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1 PublicationX-ray structure of 2-(diphenylphosphano)phenyl-4-(hydroxymethyl)benzoate
Mamat, C.; Flemming, A.; Köckerling, M.
Abstract
The title compound, C26H21O3P, was obtained as by-product due to the hydrolysis of the desired tosylated compound. The dihedral angles between the three aromatic rings attached to the P atom lie in the range 78.1 (1)–87.6 (1) . The hydroxymethyl group is disordered between two conformations in a 0.719 (9):0.281 (9) ratio. The hydroxy H atom is not involved in intermolecular interactions, while the hydroxy O atom serves as a donor for weak C-H...O hydrogen bonds, which link the molecules into chains propagating in [011].
Keywords: crystal structure; benzoate functionalized 2-(diphenylphosphano)phenol derivative; hydrogen bonding
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Acta Crystallographica Section E E70(2014), o1288-o1289
DOI: 10.1107/S1600536814024623
ISSN: 1600-5368
Permalink: https://www.hzdr.de/publications/Publ-21075