineering Science 260(2022), 117915
DOI: 10.1016/j.ces.2022.117915
Cited 3 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34246
Laboratory Investigation of Tomography-Controlled Continuous Steel Casting
Glavinic, I.; Muttakin, I.; Abouelazayem, S.; Blishchik, A.; Stefani, F.; Eckert, S.; Soleimani, M.; Saidani, I.; Hlava, J.; Kenjereš, S.; Wondrak, T.
Abstract
More than 96% of steel in the world is produced via the method of continuous casting. The flow condition in the mould, where the initial solidification occurs, has a significant impact on the quality of steel products. It is important to have timely, and perhaps automated, control of the flow during casting. This work presents a new concept of using contactless inductive flow tomography (CIFT) as a sensor for a novel controller, which alters the strength of an electromagnetic brake (EMBr) of ruler type based on the reconstructed flow structure in the mould. The method was developed for the small-scale Liquid Metal Model for Continuous Casting (mini-LIMMCAST) facility available at the Helmholtz-Zentrum Dresden-Rossendorf. As an example of an undesired flow condition, clogging of the submerged entry nozzle (SEN) was modelled by partly closing one of the side ports of the SEN; in combination with an active EMBr, the jet penetrates deeper into the mould than when the EMBr is switched off. Corresponding flow patterns are detected by extracting the impingement position of the jets at the narrow faces of the mould from the CIFT reconstruction. The controller is designed to detect to undesired flow condition and switch off the EMBr. The temporal resolution of CIFT is 0.5 s.
Keywords: Contactless Inductive Flow Tomography; Continuous casting; Clogging; Flow control; EMBr; Inductive measurements; Mini-LIMMCAST
Related publications
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Data publication: Laboratory investigation of tomography-controlled continuous …
ROBIS: 34346 HZDR-primary research data are used by this (Id 34245) publication
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Sensors 22(2022)6, 2195
DOI: 10.3390/s22062195
Cited 6 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34245
Kaon and pion parton distributions
Cui, Z.-F.; Ding, M.; Gao, F.; Raya, K.; Binosi, D.; Chang, L.; Roberts, C. D.; Rodriguez-Quintero, J.; Schmidt, S. M.
Abstract
Beginning with results for the leading-twist two-particle distribution amplitudes of π- and K-mesons, each of which exhibits dilation driven by the mechanism responsible for the emergence of hadronic mass, we develop parameter-free predictions for the pointwise behaviour of all π and K distribution functions (DFs), including glue and sea. The large-x behaviour of each DF meets expectations based on quantum chromodynamics; the valence-quark distributions match extractions from available data, including the pion case when threshold resummation effects are included; and at ζ5=5.2GeV, the scale of existing measurements, the light-front momentum of these hadrons is shared as follows: ⟨xvalence⟩π=0.41(4), ⟨xglue⟩π=0.45(2), ⟨xsea⟩π=0.14(2); and ⟨xvalence⟩K=0.42(3), ⟨xglue⟩K=0.44(2), ⟨xsea⟩K=0.14(2). The kaon’s glue and sea distributions are similar to those in the pion, although the inclusion of mass-dependent splitting functions introduces some differences on the valence-quark domain. This study should stimulate improved analyses of existing data and motivate new experiments sensitive to all π and K DFs. With little known empirically about the structure of the Standard Model’s (pseudo-) Nambu-Goldstone modes and analyses of existing, limited data being controversial, it is likely that new generation experiments at upgraded and anticipated facilities will provide the information needed to resolve the puzzles and complete the picture of these complex bound states.
Keywords: parton; Kaon
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European Physical Journal C 80(2020)1064
DOI: 10.1140/epjc/s10052-020-08578-4
Cited 63 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34244
Towards attosecond imaging at the nanoscale using broadband holography-assisted coherent imaging in the extreme ultraviolet
Eschen, W.; Wang, S.; Liu, C.; Klas, R.; Steinert, M.; Yulin, S.; Meißner, H.; Bussmann, M.; Pertsch, T.; Limpert, J.; Rothhardt, J.
Abstract
Nanoscale coherent imaging has emerged as an indispensable modality, allowing to surpass the resolution limit given by classical imaging optics. At the same time, attosecond science has experienced enormous progress and has revealed the ultrafast dynamics in complex materials. Combining attosecond temporal resolution of pump-probe experiments with nanometer spatial resolution would allow studying ultrafast dynamics on the smallest spatio-temporal scales but has not been demonstrated yet. To date, the large bandwidth of attosecond pulses poses a major challenge to high-resolution coherent imaging. Here, we present broadband holography-enhanced coherent imaging, which enables the combination of high-resolution coherent imaging with a large spectral bandwidth. By implementing our method at a high harmonic source, we demonstrate a spatial resolution of 34 nm in combination with a spectral bandwidth of 5.5 eV at a central photon energy of 92 eV. The method is single-shot capable and retrieves the spectrum from the measured diffraction pattern.
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Communications Physics 4(2021), 154
DOI: 10.1038/s42005-021-00658-5
Cited 6 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34243
Reflections upon the Emergence of Hadronic Mass
Roberts, C. D.; Schmidt, S. M.
Abstract
With discovery of the Higgs boson, science has located the source for ≲2% of the mass of visible matter. The focus of attention can now shift to the search for the origin of the remaining ≳98%. The instruments at work here must be capable of simultaneously generating the 1 GeV mass-scale associated with the nucleon and ensuring that this mass-scale is completely hidden in the chiral-limit pion. This hunt for an understanding of the emergence of hadronic mass (EHM) has actually been underway for many years. What is changing are the impacts of QCD-related theory, through the elucidation of clear signals for EHM in hadron observables, and the ability of modern and planned experimental facilities to access these observables. These developments are exemplified in a discussion of the evolving understanding of pion and kaon parton distributions.
Keywords: hadronic; Phenomenology; physics
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European Physical Journal - Special Topics 229(2020), 3319-3340
DOI: 10.1140/epjst/e2020-000064-6
Cited 41 times in Scopus -
Contribution to WWW
arXiv:2006.08782: https://arxiv.org/abs/2006.08782
Downloads
Permalink: https://www.hzdr.de/publications/Publ-34242
Nucleon elastic form factors at accessible large spacelike momenta
Cui, Z.-F.; Chen, C.; Binosi, D.; Soto, F. D.; Roberts, C. D.; Rodríguez-Quintero, J.; Schmidt, S. M.; Segovia, J.
Abstract
A Poincaré-covariant quark+diquark Faddeev equation is used to compute nucleon elastic form factors on 0≤Q2≤18m2N (mN is the nucleon mass) and elucidate their role as probes of emergent hadronic mass in the Standard Model. The calculations expose features of the form factors that can be tested in new generation experiments at existing facilities, e.g. a zero in GpE/GpM; a maximum in GnE/GnM; and a zero in the proton's d-quark Dirac form factor, Fd1. Additionally, examination of the associated light-front-transverse number and anomalous magnetisation densities reveals, inter alia: a marked excess of valence u-quarks in the neighbourhood of the proton's centre of transverse momentum; and that the valence d-quark is markedly more active magnetically than either of the valence u-quarks. The calculations and analysis also reveal other aspects of nucleon structure that could be tested with a high-luminosity accelerator capable of delivering higher beam energies than are currently available.
Keywords: nucleon; quark
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Physical Review D 102(2020)1, 014043
DOI: 10.1103/PhysRevD.102.014043
Cited 32 times in Scopus -
Contribution to WWW
arXiv:2003.11655: https://arxiv.org/abs/2003.11655
Permalink: https://www.hzdr.de/publications/Publ-34241
Valence quark ratio in the proton
Cui, Z.-F.; Gao, F.; Binosi, D.; Chang, L.; Roberts, C. D.; Schmidt, S. M.
Abstract
Beginning with precise data on the ratio of structure functions in deep inelastic scattering (DIS) from 3He and 3H, collected on the domain 0.19≤xB≤0.83, where xB is the Bjorken scaling variable, we employ a robust method for extrapolating such data to arrive at a model-independent result for the xB=1 value of the ratio of neutron and proton structure functions. Combining this with information obtained in analyses of DIS from nuclei, corrected for target-structure dependence, we arrive at a prediction for the proton's valence-quark ratio: dv/uv|xB→1=0.230(57). Requiring consistency with this result presents a challenge to many descriptions of proton structure.
Keywords: quark; proton; valence; ratio
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Contribution to WWW
arXiv:2108.11493: https://arxiv.org/abs/2108.11493
Permalink: https://www.hzdr.de/publications/Publ-34240
Pauli Radius of the Proton
Cui, Z.-F.; Binosi, D.; Roberts, C. D.; Schmidt, S. M.
Abstract
Using a procedure based on interpolation via continued fractions supplemented by statistical sampling, we analyze proton magnetic form factor data obtained via electron+proton scattering on Q2∈[0.027,0.55] GeV2 with the goal of determining the proton magnetic radius. The approach avoids assumptions about the function form used for data interpolation and ensuing extrapolation onto Q2≃0 for extraction of the form factor slope. In this way, we find Tm=0.817(27) fm. Regarding the difference between proton electric and magnetic radii calculated in this way, extant data are seen to be compatible with the possibility that the slopes of the proton Dirac and Pauli form factors, F1,2(Q2), are not truly independent observables; to wit, the difference F′1(0)−F′2(0)/κp=[1+κp]/[4m2p], viz., the proton Foldy term.
Keywords: pauli; radius; proton
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Chinese Physics Letters 38(2021)12, 121401
DOI: 10.1088/0256-307X/38/12/121401
Cited 8 times in Scopus -
Contribution to WWW
arXiv:2109.08768 [hep-ph]: https://arxiv.org/abs/2109.08768
Downloads
Permalink: https://www.hzdr.de/publications/Publ-34239
Pion charge radius from pion and electron elastic scattering data
Cui, Z.-F.; Binosi, D.; Roberts, C. D.; Schmidt, S. M.
Abstract
With the aim of extracting the pion charge radius, we analyse extant precise pion+electron elastic scattering data on Q2∈[0.015,0.144]GeV2 using a method based on interpolation via continued fractions augmented by statistical sampling. The scheme avoids any assumptions on the form of function used for the representation of data and subsequent extrapolation onto Q2≃0. Combining results obtained from the two available data sets, we obtain rπ=0.640(7)fm, a value 2.4σ below today's commonly quoted average. The tension may be relieved by collection and similar analysis of new precise data that densely cover a domain which reaches well below Q2=0.015GeV2. Considering available kaon+electron elastic scattering data sets, our analysis reveals that they contain insufficient information to extract an objective result for the charged-kaon radius, rK. New data with much improved precision, low-Q2 reach and coverage are necessary before a sound result for rK can be recorded.
Keywords: pion; electron; scattering
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Physics Letters B 822(2021), 136631
DOI: 10.1016/j.physletb.2021.136631
Cited 14 times in Scopus -
Contribution to WWW
arXiv:2108.04948 [hep-ph]: https://arxiv.org/abs/2108.04948
Permalink: https://www.hzdr.de/publications/Publ-34238
Fresh Extraction of the Proton Charge Radius from Electron Scattering
Cui, Z.-F.; Roberts, C. D.; Binosi, D.; Schmidt, S. M.
Abstract
We present a novel method for extracting the proton radius from elastic electron-proton (ep) scattering data. The approach is based on interpolation via continued fractions augmented by statistical sampling and avoids any assumptions on the form of function used for the representation of data and subsequent
extrapolation onto Q2 ≃ 0. Applying the method to extant modern ep datasets, we find that all results are mutually consistent and, combining them, we arrive at rp = 0.847(8) fm. This result compares favorably with values obtained from contemporary measurements of the Lamb shift in muonic hydrogen, transitions
in electronic hydrogen, and muonic deuterium spectroscopy.
Keywords: electron; scattering; proton
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Physical Review Letters 127(2021)9, 092001
DOI: 10.1103/PhysRevLett.127.092001
Cited 20 times in Scopus -
Contribution to WWW
arXiv:2102.01180 [hep-ph]: https://arxiv.org/abs/2102.01180
Permalink: https://www.hzdr.de/publications/Publ-34237
Prolificacy Assessment of Spermatozoan via State-of-the-Art Deep Learning Frameworks
Chandra, S.; Gourisaria, M. K.; Konar, D.; Gao, X.; Wang, T.; Min, X.; Gm, H.
Abstract
Childlessness or infertility among couples has become a global health concern. Due to the rise in infertility, couples are looking for medical supports to attain reproduction. This paper deals with diagnosing infertility among men and the major factor in diagnosing infertility among men is the Sperm Morphology Analysis (SMA). In this manuscript, we explore establishing deep learning frameworks to automate the classification problem in the fertilization of sperm cells. We investigate the performance of multiple state-of-the-art deep neural networks on the MHSMA dataset. The experimental results demonstrate that the deep learning-based framework outperforms human experts on sperm classification in terms of accuracy, throughput and reliability. We further analyse the sperm cell data by visualizing the feature activations of the deep learning models, providing a new perspective to understand the data. Finally, a comprehensive analysis is also demonstrated on the experimental results obtained and attributing them to pertinent reasons.
Keywords: Sperm abnormality; deep learning; transfer learning
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IEEE Access 10(2022), 3146334
DOI: 10.1109/ACCESS.2022.3146334
ISSN: 2169-3536
Cited 17 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34236
A correspondence between the free and interacting field theories
Gao, F.; Ding, M.; Liu, Y.; Schmidt, S. M.
Abstract
We discover a correspondence between the free field and the interacting states. This correspondence is firstly given from the fact that the free propagator can be converted into a tower of propagators for massive states, when expanded with the Hermite function basis. The equivalence of propagators reveals that in this particular case the duality can naturally be regarded as the equivalence of one theory on the plane wave basis to the other on the Hermite function basis. More generally, the Hermite function basis provides an alternative quantization process with the creation/annihilation operators that correspond directly to the interacting fields. Moreover, the Hermite function basis defines an exact way of dimensional reduction. As an illustration, we apply this basis on 3+1 dimensional Yang-Mills theory with three dimensional space being reduced through the Hermite function basis, and if with only the lowest order Hermite function, the equivalent action becomes the Banks-Fischler-Shenker-Susskind (BFSS) matrix model.
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Contribution to WWW
https://arxiv.org/abs/2202.03191 -
European Physical Journal C 83(2023), 144
DOI: 10.1140/epjc/s10052-023-11278-4
Permalink: https://www.hzdr.de/publications/Publ-34235
Strahlenschutz im HZDR und im Institut für Radiopharmazeutische Krebsforschung
Wendler, M.
Abstract
Vorstellung des Strahlenschutzes und der Strahlenschutzstruktur am HZDR. Es wird die Strahlenschutzpraxis im Institut für radiopharmazeutische Krebsforschung erläutert und aktuelle Projekte wie die Beantragung von Freigabewerten und das Alpha-Projekt aus Strahlenschutzsicht erläutert.
Keywords: Institut für radiopharmazeutische Krebsforschung; Radiation Protection; Betrieblicher Strahlenschutz
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Lecture (others)
(Online presentation)
Sitzung des Arbeitskreis Praktischer Strahlenschutz im Fachverband Strahlenschutz, 17.03.2022, Deutsch, Deutschland
Permalink: https://www.hzdr.de/publications/Publ-34234
Quantum Zeno Manipulation of Quantum Dots
Ahmadiniaz, N.; Paul Geller, M.; König, J.; Kratzer, P.; Lorke, A.; Schaller, G.; Schützhold, R.
Abstract
We investigate whether and how the quantum Zeno effect, i.e., the inhibition of quantum evolution by frequent measurements, can be employed to isolate a quantum dot from its surrounding electron reservoir. In contrast to the often studied case of tunneling between discrete levels, we consider the tunnelling of an electron from a continuum reservoir to a discrete level in the dot. Realizing the quantum Zeno effect in this scenario can be much harder because the measurements should be repeated before the wave packet of the hole left behind in the reservoir moves away from the vicinity of the dot. Thus, the required repetition rate could be lowered by having a flat band (with a slow group velocity) in resonance with the dot or a sufficiently small Fermi velocity or a strong external magnetic field.
Keywords: Quantum Zeno effect; quantum dots; wave packet decay; measurement problem; perturbation theory
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Contribution to WWW
arXiv:2201.11718 [cond-mat.mes-hall]: https://arxiv.org/abs/2201.11718 -
Physical Review Research 4(2022), L032045
DOI: 10.1103/PhysRevResearch.4.L032045
ISSN: 2643-1564
Cited 2 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34233
Decay of quantum sensitivity due to three-body loss in Bose-Einstein condensates
Abstract
In view of the coherent properties of a large number of atoms, Bose-Einstein condensates (BECs) have a high potential for sensing applications. Several proposals have been put forward to use collective excitations such as phonons in BECs for quantum-enhanced sensing in quantum metrology. However, the associated highly nonclassical states tend to be very vulnerable to decoherence. In this article, we investigate the effect of decoherence due to the omnipresent process of three-body loss in BECs.We find strong restrictions for a wide range of parameters, and we discuss possibilities to limit these restrictions.
Keywords: quantum; Bose-Einstein
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Physical Review A 103(2021)6, 063321
DOI: 10.1103/PhysRevA.103.063321
Cited 5 times in Scopus -
Contribution to WWW
arXiv:2101.05312: https://arxiv.org/abs/2101.05312
Downloads
Permalink: https://www.hzdr.de/publications/Publ-34231
Technische Umsetzung von RDM Services: RODARE - InvenioRDM am HZDR
Abstract
The presentation highlights the research data repository of the HZDR RODARE.
In the first part Maik Fiedler gives an overview of the current use of the repository, shows features and statistics on the development and embeds the system in the publication economy of the HZDR.
In the second part the update upgrade from Rodare to an InvenioRDM-based RODARE-RDM is introduced with the technical background and conditions by Oliver Knodel. Furthermore, the concept for the integration of Rodare into the HELIPORT data management system HELIPORT is presented.
Keywords: Helmholtz Open Science Office; Research data; Research software; Data Management
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Invited lecture (Conferences)
(Online presentation)
Praxisforum Forschungsdatenmanagement, 03.02.2022, Online, Deutschland
DOI: 10.48440/os.helmholtz.044
Permalink: https://www.hzdr.de/publications/Publ-34230
Radiocarbon-dated evidence for Late Pleistocene and Holocene coastal change at Yzerfontein, Western Cape, South Africa
Woodborne, S.; Miller, D.; Evans, M.; Winkler, S.
Abstract
We report radiocarbon dates obtained from on-shore marine and near-shore terrestrial deposits near Yzerfontein, on the West Coast of South Africa. These include Late Pleistocene shell concretions from the southern end of 16 Mile Beach and a marine shell deposit inland of the coastal Rooipan; mid-Holocene coastal pan deposits exposed by modern storm erosion of the sandy 16 Mile Beach; and four Holocene storm beach deposits on a rocky shore to the south. We interpret the results in terms of local geomorphology constraints on sea-level fluctuations. The eastern margin of Rooipan is a >40 ka elevated beach deposit in a dune cordon that separates it from the adjacent Yzerfonteinpan. Both pans have gypsum deposits up to 2 m thick formed by repeated marine overwash. Saline pan deposits that are exposed intermittently on the beach are mid-Holocene and indicate a former westward extension of Rooipan. This is in contrast to storm beaches dating 9 000–3 000 cal BP at higher elevations on a rocky platform further south. This suggests that a dune barrier existed seaward of the present shoreline near Rooipan at this time. The coastal changes described here show that deposition and erosion can be affected significantly by the local palaeo-geomorphology and cannot be ascribed solely to sea-level change.
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South African Journal of Science 119(2023)11/12, 15505
DOI: 10.17159/sajs.2023/15505
Permalink: https://www.hzdr.de/publications/Publ-34229
Highlight selection of radiochemistry and radiopharmacy developments by editorial board
Bernardes, E.; Caravan, P.; van Dam, M.; Deuther-Conrad, W.; Ellis, B.; Furumoto, S.; Guillet, B.; Huang, Y.-Y.; Jia, H.; Laverman, P.; Li, Z.; Liu, Z.; Lodi, F.; Miao, Y.; Perk, L.; Schirrmacher, R.; Vercoullie, J.; Yang, H.; Yang, M.; Yang, X.; Zhang, J.; Zhang, M.-R.; Zhu, H.
Abstract
Background: The Editorial Board of EJNMMI Radiopharmacy and Chemistry releases a biyearly highlight commentary to update the readership on trends in the field of radiopharmaceutical development.
Results: This commentary of highlights has resulted in 23 different topics selected by each member of the Editorial Board addressing a variety of aspects ranging from novel radiochemistry to first in man application of novel radiopharmaceuticals and also a contribution in relation to MRI-agents is included.
Conclusion: Trends in (radio)chemistry and radiopharmacy are highlighted demonstrating the progress in the research field being the scope of EJNMMI Radiopharmacy and Chemistry.
Keywords: Radiopharmacy; Radiochemistry; Radiopharmaceuticals
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EJNMMI Radiopharmacy and Chemistry 7(2022)1, 9
DOI: 10.1186/s41181-022-00162-3
Cited 1 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34228
The effects of Calcigel bentonite naturally occurring microorganisms on corrosion of cast iron
Sushko, V.; Matschiavelli, N.; Wei, T.; Stumpf, T.; Cherkouk, A.
Abstract
In light of Germany's exploration of clay formations as potential hosts for deep geological repositories (DGR), and the most likely use of bentonite as a buffer material, copper or carbon steel/cast iron would be the most appropriate container material [1]. The surface of the metal containers is a subject to anaerobic corrosion and microbially influenced corrosion in a DGR. The interactions at the metal/bentonite interface can determine the performance of such a multi barrier system [2].
This study investigates the microbial processes that can occur at the interface between metal container and bentonite, and evaluates the effects of the microbial communities naturally occurring in bentonite may have on the corrosion of the nuclear waste
container.
Microcosm experiments as described in [3] were performed with Calcigel bentonite. The microcosms, containing GGG40 cast iron coupons, artificial Opalinus Clay porewater and bentonite, were incubated in N2-atmosphere at 37 °C. Some of the microcosms were supplemented with sodium lactate to stimulate microbial activity. After the incubation period the content of the microcosms was investigated by various geochemical analysis, DNA isolation and amplification for microbial community analysis, SEM-EDX and RAMAN spectroscopy to characterize the surface structure of the cast iron coupons. Geochemical investigation of the samples showed a slight
lactate consumption. Surface analysis of the coupons with SEM confirmed a corrosion ofr the coupons incubated with Calcigel bentonite, as well as crystalline structures covering the coupons to some extent. The cast iron coupons incubated with bentonite including naturally occurring microorganisms showed a faster corrosion than control samples with sterilized bentonite. To get a better overview about the ongoing microbial processes, microbial diversity analysis and incubations for a longer time-frame are currently still under investigation.
References
1. Nieder-Westerman, G.H., et al. 2013, Radioactive Waste Management and Contaminated Site Clean-Up, 462-488.
2. Kaufhold, S., et al. 2020, ACS Earth Space Chem. 4, 5, 711–721.
3. Matschiavelli, N. et al., 2019, Environ. Sci. Technol., 53, 17, 10514–10524
Keywords: Microbially influenced corrosion; Microcosm experiment; SEM
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Poster
EUROCORR 2022, 28.08.-1.09.2022, Berlin, Deutschland
Permalink: https://www.hzdr.de/publications/Publ-34227
Numerical simulations of counter-current two-phase flow experiments in a PWR hot leg model
Abstract
In order to improve the understanding of counter-current two-phase flows and to validate new physical
models, CFD simulations of 1/3rd scale model of the hot leg of a German Konvoi PWR with rectangular
cross section was performed. Selected counter-current flow limitation (CCFL) experiments at the Helmholtz–
Zentrum Dresden–Rossendorf (HZDR) were calculated with ANSYS CFX 12.1 using the multi-fluid
Euler–Euler modeling approach. The transient calculations were carried out using a gas/liquid inhomogeneous
multiphase flow model coupled with a k-x turbulence model for each phase. In the simulation, the
surface drag was approached by a new correlation inside the Algebraic Interfacial Area Density (AIAD)
model. The AIAD model allows the detection of the morphological form of the two phase flow and the
corresponding switching via a blending function of each correlation from one object pair to another.
As a result this model can distinguish between bubbles, droplets and the free surface using the local
liquid phase volume fraction value. A comparison with the high-speed video observations shows a good
qualitative agreement. The results indicated that quantitative agreement of the CCFL characteristics
between calculation and experimental data was obtained. The goal is to provide an easy usable AIAD
framework for all Code users, with the possibility of the implementation of their own correlations.
Keywords: Numerical simulation; CFD; CCFL; AIAD model; Reflux condensation; PWR hot leg; Air–water experiment
Involved research facilities
- TOPFLOW Facility
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Invited lecture (Conferences)
(Online presentation)
NURETH19, 09.03.2022, Brüssel, Belgien
Permalink: https://www.hzdr.de/publications/Publ-34226
Prompt-gamma based treatment verification: Multi-institutional benchmark experiment of a prompt-gamma-imaging and a prompt-gamma-spectroscopy prototype system using an anthropomorphic head phantom
Berthold, J.; Hueso González, F.; Wohlfahrt, P.; Bortfeld, T.; Khamfongkhruea, C.; Tattenberg, S.; Zarifi, M.; Richter, C.; Verburg, J.
Abstract
Introduction
Prompt-gamma-based range verification has been clinically implemented using either prompt-gamma-imaging (PGI) or prompt-gamma-spectroscopy (PGS). Here, two proton therapy centers, currently investigating the clinical benefit of PGI and PGS, collaborated to systematically compare the two techniques in a set of benchmark experiments under equalized conditions.
Materials&Methods
The same anthropomorphic head phantom (CIRS, USA) was used for treatment planning, beam delivery and PG monitoring in both centers. Two pencil-beam-scanning fields (1GyE) targeting a brain lesion were optimized on a Dual-energy-CT using the same spot positions and energies in both centers, enabling spot-wise comparison. The horizontal short-range field was clinically realistic. The long-range, oblique field served as stress test. Absolute range verification accuracy against a blinded ground truth (SPR map) for both fields as well as the capability to detect relative range shifts, introduced by plastic slabs (2 and 5mm) on half of the short-range field, was assessed.
Results (µ±σ)
The absolute accuracy of PGI and PGS were (-0.5±0.8)mm or (2.4±0.8)mm for the short-range and (2.4±1.9)mm or (1.3±1.5)mm for the long-range field, respectively. Relative range shifts were detected with (2.0±0.9)mm or (4.2±0.8)mm accuracy for PGI, and (1.8±0.5)mm or (4.8±0.4)mm for PGS. Both systems show a performance worthy of clinical application for the detection of range deviations. Future improvements of their sensitivity are ongoing.
Conclusion
For the first time, two independent PG range verification systems utilizing different PG information have been successfully benchmarked under equalized conditions in two proton therapy centers. This marks an important milestone for translational research on proton treatment verification.
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Lecture (Conference)
PTCOG 60, 27.06.-02.07.2022, Miami, U.S.A. -
Abstract in refereed journal
International Journal of Particle Therapy 9(2023)4, 306-470
DOI: 10.14338/IJPT-23-PTCOG60-9.4
Cited 1 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34225
MOFs with 12-coordinate 5f-block metal centers
Lv, K.; Urbank, C.; Patzschke, M.; März, J.; Kaden, P.; Weiß, S.; Schmidt, M.
Abstract
We have constructed an unprecedented MOF platform that accommodates a range of 5f-block metal ions (Th4+, U4+, Np4+, Pu4+) as the primary building block. The isoreticular actinide metal-organic frameworks (An-MOFs) exhibit periodic trends in the 12-coordinate metal environment, ligand configuration, and resulting ultramicroporosity. It holds potential in distinguishing neighboring tetravalent actinides. The metal ionic radius, carboxylate bite angle, anthracene plane twisting, inter-ligand interac-tions, and countercation templating collectively determine an interplay between solvation, modulation, and complexation, re-sulting in a coordination saturation of the central actinide while lanthanide counterparts are stabilized by the formation of a dimer-based motif. Quantum chemical calculations indicate that this large coordination number is only feasible in the high-symmetry environment provided by the An-MOFs. This category of MOFs not only demonstrates autoluminescence (4.16 ×104 counts per second per gram) but also portends a wide-bandgap (2.84 eV) semiconducting property with implications for a multitude of applications such as hard radiation detection.
Keywords: Actinides; Metal-Organic Frameworks; Autoluminescence; Semiconductor
Related publications
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Data publication: MOFs with 12-coordinate 5f-block metal centers
ROBIS: 34272 HZDR-primary research data are used by this (Id 34224) publication
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Journal of the American Chemical Society 144(2022)7, 2879-2884
DOI: 10.1021/jacs.1c13127
Cited 15 times in Scopus
Downloads
- Final Draft PDF 994 kB Secondary publication
Permalink: https://www.hzdr.de/publications/Publ-34224
A multimodal approach to revisiting oxidation defects in Cr2O3
Auguste, R.; Chan, H. L.; Romanovskaia, E.; Qiu, J.; Schoell, R.; Liedke, M. O.; Butterling, M.; Hirschmann, E.; Elsherif, A. G. A.; Wagner, A.; Selim, F. A.; Kaoumi, D.; Uberuaga, B. P.; Hosemann, P.; Scully, J. R.
Abstract
The oxidation of chromium in air at 700 °C was investigated with a focus on point defect behavior and transport during oxide layer growth. A comprehensive set of characterization techniques targeted characteristics of chromium oxide microstructure and chemical composition analysis. TEM showed that the oxide was thicker with longer oxidation times and that, for the thicker oxides, voids formed at the metal/oxide interface. PAS revealed that the longer the oxidation time, there was an overall reduction in vacancy-type defects, though chromium monovacancies were not found in either case. EIS found that the longer oxidized material was more electrochemically stable and that, while all oxides displayed p-type character, the thicker oxide had an overall lower charge carrier density. Together, the results suggest anion oxygen interstitials and chromium vacancy cluster complexes drive transport in an oxidizing environment at this temperature, providing invaluable insight into the mechanisms that regulate corrosion.
Keywords: Cr2O3; oxidation; defects; positron annihilation spectroscopy; transmission electron microscopy; Raman spectroscopy
Involved research facilities
- Radiation Source ELBE DOI: 10.17815/jlsrf-2-58
- P-ELBE
Related publications
- DOI: 10.17815/jlsrf-2-58 is cited by this (Id 34223) publication
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npj Materials Degradation 6(2022), 61
DOI: 10.1038/s41529-022-00269-7
Cited 8 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34223
Spatially resolved temperature distribution in a rare-earth-doped transparent glass-ceramic
Sedmak, I.; Podlipec, R.; Urbancic, I.; Strancar, J.; Mortier, M.; Golobic, I.
Abstract
Knowing the temperature distribution within the conducting walls of various multilayer-type materials is crucial for a better understanding of heat-transfer processes. This applies to many engineering fields, good examples being photovoltaics and microelectronics. In this work, we present a novel fluorescence technique that makes possible the non-invasive imaging of local temperature distributions within a transparent, temperature-sensitive, co-doped Er:GPF1Yb0.5Er glass-ceramic with micrometer spatial resolution. The thermal imaging was performed with a high-resolution, fluorescence microscopy system, measuring different focal planes along the z-axis. This ultimately enabled a precise axial reconstruction of the temperature distribution across a 500-µm-thick glass-ceramic sample. The experimental measurements showed excellent agreement with computer-modeled heat simulations and suggest that the technique could be adopted for the spatial analyses of local thermal processes within optically transparent materials. For instance, the technique could be used to measure the temperature distribution of intermediate, transparent layers of novel ultra-high-efficiency solar cells at the micron and sub-micron levels.
Keywords: Temperature-dependent fluorescence; co-doped glass-ceramic; axial temperature distribution; micro-scale temperature measurements
Related publications
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Dataset: spatially resolved temperature distribution in a rare-earth-doped …
ROBIS: 34411 HZDR-primary research data are used by this (Id 34222) publication
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Sensors 22(2022)5, 1970
DOI: 10.3390/s22051970
Cited 2 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34222
f-electron hybridised Fermi surface in magnetic field-induced metallic YbB12
Liu, H.; Hickey, A. J.; Hartstein, M.; Davies, A. J.; Eaton, A. G.; Elvin, T.; Polyakov, E.; Vu, T. H.; Wichitwechkarn, V.; Förster, T.; Wosnitza, J.; Murphy, T. P.; Shitsevalova, N.; Johannes, M. D.; Ciomaga Hatnean, M.; Balakrishnan, G.; Lonzarich, G. G.; Sebastian, S. E.
Abstract
The nature of the Fermi surface observed in the recently discovered family of unconventional insulators starting with SmB6 is a subject of intense inquiry. Here we shed light on this question by accessing quantum oscillations in the high magnetic field-induced metallic regime above ≈47 T in YbB12, which we compare with the unconventional insulating regime. In the field-induced metallic regime, we find prominent quantum oscillations in the electrical resistivity characterised by multiple frequencies and heavy effective masses. The close similarity in Lifshitz-Kosevich low-temperature growth of quantum oscillation amplitude in insulating YbB12 to field-induced metallic YbB12, points to an origin of quantum oscillations in insulating YbB12 from in-gap neutral low energy excitations. Higher frequency Fermi surface sheets of heavy quasiparticle effective mass emerge in the field-induced metallic regime of YbB12 in addition to multiple heavy Fermi surface sheets observed in both insulating and metallic regimes. f-electron hybridisation is thus observed to persist from the unconventional insulating to the field-induced metallic regime of YbB12, in contrast to the unhybridised conduction electron Fermi surface observed in unconventional insulating SmB6. Our findings thus require an alternative model for YbB12, of neutral in-gap low energy excitations, wherein the f-electron hybridisation is retained.
Involved research facilities
- High Magnetic Field Laboratory (HLD)
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npj Quantum Materials 7(2022), 12
DOI: 10.1038/s41535-021-00413-7
Cited 8 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34221
The importance of understanding Technetium environmental behaviour
Abstract
The talk shows the work carried out at Institute of Resource Ecology in the last four years in the frame of Tc immobilization by Fe(II)-minerals and the future perspectives for collaboration between Freie Universität Berlin.
Keywords: Technetium; Environment; Remediation; Sorption
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Lecture (others)
(Online presentation)
Seminar at Freie Universität Berlin, 07.02.2022, Berlin, Germany
Permalink: https://www.hzdr.de/publications/Publ-34220
Annual Report 2021 - Institute of Resource Ecology
Stumpf, T.; Foerstendorf, H.; Bok, F.; Richter, A.
Abstract
The Institute of Resource Ecology (IRE) is one of the eight institutes of the Helmholtz-Zentrum Dresden–Rossendorf (HZDR). Our research activities are mainly integrated into the program “Nuclear Waste Management, Safety and Radiation Research (NUSAFE)” of the Helmholtz Association (HGF) and focus on the topics “Safety of Nuclear Waste Disposal” and “Safety Research for Nuclear Reactors”. The program NUSAFE, and therefore all work which is done at IRE, belong to the research field “Energy” of the HGF.
IRE conducts applied basic research to protect humans and the environment from the effects of radioactive radiation.
For this purpose, we develop molecular process understand-ing using state-of-the-art methods of microscopy, spectroscopy, diffraction, numerical simulation, theoretical chemistry and systems biology. We implement this in a cross-institutional research environment at the HZDR. Our active interdisciplinarity combines radiochemistry, geosciences and biosciences as well as materials science and reactor physics.
We provide knowledge that is applied in particular to reactor and repository safety as well as in radioecology.
We achieve this goal with a unique infrastructure comprising chemical and biological laboratories as well as hot cells in corresponding radiation and biology safety laboratories in Dresden, Leipzig and Grenoble. In Grenoble, at the European Synchrotron Radiation Facility (ESRF), the institute operates a beamline with four experimental stations for continuously advanced X-ray spectroscopy and diffraction of radio-active samples, which is also available to external users.
Involved research facilities
- Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265
Related publications
- DOI: 10.1107/S1600577520014265 is cited by this (Id 34219) publication
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Wissenschaftlich-Technische Berichte / Helmholtz-Zentrum Dresden-Rossendorf; HZDR-119 2022
ISSN: 2191-8708, eISSN: 2191-8716
Downloads
Permalink: https://www.hzdr.de/publications/Publ-34219
A pharmacokinetic and metabolism study of the TRPC6 inhibitor SH045 in mice by LC-MS/MS
Chai, X.-N.; Ludwig, F.-A.; Müglitz, A.; Gong, Y.; Schaefer, M.; Regenthal, R.; Krügel, U.
Abstract
TRPC6, the sixth member of the family of canonical transient receptor potential (TRP) channels, contributes to a variety of physiological processes and human pathologies. This study extends the knowledge on the newly developed TRPC6 blocker SH045 with respect to its main target organs beyond the description of plasma kinetics. According to the concentration-time course in mice plasma, SH045 is available in pharmacological effective plasma concentrations up to 24 h after administration of 20 mg/kg BW (i.v.) and up to the 5-fold of its IC50 until 6 hours, orally. The short plasma half-life and rather low oral bioavailability are contrasted by its high potency. Dosage limits were not worked out, but absence of safety concerns for 20 mg/kg BW supports further dose exploration. The disposition of SH045 is described. In particular, a high extravascular distribution, most prominent in lung, and a considerable renal elimination of SH045 were observed. SH045 is substrate of CYP3A4 and CYP2A6. Hydroxylated and glucuronidated metabolites were identified under optimized LC-MS/MS conditions. The results guide a reasonable selection of dose and application route of SH045 for target-directed preclinical studies in vivo with one of the rare high potent and subtype-selective TRPC6 inhibitors available.
Keywords: cytochrome P450 enzyme; kidney; larixol; LC-MS/MS; lung; mice; microsomes; pharmacokinetics; toxicity; SH045; TRPC6 inhibitor
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International Journal of Molecular Sciences 23(2022)7, 3635
DOI: 10.3390/ijms23073635
Cited 1 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34218
Prototype system for first-in-human MR-integrated proton therapy combining a 0.32T open MR scanner with a horizontal proton pencil beam scanning beamline
Schneider, S.; Karsch, L.; Hoffmann, A. L.
Abstract
Target audience: Audience interested in image-guided radiation therapy, innovative use-cases for MRI and experimental hardware developments.
Purpose: The physical integration of magnetic resonance imaging (MRI) with proton therapy (PT) into an MR-integrated PT (MRiPT) system is expected to improve the targeting accuracy of PT [1]. However, a successful integration has so far only been achieved in a proof-of-concept study [2], which demonstrated that in-beam MR imaging during proton beam irradiation at a fixed PT beamline is feasible. The purpose of this study was to develop a prototype system combining a low-field MRI scanner with a proton pencil beam scanning (PBS) beamline to enable a first in-human MRiPT treatment. This contribution presents first results of the installation and commissioning of the MRiPT system where the positioning reproducibility, magnet shimming performance and image quality were analyzed.
Methods: The setup consists of an open C-shaped 0.32 T MRI scanner (MRJ3300, ASG Superconductors SpA, Genoa, Italy) positioned in close proximity of the nozzle of a horizontal proton PBS beamline (Figure 1). The MRI scanner, which utilizes a permanent magnet, was encased in a custom-designed compact aluminum Faraday cage. At the location of the beam exit window of the nozzle, a beam entrance opening was incorporated in the wall of the RF cage, which was sealed by a thin (40 µm) aluminum foil to combine high RF attenuation and small lateral spreading of the traversing proton beam. The scanner and RF cage were mounted on top of an air-cushion-based transport platform, allowing the assembly to be accurately positioned in the beam path exiting the nozzle. The maneuvering of the assembly into treatment position was thereby visually guided based on room lasers that intersect at the natural beam isocenter and project onto the outer wall of the cage. The magnet was shimmed in treatment position close to ferromagnetic components of the nozzle where field homogeneity was measured using a magnetic field camera (MFC3045, Metrolab Technology SA, Geneva, Switzerland). During commissioning the MR image quality was assessed both quantitatively and quantitatively using the ACR Small MRI Phantom [3] and images of a healthy volunteer’s extremities acquired in coronal and transversal directions using various scan protocols (T1w SE, T2w TSE, T2w STIR, T1w 3D GE), respectively.
Results: The positioning accuracy and precision of the mobile in-beam MRI system was below 1 mm. A peak-to-peak B0 field homogeneity of 43 ppm over a 25 cm diameter spherical volume (DSV) around the MR magnetic isocenter was achieved during magnet shimming. Phantom imaging revealed a signal-to-noise ratio (SNR) of >80 and a geometric distortion of <1 mm over a 10 cm DSV around the magnetic isocenter. The quality of the MR images was deemed clinically useful for structural imaging and promising for the localization and monitoring of extremity soft-tissue tumors.
Discussion: Tumor visualization capabilities should be further investigated in patients with malignant soft-tissue tumors. A full workflow for patient positioning and irradiation is currently under development, including the development of accurate methods for PT treatment planning and dose verification that take into account the presence of the MR magnetic fields during dose delivery.
Conclusion: A 0.32 T in-beam MRI scanner was successfully installed and commissioned in front of a horizontal proton PBS beamline in preparation for the development of a first clinical prototype MRiPT system. Further developments in patient positioning, dosimetry and treatment planning are indispensable before a first in-human irradiation can be safely performed.
References:
[1] A. Hoffmann et al. 2020 Radiat. Oncol.
[2] S. Schellhammer et al. 2018 Phys. Med. Biol.
[3] Small Phantom Guide 4/17/18. American College of Radiology
Keywords: Magnetic resonance integrated proton therapy; Image guided proton therapy; Magnetic resonance imaging; Proton therapy
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Lecture (others)
(Online presentation)
ISMRM Workshop on Low Field MRI 2022, 17.-18.03.2022, Virtuell, Virtuell
Permalink: https://www.hzdr.de/publications/Publ-34215
Multivariate statistical modelling enhances the predictive power of Prompt Gamma-Ray Timing for proton treatment verification
Schellhammer, S.; Wiedkamp, J.; Löck, S.; Kögler, T.
Abstract
Given its sensitivity to anatomical variations, proton therapy is expected to benefit strongly from reliable on-line treatment verification. As a light-weight, collimator-free technique that can be easily integrated into existing systems, Prompt Gamma-Ray Timing is a promising candidate for this purpose. The development of such a system is challenging, as the proton range delivered in the patient needs to be reconstructed with high accuracy from the temporal distribution of a very limited number of gamma-rays. So far, this reconstruction has been based on the mean and standard deviation of the distribution, but the accuracy of this method was found to be insufficient. We therefore developed multivariate statistical models based on additional histogram characteristics to improve proton range reconstruction.
Prompt Gamma-Ray Timing distributions acquired during pencil beam irradiation of an acrylic glass phantom with air cavities of different thicknesses were analysed. Relevant histogram features were chosen using forward selection and the Least Absolute Shrinkage and Selection Operator (LASSO) from a feature assortment based on recommendations of the Image Biomarker Standardisation Initiative. Candidate models were defined by multivariate linear regression and evaluated based on their coefficient of determination R2 and root mean square error RMSE on an independent dataset.
The newly developed models showed a strongly improved predictive power (R2 > 0.6) compared to the previously used models (R2 < 0.1). These results demonstrate that elaborate statistical modelling is a valuable tool to enhance the Prompt Gamma-Ray Timing method and increase its potential to be used for proton treatment verification.
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Lecture (Conference)
PTCOG 60, 27.06.-02.07.2022, Miami, USA
Permalink: https://www.hzdr.de/publications/Publ-34214
Caenorhabditis elegans microscopy dataset with lifespan, movement and segmentation annotations.
Galimov, E.; Pincus, Z.; Yakimovich, A.
Abstract
The nematode Caenorhabditis elegans (C. elegans) is an established model for studying various interventions into the ageing process, which allowed to find numerous genes and drugs interfering with agein. This dataset of widefield time-lapse (days 1 to 3) &&>&&>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>micrographs of C. elegans was initially obtained in the Pincus lab (Pincus et al. 2011, Zhang et al. 2016). Here, the dataset was annotated for lifespan, movement and segmentation of C. elegans, and was employed for developing a machine learning framework (Yakimovich et al. 2021). &&>&&>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>lt>&&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>nbsp&>&&>lt>nbsp&>lt>lt>&&>lt>nbsp&>lt>All files are in 8-bit PNG format. Movement and lifespan annotations are provided using folder structure. Segmentation annotation is provided by the accompanying masks.
Keywords: C. elegans; Caenorhabditis elegans; lifespan; movement; segmentation; microscopy
Related publications
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Data publication: Caenorhabditis elegans microscopy dataset with lifespan …
ROBIS: 34491 HZDR-primary research data are used by this (Id 34213) publication -
A tandem segmentation-classification approach for the localization of …
ROBIS: 34496 has used this (Id 34213) publication of HZDR-primary research data
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Reseach data in external data repository
Publication year 2022
License: MIT (Link to license text)
Hosted on BioImage Archive: Link to location
Permalink: https://www.hzdr.de/publications/Publ-34213
Plasmonic gratings from highly doped Ge1-y Sn (y) films on Si
Berkmann, F.; Ayasse, M.; Schlipf, J.; Mörz, F.; Weißhaupt, D.; Oehme, M.; Prucnal, S.; Kawaguchi, Y.; Schwarz, D.; Fischer, I. A.; Schulze, J.
Abstract
Plasmonic modes in metal structures are of great interest for optical applications. While metals such as Au and Ag are highly suitable for such applications at visible wavelengths, their high Drude losses limit their usefulness at mid-infrared wavelengths. Highly n-doped Ge1−ySny alloys are interesting possible alternative materials for plasmonic applications in this wavelength range. Here, we investigate the use of highly n-doped Ge1−ySny films grown directly on Si by molecular beam epitaxy with varying Sn-content from 0% up to 7.6% for plasmonic grating structures. We compare plasma wavelengths and relaxation times obtained from electrical and optical characterization. While theoretical considerations indicate that the decreasing effective mass with increasing Sn content in Ge1−ySny films could improve performance for plasmonic applications, our optical characterization results show that the utilization of Ge1−ySny films grown directly on Si is only beneficial if material quality can be improved.
Keywords: GeSn; plasmonics; doping
Involved research facilities
- Ion Beam Center DOI: 10.17815/jlsrf-3-159
Related publications
- DOI: 10.17815/jlsrf-3-159 is cited by this (Id 34212) publication
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Journal of Physics D: Applied Physics 54(2021), 445109
DOI: 10.1088/1361-6463/ac1f51
Cited 3 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34212
A review on fast tomographic imaging techniques and their potential application in industrial process control
Hampel, U.; Babout, L.; Banasiak, R.; Schleicher, E.; Soleimani, M.; Wondrak, T.; Vauhkonen, M.; Lähivaara, T.; Tan, C.; Hoyle, B.; Penn, A.
Abstract
With the ongoing digitalization of industry, imaging sensors are becoming increasingly im-portant for industrial process control. In addition to direct imaging techniques such as those provided by video or infrared cameras, tomographic sensors are of interest in the process indus-try where harsh process conditions and opaque fluids require non-intrusive and non-optical sensing techniques. Because most tomographic sensors rely on complex and often time-multiplexed excitation and measurement schemes and require computationally intensive image reconstruction, their application in the control of highly dynamic processes is often hindered. This article provides an overview of the current state of the art in fast process tomography and its potential for use in industry.
Keywords: Process tomography; Tomographic sensors; Image reconstruction; Industrial process monitoring and control
Involved research facilities
- TOPFLOW Facility
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Sensors 22(2022)6, 2309
DOI: 10.3390/s22062309
Cited 18 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34211
Data for: Spin-wave frequency combs
Hula, T.; Schultheiß, K.; Trindade Goncalves, F. J.; Körber, L.; Bejarano, M.; Copus, M.; Flacke, L.; Liensberger, L.; Buzdakov, A.; Kakay, A.; Weiler, M.; Camley, R.; Faßbender, J.; Schultheiß, H.
Abstract
Data were obtained by means of Brillouin light scattering microscopy, micro magnetic simulations in MuMax3 and analytic calculations.
Keywords: Brillouin light scattering; micro magnetic simulations; spin waves; magnons; nonlinear
Related publications
- DOI: 10.1063/5.0090033 references this (Id 34210) publication
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Data for: Spin-wave frequency combs
ROBIS: 34210 HZDR-primary research data are used by this (Id 34210) publication -
Spin-wave frequency combs
ROBIS: 32565 has used this (Id 34210) publication of HZDR-primary research data -
Data for: Spin-wave frequency combs
ROBIS: 34210 has used this (Id 34210) publication of HZDR-primary research data
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Reseach data in the HZDR data repository RODARE
Publication date: 2022-02-01 Open access
DOI: 10.14278/rodare.1431
Versions: 10.14278/rodare.1432
License: CC-BY-4.0
Downloads
Permalink: https://www.hzdr.de/publications/Publ-34210
Fully Chelating N3O2-Pentadentate Planar Ligands Designed for Strongest and Selective Capture of Uranium from Seawater
Mizumachi, T.; Sato, M.; Kaneko, M.; Takeyama, T.; Tsushima, S.; Takao, K.
Abstract
Based on unique 5-fold equatorial coordination of UO22+, water-compatible pentadentate planar ligands, H2saldian and its derivatives, were designed as strong and selective capture of UO22+ in seawater. In the simulated seawater condition (0.5 M NaCl + 2.3 mM HCO3−/CO32−, pH 8), saldian2− shows the strongest complexation with UO22+ to form UO2(saldian) (log β11 = 27.5), which is more than 10 order of magnitude greater than amidoxime-based or -inspired ligand systems most commonly employed for U capture from seawater. Good selectivity for UO22+ from other metal ions coexisting in seawater was also demonstrated.
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Inorganic Chemistry 61(2022)16, 6175-6181
DOI: 10.1021/acs.inorgchem.2c00306
Cited 5 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34209
Hydrophobic Core Formation and Secondary Structure Elements in Uranyl(VI)–Binding Peptides
Abstract
Cyclic peptides as well as modified EF-hand of calmodulin have been newly designed to achieve high affinity towards uranyl(VI). Cyclic peptides may be engineered to bind uranyl(VI) to its backbone under acidic condition, which may enhance its selectivity. For the modified EF-Hand motif of calmodulin, strong electrostatic interactions between uranyl(VI) and negatively charged side chains play important role in achieving high affinity, however, it is also essential to have secondary structure element and formation of hydrophobic cores in the metal-bound state of the peptide.
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Physical Chemistry Chemical Physics 24(2022), 4455-4461
DOI: 10.1039/D1CP05401E
Cited 2 times in Scopus -
Lecture (Conference)
ATAS-AnXAS-2022, 17.-21.10.2022, Grenoble, France
Permalink: https://www.hzdr.de/publications/Publ-34208
Synthesis and characterization of a uranyl(vi) complex with 2,6-pyridine-bis(methylaminophenolato) and its ligand-centred aerobic oxidation mechanism to a diimino derivative
Takeyama, T.; Iwatsuki, S.; Tsushima, S.; Takao, K.
Abstract
A uranyl(VI) complex with 2,6-bis(3,5-di-tert-butyl-ophenolateaminomethyl) pyridine (UO2(tBu-pdaop), 1) was synthesized and thoroughly characterized by 1H NMR, IR, elemental analysis, and single-crystal XRD. Right after dissolution of complex 1 in pyridine or DMSO, the solutions were pale red, whereas it gradually turned to dark purple under ambient atmosphere. 1H NMR spectra at the initial and final states suggested that both of the two aminomethyl groups in 1 were converted to azomethine ones through aerobic oxidation. Indeed, a uranyl(VI) complex with 2,6-bis(3,5-di-tert-butyl-ophenolateiminomethyl) pyridine (UO2(tBu-pdiop), 2) was obtained from the concentrated solution once the reaction is completed, which was characterized by IR, elemental analysis, and singlecrystal XRD. Kinetic analyses as well as mechanistic study based on quantum chemical calculations suggested that hydrogen atom transfer from one of the amino groups in complex 1 to nearby O2 initiates the stepwise oxidation processes to finally afford 2. To the best of our knowledge, this is the first report on an air-oxidizable uranyl(VI) complex. The present findings demonstrate the novel reactivity of a uranyl(VI) complex, and provide new insights to construct thermally-driven molecular conversion system by a UO22+ complex catalyst.
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Dalton Transactions 51(2022), 6576-6585
DOI: 10.1039/D2DT00325B
Cited 5 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34207
Terahertz control of photoluminescence emission in few-layer InSe
Venanzi, T.; Selig, M.; Pashkin, A.; Winnerl, S.; Katzer, M.; Arora, H.; Erbe, A.; Patanè, A.; Kudrynskyi, Z. R.; Kovalyuk, Z. D.; Baldassarre, L.; Knorr, A.; Helm, M.; Schneider, H.
Abstract
A promising route for the development of new technology is to use terahertz radiation to modulate the optical properties of semiconductors. Here we demonstrate the dynamical control of photoluminescence (PL) emission in few-layer InSe using picosecond terahertz pulses. We observe a strong PL quenching (up to 50%) after the arrival of the terahertz pulse followed by a reversible recovery of the emission on the time scale of 50ps at T =10K.Microscopic calculations reveal that the origin of the photoluminescence quenching is the terahertz absorption by photo-excited carriers: this leads to a heating of the carrier distribution that reduces the overlap of the hole and electron wavefunctions in the proximity of the band edges and, therefore, the luminescence. By numerically evaluating the Boltzmann equation, we are able to clarify the individual roles of optical and acoustic phonons in the subsequent cooling process. The same PL quenching mechanism is expected in other van der Waals semiconductors and the effect will be particularly strong for materials with low carrier masses and long carrier relaxation time, which is the case for InSe. This work gives a solid background for the development of opto-electronic applications based on InSe, such as THz detectors and optical modulators.
Keywords: 2D materials; InSe; photoluminescence; hot carrier response
Involved research facilities
- Radiation Source ELBE DOI: 10.17815/jlsrf-2-58
Related publications
- DOI: 10.17815/jlsrf-2-58 is cited by this (Id 34205) publication
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Data publication: Terahertz control of photoluminescence emission in few-layer …
ROBIS: 36445 HZDR-primary research data are used by this (Id 34205) publication -
Data publication: Terahertz control of photoluminescence emission in few-layer …
RODARE: 2114 HZDR-primary research data are used by this (Id 34205) publication
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Applied Physics Letters 120(2022)9, 092104
DOI: 10.1063/5.0080784
Cited 4 times in Scopus
Downloads
- Open Access Version from aip.scitation.org
- Secondary publication expected
Permalink: https://www.hzdr.de/publications/Publ-34205
Standalone extended gate FET-based multiplexed sensing platform
Janićijević, Ž.; Nguyen Le, T. A.; Baraban, L.
Abstract
Reliable biosensing is crucial in demanding fields such as theranostics and drug discovery. Multiplexing can improve biosensing performance and stability by enabling simultaneous multimarker sensing, more accurate differential measurements, and robust measurement statistics. Biosensing platforms based on field-effect transistors (FETs) comprising extended gate (EG) as a disposable cost-effective sensing element and reusable FET transducer are widely used for electrical label-free detection of biological and chemical analytes. EG electrodes can be modified to detect various analytes while allowing for easy integration of many sensing elements within the same chip. Useful features of EG open the possibility for multiplexed analyte sensing with an EG electrode array and a single FET transducer. Current EG FET-based platforms do not include large-scale multiplexing and rely on external modules such as specialized instruments for electrical measurements and bulky reference electrodes. We present the concept of a standalone EG FET platform for multiplexed sensing based on custom-built electronics interfaced with the EG chip comprising a common integrated reference electrode and microfluidic reservoir. Arduino Uno board enables the digital control of the reed relay-based multiplexing module and FET transducer readout circuit. Readout of the sensor signal is performed by sweeping in constant charge mode. Our platform is a practical and versatile laboratory tool adaptable for sensing different analytes.
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Poster
NanoNet+ Annual Workshop 2021, 21.-23.09.2021, Klingenberg, Deutschland
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Permalink: https://www.hzdr.de/publications/Publ-34204
Flashing Feed and Mist Eliminator Performance at Critical Fluid Properties
Döß, A.; Schubert, M.; Schleicher, E.; Flegiel, F.; Hampel, U.
Abstract
The design and construction of thermal separation equipment for processing mixtures with critical fluid properties, i.e. low surface tensions and viscosities, is challenging. Conventional design rules are hardly applicable and experimental data are limited. The corresponding design uncertainties lead to costly safety margins and oversized equipment. A separation column mockup with refrigerant cycle setup at our TOPFLOW laboratory allows studying isenthalpic feed flashing and knitted mesh separation capacities at such critical conditions. Liquid surface tension and viscosities can reach below 10 mN/m and 0.5 mPas, respectively, at vapor-liquid density differences between 1400 and 937 kg/m³. This study provides a comprehensive analysis of morphologies in the feed pipe evolving downstream a flash valve. Additionally, knitted mesh flooding points were determined and utilized for a modified design approach for mist eliminators.
Keywords: Critical fluid parameters; Refrigerant cycle; Two-phase feed; Droplet separation
Involved research facilities
- TOPFLOW Facility
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Contribution to proceedings
The 12th international conference Distillation & Absorption 2022, 18.-21.09.2022, Toulouse, Frankreich
Proceedings of the 12th international conference Distillation & Absorption 2022 -
Poster
The 12th international conference Distillation & Absorption 2022, 19.-21.09.2022, Toulouse, France
Permalink: https://www.hzdr.de/publications/Publ-34203
Improved Germanium photoswitch for cavity dumping of a free-electron laser
Rana, R.; Klopf, J. M.; Ciano, C.; Singh, A.; Winnerl, S.; Schneider, H.; Helm, M.; Pashkin, O.
Abstract
We demonstrate an optical switch based on gold implanted germanium (Ge:Au) suitable for cavity dumping of a free-electron laser (FEL). We achieve a switching contrast of more than 50 % in a broad range of FEL wavelengths from 6 to 90 µm. A linear relationship between the switching fluence and the frequency of the FEL optical field supported by our simulation highlights the role of a photoinduced finite sub-µm thickness of the reflecting plasma layer. The plasma switch exhibits negligible absorption of the FEL radiation in the ʻoffʼ state and requires only a moderate thermoelectric cooling at incident FEL power of several Watts.
Keywords: Free eletron laser; Photoswitch; Ion implantation; Terahertz radiation
Involved research facilities
- Radiation Source ELBE DOI: 10.17815/jlsrf-2-58
- Ion Beam Center DOI: 10.17815/jlsrf-3-159
Related publications
- DOI: 10.17815/jlsrf-3-159 is cited by this (Id 34202) publication
- DOI: 10.17815/jlsrf-2-58 is cited by this (Id 34202) publication
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Contribution to proceedings
46th International Conference on Infrared, Millimeter and Terahertz Waves (IRMMW-THz) 2021, 29.08.-03.09.2021, Chengdu, China
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Permalink: https://www.hzdr.de/publications/Publ-34202
Self-driven Broadband Photodetector Based on MoSe2/FePS3 Van der Waals n-p Type-II Heterostructures
Duan, J.; Chava, P.; Ghorbani Asl, M.; Lu, Y.; Erb, D.; Hu, L.; Echresh, A.; Rebohle, L.; Erbe, A.; Krasheninnikov, A.; Helm, M.; Zeng, Y.-J.; Zhou, S.; Prucnal, S.
Abstract
2D van der Waals materials with broad-band optical absorption are promising candidates for next-generation UV-vis-NIR photodetectors. FePS3, one of the emerging antiferromagnetic van der Waals materials with a wide bandgap and p-type conductivity, has been reported as an excellent candidate for UV optoelectronics. However, a high sensitivity photodetector with a self-driven mode based on FePS3 has not yet been realized. Here, we report a high-performance and self-powered photodetector based on multilayer MoSe2/FePS3 type-II n-p heterojunction with a working range from 350 to 900 nm. The presented photodetector, operating at zero bias and at room temperature under ambient conditions, exhibits the maximum responsivity (Rmax) of 52 mA W-1 and external quantum efficiency (EQEmax) of 12% at 522 nm, which are better than the characteristics of its individual constituents and many other photodetectors made of 2D heterostructures. The high performance of MoSe2/FePS3 is attributed to the built-in electric field in the MoSe2/FePS3 n-p junction. Our approach provides a promising platform for broadband self-driven photodetector applications.
Keywords: Molybdenum diselenide; Iron Phosphorus Trisulfide; Van der Waals heterojunction; Broadband photodetector; Type-II band alignment
Involved research facilities
- Ion Beam Center DOI: 10.17815/jlsrf-3-159
Related publications
- DOI: 10.17815/jlsrf-3-159 is cited by this (Id 34200) publication
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ACS Applied Materials and Interfaces 14(2022)9, 11927-11936
DOI: 10.1021/acsami.1c24308
Cited 41 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34200
Ores drive operations: Economic geology is the foundation for geometallurgy (geomet)
Olson Hoal, K. E.; Frenzel, M.
Abstract
Economic geology and geometallurgy are intimately linked. Geologists understand the value in knowing the details of ore variability, the formation of mineral deposits, the continuity and the spatial distribution of ore types, and the mineral and textural characteristics that control grades. Beyond exploration and discovery, however, explorers may not recognize that the geological knowledge developed around a mineral prospect is also of great value to the miners and metallurgists, reclamation and environmental specialists, and economists and investors who are interested in developing the discovery. Geometallurgy is the interdisciplinary method that links geological, mineralogical and geochemical characteristics of mineral deposits to the mining, processing, and metallurgical activities that are involved in the development of mines. Geometallurgy is not a new field, but recent developments in analytical capabilities and the ability to conduct predictive, statistical data analysis and modeling of very large data sets have made geometallurgy an impactful and widely used method for optimizing mining operations. While there are many approaches, depending upon the nature of the ore deposit and the mine operating conditions and goals, the most important step explorers can take is to establish partnerships with the other areas of specialization in the project (mining, metallurgy, environmental, economics) and work together to understand the critical factors to use in order to best develop the deposit. Representative sampling of geological variability and understanding the controls of throughput and recovery in the mining operation are fundamental to making projects more effective. Here, we describe some of the technical drivers of geometallurgy as well as workflows and outcomes of which explorers should be aware. For exploration and prefeasibility timelines, information on spatial ore characteristics can provide some preliminary assessment of the processibility of a deposit. These steps can be taken in advance of, during, and in partnership with mine designers and plant flowsheet developers and may help avoid large capital expenditures made on erroneous assumptions of ore characteristics.
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SEG Discovery 129(2022), 30-43
DOI: 10.5382/Geo-and-Mining-15
Permalink: https://www.hzdr.de/publications/Publ-34196
Global tellurium supply potential
Nassar, N.; Kim, H.; Frenzel, M.; Moats, M.; Hayes, S.
Abstract
The transition towards renewable energy generation requires increasing quantities of nonfuel mineral commodities, including tellurium (Te) used in cadmium-telluride based thin-film photovoltaics. While demand for Te may be poised to increase markedly, the potential to increase Te supply is not well-understood. In this analysis, we provide detailed by-country estimates of the quantity of Te contained in anode slimes generated by electrolytic copper (Cu) refining between 1986 and 2018, including uncertainties. We do this by combining all available data on facility-level Cu cathode production and Cu anode compositions. For 2018, the results of Monte Carlo simulations indicate a total of 1,930 t of Te was contained in anode slimes, with the 95% confidence interval ranging from 1,500 to 2,770 t. This quantity is nearly quadruple the reported Te production for the same year (~ 500 t), indicating a great potential to increase Te supplies. The results also indicate that China is not only the largest Te producer but also has the greatest potential to increase Te supplies. However, most of the Te produced by or potentially recoverable from Chinese refineries appears to come from Cu ores mined elsewhere. Translating the physical availability of Te into economic availability requires further research into the costs associated with Te recovery. Nevertheless, this study represents an important development in the assessment of Te supply potential and, further, presents a methodology that could be extended to other byproduct critical elements.
Keywords: critical minerals; solar photovoltaics; minor metals; byproducts; copper
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Resources, Conservation and Recycling 184(2022), 106434
DOI: 10.1016/j.resconrec.2022.106434
Cited 21 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34195
The Dyadic Radionuclide System 60Fe / 53Mn to Distinguish Interstellar from Interplanetary 60Fe
Koll, D.; Faestermann, T.; Korschinek, G.; Leya, I.; Merchel, S.; Wallner, A.
Abstract
The discovery of live 60Fe in a deep-sea crust with proposed interstellar origin followed by evidence
for elevated interplanetary 3He in the same crust raised the question on how to unambiguously identify the true
production site of the identified 60Fe. Here, we show the implementation of the dyadic radionuclide system
60Fe / 53Mn to serve as a tool for the identification of surplus interstellar 60Fe over interplanetary production.
The recent updates in experimental 60Fe and 53Mn data from iron meteorites as well as in production rate models
confirm the validity and robustness of this dyadic system for future applications.
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Contribution to proceedings
Nuclei in the Cosmos, 22.09.2021, Chengdu, China: EPJ
DOI: 10.1051/epjconf/202226011022
Cited 1 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34194
Kinetic Monte-Carlo simulation of exciton hopping: Urbach-tails in gas-molecule decorated MoSe2
Wagner, C.; Schwuchow, M.; Venanzi, T.; Schneider, H.; Winnerl, S.; Thränhardt, A.
Abstract
We quantitatively investigate disorder parameters of gas-molecule decorated monolayer MoSe2. This material system is interesting because disorder may be introduced and removed at will by regulating the number of adsorbed gas molecules through laser annealing. These molecules electrostatically trap excitons leading to localized defect states, which are exponentially distributed in energy. Here, experiments are described by kinetic Monte-Carlo simulations, in summary enabling richer studies than within crystalline materials with a fixed degree of disorder. We find that the surface coverage of the MoSe2 may reach up to one molecule per 2nm2 and that the density of adsorbed molecules depends on the laser power by a power law.
Keywords: two-dimensional materials; dichalcogenide; molybdenum selenide; optical properties; low temperature; disorder; Urbach tail
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Physica Status Solidi (B) 258(2021)11, 2100186
DOI: 10.1002/pssb.202100186
Permalink: https://www.hzdr.de/publications/Publ-34193
Complex quantum dots in III-As nanowires
Hilliard, D.; Tauchnitz, T.; Hübner, R.; Schneider, H.; Helm, M.; Dimakis, E.
Abstract
Single quantum dots embedded in the core of freestanding semiconductor nanowires grown directly on Si offer a novel and promising scheme for the realization of on-demand sources of single photons or entangled photon pairs in quantum technology systems. The primary challenge in using the nanowire growth medium lies in reducing the compositional grading effect of the axial barrier’s constituent materials.
Here, we have investigated the Ga-catalyzed vapor-liquid-solid growth mechanism and optical properties of axial GaAs quantum dots confined between two Al(x)Ga(1-x)As/Al(y)Ga(1-y)As short-period superlattices inside GaAs/InxAl(1-x)As and GaAs/Al(x)Ga(1-x)As core/shell nanowires. By increasing the interfacial abruptness between the axial barrier and quantum dot, its relevance was highlighted by significant improvements in the quantum dot emission linewidth. Using tensile strain, the tuneabilty of the quantum dot emission energy was clearly demonstrated across a wide range of wavelengths by employing lattice mismatched InxAl1-xAs shells as radial barriers, showing the potential for telecom band access.
Keywords: Nanowire; Quantum dot; Superlattice; Interface; Strain
Involved research facilities
- Ion Beam Center DOI: 10.17815/jlsrf-3-159
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- DOI: 10.17815/jlsrf-3-159 is cited by this (Id 34192) publication
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Poster
(Online presentation)
From Matter to Materials and Life (MML), 22.-24.11.2021, Dresden, Deutschland
Permalink: https://www.hzdr.de/publications/Publ-34192
Complex quantum dots in III-As nanowires
Hilliard, D.; Tauchnitz, T.; Hübner, R.; Schneider, H.; Helm, M.; Dimakis, E.
Abstract
Single quantum dots embedded in the core of freestanding semiconductor nanowires grown directly on Si offer a novel and promising scheme for the realization of on-demand sources of single photons or entangled photon pairs in quantum technology systems. Here, we have investigated the growth mechanism and optical properties of axial quantum dots embedded in GaAs nanowires grown in self-catalyzed vapor-liquid-solid mode while demonstrating the tuneabilty of their emission energy across a wide range of wavelengths with the potential for telecom band access.
We have incorporated GaAs complex quantum dots inside GaAs/In(x)Al(1-x)As and GaAs/Al(x)Ga(1-x)As core/shell nanowires grown via our nanowire growth technique called droplet-confined alternate pulsed-epitaxy (DCAPE)[1] (an adaptation of conventional molecular beam epitaxy (MBE)), which grants precise control over the axial growth rate and droplet composition. Using a combination of conventional MBE and DCAPE the growth of highly symmetrical quantum dots, as little as 10 nm in diameter and just a few nanometers in height, were made possible. Strong axial confinement was achieved in the form of a double axial heterostructure by incorporating two Al(x)Ga(1-x)As/Al(y)Ga(1-y)As short-period superlattices separated by a thin GaAs segment (figure 1(a)). The complexity of our quantum dots is derived from the unique possibility of using different ternary alloys for the axial and radial confinement. By introducing a latticed mismatched ternary alloy shell as the radial barrier (In(x)Al(1-x)As), we demonstrated controlled hydrostatic strain induced redshifts of the highly polarized quantum dot emission energy by adjusting the In content of the shell. For 39% In we measured a redshift in the quantum dot emission of 320 meV, from an unstrained quantum dot reference (Al(x)Ga(1-x)As shell), as shown by the photoluminescence measurements in figure 1 (b).
To optimize the emission quality, the compositional grading effect of the constituent superlattice materials across the interfaces must be addressed. High-angle annular dark-field scanning transmission electron microscopy, energy-dispersive X-ray spectroscopy, and nanowire growth models were utilized to gain an understanding of the compositional grading mechanism at the quantum dot/superlattice interface. We found that interfacial sharpness increases significantly by reducing the superlattice growth temperature and nanowire radius. Notwithstanding, limitations in what can be achieved ensue and possible strategies to overcome them will be presented.
[1] Balaghi et al., Nano Lett. 16, 4032 (2016)
Keywords: Nanowire; Quantum dot; Superlattice; Interface; Strain
Involved research facilities
- Ion Beam Center DOI: 10.17815/jlsrf-3-159
Related publications
- DOI: 10.17815/jlsrf-3-159 is cited by this (Id 34191) publication
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Lecture (Conference)
(Online presentation)
24th International Conference on Electronic Properties of Two-Dimensional Systems / 20th International Conference on Modulated Semiconductor Structures (EP2DS-24/MSS-20), 31.10.-05.11.2021, Toyama, Japan
Permalink: https://www.hzdr.de/publications/Publ-34191
Al(x)Ga(1-x)As /Al(y)Ga(1-y)As axial short-period superlattices in self-catalyzed nanowires
Hilliard, D.; Tauchnitz, T.; Hübner, R.; Schneider, H.; Helm, M.; Dimakis, E.
Abstract
Short-period superlattices have diverse functionality in electronic and optoelectronic devices. Implementing such systems as axial heterostructures in freestanding semiconducting nanowires further broadens the scope of potential applications, for example: distributed Bragg reflectors, high-efficiency light-emitting diodes, and quantum dot heterostructures. The challenge, however, lies in reducing the compositional grading effect of the constituent superlattice materials across the interfaces in nanowires grown in vapor-liquid-solid mode.
Here, our previously developed nanowire growth technique called droplet-confined alternate pulsed-epitaxy[1] (an adaptation of conventional molecular beam epitaxy), which grants precise control over the axial growth rate and droplet composition, was employed to grow Al(x)Ga(1-x)As/Al(y)Ga(1-y)As axial superlattices in self-catalyzed GaAs nanowires with diameters as thin as 25 nm. High-angle annular dark-field scanning transmission electron microscopy, energy-dispersive X-ray spectroscopy, and growth models were utilized to gain an understanding of the compositional grading mechanism. By varying several growth parameters involving growth temperature, nanowire diameter, and droplet contact angle, the link between them and the superlattice characteristics was explored. We found that interfacial abruptness increases significantly by reducing the superlattice growth temperature and nanowire radius. Moreover, we studied the impact of an unstable contact angle on the superlattice growth rate, showing good agreement with analytical growth models and demonstrating the importance of growth rate stability in obtaining reproducible Al contents across successive superlattice periods.
Finally, we confirmed with monolayer resolution, controlled Al contents in the whole compositional range and superlattice period widths of just a few monolayers. Notwithstanding, limitations in what can be accomplished are present and possible strategies to overcome them will be presented. The quality of our short-period superlattices was successfully tested via their employment as barriers in quantum dot nanowire heterostructures.
[1] Balaghi et al., Nano Lett. 16, 4032 (2016)
Keywords: Nanowire; Quantum dot; Superlattice; Interface
Involved research facilities
- Ion Beam Center DOI: 10.17815/jlsrf-3-159
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- DOI: 10.17815/jlsrf-3-159 is cited by this (Id 34190) publication
-
Lecture (Conference)
(Online presentation)
European Congress and Exhibition on Advanced Materials and Processes (EUROMAT 2021), 13.-17.09.2021, Wien, Österreich
Permalink: https://www.hzdr.de/publications/Publ-34190
Al(x)Ga(1-x)As /Al(y)Ga(1-y)As axial short-period superlattices in self-catalyzed nanowires
Hilliard, D.; Tauchnitz, T.; Hübner, R.; Schneider, H.; Helm, M.; Dimakis, E.
Abstract
Shrt abstract:
Using our nanowire growth technique called droplet-confined alternate pulsed-epitaxy, which provides precise control over the axial growth rate and droplet composition, the growth mechanism of self-catalyzed GaAs epitaxial nanowires containing AlxGa1-xAs/AlyGa1-yAs axial short-period superlattices, was systematically examined. Significant increases in interfacial abruptness were confirmed by reducing the nanowire diameter and superlattice growth temperature. Additionally, we found that an unstable droplet contact angle impacts the superlattice growth rate considerably. The unique versatility of our short-period superlattices was tested by using them as axial barriers for GaAs quantum dot heterostructures embedded in nanowires. Furthermore, encapsulating the nanowire in lattice-mismatched shells operating as radial barriers, we demonstrated the tuneabilty of the quantum dot emission energy via strain engineering.
Long abstract
Short-period superlattices have diverse functionality in electronic and optoelectronic devices. Implementing such systems as axial heterostructures in freestanding semiconducting nanowires further broadens the scope of potential applications, for example: distributed Bragg reflectors, high-efficiency light-emitting diodes, and quantum dot heterostructures. The challenge, however, lies in reducing the compositional grading effect of the constituent superlattice materials across the interfaces in nanowires grown in self-catalyzed vapor-liquid-solid mode.
Here, our previously developed nanowire growth technique called droplet-confined alternate pulsed-epitaxy[1] (an adaptation of conventional molecular beam epitaxy), which grants precise control over the axial growth rate and droplet composition, was employed to grow Al(x)Ga(1-x)As/Al(y)Ga(1-y)As axial superlattices in self-catalyzed GaAs nanowires with diameters as thin as 20 nm. High-angle annular dark-field scanning transmission electron microscopy (figure 1(a)), energy-dispersive X-ray spectroscopy, and growth models were utilized to gain an understanding of the compositional grading mechanism. By varying several growth parameters involving growth temperature, nanowire diameter, and droplet contact angle, the link between them and the superlattice characteristics was explored. We found that interfacial abruptness increases significantly by reducing the superlattice growth temperature and nanowire radius. Moreover, we studied the impact of an unstable contact angle on the superlattice growth rate, showing good agreement with analytical growth models and demonstrating the importance of growth rate stability in obtaining reproducible Al contents across successive superlattice periods. We confirmed with monolayer resolution, controlled Al contents in a wide compositional range and superlattice period widths of just a few monolayers (figure 1 (b)).
The quality of our short-period superlattices was successfully tested via their employment as axial barriers in quantum dot nanowire heterostructures (figure 1 (c)). Additionally, by introducing a lattice-mismatched ternary alloy shell as the radial barrier (In(x)Al(1-x)As in this case), we demonstrated controlled strain-induced redshifts of the quantum dot emission energy by adjusting the In content of the shell. For 39% In, we measured a redshift in the quantum dot emission of 180 meV as shown by the photoluminescence measurements in figure 1 (d). Notwithstanding, limitations in what can be accomplished are present and possible strategies to overcome them will be presented.
[1] Balaghi et al., Nano Lett. 16, 4032 (2016)
Keywords: Nanowire; Quantum dot; Superlattice; Interface; Strain
Involved research facilities
- Ion Beam Center DOI: 10.17815/jlsrf-3-159
Related publications
- DOI: 10.17815/jlsrf-3-159 is cited by this (Id 34189) publication
-
Lecture (Conference)
(Online presentation)
21st International Conference on Molecular Beam Epitaxy (21st ICMBE), 06.-09.09.2021, Puerto Vallarta, Mexico
Permalink: https://www.hzdr.de/publications/Publ-34189
Characterization of protein corona formation on nanoparticles via the analysis of dynamic interfacial properties: Bovine serum albumin - silica particle interaction
Shourni, S.; Javadi, A.; Hosseinpour, N.; Bahramian, A.; Raoufi, M.
Abstract
Protein corona adsorption layers on nanoparticle surfaces, dispersed in biological fluids, can significantly change the interfacial interactions, reactivity, and mobility of the original nanoparticles designed as a drug carrier or existing as bioaerosols, bacteria, or viruses. The evaluation of the level of interactions (hard/soft corona), dispersion stability, and the ratio of the attached proteins per nanoparticle are essential parameters for the characterization of the protein corona formation on nanoparticle (PCN). In spite of development of several experimental techniques for this purpose, still more powerful, economical and fast measuring techniques are needed to work in-situ at original solution samples (near the physiological conditions), without requirement of additional sample preparation which can change the quality/quantity of the original interactions. In this study, a novel experimental protocol based on the analysis of dynamic interfacial properties (ADIP) is developed for in-situ evaluation of the protein–nanoparticle interactions under original conditions. For this purpose, dynamic surface tension and interfacial elasticity values of the bovine serum albumin (BSA) solutions alone and in mixed solutions with silica nanofluids are measured using drop profile analysis tensiometry. A considerable difference between the dynamic surface tension of BSA and protein corona solutions (BSA + SiO2 NPs complexes) demonstrates significant adsorption of the protein molecules at nanoparticles, confirmed by Fourier Transform Infrared Spectroscopy (FTIR) analysis. PCN complexes illustrate much slower kinetics of adsorption due to a smaller diffusion coefficient according to their larger size. The free proteins available in the solution were estimated considering early-time values of the dynamic surface tension, used for estimation of the adsorbed proteins per unit area of the silica surface (mol/cm2), considering the initial protein concentration in the bulk. The results show very good agreement with others’ results provided by AFM, DLS, UV–vis Spectroscopy, Multi-Parametric Surface Plasmon Resonance (MP-SPR), and Quartz Crystal Microbalance (QCM). Our novel experimental protocols and data analysis, demonstrates promising results for differentiation of the hard and soft corona layers, and unique for soft corona layer recognition, which is difficult by other available techniques, due to quick disturbances of weak protein-protein interaction in soft corona. The measured interfacial elasticity values confirm PCN formation and provides additional information for better differentiations of the corona layers.
Keywords: Protein corona on nanoparticle (PCN); Bovine serum albumin (BSA); SiO2 nanoparticles; Dynamic surface tension; Kinetics of adsorption; Interfacial elasticity; Drug delivery
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Data publication: Characterization of protein corona formation on …
ROBIS: 34470 HZDR-primary research data are used by this (Id 34188) publication
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Colloids and Surfaces A: Physicochemical and Engineering Aspects 638(2022), 128273
DOI: 10.1016/j.colsurfa.2022.128273
Cited 14 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-34188
Experimental techniques to study protein–surfactant interactions: New insights into competitive adsorptions via drop subphase and Interface exchange
Javadi, A.; Dowlati, S.; Shourni, S.; Miller, R.; Kraume, M.; Kopka, K.; Eckert, K.
Abstract
Experimental techniques to study protein–surfactant interactions: New insights into competitive adsorptions via drop subphase and Interface exchange
Keywords: Protein–surfactant interactions; Mixed adsorbed layers; Coaxial double capillary; Profile analysis tensiometry; Dynamic surface properties; Bovin serum albumin; Lysozyme; Lipase Enzyme
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Advances in Colloid and Interface Science 301(2022), 102601
DOI: 10.1016/j.cis.2022.102601
Cited 25 times in Scopus
Downloads
Permalink: https://www.hzdr.de/publications/Publ-34186
Studies of Pyrroloquinoline Quinone Species in Solution and in Lanthanide-dependent Methanol Dehydrogenases
Al Danaf, N.; Kretzschmar, J.; Jahn, B.; Singer, H.; Pol, A.; Op Den Camp, H. J. M.; Steudtner, R.; Lamb, D. C.; Drobot, B.; Daumann, L. J.
Abstract
Pyrroloquinoline quinone (PQQ) is a redox cofactor in calcium- and lanthanide-dependent alcohol dehydrogenases that has been known and studied for over 40 years. Despite its long history, many questions regarding its fluorescence properties, speciation in solution and in the active site of alcohol dehydrogenase remain open. Here we investigate the effects of pH and temperature on the distribution of different PQQ species (H₃PQQ to PQQ³⁻ as well as water adducts and in complex with lanthanides (Lns)) using NMR and UV-Vis spectroscopy as well as time-resolved laser-induced fluorescence spectroscopy (TRLFS). Using a europium derivative from a new, recently-discovered class of lanthanide-dependent methanol dehydrogenase (MDH) enzymes, we utilized two techniques to monitor Ln binding to the active sites of these enzymes. Using TRLFS, we were able to follow Eu(III) binding directly to the active site of MDH using its luminescence and could quantify three Eu states: Eu in the active site of MDH, but also in solution as PQQ-bound Eu and in the aquo-ion form. Additionally, we used the antenna effect to study PQQ and simultaneously Eu in the active site.
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Physical Chemistry Chemical Physics 24(2022), 15397-15405
DOI: 10.1039/D2CP00311B
Cited 3 times in Scopus
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- Final Draft PDF 2,8 MB Secondary publication
Permalink: https://www.hzdr.de/publications/Publ-34185
Data publication: Terahertz-Induced Energy Transfer from Hot Carriers to Trions in a MoSe2 Monolayer
Venanzi, T.; Selig, M.; Winnerl, S.; Pashkin, A.; Knorr, A.; Helm, M.; Schneider, H.
Abstract
Orginaldaten der in der Publikation verwendet Bilder
Keywords: 2D materials; terahertz; hot carriers; trions; MoSe2
Involved research facilities
- Radiation Source ELBE DOI: 10.17815/jlsrf-2-58
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- DOI: 10.17815/jlsrf-2-58 is cited by this (Id 34184) publication
- DOI: 10.1021/acsphotonics.1c00394 references this (Id 34184) publication
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Terahertz-Induced Energy Transfer from Hot Carriers to Trions in a MoSe2 …
ROBIS: 34182 has used this (Id 34184) publication of HZDR-primary research data
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Reseach data in the HZDR data repository RODARE
Publication date: 2022-01-31 Open access
DOI: 10.14278/rodare.1429
Versions: 10.14278/rodare.1430
License: CC-BY-4.0
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Permalink: https://www.hzdr.de/publications/Publ-34184
Terahertz-Induced Energy Transfer from Hot Carriers to Trions in a MoSe2 Monolayer
Venanzi, T.; Selig, M.; Winnerl, S.; Pashkin, A.; Knorr, A.; Helm, M.; Schneider, H.
Abstract
Interaction of terahertz (THz) radiation with van der Waals semiconductors represents a considerable interest for optoelectronic applications. Here we report a redshift (around 1 meV) of the trion resonance in the MoSe2 monolayer induced by picosecond THz pulses. As its origin, we identify the kinetic excess energy gained by hot carriers due to absorption of THz light which is transferred during the formation of trions. By performing time-resolved measurements, we have determined the electron cooling time (tau = 70 ps) and estimated the absorption at 7.7 THz (α = 0.3%). A quantitative model based on the Heisenberg equation of motion explains the experimental observations and can reproduce the data with good accuracy. The present work gives important insights for understanding the trions in van der Waals semiconductors and their interaction with hot electrons driven by THz radiation.
Keywords: 2D materials; terahertz; hot carriers; trions; MoSe2
Involved research facilities
- Radiation Source ELBE DOI: 10.17815/jlsrf-2-58
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- DOI: 10.17815/jlsrf-2-58 is cited by this (Id 34182) publication
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Data publication: Terahertz-Induced Energy Transfer from Hot Carriers to …
ROBIS: 34184 HZDR-primary research data are used by this (Id 34182) publication
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ACS Photonics 8(2021), 2931-2939
DOI: 10.1021/acsphotonics.1c00394
Cited 9 times in Scopus
Downloads
- Final Draft PDF 2 MB Secondary publication
Permalink: https://www.hzdr.de/publications/Publ-34182
Ultrafast Pump-Probe Spectroscopy of BaFe₂As₂ under High Pressures
Fotev, I.; Aswartham, S.; Büchner, B.; Schneider, H.; Helm, M.; Pashkin, O.
Abstract
An important member of the iron-based high-temperature superconductor family, BaFe₂As₂ undergoes a transition to a spin-density wave (SDW) state on cooling below 137 K. Under application of external pressure the SDW transition temperature gradually decreases, and the SDW phase gets completely suppressed above 3 GPa, enabling the onset of superconductivity. Such phenomenon is often referred to as quantum phase transition. Optical pump-probe spectroscopy has been used previously to investigate the dynamics of the SDW and the superconducting order at various temperatures and different doping levels. However, a direct study of the quantum phase transition induced by external high pressure has not been carried out until now.
In our study, pump and probe pulses with the central wavelength of 800 nm were focused onto the sample inside the diamond anvil cell, mounted inside a cryostat. The reflected probe signal was collected using a confocal microscopy scheme. From the measured pump-probe traces the quasiparticle lifetimes and the condensation energy of the SDW state were obtained at various pressures up to 4.4 GPa and the fixed temperature of 8 K. The SDW condensation energy decreases with pressure, and already below 4.4 GPa the SDW state is completely suppressed. At the same time, the decrease of the condensation energy is accompanied by the increase of the quasiparticle lifetimes. Since the lifetimes should be inversely proportional to the SDW gap energy, this critical slowing down of the quasiparticle relaxation dynamics confirms the vanishing of the SDW gap at the quantum phase transition.
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Poster
International Conference on Low Energy Electrodynamics in Solids (LEES), 28.06.-08.07.2021, Portland, Maine, USA
Permalink: https://www.hzdr.de/publications/Publ-34181
BaFe₂As₂ Investigated by Pump-Probe Spectroscopy under High Pressures
Fotev, I.; Aswartham, S.; Büchner, B.; Schneider, H.; Helm, M.; Pashkin, O.
Abstract
We utilize pump-probe spectroscopy at pressures in the GPa range to measure the quasiparticle relaxation dynamics of BaFe₂As₂. The results reveal the pressure dependences of the spin-density wave condensate energy and the photoexcited quasiparticle lifetimes.
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Contribution to proceedings
CLEO Conference, 09.-14.05.2021, San Jose, California, USA: OSA -
Lecture (Conference)
(Online presentation)
CLEO Conference, 09.-14.05.2021, San Jose, California, USA
Permalink: https://www.hzdr.de/publications/Publ-34180
Subsecond Thermal Processing Using Flash Lamps for the Nanoscale and Beyond
Skorupa, W.; Prucnal, S.; Cherkouk, C.; Zhou, S. Q.; Rebohle, L.
Abstract
Undoubtedly, thermal activation processes in advanced materials technologies underwent a dramatic development during the last 40 years. Especially, the use of lasers and lamps allowed the move from long time (10 min to several hours) to short time (several fs-1 min) annealing approaches. From the application viewpoint, the main driver was semiconductor-based chip technology. After 1980, annealing with halogen lamp arrangements allowed annealing times in the range of 10 min and below arriving in advanced chip technology the limit of about 1 sec around the year 2000. To reach annealing times down to the ns range lasers and xenon-filled flash lamps came on stream. In this talk a short introduction to flash lamp annealing technology will be presented together with a few promising research approaches: dissolution of point defect clusters, doping of 2D materials, lithium battery electrode engineering.
Keywords: subsecond thermal processing; flash lamp annealing; silicon; 2D materials; lithium battery electrode; point defects
Involved research facilities
- Ion Beam Center DOI: 10.17815/jlsrf-3-159
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- DOI: 10.17815/jlsrf-3-159 is cited by this (Id 34179) publication
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Lecture (Conference)
International Symposium on Nanostructure Research, 19.-21.09.2021, Leoben, Oesterreich
Permalink: https://www.hzdr.de/publications/Publ-34179
Anisotropic nonlinear terahertz response of bilayer graphene
Seidl, A.; Anvari, R.; Dignam, M. M.; Richter, P.; Seyller, T.; Schneider, H.; Helm, M.; Winnerl, S.
Abstract
We studied the pump-induced anisotropy of the intraband excitation
in bilayer graphene in degenerate terahertz pump-probe experiments.
The differential transmission signal increases approximately linearly
with the excitation field, in qualitative agreement with our microscopic
model.
Keywords: bilayer graphene; pump-probe; density matrix formalism; anisotropy; terahertz
Involved research facilities
- Radiation Source ELBE DOI: 10.17815/jlsrf-2-58
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- DOI: 10.17815/jlsrf-2-58 is cited by this (Id 34178) publication
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Lecture (Conference)
(Online presentation)
The European Conference on Lasers and Electro-Optics, 23.06.2021, digital, digital
Permalink: https://www.hzdr.de/publications/Publ-34178
Spectroscopy on Landau-quantized charge neutral graphene
Seidl, A.; Lara-Avila, S.; Orlita, M.; Wyzula, J.; Anvari, R.; Dignam, M.; Schneider, H.; Helm, M.; Winnerl, S.
Abstract
Landau level spectroscopy is a powerful tool to determine the Fermi velocity in Dirac-like
materials. In our study, we investigate the optical properties of charge neutral graphene on
SiC in presence of strong magnetic fields applied perpendicularly to the sample. For details
about this neutral large-area monolayer graphene, see [1]. We measured the linear
transmission in dependence of the magnitude of the magnetic fields from 0 to 8 T for photon
energies up to 100 meV. We observe a broad resonance resulting from the LL-1(LL0)→LL0(LL1)
transition. It corresponds to a low Fermi velocity of 0.85x106 m/s, which is the limit of low
electron-electron interaction [2]. The efficient screening is supported by the dielectric
environment of the polymer layer on top of the graphene [3]. We support our understanding
of the low Fermi velocity by density functional theory (DFT) calculations. In addition, we
studied the dynamics of the LL-1→LL0 and LL0→LL1 transitions using circularly polarized light
at 75 meV. We observe a fast decay of about 10 ps. Addressing the transitions with all four
combinations of pump and probe beam polarizations, we obtain only one negative
differential transmission signal. Following [4], we attribute this and the fast decay to very
efficient Auger scattering processes. The observed fluence dependence of the relaxation
with time constants decreasing with increasing fluence is also in accordance with this
interpretation.
[1] H. He, K. H. Kim, A. Danilov et al., Nat. Comm., 9, (2018) 3956.
[2] D. Siegel, C.-H. Park, C. Hwang et al., PNAS, 108, 28 (2011) pp. 11365-11369.
[3] P. Yadav and S. Ghosh, AIP Conference Proceedings, 1665, (2015) 050075.
[4] M. Mittendorff, F. Wendler, E. Malic et al., Nat. Phys., 11 (2015) pp. 75-81.
Keywords: charge-neutral; graphene; pump-probe; screening
Involved research facilities
- Radiation Source ELBE DOI: 10.17815/jlsrf-2-58
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- DOI: 10.17815/jlsrf-2-58 is cited by this (Id 34177) publication
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Lecture (Conference)
Graphene 2021, 28.10.2021, Grenoble, Frankreich
Permalink: https://www.hzdr.de/publications/Publ-34177
Pages: [1.] [2.] [3.] [4.] [5.] [6.] [7.] [8.] [9.] [10.] [11.] [12.] [13.] [14.] [15.] [16.] [17.] [18.] [19.] [20.] [21.] [22.] [23.] [24.] [25.] [26.] [27.] [28.] [29.] [30.] [31.] [32.] [33.] [34.] [35.] [36.] [37.] [38.] [39.] [40.] [41.] [42.] [43.] [44.] [45.] [46.] [47.] [48.] [49.] [50.] [51.] [52.] [53.] [54.] [55.] [56.] [57.] [58.] [59.] [60.] [61.] [62.] [63.] [64.] [65.] [66.] [67.] [68.] [69.] [70.] [71.] [72.] [73.] [74.] [75.] [76.] [77.] [78.] [79.] [80.] [81.] [82.] [83.] [84.] [85.] [86.] [87.] [88.] [89.] [90.] [91.] [92.] [93.] [94.] [95.] [96.] [97.] [98.] [99.] [100.] [101.] [102.] [103.] [104.] [105.] [106.] [107.] [108.] [109.] [110.] [111.] [112.] [113.] [114.] [115.] [116.] [117.] [118.] [119.] [120.] [121.] [122.] [123.] [124.] [125.] [126.] [127.] [128.] [129.] [130.] [131.] [132.] [133.] [134.] [135.] [136.] [137.] [138.] [139.] [140.] [141.] [142.] [143.] [144.] [145.] [146.] [147.] [148.] [149.] [150.] [151.] [152.] [153.] [154.] [155.] [156.] [157.] [158.] [159.] [160.] [161.] [162.] [163.] [164.] [165.] [166.] [167.] [168.] [169.] [170.] [171.] [172.] [173.] [174.] [175.] [176.] [177.] [178.] [179.] [180.] [181.] [182.] [183.] [184.] [185.] [186.] [187.] [188.] [189.] [190.] [191.] [192.] [193.] [194.] [195.] [196.] [197.] [198.] [199.] [200.] [201.] [202.] [203.] [204.] [205.] [206.] [207.] [208.] [209.] [210.] [211.] [212.] [213.] [214.] [215.] [216.] [217.] [218.] [219.] [220.] [221.] [222.] [223.] [224.] [225.] [226.] [227.] [228.] [229.] [230.] [231.] [232.] [233.] [234.] [235.] [236.] [237.] [238.] [239.] [240.] [241.] [242.] [243.] [244.] [245.] [246.] [247.] [248.] [249.] [250.] [251.] [252.] [253.] [254.] [255.] [256.] [257.] [258.] [259.] [260.] [261.] [262.] [263.] [264.] [265.] [266.] [267.] [268.] [269.] [270.] [271.] [272.] [273.] [274.] [275.] [276.] [277.] [278.] [279.] [280.] [281.] [282.] [283.] [284.] [285.] [286.] [287.] [288.] [289.] [290.] [291.] [292.] [293.] [294.] [295.] [296.] [297.] [298.] [299.] [300.] [301.] [302.] [303.] [304.] [305.] [306.] [307.] [308.] [309.] [310.] [311.] [312.] [313.] [314.] [315.] [316.] [317.] [318.] [319.] [320.] [321.] [322.] [323.] [324.] [325.] [326.] [327.] [328.] [329.] [330.] [331.] [332.] [333.] [334.] [335.] [336.] [337.] [338.] [339.] [340.] [341.] [342.] [343.] [344.] [345.] [346.] [347.] [348.] [349.] [350.] [351.] [352.]