Publications Repository - Helmholtz-Zentrum Dresden-Rossendorf

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34106 Publications

Ultrafast carrier dynamics in nitrogen containing GaAs

Sinning, S.; Dekorsy, T.; Helm, M.; Mussler, G.; Daweritz, L.; Ploog, K. H.

Poster of experimental results of time resolved carrier dynamics of nitrogen containing GaAs.

Keywords: GaNAs; Nitrogen; III-V; ultrafast; carrier dynamics

  • Poster
    presented at the EMRS 2004, Strasbourg, France, May 24-28, 2004

Permalink: https://www.hzdr.de/publications/Publ-6713
Publ.-Id: 6713


Magnetic field controlled solidification of Nd-Fe-B melts

Hermann, R.; Filip, O.; Gerbeth, G.; Priede, J.; Shatrov, V.

The reduction of the a-Fe volume fraction and the a-Fe grain size represents a known objective for the improvement of this magnet material. It is attained here by a controlled influence on the melt flow via tailored magnetic fields. The reduction of the internal melt motion results in a significant decrease of the a-Fe volume fraction in the solidified Nd-Fe-B material.

  • Poster
    Konferenz "High performance magnets and their applications", Annecy (France), 29.8.-2.9.2004

Permalink: https://www.hzdr.de/publications/Publ-6712
Publ.-Id: 6712


Multiplicity correlations of intermediate-mass fragments with pions and fast protons in C-12+Au-197

Turzo, K.; Auger, G.; Begemann-Blaich, M.; Et Al.

Low-energy pi(+) (E-pi less than or similar to 35 MeV) from C-12 + Au-197 collisions at incident energies from 300 to 1800 MeV per nucleon were detected with the Si-Si(Li)-CsI(Tl) calibration telescopes of the INDRA multidetector. The inclusive angular distributions are approximately isotropic, consistent with multiple rescattering in the target spectator. The multiplicity correlations of the low-energy pions and of energetic protons (E-p greater than or similar to 150 MeV) with intermediate-mass fragments were determined from the measured coincidence data. The deduced correlation functions 1 + R approximate to 1.3 for inclusive event samples reflect the strong correlations evident from the common impact parameter dependence of the considered multiplicities. For narrow impact parameter bins (based on charged-particle multiplicity), the correlation functions are close to unity and do not indicate strong additional correlations. Only for pions at high particle multiplicities (! central collisions) a weak anticorrelation is observed, probably due to a limited competition between these emissions. Overall, the results are consistent with the equilibrium assumption made in statistical multifragmentation scenarios. Predictions obtained with intranuclear-cascade models coupled to the Statistical Multifragmentation Model are in good agreement with the experimental data.

Permalink: https://www.hzdr.de/publications/Publ-6711
Publ.-Id: 6711


Dendritic Carriers and Cage Compounds for Radionuclides

Stephan, H.

  • Invited lecture (Conferences)
    Kolloquium, Department of Materials Science, JAERI, Tokai-mura (Japan), 26.11.2003

Permalink: https://www.hzdr.de/publications/Publ-6709
Publ.-Id: 6709


Solvent Extraction As a Helpful Tool for the Characterisation of Supramolecular Receptors

Stephan, H.

  • Invited lecture (Conferences)
    Kolloquium, Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, Tokyo (Japan), 25.11.2003

Permalink: https://www.hzdr.de/publications/Publ-6708
Publ.-Id: 6708


Novel Approaches for Binding Therapeutically Relevant Copper and Rhenium Radionuclides

Stephan, H.

  • Invited lecture (Conferences)
    Kolloquium, Department of Chemistry, Tohoku University, Sendai (Japan), 19.11.2003

Permalink: https://www.hzdr.de/publications/Publ-6707
Publ.-Id: 6707


Development of Rhenium Complexes and Metal Clusters for Therapy

Stephan, H.

  • Invited lecture (Conferences)
    Kolloquium, Department of Applied Chemistry, Saga University, Saga (Japan), 14.11.2003
  • Invited lecture (Conferences)
    Kolloquium, Department och Chemical Processes and Environments, University Kitakyushu, Kitakyushu, Japan, 11.11.2003

Permalink: https://www.hzdr.de/publications/Publ-6706
Publ.-Id: 6706


Development of Highly Stable Rhenium Complexes

Stephan, H.

  • Invited lecture (Conferences)
    Kolloquium, Department of Chemical Processes and Environments, University Kitakyushu, Kitakyushu (Japan), 11.11.2003

Permalink: https://www.hzdr.de/publications/Publ-6705
Publ.-Id: 6705


Design of a Travelling Magnetic Field for Vertical Gradient Freeze - Crystal Growth

Lantzsch, R.; Galindo, V.; Gerbeth, G.; Cröll, A.

The melt flow in the vertical Gradient Freeze growth of GaAs can efficiently be controlled by an external travelling magnetic field. The latter directly provides for a poloidal flow in the molten part. Controlling this flow offers the possibility to influence the interface shape, to increase the growth rate or to improve the homogeneity of the crystal. We report on the design of the magnetic field system and preliminary flow measurements with it.

  • Lecture (Conference)
    Workshop „Angewandte Simulation in der Kristallzüchtung“, 05.-06.02.2004, Volkach, Germany

Permalink: https://www.hzdr.de/publications/Publ-6704
Publ.-Id: 6704


Calorimetric and Potentiometric Study of PAMAM Dendrimers: Protonation and Interactions with Human Serum Albumin

Kirchner, R.; Seidel, J.; Gloe, K.; Stephan, H.

  • Poster
    3rd International Dendrimer Symposium, Berlin, 17.–20.09.2003

Permalink: https://www.hzdr.de/publications/Publ-6703
Publ.-Id: 6703


Development of Dendrons for Binding Rhenium Radionuclides

Appelhans, D.; Clausnitzer, C.; Gloe, K.; Johannsen, B.; Spies, H.; Stephan, H.; Stute, S.; Voit, B.

  • Poster
    3rd International Dendrimer Symposium, Berlin, 17.–20.09.2003

Permalink: https://www.hzdr.de/publications/Publ-6702
Publ.-Id: 6702


Dendritic Receptors for Binding Therapeutically Relevant Copper and Rhenium Radionuclides

Stephan, H.

  • Lecture (Conference)
    10th International Conference “Separation of Ionic Solutes”, Podbanske (Slovakia), 06.–11.09.2003

Permalink: https://www.hzdr.de/publications/Publ-6701
Publ.-Id: 6701


Preparation and Characterisation of Polyoxotungstates

Stephan, H.; Sawatzki, A.-K.

  • Lecture (others)
    Institutskolloquium, Institute of Chemical Technology Prag, 20.08.2003

Permalink: https://www.hzdr.de/publications/Publ-6700
Publ.-Id: 6700


Neue Rhenium- und Kupfer-Koordinationsverbindungen für die Radiotherapie

Stephan, H.

  • Invited lecture (Conferences)
    Institutskolloquium, Universität Heidelberg, Institut für Anorganische Chemie, 30.06.2003

Permalink: https://www.hzdr.de/publications/Publ-6699
Publ.-Id: 6699


Oxathiaaza-Makrocyclen: Potentielle Extraktionsmittel für Metallionen und Metallsalze

Antonioli, B.; Gloe, K.; Goretzki, G.; Glenny, M. W.; Schröder, M.; Herrmann, E.; Stephan, H.

  • Lecture (others)
    DECHEMA-Sitzung „Das Neue geschieht an den Grenzflächen“, Würzburg, 05.-07.03.2003

Permalink: https://www.hzdr.de/publications/Publ-6698
Publ.-Id: 6698


Supramolecular Systems in the Design of Radiopharmaceuticals

Stephan, H.; Johannsen, B.

  • Lecture (others)
    Workshop FWB Rossendorf/Schering AG, Hinterhermsdorf, 4. – 5. April 2002

Permalink: https://www.hzdr.de/publications/Publ-6697
Publ.-Id: 6697


Synergistic Solvent Extraction of Cu(II), Zn(II), and Ni(II) Based on Supramolecular Assemblies

Gasperov, V.; Gloe, K.; Leong, A. J.; Lindoy, L. F.; Mahinay, M. S.; Stephan, H.; Tasker, P. A.; Wichmann, K.

  • Lecture (Conference)
    Int. Solvent Extraction Conference 2002, Cape Town (South Africa), 17 – 21 März 2002

Permalink: https://www.hzdr.de/publications/Publ-6696
Publ.-Id: 6696


Binding and in vitro transport behaviour of polyoxotungstates in the presence of aminosaccharides

Stephan, H.; Bergmann, R.; Rode, K.; Röllich, A.; Sawatzki, A.-K.; Inoue, K.; Jelínek, L.; Parschová, H.; Matejka, Z.

  • Lecture (Conference)
    International Conference on Supramolecular Science & Technology , 05.-09.09.2004, Prag, Czech Republic
  • Contribution to proceedings
    Chemické Listy 98(2004), s35-36

Permalink: https://www.hzdr.de/publications/Publ-6695
Publ.-Id: 6695


Octahedral Rhenium Cluster Complexes with Organic Ligands as New Preparations for Medical Applications

Fedorov, V.; Mironov, Y.; Shestopalov, M.; Brylev, K.; Yarovoi, S.; Spies, H.; Pietzsch, H.-J.; Stephan, H.; Kraus, W.

  • Lecture (Conference)
    Topical Meeting of the European Ceramic Society “Nanostuctures & Nanocomposites”, 05.-07.07.2004, St. Petersburg, Russia

Permalink: https://www.hzdr.de/publications/Publ-6694
Publ.-Id: 6694


Interaction of Polyoxotungstates with Aminosaccharide Based Sorbents: Sorption Kinetics, Complex Stability and Implications for the Therapeutic Application of Polyoxotungstates

Jelínek, L.; Krotká, P.; Burda, R.; Parschová, H.; Matejka, Z.; Sawatzki, A.-K.; Röllich, A.; Stephan, H.

  • Lecture (Conference)
    XVIVth International Symposium “Ars Separatoria 2004”, 10.-13.06.2004, Potok, Poland
  • Contribution to proceedings
    Proceedings of the XIXth International Symposium “Ars Separatoria 2004”, 86-88

Permalink: https://www.hzdr.de/publications/Publ-6693
Publ.-Id: 6693


Improved Binding of Polyoxotungstates by Polysaccharides

Röllich, A.; Stephan, H.

Improved Binding of Polyoxotungstates by Polysaccharides

  • Lecture (others)
    Institutskolloquium, Institute of Chemical Technology Prag, 27.05.2004, Prag, Czech Republic

Permalink: https://www.hzdr.de/publications/Publ-6692
Publ.-Id: 6692


Dendritic encapsulation of rhenium and copper

Stephan, H.

  • Invited lecture (Conferences)
    Supraphone-Meeting, 06.-08.05.2004, Xanten, Germany

Permalink: https://www.hzdr.de/publications/Publ-6691
Publ.-Id: 6691


Käfigstrukturen für die nuklearmedizinische Diagnostik

Kraus, W.; Stephan, H.; Spies, H.; Reck, G.

  • Poster
    Gemeinsame Jahrestagung DGK und DGKK, Jena, 15.-19.03.2004

Permalink: https://www.hzdr.de/publications/Publ-6690
Publ.-Id: 6690


Numerical Simulation of Coolant Mixing at the ROCOM Test Facility with CFX-5

Höhne, T.; Kliem, S.; Rohde, U.

The work was aimed at the experimental investigation and numerical simulation of coolant mixing in the downcomer and the lower plenum of pressurized water reactors (PWR). For the investigation of the relevant mixing phenomena, the Rossendorf test facility ROCOM has been designed. ROCOM is a 1:5 scaled Plexiglas model of a German PWR (Fig. 1) allowing conductivity measurements by wire mesh sensors and velocity measurements by LDA technique. Due to the fact, that the mixing is dominated by turbulent mechanisms, it is assumed that the concentration field of a tracer solution can model both boron concentration and temperature fields. The salt significantly changes the conductivity of the water what can be measured by conductance methods. In the facility, so called wire mesh sensors are applied. The measured conductivities were transferred to a mixing scalar Qx,y,z(t) representing the contribution of the coolant from the disturbed loop to the mixture at the given position x,y,z.

It is calculated from the local instantaneous conductivity sx,y,z(t) by relating it to the amplitude of the conductivity range in the inlet nozzle of the disturbed loop.

Recent experiments at ROCOM, together with data on mixing obtained at the Vattenfall test facility; the Russian VVER-1000 mock-up and measurements at the VVER-440 NPP in Paks (Hungary) are integrated into the research project FLOMIX-R within the 5th Framework Programme of EC. The objective of the project is to obtain complementary and confirmatory data on slug mixing using improved measurement techniques with enhanced resolution in space and time. The experimental data will be used to contribute to the validation of CFD codes for the analysis of turbulent mixing problems. A few benchmark problems based on selected experiments will be used justify the application of various turbulence and turbulent mixing models for various flow conditions, to suppress numerical diffusion and to decrease grid, time step and user effects in the CFD analyses.

The CFD calculations were carried out with the CFD-code CFX-5. The ERCOFTAC Best Practice Guidelines, which have been specified for nuclear reactor safety calculations within the ECORA project, have been used when making sensitivity tests for: computational mesh, numerical schemes, convergence criteria, time step, boundary positions, boundary conditions, internal geometry modelling and turbulence models.
Based on these tests the production mesh was created and the final CFD calculations were performed.

In the case of stationary mixing (4 loop operation), the maximum value of the averaged mixing scalar in the downcomer (Fig. 2) and at the core inlet was found in the sector below the inlet nozzle, where the tracer was injected. There is a good agreement between the measurement and the CFD calculation, esp. in the averaged global mixing scalar at the core inlet (Fig. 3). In the calculation the maximum mixing scalar gives the same value at the peak in the same region compared to the experiment (94%).

For turbulent flows the CFD-Code CFX-5 were validated and can be used in reactor safety analysis. Due to the good agreement between measured results and the corresponding CFD-calculations efficient modules for the coupling of thermal hydraulic computer codes with three-dimensional neutron-kinetic models using the results of this work can be developed. A better description of the mixing processes inside the RPV is the basis of a more realistic safety assessment.

Keywords: Boron Dilution; CFD; PWR; Coolant Mixing

  • Contribution to proceedings
    22nd CAD-FEM Users’ Meeting 2004, International Congress on FEM Technology with ANSYS CFX & ICEM CFD, 10.-12.11.2004, Dresden, Germany, Conference Proceedings 2.6.26
  • Lecture (Conference)
    22nd CAD-FEM Users’ Meeting 2004, International Congress on FEM Technology with ANSYS CFX & ICEM CFD, 12.11.2004, Dresden, Germany

Permalink: https://www.hzdr.de/publications/Publ-6689
Publ.-Id: 6689


Strangeness and charm in QCD matter

Kämpfer, B.; Bluhm, M.

Strangeness and charm degrees of freedom in strongly interacting matter are discussed within a quasi-particle model adjusted to lattice QCD data. While strangeness is found to appear as copious as the other light quark and gluon excitations, the charm quarks are thermally suppressed.
The model allows to extrapolate lattice QCD data to large baryo-chemical potential.
We outline the thermal evolution of matter in the early universe at and slightly after confinement and comment briefly on charm dynamics in relativistic heavy-ion collisions.

Keywords: strangeness; charm; strongly interacting matter; QCD

  • Journal of Physics G 31(2005)6, 1141-1145
  • Invited lecture (Conferences)
    Strangness in Quark Matter 2004, 15.-20.09.2004, Cape Town, South Africa

Permalink: https://www.hzdr.de/publications/Publ-6688
Publ.-Id: 6688


Application of Several Physics Environments for a Coupled Simulation of Pressure Vessel Creep Failure Experiments

Willschütz, H.-G.; Altstadt, E.

For the calculation of experiments simulating the behavior of the lower head of a nuclear power station in case of a core meltdown scenario like FOREVER (performed at the Royal Institute of Technology, Stockholm) it is necessary to model the melt pool convection and the temperature field within the vessel as well as creep and plasticity processes. Therefore a 2D Finite Element Model with 3 different physics environments is developed based on the code ANSYS® Multiphysics.
A thermal environment was build up including planar and contact elements for conductive heat transfer, additional surface elements to simulate convection and radiation from outer surface areas and a radiation matrix to account for internal radiative heat exchange. Normally a CFD-simulation would have been required for the natural convective heat transfer in the melt pool, but at very high internal Rayleigh numbers no turbulence model is capable for a correct simulation. Therefore an Effective Conductivity Convectivity Model (ECCM) was developed to simulate the heat transfer from the melt pool to its environment.
The resulting temperature field of the vessel wall is applied to the mechanical model. To describe the visco-plastic deformation a numerical creep data base (CDB) is developed where the creep strain rate is evaluated in dependence on the current total strain, temperature and equivalent stress. In this way the use of a single creep law, which employs constants derived from the data for a limited stress and temperature range, is avoided. For an evaluation of the failure times a damage model according to an approach of Lemaitre is applied.
The third physics environment is a kind of fictitious physics environment: it uses hyperelasticity and contact to move the melt pool along with the creeping vessel wall.
In this paper problems on the numerical side are explained and differences between the results of a simple coupled and a kinematically coupled FE-simulation are highlighted. The final comparison with the experiments shows that the kinematically coupled model is closer to reality than the single step model.

Keywords: Fully Coupled Physics Environments; Effective Conductivity Convectivity Model; Creep and Plasticity of Pressure Vessel Steel

  • Contribution to proceedings
    22nd CAD-FEM Users’ Meeting 2004, International Congress on FEM Technology with ANSYS CFX & ICEM CFD, 10.-12.11.2004, Dresden, Germany, paper 1.1.13
  • Lecture (Conference)
    22nd CAD-FEM Users Meeting 2004, International Congress on FEM Technology with ANSYS CFX & ICEM CFD, 10.-12.11.2004, Dresden, Germany

Permalink: https://www.hzdr.de/publications/Publ-6687
Publ.-Id: 6687


Decay of 1+ states as a new probe of the structure of 0+ shape isomers

Rusev, G.; Schwengner, R.; Dönau, F.; Frauendorf, S.; Käubler, L.; Kostov, L. K.; Mallion, S.; Schilling, K. D.; Wagner, A.; von Garrel, H.; Kneissl, U.; Kohstall, C.; Kreutz, M.; Pitz, H. H.; Scheck, M.; Stedile, F.; von Brentano, P.; Jolie, J.; Linnemann, A.; Pietralla, N.; Werner, V.

The nuclides 98Mo and100Mo have been studied in photon-scattering experiments by using bremsstrahlung produced from electron beams with energies from 3.2 to 3.8 MeV. Six dipole transitions in 98Mo and 19 in 100Mo were observed for the first time in the energy range from 2 to 4 MeV.
A specific feature in both nuclides is the deexcitation of one state with spin J = 1 to the 0+ ground state as well as to the first excited 0+ state, which cannot be explained in standard models. We present a model based on one-particle-one-hole excitations, which allows us to deduce the mixing amplitudes for the two 0+ shape-isomeric states from the experimental ratio of the transition strengths from the J = 1 state to the 0+ ground state and to the 0+ excited state.

Keywords: photon scattering; J=1 states; shape isomers; mixing amplitudes

  • Physical Review Letters 95(2005), 062501

Permalink: https://www.hzdr.de/publications/Publ-6686
Publ.-Id: 6686


Test Measurements of a new TESLA Cavity Beam Position Monitor at the ELBE Linac

Sargsyan, V.; Schreiber, H. J.; Evtushenko, P.; Schurig, R.

A new type of a cavity BPM proposed for beam position determination along the TESLA linac was tested at the accelerator ELBE in Rossendorf / Dresden. Measurements using an improved BPM (large and stable cross-talk isolation, signicantly less energy dissipation, a novel LO signal generation) were performed in single- and multi-bunch regimes. Agreement with expectations was found. The low bunch charge available allowed for preliminary measurements on sensitivity and position resolution, which extrapolated to TESLA would full the demands for precise bunch-to-bunch position determination. Possible improvements, in particular on the signal processing scheme, are also discussed.

  • Other report
    2004 TESLA Reports, Papers from the TESLA collaboration September 2004

Permalink: https://www.hzdr.de/publications/Publ-6685
Publ.-Id: 6685


Medium effects on phi-meson production in near threshold proton-nucleus collisions

Zetenyi, M.; Barz, H.-W.

We study the cross section of phi-meson production in proton-nucleus collisions. The decay width of the phi-meson is affected by the change of the masses of the phi, K+, K- mesons in medium. A strong attractive K_ potential leads to a broadening of the phi-meson, which results in a measurable change of the behavior of the cross section as a function of the target mass.

Keywords: proton-nucleus collisions; in-medium effects; antikaon potential

  • Contribution to proceedings
    18th International Nuclear Physics Divisional Conference, 23.-29.08.2004, Praha, Czech Republic
  • Nuclear Physics A 749(2005), 174

Permalink: https://www.hzdr.de/publications/Publ-6684
Publ.-Id: 6684


On the integral equation approach and some related inverse problems in MHD

Xu, M.; Gerbeth, G.; Gundrum, T.; Stefani, F.

Solving the induction equation has become a synonym for kinematic dynamo studies. We present an alternative integral equation method to solve steady and time-dependent kinematic dynamo problems. This method, which relies on Biot-Savart's law, can be efficiently used to handle dynamos in arbitrary domains, for example in rectangular geometry and finite cylinders. The approach serves also as the basis for various inverse problems in MHD at small and large magnetic Reynolds numbers. The solution of such inverse problems is illustrated by the "Contactless inductive flow tomography" and by the inference of flow features in the Riga dynamo experiment from externally measured magnetic field data.

  • Lecture (Conference)
    Perm Dynamo Days, 07.-11.02.2005, Perm, Russia

Permalink: https://www.hzdr.de/publications/Publ-6681
Publ.-Id: 6681


Have we understood the Riga dynamo?

Stefani, F.; Gerbeth, G.; Gailitis, A.; Lielausis, O.; Platacis, E.

The experimental campaigns at the Riga sodium facility, carried out from November 1999 until recently, have brought about a wealth of data on the kinematic and the saturation regime of this hydromagnetic dynamo. In the kinematic regime, the measured growth rates and frequencies of the eigenfield differ from the numerical predictions only by a few per cent. A qualitative understanding of the saturation regime can be well achieved within a simple one-dimensional model of downward braking of the azimuthal velocity component by the Lorentz forces. This model can be refined by taking into account the Lorentz force driven flow in the outermost cylinder. We summarize our present understanding of the Riga experiment, and comment on some open questions.

  • Lecture (Conference)
    Perm Dynamo Days, 07.-11.02.2005, Perm, Russia

Permalink: https://www.hzdr.de/publications/Publ-6680
Publ.-Id: 6680


New measurements of magnetic fields, pressure and velocity at the Riga dynamo experiment

Gailitis, A.; Lielausis, O.; Platacis, E.; Gerbeth, G.; Gundrum, T.; Stefani, F.

In May 2004, the sixth experimental campaign has been carried out at the Riga dynamo facility. Besides the refined magnetic field measurements, we present pressure data recorded in the innermost cylinder and the first successful measurement of velocities in the outermost cylinder by ultrasonic Doppler velocimetry (UDV). The pressure data exhibit clear signals of the double and quadruple of the magnetic eigenmode frequency. The velocity UDV measurements confirm the numerical prediction that the Lorentz forces produce a global rotation and a double poloidal vortex in the outermost cylinder. We comment also on the demands and the prospects for future experimental campaigns.

  • Lecture (Conference)
    Perm Dynamo Days, 07.-11.02.2005, Perm, Russia

Permalink: https://www.hzdr.de/publications/Publ-6679
Publ.-Id: 6679


Proposal for a Taylor-Dean experiment to investigate the magnetorotational instability

Gerbeth, G.; Stefani, F.

The magnetorotational instability (MRI) is one of the most promising candidates to explain why accretion disks, which exhibit a Keplerian flow profile and should therefore be hydrodynamically stable, allow for a rate of angular transport which cannot be attributed to the molecular viscosity of the disk. Like the dynamo effect, MRI occurs only at large magnetic Reynolds numbers, making its laboratory investigation rather expensive. Recently, there are strong activities to study MRI in a liquid metal Taylor-Couette flow, and it might be that MRI has already been found in a spherical Couette flow of liquid sodium. We propose an alternative experimental configuration which is based on the Taylor-Dean flow. This flow is a combination of the usual cylindrical Couette flow and an additional Dean flow which is driven by an azimuthal force. This force can be realized in the form of an externally applied pressure gradient or, more elegantly, by a Lorentz force due to a radial current and an axial magnetic field. Our main idea is that, for a well adjusted ratio of Dean flow to Taylor-Couette flow, one gets an angular velocity that is decreasing with the radius and an angular momentum that is increasing with the radius, hence a situation that is prone to the study of MRI. Our main focus is on a particular configuration in which the outer and inner cylinders rotate at the same angular velocity. Evidently, this would simplify the mechanical part of the experiment dramatically. We find that, for sufficiently small values of the ratio of inner to outer radius, such an experiment seems indeed feasible.

  • Lecture (Conference)
    Perm Dynamo Days, 07.-11.02.2005, Perm, Russia

Permalink: https://www.hzdr.de/publications/Publ-6678
Publ.-Id: 6678


The beauty of spherically symmetric alpha2-dynamos: Exceptional points, oscillations, and chaotic reversals

Günther, U.; Gerbeth, G.; Stefani, F.

For dynamo theory, the spherically symmetric alpha^2-dynamo represents a similar paradigm as the harmonic oscillator does for quantum mechanics. For alpha(r)=const, the spectrum is rather boring due to the self-adjointness of the dynamo operator. However, the spectral properties become more interesting if we allow alpha to vary with the radius. We illustrate the spectral behaviour of those dynamos, including such features as exceptional points, level crossings and avoided level crossings. Then we focus on truly oscillatory dynamos which have been identified only recently. When including a simple alpha-quenching back-reaction and some random fluctuation of alpha, these dynamos exhibit a quite similar time behaviour as the geodynamo, including chaotic reversals and asymmetric polarity transitions.

  • Lecture (Conference)
    Perm Dynamo Days, 07.-11.02.2005, Perm, Russia

Permalink: https://www.hzdr.de/publications/Publ-6677
Publ.-Id: 6677


Ion beam analysis and computer simulation of damage accumulation in nitrogen implanted 6H-SiC: effects of channeling

Zolnai, Z.; Ster, A.; Khanh, N. Q.; Kotai, E.; Posselt, M.; Battistig, G.; Lohner, T.; Gyulai, J.

500 keV nitrogen implantations at different tilt angles (0o, 0.5o, 1.2o, 1.6o, 4o) with respect to the c-axis of 6H-SiC were carried out. Radiation damage distributions have been investigated by Backscattering Spectrometry combined with channeling technique (BS/C) using 3550 keV 4He+ ion beam. A comparative simultaneous evaluation of the damage depth distributions in the Si and C sublattices of 6H-SiC led to a <0001>-channeling to random correction factor of 0.8 in the electronic stopping power of 4He+ ions. Full-cascade Crystal-TRIM simulations with the same set of damage accumulation model parameters could reconstruct the measured shapes and heights of damage distributions for all implantation tilt angles. Secondary defect generation effects in addition to the primary point defect accumulation were assumed in the analysis.

Keywords: Silicon Carbide; Channeling; Electronic Stopping Power; Radiation Defects; Backscattering Spectrometry; Computer Simulation

  • Lecture (Conference)
    5th European Conference on Silicon Carbide and Related Materials (ECSCRM 2004), 31.08.-04.09.2004, Bologna, Italy

Permalink: https://www.hzdr.de/publications/Publ-6676
Publ.-Id: 6676


Antisite pair recombination in cubic SiC by a concerted exchange mechanism

Posselt, M.; Gao, F.; Weber, W. J.

An antisite pair consists of two neighboring atoms on “wrong” lattice sites, namely a Si atom on a C site and a C atom on a Si site. This defect can be formed by irradiation with energetic particles, e.g. during ion implantation doping. Investigations on the thermal stability of the antisite pair are important for electronic and nuclear applications of SiC.
In this work the recombination of an antisite pair is studied by classical molecular dynamics simulations using the interatomic potential developed by Gao and Weber [1]. The formation energy of the antisite pair is calculated and compared with literature data. Then, the lifetime of the defect is determined for the temperatures between 800 and 2500 K, and the effective recombination barrier is estimated. The lifetime for 2000 and 2500 K is compared with the results obtained using ab-initio molecular dynamics simulations. The analysis of atomic rearrangements during recombination shows that the mechanism of the antisite pair recombination is a concerted exchange. Due to the different atomic sizes of Si and C, the concerted exchange mechanism in SiC is not identical to that proposed for silicon [2]. During recombination a number of intermediate defect configurations are observed. Two of them are similar to the bond defect in silicon [3,4]. They can be considered as the result of an incomplete recombination of a carbon vacancy and a C+Si<100> dumbbell interstitial. Therefore, the present work yields not only details of the recombination of the antisite pair but also information about possible mechanisms for antisite pair formation.
[1] F. Gao, W. J. Weber, Nucl. Instr. Meth. B 191 (2002) 504
[2] K. C. Pandey, Phys. Rev. Lett. 57 (1986) 2287
[3] M. Tang, L. Colombo, J. Zhu, T. Diaz de la Rubia, Phys. Rev. B55 (1997) 14279
[4] L. A. Marques, L. Pelaz, J. Hernandez, J. Barbolla, G. H. Gilmer, Phys. Rev. B 64 (2001) 045214

Keywords: SiC; point defects; molecular dynamics

  • Lecture (Conference)
    14th Int. Conf. on Ion Beam Modification of Materials (IBMM 2004), September 5-10, 2004, Monterey, USA

Permalink: https://www.hzdr.de/publications/Publ-6675
Publ.-Id: 6675


CoSi2 nano wires synthesized by FIB processing

Bischoff, L.; Schmidt, B.; Akhmadaliev, C.; Röntzsch, L.

Nano structures, like wires or pearl chains play an increasing role in areas as plasmonics, nano-optics or nano-electronics as well as in the implementation of optical components in microelectronic devices. CoSi2 is a promising materials candidate due to its metallic behaviour with low resistivity and the compatibility to the microelectronics technology. Two methods to fabricate CoSi2 -nano – wires using FIB technique in terms of ion beam synthesis (IBS) are investigated. An oxide layer, structured by use of a high resolution Ga beam, acting as an implantation mask for a broad beam Co doping and subsequent annealing was investigated and discussed. Secondly, a mass separated FIB of cobalt is applied for a direct writing IBS process. Therefore different alloys as source materials were tested and applied in the FIB column (Canion 31Mplus, Orsay Physics). The use of the doubly charged ions emitted from the Co source allows to increase the implantation energy up to 60 keV, important to obtain buried structures of high quality.

Keywords: Ion Beam Synthesis; Focused Ion Beam; CoSi2; nano-wires

  • Lecture (Conference)
    European Focused Ion Beam Users Group EFUGAnnual meeting 2004, 04.10.2004, Zürich, Swizerland

Permalink: https://www.hzdr.de/publications/Publ-6674
Publ.-Id: 6674


Determination of the minimal sample thickness for diffusion experiments with strong sorbing tracers

Mibus, J.; Trepte, P.; Brendler, V.

The long-term risk assessment of underground repositories for radioactive waste requires among others diffusion coefficients of actinides in bentonite to account for the steady state diffusion process after exhaustion of the limited sorption capacity of the bentonite sealing. The determination of effective diffusion parameters of strong sorbing tracers such as actinides in laboratory diffusion experiments is very time consuming. For that, the sample thickness has to be reduced to a minimum. However, falling below a critical distance may lead to a distur-bance of the clay texture and to inadequate boundary conditions and thus, to a misinterpreta-tion of the diffusion data. Our work focuses on the dependence of the diffusion parameters of tritiated water (HTO) in bentonite on the sample thickness.
We conclude, that the clay plugs are mechanically stable and fulfill the hydraulic sealing function. From the relationship between sample thickness and De we see that the filter plates exert a significant influence on the boundary condition as soon as sample and filter plate are of the same thickness. Filter plates should be of about 1 to 2 mm thickness to resist the swell-ing pressure. Thus, a sample thickness in this dimension is possible to work with strong sorb-ing tracers minimizing the duration of the diffusion experiment and providing representative results.
Based on literature values for MX-80 pore water chemistry and sorption data of Uranium on montmorillonite a distribution coefficient KD was estimated. This approach utilized the sur-face complexation model and a respective data base (RES³T). Computations were performed with the FITEQL 3.2 code. The calculated KD’s range from 30 to 300 ml g-1. This enables a blind prediction of the accumulated diffused activity for different sample thickness. A time frame of at least one year will be necessary to reach steady state. This will be checked by re-spective long lasting diffusion experiments.

Keywords: Clay; Uranium; Diffusion; Sorption

  • Contribution to proceedings
    2nd International Meeting, Clays in Natural and Engineered Barriers for Radioactive Waste Confinement, ANDRA, March 14 – 18, 2005, Tours, France
  • Poster
    2nd Int. Meeting, Clays in Natural and Engineered Barriers for Radioactive Waste Confinement, 14.-18.03.2005, Tours, France

Permalink: https://www.hzdr.de/publications/Publ-6673
Publ.-Id: 6673


Compositional transformations in ion implanted polymers

Abdul-Kader, A. M.; Turos, A.; Grambole, D.; Jagielski, J.; Piatkowska, A.; Madi, N. K.; Al-Maadeed, M.

Changes of surface layer composition produced by ion bombardment of polyethylene and polypropylene samples were studied. These materials are under consideration for load bearing surfaces in biological and technical applications. To improve their tribological properties surface layers are usually modified by ionizing radiation. To study mechanism of transformations induced by ion beam bombardment selected polymers were implanted with H, He and Ar ions to the fluences ranging from 3x1014 to 2x1016 1/cm². RBS and NRA techniques were applied for sample analysis. Important hydrogen release was observed with increasing ion dose and was correlated with the ion stopping power. Another important effect observed was the rapid oxidation of samples, which apparently occurs after exposure of implanted samples to the air. Up to 10 at.% of oxygen can be incorporated in the implanted layer.

Keywords: surface modification; polymers; ion bombardment; hydrogen release; oxidation

  • Lecture (Conference)
    8th European Conference on Accelerators in Applied Research and Technology, Sept. 20 - 24, 2004, Paris, France
  • Nuclear Instruments and Methods in Physics Research B 240(2005)1-2, 152-156

Permalink: https://www.hzdr.de/publications/Publ-6672
Publ.-Id: 6672


Natürliche Hintergrundwerte des Uran

Bernhard, G.

Abstract:

  • Invited lecture (Conferences)
    1. Statusseminar zum Thema Uran, Uran-Umwelt-Unbehagen, Bundesforschungsanstalt für Landwirtschaft, 14.10.2004, Braunschweig, Germany

Permalink: https://www.hzdr.de/publications/Publ-6671
Publ.-Id: 6671


Aspekte der biogeochemischen Forschung im Institut für Radiochemie des Forschungszentrums Rossendorf

Bernhard, G.

Abstract:

  • Invited lecture (Conferences)
    5. Leipziger Kolloquium "Radionuklidanwendung zur Gesunderhaltung des Menschen", 27.10.2004, Leipzig, Germany

Permalink: https://www.hzdr.de/publications/Publ-6670
Publ.-Id: 6670


Uranium Speciation in Biogeochemistry

Bernhard, G.

Abstract:

  • Invited lecture (Conferences)
    3. Jenaer Sanierungskolloquium "Geomicrobiology in remediation of mine waste", 03.-06.10.2004, Jena, Germany

Permalink: https://www.hzdr.de/publications/Publ-6669
Publ.-Id: 6669


Complexation of Curium(III) by Adenosine 5’-triphosphate (ATP): A Time-resolved Laser-induced Fluorescence Spectroscopy (TRLFS) Study.

Moll, H.; Geipel, G.; Bernhard, G.

The complex formation of curium(III) with adenosine 5’-triphosphate (ATP) was determined by time-resolved laser-induced fluorescence spectroscopy (TRLFS). The interaction between soluble species of curium(III) with ATP was studied at trace Cm(III) concentrations (3x10-7 M). The concentrations of ATP are varied between 6x10-7 and 1.5x10-4 M in the pH range of 1.5 to 7.0 using 0.154 M NaCl as background electrolyte.
Three Cm-ATP species, MpHqLr, could be identified from the fluorescence emission spectra: (i) CmH2ATP+ with a peak maximum at 598.6 nm, (ii) CmHATP with a peak maximum at 600.3 nm, and (iii) CmATP- with a peak maximum at 601.0 nm. The formation constants of these complexes were calculated from TRLFS measurements to be log β121 = 16.86 ± 0.09, log β111 = 13.23 ± 0.10, and log β101 = 8.19 ± 0.16. The hydrated Cm-ATP species showed fluorescence lifetimes between 88 and 96 µs; whereas the CmATP- complex has a significantly longer fluorescence lifetime of 187 ± 7 µs.

Keywords: Adenosine triphosphate (ATP); Aqueous solution; TRLFS; Curium; Complexation

  • Inorganica Chimica Acta 358(2005), 2275-2282

Permalink: https://www.hzdr.de/publications/Publ-6667
Publ.-Id: 6667


Status of the 3 ½ Cell Rossendorf Superconducting RF

Janssen, D.; Büttig, H.; Evtushenko, P.; Lehnert, U.; Michel, P.; Schneider, C.; Stephan, J.; Teichert, J.; Volkov, V.; Kruchkov, S.; Myskin, O.

The status of the Rossendorf superconducting RF gun is discussed. This gun allows continuous wave operation with an energy of 9.5 MeV and an average current of 1mA. The 3½ cell niobium cavity contains a normal conducting photocathode. A special choke flange filter at the cathode side prevent the RF leakage of the cavity. The design of the cavity, the tuner, the RF coupler the LHevessel together with the cryostat is finished and now in manufacturing. In the paper three features are discussed, which follows from the special demands of the 3½ cell superconducting RF gun. The first feature is the tuning system. For the cavity two different tuners are necessary, one for the half cell (gun cell) and one for the accelerating cells. The second feature is the tuning of the cathode. The beam properties depend very sensitive on the athode position. Therefore a special cathode tuner has been developed, which allows to move and to adjust the cathode position inside the cavity. The third no conventional feature is the excitation of a second RF mode inside the cavity. This is a magnetic mode (TE mode) which replaces the static magnetic field in normal conducting RF guns and decreases the transverse emittance of the beam by more than a factor of two.

  • Lecture (Conference)
    26th International Free Electron Laser Conference and 11th FEL Users Workshop, 29.08. - 03.09.2004, Trieste, Italy
  • Contribution to proceedings
    Proceedings of the 26th International Free Electron Laser Conference and 11th FEL Users Workshop, 359-362, THBOC05, 29.08.-03.09. 2004, Stazione Marittima, Trieste, Italy, 2005, ISBN: 88-87-992-02-9,

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Permalink: https://www.hzdr.de/publications/Publ-6665
Publ.-Id: 6665


Estimating the depth of the roof and floor of intra-crystalline inclusions in a light-mineral matrix: application of RBS spectrometry

Strivay, D.; Ramboz, C.; Sauvage, T.; Gallien, J.-P.; Grambole, D.

A characteristic feature of the nuclear microprobe using 3 MeV proton beam is the long range of particles: ≈ 70 µm in light matrices. The PIXE method, with EDS analysis and using the multilayer approach for treating the X-Ray spectrum allows the chemistry of an intracrystalline inclusion to be measured, provided the inclusion roof and thickness at the impact point of the beam (R and F, respectively) are known (the depth of the inclusion floor is R+F). The parameter R of an inclusion in a mineral can be measured with a precision of ±1 µm using a motorized microscope. However, this value may significantly depart from R if the analysed FI has a complex shape. The parameter F can hardly be measured optically, unless a confocal microscope is used.
Measuring R and F by RBS spectrometry:
A negative crystal-shaped FI in quartz, containing ≈ 4 wt.% solutes, was analysed by PIXE using a 2.5 MeV proton beam, 3 x 3 µm² in size (charge on the target 0.3 µC). Simultaneously, a RBS spectrum was obtained with an annular charged-particle detector (alpha ≈ 170°). The depression at 1500 keV on the spectrum corresponds to the H2O-filled cavity along the beam path. Modeling of the spectrum using the SIMNRA program allows R to be measured at 11.6 µm, in good agreement with the optically determined value (11 µm). Simulation also fixes the depth of the FI floor at 17 µm in quartz. This paper will present preliminary measurements on synthetic samples to investigate the advantages of the technique, and also on natural solid and fluid inclusions in quartz. The influence of the geometrical parameters will be discussed with regard to the concentration determination by PIXE. In particular, accuracy of monazite micro-inclusion dating by coupled PIXE-RBS will be presented.

  • Lecture (Conference)
    9th International Conference on Nuclear Microprobe Technology and Applications (ICNMTA-2004), Sept. 13 -17 2004, Cavtat, Dubrovnik, Croatia

Permalink: https://www.hzdr.de/publications/Publ-6664
Publ.-Id: 6664


Romanian ancient gold objects provenance studies using micro-beam methods: the case of Pietroasa hoard

Constantinescu, B.; Bugoi, R.; Cojocaru, V.; Voiculescu, D.; Grambole, D.; Herrmann, F.; Ceccato, D.

Five fragments of ancient gold objects belonging to Pietroasa “Cloşca cu Puii de Aur” (“The Golden Brood Hen with Its Chickens”) Romanian hoard were analyzed using the micro-PIXE (Particle Induced X-ray Emission) technique. The purpose of the study was to gain some more knowledge regarding the metal provenance by determining the presence of PGE (Platinum Group Elements) and other high-temperature melting point trace elements (Ta, Nb, Cr) at a micrometric scale. Ta and Nb inclusions (micrometeric areas of composition different from the surroundings) on two samples and Pd inclusions on one sample were found. The measurements led to some conclusions for the possible gold ore sources of Pietroasa treasury: the South-Ural Mountains, Nubia (Sudan) and/or Anatolian deposits and Roman imperial coins.

Keywords: micro-PIXE; archaeometry; gold; PGE; inclusions; provenance

  • Lecture (Conference)
    9th International Conference on Nuclear Microprobe Technology and Applications (ICNMTA-2004), Sept. 13 -17 2004, Cavtat, Dubrovnik, Croatia
  • Nuclear Instruments and Methods in Physics Research B 231(2005), 541-545

Permalink: https://www.hzdr.de/publications/Publ-6663
Publ.-Id: 6663


High-efficient wire sawing of GaAs-wafers by utilization of crack nucleation mechanisms

Hammer, R.; Kleinwechter, A.; Jurisch, M.; Schaper, M.; Bergner, F.

One of the big challenges for wire sawing of semiconductor wafers is warp and waviness, which are mainly caused by wire deflection during cutting process. Therefore, lapping or grinding steps are often used to improve quality but accompanied by additional material losses. The mechanisms of a high quality wire sawing process for compound semiconductors will be presented here. The commonly accepted model for out-of-plane deviation of wires during wire sawing process was expanded by including intrinsic forces in addition to commonly considered technological ones, which are determined by material properties of the semiconductor used. For this the concept of a critical cutting depth for ductile-brittle-transition underlying cutting and grinding processes of brittle materials has been revised. Both Vickers hardness tests and single scratching tests were used to study the ductile-brittle-transition in greater detail. It was found that mainly two types of cracks (called A- and B-cracks) nucleate in GaAs, which are characterized by different threshold loads for their appearance. The effect is related to the existence of two types of dislocations with different PEIERLS-barriers, which dominate in III-V compounds, the 600 a- and b-dislocations. The micro crack nucleation is assisted by pile-ups of these dislocations, which leads to different crack initiation probabilities n for A- and B-cracks at a given load with nA > nB. This effect causes a significant dependence of the critical penetration depth for ductile-brittle-transition from the direction of a moving indenter in scratching tests. This critical penetration depth and the corresponding critical load determines measurable constraint forces, which act on the wire during the sawing process. Under certain well-defined conditions these constraint forces maintain the wire in a stable position perpendicular to the cutting direction, i. e. the out-of-plane-deviation of the wires is near to zero and, consequently, warp and bow will be minimal. This context has been proven by wire sawing experiments at a industrial multi-wire saw and by optical flatness measurements of GaAs-wafers. The result of this investigation was verified in a high efficient wire sawing technology for mass production of 150-mm-GaAs-wafers. Commonly used technological steps like lapping or surface grinding are no longer necessary and, in consequence, the material losses are reduced. Furthermore, the feed rates could be increased up to 400 percent compared to standard wire sawing of GaAs with improved geometrical parameters of the wafers.

Keywords: GaAs wafer; Wire sawing; Waviness; Cracking

  • Poster
    19th Annual Meeting of the American Society of Precision Engineering (ASPE), Orlando, Florida, October 24-29, 2004
  • Contribution to proceedings
    Proceedings of the 19th Annual Meeting of the American Society of Precision Engineering (ASPE), 24.-29.10.2004, Orlando, Florida, United States

Permalink: https://www.hzdr.de/publications/Publ-6662
Publ.-Id: 6662


Uranyl Sorption Onto Gibbsite Studied by Time-Resolved Laser-Induced Fluorescence Spectroscopy (TRLFS)

Baumann, N.; Brendler, V.; Arnold, T.; Geipel, G.; Bernhard, G.

Time-resolved laser-induced fluorescence spectroscopy (TRLFS) was combined with batch experiments to study the sorption of uranium(VI) onto gibbsite (γ-Al(OH)3). The experiments were performed under ambient conditions in 0.1 M NaClO4 solution in the pH range from 5.0 to 8.5 using a total uranium concentration of 1 x 10-5 M, and a solid concentration of 0.5 g/40 mL. Two uranyl surface species with fluorescence lifetimes of 330 ± 115 ns and 5600 ± 1640 ns, respectively, were identified. The first species was dominating the more acid pH region whereas the second one became gradually more prominent towards higher pH values. The fluorescence spectra of both adsorbed uranyl(VI) surface species were described with six characteristic fluorescence emission bands situated at 479.5 ± 1.1, 497.4 ± 0.8, 518.7 ± 1.0, 541.6 ± 0.7, 563.9 ± 1.2, and 585.8 ± 2.1 nm. The surface species with the short-lived fluorescence lifetime of 330 ns is attributed to a bidentate mononuclear inner-sphere surface complex in which the uranyl(VI) is bound to two reactive OH- groups at the broken edge linked to one Al. The second surface species with the significant longer fluorescence lifetime of 5600 ns was attributed to small sorbed clusters of polynuclear uranyl(VI) surface species. The longer fluorescence lifetime of the long-lived uranyl surface species at pH 8.5 is explained with the growing average size of the adsorbed polynuclear uranyl surface species.

  • Journal of Colloid and Interface Science 290(2005)2, 318-324

Permalink: https://www.hzdr.de/publications/Publ-6661
Publ.-Id: 6661


Detection of Adsorbed U(VI) Surface Species on Muscovite by TRLFS

Arnold, T.; Baumann, N.; Brendler, V.; Geipel, G.

Spectroscopic evidence for two adsorbed uranium(VI) surface species on edge surfaces of a muscovite platelet was obtained by Time-resolved Laser-induced Fluorescence Spectroscopy (TRLFS). In contrast, no fluorescence signal was obtained on the basal plane surfaces clearly indicating that U(VI) sorption on muscovite predominantly takes place at the edge surfaces. TRLFS spectra of adsorbed U(VI) surface species on gibbsite are very similar and show that U(VI) sorption on muscovite occurs on aluminol sites of the edge surfaces.

  • Lecture (Conference)
    SORPO Workshop, 25.-26.03.2004, Karlsruhe, Germany
  • Contribution to proceedings
    SOPRO Workshop, 25.-26.03.2004, Karlsruhe, Germany; FZKA Report 6986, 3-6

Permalink: https://www.hzdr.de/publications/Publ-6660
Publ.-Id: 6660


Actinide Speciation Based on EXAFS Spectroscopy: From Shell Fitting to MCTFA

Rossberg, A.; Scheinost, A.

Abstract:

  • Lecture (Conference)
    Actinide-XAS-2004, 14.-16.09.2004, Berkeley, United States
  • Contribution to proceedings
    Actinide-XAS-2004, 14.-16.09.2004, Berkeley, United States
    Proceedings

Permalink: https://www.hzdr.de/publications/Publ-6659
Publ.-Id: 6659


Annual Report 2003 - Institute of Safety Research

Weiß, F.-P.; Rindelhardt, U.; (Editors)

  • Open Access Logo Wissenschaftlich-Technische Berichte / Forschungszentrum Rossendorf; FZR-407
    ISSN: 1437-322X

Downloads:

Permalink: https://www.hzdr.de/publications/Publ-6657
Publ.-Id: 6657


Determination of RBE of 10 kV and 25 kV X-rays

Panteleeva, A.; Enghardt, W.; Lessmann, E.; Pawelke, J.; Wagner, W.; Dörr, W.

X-rays in the range ~10 – 50 keV are widely applied in the diagnostic radiology (particularly mammography) and radiotherapy (e. g. brachytherapy). However, the published data about their relative biological effectiveness (RBE) allow up to now no definitive conclusions about the action on different biological systems. Moreover, the biological effects depend on the spectral distribution of the photon source. In order to study this dependence, the RBE of 10 kV and 25 kV X-rays has been determined relative to 200 kV X-rays by X-ray tube irradiation.
The studies were carried out on the mouse fibroblasts NIH/3T3 and the human mammary epithelial cells MCF-12A. For the soft X-rays irradiation, a tungsten-anode X-ray tube operated at 10 kV (no filtration) or at 25 kV (0.3 mm Al filtration) was used. The reference irradiation was performed with a 200 kV X-ray tube with 0.5 mm Cu filter. The dose rate for all irradiations was in the range 0.3 – 1.9 Gy/min. The spectral dose distribution of all radiation qualities was also determined. Cell survival was studied after irradiation with 0.5 – 10 Gy by the clonogenic assay. Chromosomal damage was assessed by the cytokinesis-block micronucleus (MN) test in the dose range 0.2 – 5 Gy. In addition, first results for the RBE determination by chromosomal aberrations induction in MCF-12A, will be presented.
The cell survival data were fitted to the linear-quadratic model, resulting in an RBE value of 1.1 – 1.3 at the 10% survival level, depending on the used radiation quality and cell line. For both cell lines, an increase of RBE was found with decreasing dose after 10 kV X-rays, whereas a decrease of RBE of 25 kV rays was observed. The MN test results for the fraction of binucleated cells (BNC) with MN and the number of MN per BNC were fitted to a quadratic dependence, resulting in an RBE of 1.1 – 1.4.
The data obtained in the present work are in good agreement with observations of other authors as well as with theoretical predictions for this photon energy range. However, the detailed RBE dependence on photon energy can be determined only at a monochromatic X-ray source. Currently, the installation of an intensive, tunable, quasi-monochromatic source for cell irradiation in the energy range 10 – 100 keV is under progress at the ELBE accelerator at Forschungszentrum Rossendorf. The experimental verification of the theoretical calculation of the spectral distribution and intensity of this novel photon source will be presented.

Keywords: soft X-rays; cell survival; micronucleus; chromosomal aberrations; ELBE

  • Poster
    33rd Annual Meeting of the ESRB, 2004, Book of Abstracts, Self Publishing, p. 220,
  • Contribution to proceedings
    33rd Annual Meeting of the ESRB, 2004, Central European Journal of Occupational and Environmental Medicine 10(2004)Suppl., 150

Permalink: https://www.hzdr.de/publications/Publ-6656
Publ.-Id: 6656


Sorption of Am(III) onto 6-Line-Ferrihydrite and its alteration products: Investigation by EXAFS

Stumpf, S.; Stumpf, T.; Fanghänel, T.; Dardenne, K.; Hennig, C.; Klenze, R.

For the long-term performance assessment of nuclear waste repositories, knowledge concerning the interactions of actinide ions with mineral surfaces is imperative. The mobility of released radionuclides is strongly dependent on the sorption/desorption processes at mineral surfaces and their incorporation into the mineral frame. Hydrous iron oxides (ferrihydrite) are globally of great importance in the environment. Upon heating pure ferrihydrite converts to crystalline goethite and hematite. In the presence of di- or trivalent metal ions the transformation is affected leading to the promotion of one crystal formation over the other and incorporation of these ions. This Study deals with the question if released Am(III) can be immobilized by sorption onto 6-line-ferrihydrite. Moreover it is studied what happens if ferrihydrite transforms to a more crystalline phase.

Keywords: Am(III); Sorption; Ferrihydrite; EXAFS

  • Poster
    Actinide-XAS-2004 Berkeley/USA 14.-16.09.2004
  • Contribution to proceedings
    Actinide-XAS-2004, 14.-16.09.2004, Berkeley, United States
    Proceedings

Permalink: https://www.hzdr.de/publications/Publ-6655
Publ.-Id: 6655


Determination of RBE of 10 kV and 25 kV X-rays for cell survival and micronuclei induction

Panteleeva, A.; Enghardt, W.; Lessmann, E.; Pawelke, J.; Wagner, W.; Dörr, W.

The data about relative biological effectiveness (RBE) of low-energy X-rays as well as the RBE dependence on photon energy allow no definitive conclusions about their action on living cells. X-rays in the range ~10 – 50 keV are widely applied in the diagnostic radiology (particularly mammography) and radiotherapy (e. g. brachytherapy). The RBE of 10 kV and 25 kV X-rays relative to 200 kV X-rays by X-ray tube irradiation was determined for cell survival and micronuclei induction in mouse fibroblasts NIH/3T3 and human mammary epithelial cells MCF 12A. The RBE was found to be in the range from 1.0 to 1.4, depending on the used radiation quality, cell line and the biological endpoint. However, the detailed RBE dependence on photon energy can be determined only at a monochromatic X-ray source. A tunable, quasi-monochromatic X-ray source in the energy range 10 – 100 keV based on the channeling of a relativistic electron beam in a diamond crystal is under construction at the ELBE accelerator at Forschungszentrum Rossendorf. The status of the commissioning of the radiation source will be presented, such as the experimental verification of the theoretical calculation of the spatial energy and intensity distribution.

Keywords: cell survival; micronucleus; soft X-rays

  • Lecture (Conference)
    GBS 2004 : 7. Jahrestagung der Gesellschaft für Biologische Strahlenforschung ; 31. 03 - 2. 04 2004, Darmstadt, Germany
  • Contribution to proceedings
    GBS 2004 : proceedings der 7. Jahrestagung der Gesellschaft für Biologische Strahlenforschung ; 31. 03 - 2. 04 2004, Darmstadt, Germany, p. 36

Permalink: https://www.hzdr.de/publications/Publ-6654
Publ.-Id: 6654


Determination of RBE of low-energy X-rays at ELBE

Panteleeva, A.; Enghardt, W.; Lessmann, E.; Pawelke, J.; Wagner, W.; Dörr, W.

The precise determination of the relative biological effectiveness (RBE) of low-energy X-rays is important because of their wide application in diagnostic radiology (particularly mammography) and radiotherapy (e. g. brachytherapy). The RBE of both 10 kV and 25 kV X-rays relative to 200 kV X-rays by X-ray tube irradiation was found to be in the range from 1.0 to 1.4, depending on the used
radiation quality, cell line and the biological endpoint. In order to study in detail the RBE dependence on photon energy, the investigations will be continued at a monochromatic X-ray source. The installation of an intensive, tunable, quasi-monochromatic source in the energy range 10 - 100 keV is currently under progress at the ELBE accelerator at Forschungszentrum Rossendorf. X-rays are produced by channeling of a relativistic electron beam in a diamond crystal. The status of the commissioning of the radiation source will be presented, such as the experimental verification of the theoretical calculation of the spatial energy and intensity distribution. Furthermore, a monochromator, designed to minimize the contribution of the background radiation to the dose in the cell target, will be presented.

Keywords: ELBE; RBE; soft X-rays; cells

  • Lecture (Conference)
    DPG-Frühjahrstagung VI, 2004

Permalink: https://www.hzdr.de/publications/Publ-6653
Publ.-Id: 6653


Electronic properties and viscosity of liquid Pb-Sn alloys

Plevachuk, Y.; Sklyachuk, V.; Yakymovych, A.; Willers, B.; Eckert, S.

Electrical conductivity, thermopower and vsicosity of liquid Pb-Sn alloys are investigated in a wide temperature range. The revealed discrepancies between heating and cooling curves of temperature dependencies of some electrophysical and structural-sensitive properties as well as a hysteresis observed in the course of heating-cooling cycles suggest a metastable microheterogeneous structure of the Pb-Sn melts.

Keywords: Material data; Thermophysical properties; Eutectic

  • Journal of Alloys and Compounds 394(2005), 63-68

Permalink: https://www.hzdr.de/publications/Publ-6652
Publ.-Id: 6652


The mass spectrum of a tin liquid metal ion source

Bischoff, L.; Mair, G. L. R.; Mair, A. W. R.; Et, A.

Tin is an important metal with new potential applications regarding the fabrication of novel devices. In this work the mass spectrum of a tin liquid metal ion source (LMIS) is studied in detail. Sn++ was found to dominate in the beam both over Sn+ and over cluster ions. By studying the behaviour of the relative intensities of Sn+ and Sn++, as a function of emission current, the conclusion is reached that both Sn+ and Sn++ are emitted as a result of direct field-evaporation from the liquid surface. Cluster ions form by ion impact-aided droplet disintegration.

Permalink: https://www.hzdr.de/publications/Publ-6650
Publ.-Id: 6650


Round Robin: measurement of H implantation distributions in Si by elastic recoil detection

Boudreault, G.; Elliman, R.; Grötzschel, R.; Et, A.

A 200 mm amorphised Si wafer was implanted with 6-keV H+ ions at a nominal fluence of 5 x 10(16) atoms/cm(2). The uniformity of the implant was better than 2% over the wafer. Samples of the wafer were analysed for absolute H fluence by nuclear reaction analysis and elastic recoil detection (ERD) analysis, including both helium and heavy ion beams, using various types of detector (Si with range foil, time of flight ERD, and a position-sensitive gas ionisation DeltaE-E detector), various ion beams (He, Cl, Cu, I, Au) and independent analytical procedures. The results are compared and the inter-lab reproducibility is evaluated. The surface H, unstable under heavy ion beams, was resolved and accounted for throughout the analysis. Estimates of total combined uncertainties are about 6% for all participants, but the inter-lab reproducibility of the measurements was found to be 2.2%. Correct quantification of the H data from the gas ionisation detector is demonstrated. The uncertain! ty budget is discussed in detail.

  • Nuclear Instruments and Methods in Physics Research B 222(2004)3-4, 547-566

Permalink: https://www.hzdr.de/publications/Publ-6649
Publ.-Id: 6649


Evidence for a narrow resonance at 1530 MeV/c(2) in the K(0)p-system of the reaction pp ->Sigma(+)K(0)p from the COSY-TOF experiment

Cosy-Tof-Collaboration; Abdel-Baryd, M.; Abdel-Samad, S.; et. al.

The hadronic reaction pp --> Sigma(+)K(0)p was measured exclusively at a beam momentum of 2.95 GeV/c using the TOF detector at the COSY storage ring. A narrow peak was observed in the invariant mass spectrum of the K(0)p-subsystem at 1530 +/- 5 MeV/c(2) with a significance of 4-6 standard deviations, depending on background assumptions. The upper limit of 18 +/- 4 MeV/c(2) (FWHM) for its width is given by the experimental resolution. The corresponding total cross section is estimated to be about 0.4 +/- 0.1 (stat) 0.1 (syst) mub. Since a resonance in this subsystem must have strangeness S = + I we claim it to be the Theta(+) state for which very recently evidence was found in various experiments. (C) 2004 Elsevier B.V. All rights reserved.

Permalink: https://www.hzdr.de/publications/Publ-6648
Publ.-Id: 6648


Gamma and X-Ray tomography for transient two-phase flows and other instrumentation developed by Rossendorf

Prasser, H.-M.

First subject of the paper is a gamma-tomography setup for imaging a periodically changing density field. It is based on a time-resolved acquisition of the detector signals. The system consists in a 5 Ci source of Cs-137 and a detector arc with 64 BGO scintillation crystals coupled with photo-multipliers. It was used to visualize the gas fraction distribution within the impeller of an axial turbo-pump operating at about 1500 rpm, that delivered a gas-liquid mixture. The detectors operated in pulse mode. The pulses were counted by several banks of 64 counters activated in a successive order - each for a period of 100 µs. The counting procedure is restarted in the first bank after each full rotation of the impeller. After a measuring time of typically 3 -6 min, projections of the density distribution inside the object are acquired in a rotation-angle resolved manner. This allowed to afterwards reconstruct the void fraction distribution inside the rotating impeller structure by applying filtered back-projection algorithms. In a second application, the tomography system was applied to a hydraulic clutch (coupling). These measurements showed the distribution of the hydraulic liquid inside both semi-filled working wheel of the clutch at different slip ratios. An advanced detector system with a total number of 320 crystals is under construction. This will allow to increase the resolution from now about 7 mm to about 2-3 mm inside the measuring plane.
In the field of X-ray tomography, the status of the development of an ultra-fast system based on a scanning electron beam is presented. An electron beam is linearly deflected over a tungsten target with a frequency of 1 kHz. X-rays generated by the traveling focus penetrate the object and arrive at a detector line placed behind the object. The detectors are read-out with a sufficiently high speed in order to obtain projections of the density distribution in different projecting directions, which change thanks to the scanning. First results showing tomographic image sequences of a phantom consisting of small spheres kept in arbitrary motion in a cylindrical test box will be presented. Moving spheres of 3 mm diameter with cylindrical holes of 1 mm diameter were resolved at a framing rate of 1 kHz. For the experiments, an electron beam of a 150 kV gun with a current of 5 mA together with a line of 64 CdZnTe detectors working in current mode with a sampling frequency of 100 kHz for each detector (total data rate: 6.4 MHz) were used. It is planned to continue this development in direction towards an application in two-phase flow experiments.
A second application of X-rays concerns a cone-beam tomography of a stirred vessel reactor. In this case, time-averaged gas fraction distributions produced by a gassing stirrer were visualized using a standard X-ray tube and a 2D detector array. The rotation of the fluid inside the reactor was used to obtain the projections necessary for the 3D reconstruction.
The paper will furthermore present a summary of other kinds of two-phase instrumentation developed in the Research Center Rossendorf. Examples are: (1) local void probes based on impedance measurements, that are equipped with a micro-thermocouple substituting the traditional electrode applied to non-adiabatic gas-liquid flows, (2) the use of high-speed video imaging together with image processing techniques for bubble-column studies, (3) the developments of an optical tomograph and other optical sensors.

Keywords: two-phase flow; gamma tomography; X-ray tomography; local void probes; optical tomography; image processing

  • Lecture (Conference)
    Advances in the Modeling Methodologies of Two-Phase Flows S, 24.-26.11.2004, Lyons, France

Permalink: https://www.hzdr.de/publications/Publ-6647
Publ.-Id: 6647


Wire-mesh sensors: an experimental tool for two-phase CFD model development and code validation

Prasser, H.-M.

The Institute of Safety Research of the Forschungszentrum Rossendorf, Germany, has developed electrode-mesh sensors, which allow the measurement of the electrical conductivity distribution in a flow duct. This can be used either for the detection of the gaseous phase in a gas-liquid flow or for mixing studies in single phase flow, when the components have different electric conductivities. Two grids of crossing wires are placed into the flow closely behind each other. The wires of the first plane (transmitter plane) are supplied with pulses of a driving voltage in a successive order. The data acquisition is done by measuring the electrical currents arriving at the second grid (receiver wires). After the last transmitter electrode has been activated, a two-dimensional matrix is available that reflects the conductivities at crossing points of the electrodes of the two grids. Sequences of these 2D distributions are recorded with a rate of up to 10 kHz.
Due to the high measuring rate each bubble is mapped in several successive instantaneous frames. This allows to obtain bubble size distributions as well as bubble-size resolved gas fraction profiles beside the visualisation and the calculation of profiles of the time-averaged void fraction. Two sensors placed behind each other can furthermore be used for bubble velocity measurements using cross-correlation techniques. Sensors with three layers of electrode grids can be used for the measurement of the velocity of individual bubbles.
The sensor is widely used to study the evolution of the flow pattern in an upwards air-water flow. The experiments aim at closure equations describing forces acting on bubbles as well as coalescence and fragmentation frequencies for the implementation in CFD-codes. The largest sensor used until now has a circular measuring cross-section of about 200 mm diameter and is equipped with two grids of 64 wires. Therefore, the spatial resolution is 3 mm, the measuring frequency is 2.5 kHz. In the meanwhile, a sensor of this kind has been constructed and successfully used in a hot steam-water flow at 70 bar and 286 °C. Experiments were carried out at a vertical test channel of 195 mm inner diameter, in which the distance between gas/steam injection and sensor can be varied in a wide range. Results will be presented.
Some other prominent examples of the application of wire-mesh sensors will be given, like (1) the use of two wire-mesh sensors at the CIRCUS test facility of the University of Delft in the Netherlands for boiling water reactor stability studies, (2) the visualization of cavitation at fast-acting cut-off valves at the Pilot Plant Pipework test facility of Fraunhofer UMSICHT, Oberhausen, (3) the visualization of the flow structure behind a closing globe valve at TU Munich, and finally (4) mixing studies in single-phase flow at the ROCOM test facility in Rossendorf, which are aimed at the mixing of deborated slugs during boron dilution transients. Results will be discussed on basis of animated data visualizations for all examples.
The accuracy and the effect of the wire grids to the flow were investigated using a sensor built into a transparent channel. The comparison with the frames of a high-speed video camera have shown that the sensor acts as a bubble fragmenting obstacle. Nevertheless it was be proved, that the sensor signal represents the bubble geometry present in the upstream flow.

Keywords: two-phase flow; wire-mesh sensor; gas fraction; gas velocity; bubble size measurement; coolant mixing; boron dilution

  • Lecture (Conference)
    Advances in the Modeling Methodologies of Two-Phase Flows S, 24.-26.11.2004, Lyons, France

Permalink: https://www.hzdr.de/publications/Publ-6646
Publ.-Id: 6646


Development of a Mineral-Specific Sorption Database for Surface Complexation Modeling (Final Report and Manual)

Brendler, V.; Richter, A.; Nebelung, C.; Vahle, A.

RES³T - the Rossendorf Expert System for Surface and Sorption Thermodynamics - is a digitized thermodynamic sorption database, implemented as a relational database. It is mineral-specific and can therefore also be used for additive models of more complex solid phases such as rocks or soils. An integrated user interface helps users to access selected mineral and sorption data, to extract internally consistent data sets for sorption modeling, and to export them into formats suitable for other modeling software. Data records comprise of mineral properties, specific surface area values, characteristics of surface binding sites and their protolysis, sorption ligand information, and surface complexation reactions. An extensive bibliography is also included, providing links not only to the above listed data items, but also to background information concerning surface complexation model theories, surface species evidence, and sorption experiment techniques.
The RES³T database is intended for an international use. This requires high standards in availability, consistency and actuality. Therefore the authors of the database decided to couple the database onto an authorization tool.

Keywords: sorption; database; mineral; RES3T; surface complexation; MS Access

  • Open Access Logo Wissenschaftlich-Technische Berichte / Forschungszentrum Rossendorf; FZR-409 2004
    ISSN: 1437-322X

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Permalink: https://www.hzdr.de/publications/Publ-6644
Publ.-Id: 6644


Structure modifications in silicon irradiated by ultra-short pulses of XUV free electron laser

Peika, J. B.; Andrejczuk, A.; Reniewicz, H.; Schell, N.; Krzywinski, J.; Sobierajski, R.; Wawro, A.; Zytkiewicz, Z. R.; Klinger, D.; Juha, L.

Structural modifications of solid Si (0 0 1) targets exposed to the XUV TESLA free electron laser radiation were studied. The samples were irradiated with the photon energy centered at 14 eV, in short pulses of only 80 fs and of peak power up to 1 GW. The FEL beam was focused on sample surfaces to microspots of size 10–100 small mu, Greekm. The energy density in the spots varied from below the ablation threshold up to far above this threshold. The structural modifications induced with the irradiation were studied by AFM, Nomarski contrast microscopy and by X-ray diffraction methods. A variety of morphological structures created in the damaged areas was found. The maps of the X-ray diffracted intensity distribution recorded around chosen spots on the Si surface made it possible to probe the damage distribution range around the spots. The observed features are related to the FEL irradiation fluencies applied.

Keywords: Semiconductors; Laser processing; XUV free electron laser; Material modification; Ablation; Silicon

  • Poster
    Proceedings of the E-MRS 2003 Fall Meeting, Warsaw, Poland, 15-19 September 2003
  • Contribution to proceedings
    Proceedings of the E-MRS 2003 Fall Meeting, Warsaw, Poland, 15-19 September 2003

Permalink: https://www.hzdr.de/publications/Publ-6643
Publ.-Id: 6643


The mechanism in efficient silicon light-emitting diodes

Sun, J. M.; Dekorsy, T.; Skorupa, W.; Schmidt, B.; Mücklich, A.; Helm, M.

Light emission from silicon is one of the hot topics of temporary semiconductor physics and technology. Recent papers report encouraging electroluminescence efficiencies observed from bulk silicon diodes prepared by boron implantation. This report deals with a detailed analysis of the mechanism in light emission from silicon pn diodes prepared by boron implantation. From low-temperature electroluminescence spectra in combination with structural analysis, we obtain evidence that the light emission is strongly related to the locally enhanced boron doping spikes produced by ion implantation and subsequent annealing, which act as potential minima for holes and barriers for electrons. The doping spikes are able to capture spatially indirect bound excitons with a low recombination rate, thus effectively suppressing the fast non-radiative recombination at defects. The captured indirect bound excitons are thermally released to free electron-hole pairs at elevated temperature; therefore contribute to an increase of the band edge electroluminescence. A model containing rate equations of bound excitons and free excitons gives a very well description on the anomalous temperature dependence, which was observed in the efficient silicon light emitting diodes.

Keywords: Electroluminescence; silicon pn diode; bound excitons

  • Contribution to proceedings
    Vth International Conference, Ion Implantation and Other Applications of Ions and Electrons, 14.-17.06.2004, Kazimierz Dolny, Poland

Permalink: https://www.hzdr.de/publications/Publ-6640
Publ.-Id: 6640


Efficient silicon light emitting diodes by boron implantation: The mechanism

Sun, J. M.; Dekorsy, T.; Skorupa, W.; Mücklich, A.; Schmidt, B.; Helm, M.

Experiments and theoretical modeling are presented on the origin of efficient electroluminescence from boron implanted Si-LEDs. At low lattice temperatures two bound exciton traps created by high dose boron implantation were observed in the most efficient LEDs with external power efficiency above 0.12%. The temperature dependence of the correlation between the EL intensity from free and bound excitons is analyzed by a rate equation model. This analysis reveals that the bound excitons have a unique characteristic of a low recombination rate. The enhancement of EL from free electron-hole pairs with increasing temperature is due to the thermal activation of carriers from bound exciton traps.

Keywords: silicon pn junction; electroluminescence; bound excitons; rate equations; and temperature dependence

  • Optical Materials 27(2005)5, 1041-1045

Permalink: https://www.hzdr.de/publications/Publ-6638
Publ.-Id: 6638


On the mechanism of electroluminescence excitation in Er-doped SiO2 containing silicon nanoclusters

Sun, J. M.; Skorupa, W.; Dekorsy, T.; Helm, M.; Nazarov, A. N.

The effect of the density of silicon nanoclusters on both electroluminescence (EL) and photoluminescence (PL) of Er3+ ions in indium-tin oxide/SiO2:Er/n-type silicon metal-oxide-semiconductor structures was studied by co-implantation of excess silicon into a 200 nm SiO2 layer with a concentration in the range of 1-15 %. Contrary to the PL, the EL from both the green and infrared peaks of Er3+ shows a dramatic quenching when the average distance between the silicon clusters decreases below 3 nm. In addition, electric-field-induced quenching of the photoluminescence from silicon clusters and Er3+is observed. These results indicate that the EL excitation process of Er3+ ions is governed by the direct impact excitation by hot electrons. An increase of the silicon nanocluster density cause direct tunneling of electrons between silicon clusters, thus reducing the population of energetic hot electrons for impact excitation of Er3+ ions.
Key words: Erbium, electroluminescence, impact excitation, silicon dioxide, nanoclusters.

Keywords: electroluminescence; Erbium; silicon; nanoclusters; metal-oxide-semiconductor

  • Optical Materials 27(2005)5, 1050-1054

Permalink: https://www.hzdr.de/publications/Publ-6636
Publ.-Id: 6636


Dileptons and Open Charm: Probes of Chiral Restoration

Gallmeister, K.; Kaempfer, B.; Zschocke, S.

We summarize the status of electromagnetic probes of strongly interacting matter produced in relativistic heavy-ion collisions at CERN-SPS with respect to indications of chiral symmetry restoration. Explorative results for studying the open charm dynamics at BNL-RHIC are presented.

Keywords: medium modifications; chiral symmetry; heavy-ion collisions

  • Contribution to external collection
    High Energy Physics, ICHEP 2004, Proceedings of the 32nd Internationale Conference, 16.-22. 08.2004, Beijing, China, 381-384

Permalink: https://www.hzdr.de/publications/Publ-6635
Publ.-Id: 6635


In-situ GIXRD characterization of the crystallization of Ni-Ti sputtered thin films

Martins, R. M. S.; Silva, R. J. C.; Braz Fernandes, F. M.; Pereira, L.; Gordo Paulo, R.; Maneira Manuel, J. P.; Schell, N.

The Ni-Ti system is the most popular of the SMA’s because of its large recovery force, a transformation temperature near room temperature and a good oxidation resistance. Although the transformation frequency is low (mainly limited by thermal inertia), a thin film of Ni-Ti coupled with silicon for heat dissipation can produce cycling frequencies much larger than the typical macrosize structures. The thin films can be electrically driven using joule heating, and they demonstrate fast cooling rates because of their large surface-to-volume ratio. The control of film composition and properties has proven difficult in sputter-deposited films, and a deeper study of deposition techniques is needed. Furthermore, the as-deposited films show an amorphous structure and thus have to be heat treated to induce crystallization in order to have the shape memory effect. In the present study, thin films have been prepared by dc and rf magnetron sputtering. The crystallization of these films has been studied by in-situ grazing incidence X-Ray diffraction (GIXRD), allowing us to establish a correlation between the deposition conditions and the tendency for crystallization.

Keywords: shape memory alloy; Nitinol; thin films; X-ray diffraction

  • Poster
    Materials Science Forum 455-456 (2004) 342-345
  • Contribution to external collection
    Materials Science Forum 455-456 (2004), 342-345

Permalink: https://www.hzdr.de/publications/Publ-6634
Publ.-Id: 6634


Scaling of self-similar long fatigue crack growth in aluminium alloys

Bergner, F.

Propagation of long fatigue cracks in thin-sheet wrought aluminium alloys at constant stress ratio and constant stress amplitude (DK range from about 10 MPa m1/2 to well below instability) is considered. The crack growth rates of aluminium alloys with strength-controlling precipitates that cannot be sheared by dislocations nearly coincide at a particular value of DK and increasingly diverge for increasing values of DK. The characteristic quantities specified by the point to which the fatigue crack growth curves converge are related to the shear modulus and the slip band spacing.

Keywords: Fatigue crack growth; Aluminium alloys; Dislocations

  • Materials Science and Engineering A 400-401(2005), 422-425
  • Poster
    International Conference on the Fundamentals of Plastic Deformation 'Dislocations 2004', La Colle-sur-Loup, France, September 13-17, 2004

Permalink: https://www.hzdr.de/publications/Publ-6632
Publ.-Id: 6632


Interactions of the native and engineered S-layer of Bacillus sphaericus JG-A12 with U, Pd, and other metals

Pollmann, K.; Raff, J.; Merroun, M.; Schnorpfeil, M.; Fahmy, K.; Selenska-Pobell, S.

The cells of the uranium mining waste pile isolate B. sphaericus JG-A12 are enveloped by a highly ordered paracrystalline protein surface layer (S-layer) with a square lattice structure (1). The protein consists of 1238 amino acids, contains three N terminal S-layer homologous (SLH) domains and is, in contrast to the other Bacillus S-layers studied up to date, phosphorylated. A comparative analysis of the amino acid sequence of the JG-A12 S-layer protein with those deposited in the GeneBank demonstrated that the SLH domains of JG-A12 possess an unique structure. However, particular parts of the central and of the C-terminal domains of the protein share high identity with some of the known B. sphaericus S-layers (2). The latter is an indication that the JG-A12 S-layer protein gene was subjected to late evolutionary events via lateral genetic transfer and rearrangements.
The interactions of the purified and re-crystallized S-layer with U (VI) and Pd (II) were studied by using x-ray and infrared spectroscopic analyses. The results of these analyses show that U(VI) is coordinated to both phosphate and carboxyl groups of the S-Layer whereas Pd(II) was bound mainly by carboxyl groups. This is in accordance to our finding that the protein is phosphorylated and also that aspartate and glutamate rich stretches are distributed in its C-terminal domain which is supposed to build the S-layer lattice pores. The latter are involved in the complexation and also in the deposition of the metals. The infrared spectroscopic analysis indicated in addition that the deposition of the Pd complexes stabilizes the structure of the protein.
In our former work the S-layer of B. sphaericus JG-A12 was successfully used for the construction of sol-gel Si02 bio-ceramics for remediation of uranium contaminated waters (3). In addition, the S-layer of another B. sphaericus strain, which is closely related to the JG-A12, was used as a template for deposition of metallic Pd nanoclusters (4). Such nanoclusters are of great importance for the development of novel catalysts and biosensors for the industry.
In this work we apply genetic engineering of the S-layer of B. sphaericus JG-A12 in order to extend its capability to interact with other metals of industrial interest.

  • Lecture (Conference)
    Biotechnology 2004, 17.-22.10.2004, Santiago de Chile, Chile
  • Contribution to proceedings
    Biotechnology 2004, 17.-22.10.2004, Santiago de Chile, Chile
    Proceedings

Permalink: https://www.hzdr.de/publications/Publ-6631
Publ.-Id: 6631


Analysis and engineering of the S-layer protein of Bacillus sphaericus JG-A12 and potential technological applications

Pollmann, K.; Raff, J.; Merroun, M.; Fahmy, K.; Mikeehenko, I.; Creamer, N.; Macaskie, L.; Selenska-Pobell, S.

Uranium mining waste isolate B. sphaericus JG-A12 is capable of selective and reversible accumulation of U, Cu, Pb, Al, and Cd from the U waste waters [1]. The cells of this strain are enveloped by a surface protein layer (S-layer), which differs significantly in its primary structure from the other B. sphaericus S-layers studied up to date [2]. The highly ordered crystalline S-layers are one of the most common cell envelope structures of bacteria and archaea [3]. Most of them are composed of identical protein monomers which possess the ability to self-assemble into two-dimensional paracrystalline lattices. The highly regular structure of the S-layers with many pores of identical size offers good binding sites for different kinds of molecules and also nucleation sites for formation of metal nanoclusters or minerals.
We demonstrate that the purified and recrystallized S-layer of B. sphaericus JG-A12 is capable to bind effectively Pd(II) from salt solutions. EXAFS and IR spectroscopic analyses demonstrate that the Pd atoms are bound to the carboxyl groups of the S-layer. In accordance to this we found aspartate and glutamate rich stretches in the C-terminal domain of the S-layer which are possibly responsible for the deposition of Pd in the pores of the protein lattices. The deposition of Pd complexes stabilizes the protein structure. In presence of reducing agents deposited Pd is reduced to metallic nanoclusters. The latter is in agreement with the studies on another S-layer [4].
We demonstrate also that Pd nanoclusters are formed on the intact cells of B. sphaericus JG-A12 via a two step process consisting of biosorption (I) and of consequent metal reduction (II) in the presence of molecular H2 as an electron donor. The metallic nature of the clusters was confirmed by EXAFS and their size was estimated to be about 9-10 Ǻ. TEM analysis showed that the clusters are localized at specific sites of the bacterial cell wall, indicating the primary role of the S-layer in their formation. The Pd nanoclusters deposited at the cells of B. sphaericus JG-A12 show catalytic activity comparable to commercial ones.
Genetic engineering of the S-layer is applied for optimizing its capability to form Pd nanoclusters with increased catalytic activity and also in order to extend its binding capacity to other metals of industrial interest.

  • Poster
    Biotechnology 2004 - Konferenz, Santiago de Chile, 17.10.-22.10.2004
  • Poster
    2nd Max Bergmann Symposium, 17.-18.02.2005, Dresden, Deutschland
  • Contribution to proceedings
    Biotechnology 2004, 17.-22.10.2004, Santiago de Chile, Chile

Permalink: https://www.hzdr.de/publications/Publ-6630
Publ.-Id: 6630


Bacterial Diversity in the Uranium Mill-Tailings Gittersee as Estimated via a 16S rDNA Approach

Satchanska, G.; Golovinski, E.; Selenska-Pobell, S.

Bacterial diversity in a soil sample collected from a uranium mill-tailings called Gittersee and situated near the city of Dresden, Germany, was analysed by using a culture-independent 16S rDNA approach exploiting PCR amplification primers 7F and 1513R. The results were compared with those obtained earlier analysing the same sample by using another primer pair, namely 43F-1404R (Selenska-Pobell et al., 2002). The two 16S rDNA approaches demonstrated that Proteobacteria were the most predominant group in the sample, followed by Citophaga/Flavobacterium/ Bacteroides and by Gram positive bacteria with low and also with high G+C content. Moreover, a large number of the 16S rDNA sequences from the two libraries were identical or almost identical. However, the ratio between the bacterial groups represented in them differed significantly.
The 7F-1513R primer set retrieved in addition to the above mentioned 16S rDNA sequences also such of green non-sulfur bacteria and sequences of representatives of the AD1 and the OP11 divisions. The latter indicates that the 7F-1513R primer set seems to be more reliable in analyses of bacterial diversity.

  • Comptes Rendues de l'Academie bulgare des Sciences 58(2005)9, 1105-1112

Permalink: https://www.hzdr.de/publications/Publ-6629
Publ.-Id: 6629


Bog ground aquifer system as a natural analogue for future redox conditions in flooded underground mines

Abraham, A.; Baraniak, L.; Bernhard, G.

To characterize the future redox milieu caused by natural degradation of wood in flooded mines, the aquifer of a highland bog ground was studied as a natural analogue site. Going from the surface to a depth of one meter in the bog water, the redox potential measured with a platinum electrode changes from 593 mV to -95 mV. From the depth-water analyses of bog gas extracted from the ground, an Eh value of -119 +/- 5 mV could be calculated. Methane and hydrogen sulfide were found in the gas, characterizing the strongly reducing condition in the bog ground. From that, the conclusion for the future mine situation can be drawn that uranium(VI) and arsenic(V) will be reduced and precipitated as U(OH)4 and As2S3. In that way, decontamination of the mine water takes place as a consequence of a natural attenuation process.

  • Journal of Radioanalytical and Nuclear Chemistry, 261(2004)3, 597-604

Permalink: https://www.hzdr.de/publications/Publ-6627
Publ.-Id: 6627


On the development of the <111> fiber texture in nanocrystalline gold during growth and annealing

Andreasen, K. P.; Schell, N.; Jensen, T.; Petersen, J. H.; Jensen, M. S.; Chevallier, J.; Bøttiger, J.

The evolution during growth and subsequent annealing of the <111> fiber texture in magnetron-sputtered nanocrystalline Au films has been studied experimentally using X-ray diffraction with synchrotron radiation. To quantitatively investigate this fiber texture, grain orientation distributions were recorded in situ during growth and during subsequent annealing using Bragg-Brentano geometry. The (111) diffraction intensity was measured as a function of the sample tilt chi, the tilt axis lying at the intersection of the film surface and the scattering plane. As a quantitative measure of the texture, we used the width of the orientation distibutions. The grain-orientation distributions narrowed during annealing. The activation energy for the process behind this texture change was found to be 0.64 ± 0.05 eV, close to the activation energy for grain boundary self-diffusion in nanocrystalline Au. This and the narrowing of the grain orientation distributions led us to suggest that the observed changes in texture originated from grain rotations and not from grain growth. Grain growth did not take place at the lower temperatures, where changes in orientation distributions were observed.

Keywords: texture development; Au-nanocrystals; magnetron sputtering

  • Poster
    Materials Research Society Symposium 2004
  • Contribution to proceedings
    Materials Research Society Symposium Proceedings 788(2003), L11-50

Permalink: https://www.hzdr.de/publications/Publ-6626
Publ.-Id: 6626


The structure and the corresponding mechanical properties of magnetron sputtered TiN–Cu nanocomposites

Andreasen, K. P.; Jensen, T.; Petersen, J. H.; Chevallier, J.; Bottiger, J.; Schell, N.

The present paper describes experimental studies of the structure and the corresponding mechanical properties of TiN–Cu nanocomposites synthesised by reactive magnetron sputtering. By X-ray diffraction, the crystalline phases appearing, the texture, the grain size and the microstrain were studied as a function of the deposition temperature and the substrate bias voltage. In addition, the nanostructure was studied by cross-section transmission electron microscopy and the surface orphology by scanning electron microscopy. At low deposition temperatures, a two-phase structure consisting of a fcc TiN phase and a highly disordered crystalline or amorphous Cu-rich phase was formed. Increasing the deposition temperature, a fcc Cu phase was observed in addition to the crystalline TiN phase. The texture varied with the deposition temperature, and the grain size increased and the microstrain decreased with rising deposition temperature. The mechanical properties were measured by nanoindentation. For the nanocomposites Ti41N46Cu13, Ti43N46Cu11 and Ti43N49Cu8, hardness values of 25, 35 and 40 GPa, respectively, were measured.

Keywords: TiN–Cu; Nanocomposites; Magnetron sputtering; X-ray diffraction; Transmission electron microscopy; Nanoindentation

  • Surface and Coating Technology 182(2004), 268-275

Permalink: https://www.hzdr.de/publications/Publ-6625
Publ.-Id: 6625


Influence parameters of martensitic transformation during low cycle fatigue for steel AISI 321

Grosse, M.; Kalkhof, D.; Keller, L.; Schell, N.

The volume fraction of martensite continuously increases with the fatigue cycle number. Consequently, the martensite amount can be used for indication of the low cycle fatigue state. Following an exponential decay function, the martensite volume fraction decreases with increasing temperature. No influence of the load frequency was found. The initial material state plays an important role for the martensite formation rate. The amount of martensite formed is much higher after cold-rolling than after solution annealing as final manufacturing process. The martensite shows a fibre texture in the annealed material. The (I 10) planes are preferentially oriented parallel and perpendicular to the loading direction. In the cold-rolled material no significant preferred orientation of this phase was found. The martensite is concentrated in the centre of the specimens. The shape of the distribution seems to be independent on the martensite amount.

Keywords: Martensitic transformation; Austenite; Martensite; Low cycle fatigue

Permalink: https://www.hzdr.de/publications/Publ-6624
Publ.-Id: 6624


Uncertainty and sensitivity analysis of a VVER-1000 start-up experiment using the coupled code DYN3D/ATHLET and the statistical code package SUSA

Kliem, S.; Mittag, S.; Langenbuch, S.

The transition from the application of conservative models to the use of best-estimate models raises the question about the uncertainty of the obtained results. This question becomes especially important, if the best-estimate models should be used for safety analyses in the field of nuclear engineering. Different methodologies were developed to assess the uncertainty of the calculation results of computer simulation codes. One of them is the methodology developed by Gesellschaft fuer Anlagen- und Reaktorsicherheit (GRS) which uses the statistical code package SUSA. In the past, this methodology was applied to the calculation results of the advanced thermal hydraulic system code ATHLET. In the frame of the recently finished EU FP5 funded research project VALCO, that methodology was extended and successfully applied to different coupled code systems, including the uncertainty analysis for neutronics. These code systems consist of a thermal hydraulic system code and a 3D neutron kinetic core model. One of the code systems applied was ATHLET coupled with the Rossendorf kinetics code DYN3D. Two real transients at NPPs with VVER-type reactors documented within the VALCO project were selected for analyses. One of them was a test with the switching-off of one of two main feed water pumps at the VVER-1000 Balakovo-4 NPP. The current paper is dedicated to the different steps of the use and implementation of the GRS methodology to coupled code systems and to the assessment of the results obtained in the calculations of the VVER-1000 transient by the DYN3D/ATHLET code.

Based on the relevant physical processes in the transient, a list of possible sources of uncertainties was compiled. Besides control parameters like control rod movement and thermal hydraulic parameters like secondary side pressure, mass flow rates, and pressurizer heater performance, different neutron kinetic parameters were included into the list of possible sources of uncertainties. These are the burn-up state of the core, the control rod efficiency for different control rod groups and the coefficients for Doppler and moderator density feed back. By use of the SUSA package, sets of input data with statistical variation of the relevant parameter values were generated for a large number of runs of the coupled code. New tools were developed for the automated implementation of the varied input parameters into the different input decks of the DYN3D/ATHLET code. The same concerns the extraction of result parameters from the output data of the calculations and statistical analysis of these results. Time-dependent rank correlation coefficients were calculated showing the influence of the varied parameters on the output parameter under investigation. The most interesting output parameters are the physical parameters for which experimental data are available. First of all, these are the core power, upper plenum pressure, loop temperatures and steam generator levels. The calculation results allowed also the determination of time-dependent tolerance intervals for given coverage and confidence. The comparison of the experimental data, the (best-estimate) reference solution and the tolerance intervals showed how the agreement between experiment and calculation could be quantified. In most of the cases the tolerance intervals include the experimental curves. A compiled list of the most important input parameters based on the rank correlation coefficients shows, which input parameters and models are responsible for the deviations. This list gives indications for further model improvements and code developments.

  • Lecture (Conference)
    14. AER Symposium, 13.-17.09.2004, Helsinki, Finnland
  • Contribution to proceedings
    14. AER Symposium, 13.-17.09.2004, Helsinki, Finnland, Proceedings, 503-516

Permalink: https://www.hzdr.de/publications/Publ-6623
Publ.-Id: 6623


Experimental study of a single bubble motion in a liquid metal column exposed to a DC magnetic field

Zhang, C.; Eckert, S.; Gerbeth, G.

The motion of single Argon bubbles rising in the eutectic alloy GaInSn under the influence of a DC longitudinal magnetic field was examined. The magnetic field strength was chosen up to 0.3 T corresponding to magnetic interaction parameters N of 1.5. The experiments were carried out in the following parameter range: 2500 < Re < 5500, 2 < Eo < 7, Mo = 2.4?10-13. The liquid metal was in a cylindrical container at rest. Bubble and liquid velocities were measured using Ultrasonic Doppler Velocimetry (UDV). The measured bubble terminal velocity showed oscillations indicating a zig-zag movement of ellipsoidal bubbles. Whereas for small bubbles (de ? 4.6 mm) an increase of the drag coefficient with increasing magnetic interaction parameter was observed, the application of the magnetic field reduces the drag coefficient of larger bubbles (de ? 5.4 mm). The measurements revealed a distinct electromagnetic damping of the bubble induced liquid velocity leading to more rectilinear bubble trajectories. Moreover, significant modifications of the bubble wake structure were observed. Raising of the magnetic field strength causes an enlargement of the eddies in the wake. The Strouhal number St decreases with increasing magnetic interaction parameter.

Keywords: Single bubble; Liquid metal; Magnetic field; Terminal velocity; Drag coefficient; Bubble wake; Ultrasound Doppler Velocimetry

  • International Journal of Multiphase Flow 31(2005), 824-842

Permalink: https://www.hzdr.de/publications/Publ-6622
Publ.-Id: 6622


Below-band gap electroluminescence related to doping spikes in boron-implanted silicon pn diodes

Sun, J. M.; Dekorsy, T.; Skorupa, W.; Schmidt, B.; Mücklich, A.; Helm, M.; (Editors)

The origin of two luminescence bands with maxima around 1.05 eV and 0.95 eV is studied in silicon pn diodes prepared by boron implantation. The two peaks are related to the formation of p-type doping spikes on a nanometer scale. These doping spikes are generated by long-time thermal activation of preformed boron clusters. The peak with a larger binding energy stems from spatially indirect excitons bound to doping spikes in a strained environment, while the peak with a lower binding energy is related to doping spikes without strain. The doping spikes are able to capture spatially indirect bound excitons with a low recombination rate, thus effectively suppressing the fast non-radiative recombination at defects. This effect leads to an efficient room temperature electroluminescence in silicon light-emitting diodes prepared by boron implantation.

Keywords: silicon; light-emitting diode; elecroluminesencce; bound excitons; ion implantation; boron

Permalink: https://www.hzdr.de/publications/Publ-6621
Publ.-Id: 6621


Spectroscopic Ellipsometry Characterization of ITO Films Prepared by Reactive MF Dual Magnetron Sputtering: Effect of Substrate Temperature

Vinnichenko, M.; Rogozin, A.; Shevchenko, N.; Kreissig, U.; Kolitsch, A.; Möller, W.

The reactive middle frequency (MF) dual magnetron sputtering is a favorable process for industrial applications. Production of low resistivity (~10^-4 Ohm*cm) ITO films by this method requires their heat treatment. The ITO film formation and evolution at elevated substrate temperatures is not properly addressed because the phase diagram of this material is not known. Thus, in situ spectroscopic ellipsometry (SE) was applied to characterize the growth of ITO films at heated substrates (Ts=RT-510 °C). The results of in situ and ex situ SE were compared with the film resistivity, stoichiometry (elastic recoil detection analysis) and structure (X-ray diffraction).
The in situ SE indicates formation of the rough film with graded optical properties. This grading is stronger for the films deposited without substrate heating. The free electron parameters were determined from parameterization of the film optical constants in Drude-Lorentz approach. Their behavior with increasing Ts agrees with concomitant resistivity dependence, measured by the four point probe method. Thus, in situ SE monitoring of the free electron parameters provides a tool for real-time contactless characterization of the growing film resistivity. Quantitative characterization of the resistivity by SE requires further improvement of the optical model. The existence of the resistivity grading through the film thickness was indicated by this method for the growth without heating. At heated substrates this grading vanishes after deposition of ~50 nm layer and homogeneous film start growing. The films grown at the Ts=400 C have resistivity of 1.2*10^-4 Ohm*cm that is comparable with the best results achieved with ceramic targets. The SE data analysis demonstrated that improvement of the film resistivity with increasing Ts is mainly due to enhancement of the free electron mobility. It is accompanied by improvement of the film stoichiometry, changes of texture and crystallinity.

Keywords: tin doped indium oxide; in situ spectroscopic ellipsometry; thin film growth

  • Lecture (Conference)
    International Conference on Metallurgical Coatings and Thin Films, April 19-24, 2004, San Diego, CA, USA

Permalink: https://www.hzdr.de/publications/Publ-6620
Publ.-Id: 6620


Plasma influence on the properties and structure of indium tin oxide films produced by reactive middle frequency pulsed magnetron sputtering

Rogozin, A.; Vinnichenko, M.; Shevchenko, N.; Kolitsch, A.; Möller, W.; (Editors)

Reactive pulsed magnetron sputtering was used to produce conductive and transparent tin-doped indium oxide (ITO) films with low thickness inhomogeneity. Due to the parallel operation of two magnetrons, the deposition system allows in situ investigations of the plasma influence on the film properties. The distribution of the film resistivity, refractive index, structure and stoichiometry along the substrate are presented and related to the spatial distribution of the plasma flow escaping the magnetrons, and the substrate temperature. A higher plasma flow likely causes a localized relaxation of the distorted In–O bonds in amorphous phase which prevails in ITO films prepared at unheated substrates. This leads to a decrease of the film resistivity due to free electrons density and mobility enhancement. The free electron density increase is caused likely by generation of oxygen vacancies. Deposition on a heated substrate (Ts /Tm=0.3) leads to a change of the film growth mode due to enhanced surface diffusion of the adatoms which results in a textured low resistivity film. This also causes significant improvements of the homogeneity of the film properties that is important for ITO applications.

Keywords: Indium tin oxide; Plasma processing and deposition; Electrical properties and measurements; Optical properties

  • Thin Solid Films 496(2)(2006)197-204, doi:10.1016/j.tsf.2005.08.273

Permalink: https://www.hzdr.de/publications/Publ-6619
Publ.-Id: 6619


Efficient ultraviolet electroluminescence from a Gd-implanted silicon metal-oxide-semiconductor device

Sun, J. M.; Skorupa, W.; Dekorsy, T.; Helm, M.; Rebohle, L.; Gebel, T.

Strong ultraviolet electroluminescence with an external quantum efficiency above 1% is observed from an indium-tin oxide/SiO2:Gd/Si metal-oxide-semiconductor structure. The SiO2:Gd active layer is prepared by thermal oxidation followed by Gd+ implantation and annealing. The electroluminescence spectra show a sharp peak at 316 nm from the 6P7/2 to 8S7/2 transition of Gd3+ions. Micrometer sized electroluminescent devices are demonstrated.

Keywords: Ultravoilet; Electroluminescence; Gd; silicon; metal-oxide-semiconductor

Permalink: https://www.hzdr.de/publications/Publ-6618
Publ.-Id: 6618


Design and operation of strain-compensated InGaAs/AlAs/InP quantum cascade lasers emitting at 3.7-4.2 micrometer

Semtsiv, M. P.; Ziegler, M.; Dressler, S.; Masselink, W. T.; Georgiev, N.; Dekorsy, T.; Helm, M.

not available

Keywords: quantum cascade laser; infrared; intersubband transition

  • Lecture (Conference)
    6th Int. Conference on Mid-Infrared Optoelectronics Materials and Devices (MIOMD-VI), 27 June-2 July 2004, St. Petersburg, Russia

Permalink: https://www.hzdr.de/publications/Publ-6617
Publ.-Id: 6617


In situ speciation of U(IV) and U(VI) aqueous complexes with a newly developed spectro-electrochemical cell

Hennig, C.; Tutschku, J.; Rossberg, A.; Scheinost, A.; Bernhard, G.

Natural aquatic and terrestrial environments exert large variations in redox state due to oxygen diffusion on one hand and microbial processes on the other hand. Actinides with their large number of oxidation states are especially susceptible to these redox changes, forming a large number of aqueous complexes which may greatly differ by solubility and mobility. These complexes are often difficult to investigate due to their thermodynamic metastability. Therefore, we developed a new spectro-electrochemical cell, which allows to study the structure and speciation of aqueous actinide complexes in-situ by X-ray absorption spectroscopy (XAS), while applying and maintaining a constant potential.

While in-situ investigations by combining electrochemical cells with XAS are not new, the prevention of any gas-releasing electrode reaction due to the special safety regulations for actinides required a new electrochemical approach. We used an Ag metal electrode as anode, where Ag+ is released and precipitates as AgCl. The cell itself consists of a double confinement following the safety regulations for the use of radioactive materials at the ESRF. The cell body and the windows are machined from one piece of chemically resistant material, which is closed by air-tight cover plates.

First U L3-edge XAS spectra have been obtained from aqueous solutions of U(VI) and U(IV) in the presence of different ligand systems. The reduction of U(VI) to U(IV) was performed by applying a constant potential for several hours. Independent UV/vis measurements of the solutions were performed in order to verify that uranium was completely reduced. A quantitative analysis of the uranium redox species during the reduction procedure was performed by iterative transformation factor analysis of the XANES spectra. Finally, EXAFS measurements were used to solve the structure of the uranium redox species.

  • Lecture (Conference)
    Actinide-XAS-2004, 14.-16.09.2004, Berkeley, United States
  • Contribution to proceedings
    Actinide-XAS-2004, 14.-16.09.2004, Berkeley, United States
    Proceedings

Permalink: https://www.hzdr.de/publications/Publ-6616
Publ.-Id: 6616


Strain-compensated AlAs/(In,Ga)As heterostructures for short wavelength intersubband absorption and laser emission

Semtsiv, M. P.; Ziegler, M.; Dressler, S.; Masselink, W. T.; Georgiev, N.; Dekorsy, T.; Helm, M.

We have investigated intersubband transitions in strain-compensated AlAs/(In,Ga)As heterostructures, demonstrating both absorption and quantum-cascade laser emission at short wavelengths. Short-wavelength optical transitions in such structures are associated with a number of challenges in both the growth and design, including managing the internal strain and designing around indirect valleys. We achieve absorption peaks at wavelengths as short as 1.7 micrometer in fully strain-compensated AlAs/(In,Ga)As structures. Quantum cascade lasers based on similar heterojunctions exhibit laser emission as short as 3.7 micrometer. These lasers exhibit low-temperature threshold current densities of 860 A/cm2 in pulsed mode and output power as high as 6W per facet (12W total). At room temperature, the threshold current density is 4.5 kA/cm2 and the maximum power 240 mW per facet.

Keywords: infrared; intersubband absorption; quantum cascade laser; semiconductor quantum wells

  • (Proceedings of MBE 2004) Journal of Crystal Growth 278(2005)1-4,526-531
  • Lecture (Conference)
    Int. Conf. on Molecular Beam Epitaxy (MBE 2004), Aug. 22-27, 2004, Edinburgh, UK

Permalink: https://www.hzdr.de/publications/Publ-6615
Publ.-Id: 6615


EPOS - intensive Positronenquelle für die Materialforschung

Krause-Rehberg, R.; Brauer, G.; Leipner, H. S.

Materialforschung mit Positronen ist eine anerkannte Spezialrichtung der Halleschen Physik. In Kooperation zwischen dem Großforschungszentrum Rossendorf und dem Interdisziplinären Zentrum für Materialwissenschaften der Martin-Luther-Universität Halle-Wittenberg befindet sich eine hochintensive Positronenquelle im Aufbau. Nach Fertigstellung wird das Labor als ein europäisches Kompetenzzentrum für Materialforschung mit Positronen auch externen Nutzern zur Verfügung stehen.

Keywords: Positron; Materialforschung; Defekte; ELBE-Quelle; MLU Halle-Wittenberg; FZ Rossendorf

  • scientia halensis 2(2004), 13-14

Permalink: https://www.hzdr.de/publications/Publ-6614
Publ.-Id: 6614


Influence of the lift force on the stability of a bubble column

Lucas, D.; Prasser, H.-M.; Manera, A.

This work investigates the role of the lift force in the transition from homogeneous to heterogeneous bubble column. On rising bubbles the lift force acts in a lateral direction, when gradients of the liquid velocity are present. Non-uniform liquid velocity fields may be induced if the gas fraction is not equally distributed, e.g. caused by local disturbances. This feedback mechanism is studied in the paper. It was found, that a positive lift coefficient (small bubbles) stabilizes the flow, while a negative coefficient (large bubbles) leads to unstable gas fraction distributions, and thus it favours the appearance of a heterogeneous bubble column regime. The turbulent dispersion force has always a stabilizing action, i.e. it partially compensates the destabilisation induced by a negative lift coefficient. A stability analysis for a mono-dispersed system nevertheless showed, that influence of the lift force is much larger, compared to the influence of the turbulent dispersion force, if only bubble induced turbulence is considered. Thus the stability condition is practically the positive sign of the lift force coefficient. The extension of the analysis to two bubbles classes, from which one being small enough to have a positive lift coefficient, results in a minimum fraction of small bubbles needed for stability. Finally a generalized criterion for N bubble classes and for a continuous bubble size distribution is given.

Keywords: Bubble columns; Bubble; Stability; Modelling; Lift force; Turbulence

  • Chemical Engineering Science 60(2005)13, 3609-3619

Permalink: https://www.hzdr.de/publications/Publ-6613
Publ.-Id: 6613


Modification of Textile Mats with Calixarenes – Separation of Uranium from Mine and Seepage Waters

Jansen, K.; Buschmann, H.-J.; Schmeide, K.; Schollmeyer, E.

More than 40 years of uranium production in Germany left abandoned equipment and mine wastes, which have to be disposed to avoid the release of contaminants into the biosphere. The separation of uranium(VI) from aqueous solution by calixarenes by means of solvent extraction has been described in literature. Calixarenes are macrocyclic ligands formed by the base inducted condensation reaction of para-substituted phenols and formaldehyde. Substituents at the hydroxyl groups control the selectivity of the ligand for the complexation of uranium(VI) ions.
The present work describes the development of a textile filter material for the separation of uranium(VI) from mine and seepage water using uranophile calixarenes. These ligands are permanently fixed on a textile substrate by a process comparable to a disperse dying procedure. For this purpose the calixarenes are statistically functionalized by spacer groups. The filter materials are especially applicable for the remediation of uranium contaminated waters at low concentration levels.

Keywords: calixarene; uranium; extraction; filter

  • Contribution to proceedings
    1st International Textile, Clothing and Design Conference – Magic World of Textiles (Z. Dragcevic, ed.). Faculty of Textile Technology University of Zagreb, Zagreb 2002, p. 692-697

Permalink: https://www.hzdr.de/publications/Publ-6612
Publ.-Id: 6612


Functionalization of Synthetic Polymers by Supramolecular Compounds: Immobilization of Calix[n]arenes on Polyester

Schollmeyer, E.; Jansen, K.; Buschmann, H.-J.; Schmeide, K.

Calix[n]arenes are macrocyclic molecules synthesized by the base induced reaction of para-substituted phenols and formaldehyde. These ligands are known to form complexes with suitable guest substances. The selectivity of the calix[n]arenes is influenced by their size and functional groups. The present paper describes the preparation and application of calix[6]arene derivatives statistically functionalized with 1-alkyl groups at the upper rim. The separation of copper(II), nickel(II), cobalt(II) and uranium(VI) from aqueous solutions has been investigated by solvent extraction, as well as by using calix[6]arene-finished polyester felt. Uranium(VI) separation was studied as a function of pH value and uranium(VI) concentration. Furthermore, the recycling of calix[6]arene finished polyester felts loaded with uranium(VI) ions by elution with different solvents was examined. The suitability for the remediation of uranium contaminated water especially at low concentration levels was shown.

Keywords: Filter; extraction; preconcentration; copper; cobalt; nickel; uranium; calix[n]arene

  • Contribution to external collection
    K.L. Mittal: Polymer Surface Modification: Relevance to Adhesion 3, Zeist: VSP, 2004, 353-366

Permalink: https://www.hzdr.de/publications/Publ-6611
Publ.-Id: 6611


Separation Control at Hydrofoils using Lorentz forces

Mutschke, G.; Gerbeth, G.; Albrecht, T.; Grundmann, R.

Lorentz forces originating from surface-mounted actuators of permanent magnets and electrodes in weakly conducting fluids like seawater can be used to control flow separation at hydrofoils. The numerical results presented here are based on direct numerical simulation in the laminar flow regime, limited to Reynolds numbers of about 500. Control by steady forcing at the suction side and by oscillatory forcing near the leading edge of the foil is investigated in the post-stall regime.

By applying a strong enough steady control, separation can be completely suppressed. Oscillatory forcing always has to compete with the natural shedding process, lock-in behavior may occur. Lift-optimum control for strong amplitudes is found in a frequency band around the natural shedding frequency. In terms of the momentum coefficient describing the control effort, appropriate excitation frequencies in relation to the natural vortex shedding frequency allow for a more effective lift control than steady forcing.

  • European Journal of Mechanics B 25(2006)2, 137-152

Permalink: https://www.hzdr.de/publications/Publ-6610
Publ.-Id: 6610


Validation of coupled neutronic/thermal-hydraulic codes for VVER reactors - final report - FIKS-CT-2001-00166

Mittag, S.; Grundmann, U.; Kliem, S.; Kozmenkov, Y.; Rindelhardt, U.; Et, A.

  • Open Access Logo Wissenschaftlich-Technische Berichte / Forschungszentrum Rossendorf; FZR-408
    ISSN: 1437-322X

Downloads:

Permalink: https://www.hzdr.de/publications/Publ-6609
Publ.-Id: 6609


CFD-Simulation of a Boron Dilution Transient During Start-Up of the Coolant Pump in the 1:5 Scaled VVER-1000 Reactor Model

Höhne, T.; Bezrukov, Y.; Kabanova, L.

During so called boron dilution transients at pressurized water reactors too weakly borated water might enter the reactor core. This can be the case e.g. during re-start of the first main coolant pump after a deborated slug has formed for instance in the loop seal of the cold leg during stop of coolant circulation under Small Break Loss of Coolant Accident (SBLOCA) conditions. The deboration results in the insertion of positive reactivity and possibly leads to a power excursion. This scenario was studied in the 1:5 scaled VVER-1000 reactor model at OKB “Gidropress”.

The deborated slug was modeled by water with lower temperature entering during the start-up of the coolant pump the hot water inside the Reactor Pressure Vessel (RPV). The experiments were repeated 5-6 times to get statistically independent results. The mass flow rate was varied in a series of experiments studying Reynolds-number effects.

The 3-D computational fluid dynamics (CFD) codes provide an effective tool for mixing calculations. In recent years, the rapid development of both the software and the computers has made it feasible to study the coolant mixing in sufficient detail and to perform the calculations for transient conditions. The experiment with the final mass flow rate of 175 m³/h was taken for CFD-validation. The CFD-Code used was CFX-5.

The geometric details of the construction internals inside the RPV have a strong influence on the flow field and on the mixing. Therefore, an exact representation of the cold leg, the inlet region, the spacer in the downcomer, the elliptical perforated plate and the complicated structures in the lower plenum were modeled in detail. Some parts of the lower plenum internals were modeled using resistance coefficients. The computational grid contained 2.5 Mio. tetrahedral elements. The inlet boundary conditions (velocity, temperature) were set at the cold leg. As an initial guess of the turbulent kinetic energy and the dissipation rate the medium intensity was used. The outlet boundary conditions were pressure controlled. As in the experiment, the temperature differences for describing the boron dilution processes were used. A constant temperature at the RPV walls was assumed.

In the VVER-1000 reactor, the same characteristic flow pattern is observed in the case of the start-up of one pump like for Western type PWR. Due to a strong momentum insertion into the flow at the inlet nozzle, also a horizontal component of the flow is generated in the upper part of the downcomer. The injected flow is distributed into two main jets, the minimum boron concentration at the core inlet appears at two outer regions of the core inlet near the affected loop. The experiment and the CFX calculation showed that for the given slug volume a rather good mixing of the slug and the ambient coolant occur.

A comparison of measured and calculated degree of mixing is performed. Reasons for deviation and directions of further model improvements are discussed.

Keywords: Boron Dilution; CFD; Turbulence; PWR

  • Lecture (Conference)
    14th Symposium of AER on VVER Reactor Physics and Reactor Safety, 13.-17.09.2004, Espoo, Finland
  • Contribution to proceedings
    14th Symposium of AER on VVER Reactor Physics and Reactor Safety, 13.-17.09.2004, Espoo, Finland, Proceedings, S.581-593

Permalink: https://www.hzdr.de/publications/Publ-6608
Publ.-Id: 6608


Validation of Trio_U for Transient Accident Scenarios – Numerical Studies of the ROCOM Buoyancy Driven Test Case Simulating ECC Injection During Natural Convection in PWR

Höhne, T.; Bieder, U.

For the validation of the Trio_U code an experiment with constant flow rate in one loop (magnitude of natural circulation) and 10% density difference between ECC and loop water was taken. For this study a LES approach was used for mesh sizes between 340000 – 1.7 mil-lion control volumes. As a result in the experiment as well as in the calculation the ECC water only partly mixes with ambient coolant in the cold leg. A stratified flow is developing during the injection. In the downcomer a momentum driven flow field is still present at the begin-ning, after this the ECC water propagates downwards the downcomer below CL 1. Trio_U calculations show a good qualitative agreement with the experiment, while at local positions some differences in the concentration field occur.

The obtained results can be used for further studies of the core behaviour using coupled thermo-hydraulic-neutron-kinetic code systems.

Keywords: Turbulence; boron dilution transients; LES; TRIO_U

  • Other report
    Note technique SMTH/LDTA N° 2003-079, CEA Grenoble, August 2004

Permalink: https://www.hzdr.de/publications/Publ-6607
Publ.-Id: 6607


In situ characterization of phase formation during high-energy oxygen ion implantation in molybdenum

Bohne, Y.; Shevchenko, N.; Prokert, F.; von Borany, J.; Rauschenbach, B.; Möller, W.

A special designed high-temperature vacuum chamber for in situ X-ray diffraction (XRD) measurements was used to study kinetics of structural phase formation and transformation in molybdenum during oxygen ion implantation and post-annealing treatment. Oxygen ions with an energy of 1.5 MeV were implanted in polycrystalline molybdenum up to a fluence of 3×1018 O+/cm2 at different temperatures (160°C - 700°C). Subsequently, implanted samples were annealed up to 700°C for in situ studying during synthesis of buried oxide layers. Complementary, Transmission Electron Microscopy (TEM) and sputter Auger Electron Spectroscopy (AES) were employed to receive depth dependent information concerning the crystal structure and the elemental composition. The formation of different molybdenum oxides during oxygen implantation and post-implantation annealing process could be observed by in situ x-ray analysis. The XRD spectra of samples implanted at 160°C show that MoO3 and/or Mo4O11 precipitates have been formed, whereas implantation in the temperature range 300°C - 700°C preferably leads to the MoO2 phase formation.

Keywords: : In situ XRD; ion implantation; molybdenum; phase formation

  • Abstract in refereed journal
    Abstract Book of the ECAART8 (8th European Conference on Accelerators in Applied. Research and Technology), September 20-24, 2004, Paris, France
  • Nuclear Instruments and Methods in Physics Research B 240(2005)1-2, 157-161

Permalink: https://www.hzdr.de/publications/Publ-6605
Publ.-Id: 6605


Laboratory astrophysics as exemplified by the Riga dynamo experiment

Gailitis, A.; Lielausis, O.; Platacis, E.; Stefani, F.; Gerbeth, G.

It has been proposed to investigate the magnetorotational instability at a large scale liquid sodium facility. This sort of laboratory astrophysics is encouraged by the recent successful dynamo experiments. We report on our experiences with the Riga dynamo experiment where magnetic field self-excitation is achieved in a cylindrical vessel filled with approximately 2 cube meters of liquid sodium which can reach flow velocities up to 20 m/s. The main experimental results on the kinematic and the saturation regime are compared with numerical modelling. Some focus is also laid on the spectra of the magnetic field and the pressure.

  • Contribution to external collection
    MHD COUETTE FLOWS: Experiments and Models, AIP Conference Proceedings 733(2004), 35-44

Permalink: https://www.hzdr.de/publications/Publ-6604
Publ.-Id: 6604


MRI in Taylor-Dean flows

Stefani, F.; Gerbeth, G.

The magnetorotational instability (MRI) can destabilize hydrodynamically stable flows which are characterized by an angular momentum that is increasing with the radius and by an angular velocity that is decreasing with radius. Its astrophysical importance comes from the fact that the Kepler flow shows exactly such a behaviour. In order to investigate MRI in a laboratory experiment, the Taylor-Couette flow has been proposed as a substitute for the Kepler flow. In this paper we consider the Taylor-Dean flow as another example of a flow profile which can exhibit the necessary radial dependence. Taylor-Dean flows are a combination of the traditional Taylor-Couette flow with an additional flow that is produced by an azimuthal force. Special focus is laid on the case that the Taylor-Couette part of the flow is a rigid body rotation and the magnitude of the Dean flow is adjusted in such a way that in the outer part of the flow the conditions for MRI are fulfilled. Based on the dispersion relation derived by Ji, Kageyama and Goodman, in combination with some preliminary global instability analysis, we give some first estimates for the physical parameters of a Taylor-Dean MRI experiment with liquid sodium.

  • Contribution to external collection
    MHD COUETTE FLOWS: Experiments and Models, AIP Conference Proceedings 733 (2004), 100-113

Permalink: https://www.hzdr.de/publications/Publ-6603
Publ.-Id: 6603


Suppression of Random Coincidences during In-Beam PET Measurements.

Crespo, P.; Barthel, T.; Frais-Kölbl, H.; Griesmayer, E.; Heidel, K.; Parodi, K.; Pawelke, J.; Enghardt, W.

In-beam positron emission tomography (PET) is currently the only method for an in-situ monitoring of charged hadron therapy. However, in-beam PET data, measured at beams with a sub-microsecond-microstructure due to the accelerator radiofrequency (RF), are highly corrupted by random coincidences arising from prompt gamma-rays following nuclear reactions as the projectiles penetrate the tissue. Therefore, since random-correction techniques from conventional PET cannot be applied, at the clinical in-beam PET at the therapy facility at the Gesellschaft fuer Schwerionenforschung (GSI) Darmstadt merely events registered in the pauses (2-3s) between the beam macropulses (< 2s) are reconstructed. Image statistics may increase up to 50% if coincidences acquired during the macropulse, but out of the micropulses, are taken into account. Two methods for suppressing the micropulse-induced random coincidences have been successfully tested at GSI with carbon ion beams. They rely on the synchronization of the gamma-gamma-coincidences measured by the positron camera with the time microstructure of the beam, either by using the RF-signal from the accelerator or the signal of a thin diamond detector placed in the beam path in front of the target. Time and energy correlated spectra, first-measured during the macropulses, together with the corresponding tomographic images of the beta+ activity induced by the beam in a phantom, clearly confirm the feasibility of the proposed random supression methods.

  • Lecture (Conference)
    IEEE Nuclear Science Symposium and Medical Imaging Conference,18.-23.10.2004, Rome, Italy
  • Contribution to proceedings
    IEEE Nuclear Science Symposium and Medical Imaging Conference, 18.-23. 10.2004, Rome, Italia, Conference Record N 45-6, Book of abstract p. 127-128

Permalink: https://www.hzdr.de/publications/Publ-6602
Publ.-Id: 6602


FE-simulation of the viscoplastic behaviour of different RPV steels in the frame of in-vessel melt retention scenarios

Altstadt, E.; Willschuetz, H.-G.; Mueller, G.

Abstract – Assuming the hypothetical scenario of a severe accident with subsequent core meltdown and formation of a melt pool in the reactor pressure vessel (RPV) lower plenum of a Light Water Reactor (LWR) leads to the question about the behav-ior of the RPV. One accident management strategy could be to stabilize the in-vessel debris configuration in the RPV as one major barrier against uncontrolled release of heat and radio nuclides.
To get an improved understanding and knowledge of the melt pool convection and the vessel creep and possible failure processes and modes occurring during the late phase of a core melt down accident the FOREVER-experiments (Failure Of REactor VEssel Retention) have been performed at the Division of Nuclear Power Safety of the Royal Institute of Technology Stockholm. These experiments are simulating the behavior of the lower head of the RPV under the thermal loads of a convecting melt pool with decay heating, and under the pressure loads that the vessel experiences in a depressurization scenario. The geometrical scale of the experiments is 1:10 com-pared to a common LWR.
Accompanying the experiments metallographical and numerical work is performed at the Forschungszentrum Rossendorf. An axisymmetric Finite Element model is devel-oped based on the multi-purpose code ANSYS®. To describe the viscoplastic defor-mation a numerical creep data base (CDB) is developed where the creep strain rate is evaluated in dependence on the current total strain, temperature and equivalent stress. In this way the use of a single creep law, which employs constants derived from the data for a limited stress and temperature range, is avoided. For an evalua-tion of the failure times a damage model according to an approach of Lemaitre is ap-plied. The microstructural investigations give insight to the material state of the vessel wall at different positions. This can be compared with the numerical damage value calculated in the Finite Element Model.
This paper deals with the experimental, numerical, and metallographical results of the creep failure experiment EC-FOREVER-4, where the American pressure vessel steel SA533B was applied for the lower head. For comparison the results of the experi-ment EC-FOREVER-3B, build of the French 16MND5 steel, are discussed, too. Em-phasis is put on the differences in the viscoplastic behaviour of different heats of the RPV steel. For this purpose, the creep tests in the frame of the LHF/OLHF experi-ments are reviewed, too. As a hypothesis it is stated that the sulphur content could be responsible for differences in the creep behaviour.

Keywords: Finite-Element-Method; In-vessel melt retention; Light water reactor; Severe accident scenarios; Creep

  • Lecture (Conference)
    MPA-Seminar, 05.07.2004, Stuttgart, Germany
  • Contribution to proceedings
    MPA-Seminar, 05.-07.10.2004, Stuttgart, Germany, Proceedings pp. 33.1-33.12

Permalink: https://www.hzdr.de/publications/Publ-6601
Publ.-Id: 6601


Efficient light emitting diodes based on nanoscale silicon

Helm, M.; Sun, J.; Potfajova, J.; Winnerl, S.; Dekorsy, T.; Skorupa, W.; Schmidt, B.; Mücklich, A.

After giving an overview about various approaches for silicon based light emitters, we will present our results on Si light emitting diodes prepared by high-dose boron implantation. The electroluminescence (EL) increases with temperature, resulting in a wall-plug efficiency of 0.1% at room temperature. Extensive low-temperature EL measurements allow us to put forward a model, which is based on the interplay between free excitons/carriers and excitons localized at nanoscale boron doping spikes. Finally, we demonstrate an electrically driven resonant-cavity LED based on silicon.

Keywords: silicon; luminescence; implantation; microcavity

  • Physica Status Solidi (c) 2 (2005) 2941-2946

Permalink: https://www.hzdr.de/publications/Publ-6600
Publ.-Id: 6600


Efficient light emitting devices based on nanoscale silicon

Helm, M.

Recently some remarkable advances concerning silicon based light emission have been reported. This has triggered the hope that a practical Si based light source may soon become reality. Several approaches are pursued by research groups worldwide: porous Si, Si nanocrystals and Er3+ in SiO2, Er3+ doped Si, Si/Ge quantum cascade structures, and also more “conventional” Si pn diodes. I will give a survey on some of these approaches and then concentrate on Si pn diodes, fabricated by high-dose boron implantation.

In these structures the electroluminescence (EL) increases with temperature, resulting in a wall-plug efficiency of 0.1% at room temperature. Extensive low-temperature EL measurements allow us to put forward a model, which is based on the interplay between free excitons/carriers and excitons localized at nanoscale boron doping spikes, similar to delta-doped layers produced by MBE. Within this model we are able to explain the EL dependence on current and temperature, as well as an electrical bistability occurring at low temperature. Finally, we have fabricated what is, to our knowledge, the first electrically driven resonant-cavity LED based on silicon.

Keywords: silicon; luminescence; implantation; microcavity

  • Invited lecture (Conferences)
    Invited talk at the International Conference on Superlattices, Nanostructures, and Nanodevices (ICSNN'04), July 19-23, 2004, Cancun, Mexico

Permalink: https://www.hzdr.de/publications/Publ-6599
Publ.-Id: 6599


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