Publications Repository - Helmholtz-Zentrum Dresden-Rossendorf

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31828 Publications
Sb-related defects in Sb-doped ZnO thin film grown by pulsed laser deposition
Luo, C.; Ping, H. L.; Azad, F.; Anwand, W.; Butterling, M.; Wagner, A.; Kuznetsov, A.; Zhu, H.; Su, S. C.; Ling, F. C. C.;
Sb-doped ZnO films were fabricated on c-plane sapphire using the pulsed laser deposition method and characterized by the Hall effect measurement, X-ray photoelectron spectroscopy, X-ray diffraction, photoluminescence and positron annihilation spectroscopy. Systematic studies on the growth conditions with different Sb composition, oxygen pressure and post-growth annealing were conducted. If the Sb doping concentration is lower than the threshold ~8×E20 cm-3, the as-grown films grown with appropriate oxygen pressure could be n~4×E20 cm-3. The shallow donor was attributed to the SbZn related defect. Annealing these samples lead to the formation of the SbZn-2VZn shallow acceptor which subsequently compensated the free carrier. For samples with Sb concentration exceeding the threshold, the yielded as-grown samples were highly resistive. X-ray diffraction results showed that the Sb dopant occupied the O site rather than the Zn site as the Sb doping exceeded the threshold, whereas the SbO related deep acceptor was responsible for the high resistivity of the samples.
Keywords: ZnO, Sb-doping, shallow donors, shallow acceptors, compensating defects

Publ.-Id: 26200 - Permalink

Magnetohydrodynamic flow simulation in liquid metal batteries
Weber, N.; Personnettaz, P.; Stefani, F.; Weier, T.;
Overview about numerical simulation of liquid metal batteries at HZDR
  • Lecture (Conference)
    OpenFuelCell Workshop, 24.10.2017, Forschungszentrum Jülich, Deutschland

Publ.-Id: 26199 - Permalink

Radionuklide in der Biosphäre - molekulare Wechselwirkung mit Mikroorganismen
Raff, J.;
Im Rahmen des Vortrags wird anhand von verschiedenden Organismen wie Algen, Bakterien und Pilzen erläutert, wie Mikroorganismen mit Radionukliden interagieren und welche Konsequenzen diese Wechselwirkung für das Migrationsverhalten von Radionukliden in der Umwelt hat.
Keywords: Mikroorganismen, Radionuklide, Wechselwirkungen, Migration
  • Invited lecture (Conferences)
    2. Workshop – Helmholtz Cross Program Activity Querschnittsthema Strahlenforschung „Transportprozesse in Mensch und Umwelt", 24.-25.10.2017, Darmstadt, Deutschland

Publ.-Id: 26198 - Permalink

Radionuclides in living organisms – Calorimetric determination of the radionuclide toxicity
Sachs, S.; Fahmy, K.ORC; Oertel, J.; Geipel, G.; Bok, F.
Quantification of radionuclide transfer within the environment and to the food chain is required for the reliable human risk assessment. The uptake of radionuclides by plants is typically described phenomenologically by transfer factors. However, investigations on a molecular level are necessary to understand the underlying processes. We studied the interaction of U(VI) with canola cells (Brassica napus) focusing on the concentration-dependent impact of U(VI) on the cell metabolism. Isothermal microcalorimetry was used to monitor the metabolic heat flow of the cells, which was compared to the cell viability. The speciation of U(VI) in the medium was determined by time-resolved laser-induced fluorescence spectroscopy and thermodynamic modeling. The data reveal the correlation of U(VI) hydroxo species with metabolic heat release and general oxidoreductase on a quantitative toxicity scale [1].

[1] Sachs, S., Geipel, G., Bok, F., Oertel, J., Fahmy, K., Calorimetrically determined U(VI) toxicity in Brassica napus correlates with oxidoreductase activity and U(VI) speciation. Env. Sci. Technol. 51 (2017) 10843.
Keywords: plant cells, uranium, cell metabolisms, isothermal microcalorimetry, cell viability, speciation, TRLFS, thermodynamic modeling, speciation
  • Invited lecture (Conferences)
    2. Workshop - Helmholtz Cross Program Activity, Querschnittsthema Strahlenforschung "Transportprozesse in Mensch und Umwelt", 24.-25.10.2017, Darmstadt, Deutschland

Publ.-Id: 26197 - Permalink

Ultra-high-speed X-ray imaging of laser-driven shock compression using synchrotron light
Olbinado, M. P.; Cantelli, V.; Mathon, O.; Pascarelli, O.; Rack, A.; Grenzer, J.; Pelka, A.; Roedel, M.; Prencipe, I.; Garcia, A. L.; Helbig, U.; Kraus, D.; Schramm, U.; Cowan, T.; Scheel, M.; Pradel, P.; de Resseguier, T.;
A high-power, nanosecond-pulsed laser impacting the surface of a material can generate an ablation plasma that drives a shock wave into it; while in situ X-ray imaging can provide a time-resolved probe of the shock-induced material behaviour on macroscopic lengths scales. Here, we report on an investigation into laser-driven shock compression of a polyurethane foam and a graphite rod by means of single-pulse synchrotron X-ray phase-contrast imaging with a MHz frame rate. A 6-J, 10-ns-pulsed laser was used to generate shock compression. Physical processes governing the laser-induced dynamic response such as elastic compression, compaction, pore collapse, fracture, and fragmentation have been imaged; and the advantage of exploiting the partial spatial coherence of a synchrotron source for studying low-density, carbon-based materials is emphasized. The successful combination of a high-energy laser and ultra-high-speed X-ray imaging using synchrotron light demonstrates the potentiality of accessing complementary information from scientific studies of laser-driven shock compression.
Keywords: laser shock, ultra-high-speed imaging, synchrotron radiation, X-ray phase contrast, time-resolved studies, foam, graphite, shock

Publ.-Id: 26196 - Permalink

Enzymatic Decolourization of Water Using Loofa Sponge as Cellular Carrier: Immobilization and Dye Degradation Performance
Mohammed, I.; Werner, A.; Schubert, M.; Hampel, U.;
In recent years, strong efforts have been made to develop sustainable biocatalytic decolorization processes for dye-polluted water. In particular, dye-oxidizing laccase enzymes immobilized on suitable carriers are promising candidates, which can be reused as long as the activity is sufficiently high.
In this work, we propose, for the first time, a new methodology to immobilize laccase from Trametes hirsute on natural-grown and decomposable cellular loofa sponge carrier and assess the capability to degrade dye-polluted water. High immobilization activity is achieved and about 70 % residual activity remains after 8 cycles. Additionally, we determined homogenous and heterogeneous kinetic parameters for free and immobilized enzymes. Results reveal four times higher Michaelis-Menten constant of the laccase immobilized on loofa due to mass transfer and mixing limitations in packed bed bio-reactor.
Eventually, the response surface methodology was applied to identify favorable operation condition in terms of dye concentration, treatment time and mixing velocity. Here, the results demonstrated a remarkable dye removal capability with shorter treatment time compared to the previous studies on immobilized laccase reported in the literature.
Keywords: Laccase, Enzymatic decolorization, Loofa sponge, Immobilization, activity analysis, Response surface methodology

Publ.-Id: 26195 - Permalink

Observation of ultrafast solid-density plasma dynamics using femtosecond X-ray pulses from a free-electron laser
Kluge, T.; Rödel, M.; Metzkes, J.; Bussmann, M.; Erbe, A.; Galtier, E.; Garcia, A. L.; Garten, M.; Georgiev, Y. M.; Gutt, C.; Hartley, N.; Huebner, U.; Lee, H. J.; Mcbride, E. E.; Nakatsutsumi, M.; Nam, I.; Pelka, A.; Prencipe, I.; Rehwald, M.; Christian, R.; Schönherr, T.; Zacharias, M.; Zeil, K.; Glenzer, S.; Schramm, U.; Cowan, T. E.;
The complex physics of the interaction between short pulse high intensity lasers and solids is so far hardly accessible by experiments. As a result of missing experimental capabilities to probe the complex electron dynamics and competing instabilities, this impedes the development of compact laser-based next generation secondary radiation sources, e.g. for tumor therapy, laboratory-astrophysics, and fusion. At present, the fundamental plasma dynamics that occur at the nanometer and femtosecond scales during the laser-solid interaction can only be elucidated by simulations. Here we show experimentally that Small Angle X-ray Scattering (SAXS) of femtosecond X-ray free-electron laser (XFEL) pulses facilitates new capabilities for direct in-situ characterization of intense short-pulse laser plasma interaction at solid density that allows simultaneous nanometer spatial and femtosecond temporal resolution, directly verifying numerical simulations of the electron density dynamics during the short pulse high intensity laser irradiation of a solid density target. For laser-driven grating targets, we measure the solid density plasma expansion and observe the generation of a transient grating structure in front of the pre-inscribed grating, due to plasma expansion, which is an hitherto unknown effect. We expect that our results will pave the way for novel time-resolved studies, guiding the development of future laser-driven particle and photon sources from solid targets.
  • Open Access LogoPhysical Review X 8(2018), 031068
    DOI: 10.1103/PhysRevX.8.031068
  • Lecture (Conference)
    59th Annual Meeting of the APS Division of Plasma Physics, 23.-27.10.2017, Milwaukee, USA
  • Lecture (Conference)
    10th International Conference on Inertial Fusion Sciences and Applications, 11.-12.09.2017, Saint Malo, Frankreich

Publ.-Id: 26194 - Permalink

Competing forces in liquid metal electrodes and batteries
Ashour, R.; Kelley, D.; Salas, A.; Starace, M.; Weber, N.; Weier, T.;
Liquid metal batteries have been proposed for low-cost grid scale energy storage. During their operation, solid intermetallic phases often form in the cathode and are known to limit the efficiency of the cell. Fluid flow in the liquid electrodes can enhance mass transfer and reduce or avoid the formation of intermetallics, and fluid flow can be promoted by careful choice of the locations and topology of a battery’s electrical connections, which affect the thermal buoyant forces and electromagnetic forces acting on the electrodes. In this context we study four phenomena that drive flow: Rayleigh-Bénard convection, internally heated convection, electro-vortex flow, and swirl flow, in both experiment and simulation. In experiments, we use ultrasound Doppler velocimetry (UDV) to measure the flow of an electrode made of liquid eutectic PbBI at 160 ◦ C and subject to all four phenomena. In numerical simulations, we isolate the phenomena and simulate each separately using OpenFOAM. Comparing simulated velocities to experiments via a UDV beam model, we find that all four phenomena can enhance mass transfer in LMBs. We explain the flow direction and structure, and give estimates for the magnitude of the mean velocity depending on the cell current. We describe how the phenomena interact and propose dimensionless numbers for estimating their mutual relevance. A brief discussion of electrical connections summarizes the engineering implications of our work.


  • Secondary publication expected

Publ.-Id: 26193 - Permalink

In-chip microstructures and photonic devices fabricated by nonlinear laser lithography deep inside silicon
Tokel, O.; Turnalı, A.; Makey, G.; Elahi, P.; Çolakoğlu, T.; Ergeçen, E.; Yavuz, Ö.; Hübner, R.; Zolfaghari Borra, M.; Pavlov, I.; Bek, A.; Turan, R.; Koray Kesim, D.; Tozburun, S.; Ilday, S.; Ilday, F. Ö.;
Silicon is an excellent material for microelectronics and integrated photonics, with untapped potential for mid-infrared optics. Despite broad recognition of the importance of the third dimension, current lithography methods do not allow the fabrication of photonic devices and functional microelements directly inside silicon chips. Even relatively simple curved geometries cannot be realized with techniques like reactive ion etching. Embedded optical elements, electronic devices and better electronic–photonic integration are lacking. Here, we demonstrate laser-based fabrication of complex 3D structures deep inside silicon using 1-μm-sized dots and rod-like structures of adjustable length as basic building blocks. The laser-modified Si has an optical index different to that in unmodified parts, enabling the creation of numerous photonic devices. Optionally, these parts can be chemically etched to produce desired 3D shapes. We exemplify a plethora of subsurface - that is, ‘in-chip’ - microstructures for microfluidic cooling of chips, vias, micro-electromechanical systems, photovoltaic applications and photonic devices that match or surpass corresponding state-of-the-art device performances.

Publ.-Id: 26192 - Permalink

Nanomagnet fabrication by ion beams
Fassbender, J.;
In recent years the tailoring of magnetic properties by means of ion irradiation and implantation techniques has become fashionable. Early investigations relied on the fact that the perpendicular magnetic anisotropy of Co/Pt multilayers depend sensitively on the interface sharpness [1]. Subsequently also the ion induced modification of exchange bias phenomena as well as interlayer exchange coupling have been investigated [2]. For single magnetic films ion implantation has been used to reduce the Curie temperature and hence the saturation magnetization [3]. Nowadays also the reverse process, i.e. the creation of nanomagnets within special binary alloys is employed [4,5]. In combination with lithography or with focused ion beams a pure magnetic patterning becomes possible [6] leading to hybrid magnetic materials [7] with properties different from both, the ion irradiated as well as the untreated material. Even ion induced chemical reduction can be employed to create a nanomagnetic pattern [8,9].
An overview of the present status in this research field will be given.
[1] C. Chappert et al., Science, 280 (1998) 1919.
[2] J. Fassbender, D. Ravelosona, Y. Samson, J. Phys. D, 37 (2004) R179. [3] J. Fassbender, J. McCord, Appl. Phys. Lett., 88 (2006) 252501.
[4] E. Menendez et al., Small, 5 (2009) 229.
[5] R. Bali et al., Nano Lett., 14 (2014) 435.
[6] J. Fassbender and J. McCord, J. Magn. Magn. Mater., 320 (2008) 579. [7] J. McCord, L. Schultz, J. Fassbender, Adv. Mater., 20 (2008) 2090.
[8] S. Kim et al., Nature Nanotechnology, 7 (2012) 567.
[9] J. Fassbender, Nature Nanotechnology, 7 (2012) 554.
Keywords: magnetism, ion irradiation, magnetic patterning
  • Invited lecture (Conferences)
    Moscow International Symposium on Magnetism, 01.-05.07.2017, Moscow, Russia

Publ.-Id: 26191 - Permalink

Gefüge und Eigenschaften des warmfesten Chromstahls P91
Kohlar, S.;
Aus einem Rohrstück des Materials P91 soll nach der Erarbeitung eines Probenplans zunächst das Gefüge in allen 3 Orientierungen metallographisch charakterisiert werden. Anschließend wird das Material mechanisch - technologisch sowie bruchmechanisch und fraktographisch untersucht. Die daraus erhaltenen Werkstoffkennwerte sollen mit dem Gefüge und dem fraktographischen Befund in Beziehung gesetzt werden.
Großer Beleg, angefertigt 2009
  • Open Access LogoWissenschaftlich-Technische Berichte / Helmholtz-Zentrum Dresden-Rossendorf; HZDR-082 2017


Publ.-Id: 26190 - Permalink

Beschleunigertechnologie und Forschung am ELBE - Zentrum für Hochleistungsstrahlenquellen
Justus, M.;
Das ELBE - Zentrum für Hochleistungsstrahlenquellen ist die größte Nutzer-Forschungsanlage des Helmholtz-Zentrums Dresden-Rossendorf (HZDR). Mit dem 40 MeV -Elektronenbeschleuniger werden Wissenschaftlern mit Hilfe von Freie-Elektronen-Lasern, Terahertz-Quellen und Festkörper-Targets verschiedenen Arten von Sekundärstrahlung für interdisziplinäre Grundlagenforschung angeboten. Im Vortrag werden Grundlagen zur Beschleunigerphysik vermittelt und die Bedeutung von Teilchenbeschleunigern für die Forschung aufgezeigt. Anhand von supraleitender Beschleunigertechnik, Freie-Elektronen-Laser, Strahldiagnostik und Kontrollsystemen werden technologischen Herausforderungen und Lösungen für den Betrieb des Elektronenbeschleunigers erläutert. Außerdem werden einige Forschungsergebnisse aus ELBE-Nutzerexperimenten vorgestellt.
  • Lecture (others)
    Wissenschaftliches Seminar, 12.12.2017, Dresden, Deutschland

Publ.-Id: 26189 - Permalink

3D motion validation with clinically used cine-MRI and a MR-LINAC phantom
Dolde, K.; Schneider, S.; Pfaffenberger, A.; Hoffmann, A. L.;
Magnetic resonance (MR)-guided radiotherapy shows high potential to improve the precision and accuracy of radiation therapy. Especially hybrid MR-LINAC devices provide the possibility to perform on-line MR imaging during dose delivery and offer efficient tumour tracking or gating techniques for high-precision treatment of moving tumours. For the commissioning of such systems, the accuracy and reliability of real-time motion tracking through MR-imaging needs to be assessed. In this study we evaluate the dynamic target localization accuracy of a programmable MRI-compatible motion phantom using clinical cine-MRI sequences in all three spatial dimensions.
The phantom (CIRS Model 008M MRI-LINAC Dynamic Phantom) has a body representing a human thorax in shape and proportion that was filled with a 6,61g/l NaCl water solution. It incorporates an off-centric cylindrical rod with embedded gel-based target that can be moved and rotated through a programmable actuator. Sinusoidal motion trajectories with patient-oriented breathing frequencies (0.1-0.2 Hz) and motion amplitudes (5 mm – 20 mm) in all three spatial dimensions were programmed in the phantom’s Motion Control Software. Balanced steady-state free procession sequences (TE/TR=2.3/4.6 ms; FOV=300×300×150 mm³; Res=1.34х1.34 mm², SliceThickness=7 mm, FA=30°) were acquired in cine mode on a 3T MR scanner (Philips Achieva) with a time resolution of 489 ms. The center-of-mass motion of the target was extracted from the cine images using a manual segmentation-based procedure. Both the measured frequency and amplitude were compared to the programmed motion parameters. The frequencies were determined with a Fast Fourier Transform (FFT). The phantom was also fed with a real patient’s 1D-navigator-based breathing pattern to evaluate the accuracy of non-regular target motion detection.
The frequencies (f) and amplitudes (A) extracted from the cine-MRI are in good agreement to the pre-set values. For the sinusoidal motion patterns, we observed 2% deviations between the measured and pre-set frequencies in IS direction for f=0.1 Hz and f=0.2 Hz with A=20 mm. In AP and LR direction the frequency deviation is 3% for f=0.2 Hz and A=5 mm. The amplitudes were determined with a precision of 99% in IS, and 92% in AP/LR direction with deviations smaller than 0.4 mm. For the real patient’s navigator breathing-pattern with main frequency components between 0.14-0.2 Hz and amplitudes between 5-20 mm we observed an amplitude accuracy of 98% with a maximum deviation of 1.2 mm in IS direction. The uncertainties in frequency and amplitude are dominated by the spatial and time resolution.
The study shows motion parameters of the MRI-LINAC Phantom to be extracted from cine-MRI with high accuracy. Dynamic target localization through cine-MRI is feasible and accurate for the management of respiratory motion in radiation oncology.
Keywords: Intrafractional Motion Management - Tracking
  • Poster
    Estro 37, 20.04.2018, Barcelona, Spain
  • Open Access LogoAbstract in refereed journal
    Radiotherapy and Oncology 127(2018), S511-S512
    DOI: 10.1016/S0167-8140(18)31251-9

Publ.-Id: 26188 - Permalink

S-layer protein-AuNP systems for the colorimetric detection of metal and metalloid ions in water
Jung, J.; Lakatos, M.; Bengs, S.; Matys, S.; Raff, J.; Blüher, A.; Cuniberti, G.;
Bacterial surface layer proteins (S-layer) possess unique binding properties for metal ions. By combining the binding capability of S-layer proteins with the optical properties of gold nanoparticles (AuNP), namely plasmonic resonance, a colorimetric detection system for metal and metalloid ions in water was developed. Eight S-layer proteins from different bacteria species were used for the functionalization of AuNP. The thus developed biohybrid systems, AuNP functionalized with S-layer proteins, were tested with different metal salt solutions, e.g. Indium(III)-chloride, Yttrium(III)-chloride or Nickel(II)-chloride, to determine their selective and sensitive binding to ionic analytes. All tested S-layer proteins displayed unique binding affinities for the different metal ions. For each S-layer and metal ion combination markedly different reaction patterns and differences in concentration range and absorption spectra were detected by UV/Vis spectroscopy. In this way, the selective detection of tested metal ions was achieved by differentiated analysis of a colorimetric screening assay of these biohybrid systems. A highly selective and sensitive detection of yttrium ions down to a concentration of 1.67×10-5 mol/l was achieved with S-layer protein SslA functionalized AuNP. The presented biohybrid systems can thus be used as a sensitive and fast sensor system for metal and metalloid ions in aqueous systems.
Keywords: S- layer; gold nanoparticles; colorimetric assay; Rare Earth Elements
  • Colloids and Surfaces B: Biointerfaces (2019)

Publ.-Id: 26187 - Permalink

Nanoscale imaging and compositional analysis in the helium ion microscope
Klingner, N.ORC; Heller, R.; Hlawacek, G.; Möller, W.; Facsko, S.
Ongoing miniaturization in semiconductor industry, nanotechnology and life science demands further improvements for high-resolution imaging, fabrication and analysis of the produced nanostructures. Continuously shrinking object dimensions led to an enhanced demand on spatial resolution and surface sensitivity of modern analysis techniques.
Ion beam analysis performed on nanometer scale may comply with this challenge. Therefore a minimal probe size is required which can be achieved using a Gas Field Ionization Source (GFIS) in a Helium Ion Microscope (HIM). Due to the high brightness of up to 5•109 A•cm-2•sr-1 and the sharp primary ion energy of 30000 ± 1 eV spot sizes of 0.5 nm can be achieved.
Besides the probe size, the nanoscale analysis is limited by the extremely small amount of sample material and the resulting severe ion beam damage. Only the combination of the techniques with highest degree of information could reveal the composition of nanoscale objects.
Secondary Ion Mass Spectrometry (SIMS), as one of the most powerful techniques for surface analysis directly provides information about elemental, molecular and even isotopic composition. However, quantification in mixed layers cannot be done from pure SIMS measurements without comparison to standards. This drawback is partly compensated by Rutherford Backscattering Spectrometry (RBS) but at a loss of sensitivity. In order to combine this compositional information with the high resolution Secondary Electron (SE) imaging correlative microscopy represents the best way.
Recently, we implemented minimal invasive Time of Flight (TOF) spectrometry into the HIM to enable SIMS as well as RBS [1, 2]. The TOF measurements are triggered by blanking the primary ion beam into an existing Faraday cup and release the beam for short time windows to ensure minimal applied fluencies and obtaining a maximum of information from the region of interest.
In the present contribution we intent to present the technical realization of our approach and show results, drawbacks and derive conclusions for the practical use of this promising technique.
[1] N. Klingner, R. Heller, G. Hlawacek, J. von Borany, J.A. Notte, J. Huang, S. Facsko. Ultramicroscopy 162 (2016), 91-97
[2] R. Heller, N. Klingner, G. Hlawacek. Helium Ion Microscopy, Chapter 12, Springer (2016)
Keywords: HIM SIMS Nano TOF
  • Invited lecture (Conferences)
    23rd International Conference on Ion Beam Analysis IBA-2017, 11.10.2017, Shanghai, China

Publ.-Id: 26186 - Permalink

Interaction between Double Diffusive Convection and Solidification in Ammonium-Chloride Solutions
Anders, S.; Eckert, S.;
This paper presents an experimental investigation of thermally and chemically driven convection with simultaneous crystallisation in a concentrated aqueous ammonium-chloride solution. Measurements were performed in a transparent Hele-Shaw cell (200·100·10mm3) between two massive copper blocks equipped with internal water channels controlling the thermal boundary conditions at the upper and lower horizontal boundaries. The temperatures were regulated by thermostats in a range between -20°C and +40°C giving Rayleigh numbers up to around 0.2·10 9 . A double-wall construction with climatisation was implemented in order to avoid thermal losses through the side walls. Temperatures were monitored by thermocouples calibrated to an accuracy better than 0.05K.
Various flow regimes were studied by choosing different temperature boundary conditions.
The focus was on configurations with negative vertical temperature gradients where thermal convection occurs once a critical temperature difference is exceeded. At sufficient supercooling free crystals nucleate in the upper part of the cell, grow and descend due to their higher density compared to the ambient fluid.
The flow field in the liquid was measured by PIV using fluorescent tracer-particles and laser illumination. PTV with LED-background lighting was used to determine the size-evolution and the trajectories of the free-moving crystals. The application of alternating lighting methods and advanced digital image filtering allows for simultaneous operation of PIV and PTV. This approach enables a quantitative study of the interplay of different convection regimes and the solidification process. For example the relation between drag-coefficient, crystal size and crystal growth was investigated.
As a reference case a stable stratification resulting from parallel cooling of the top and bottom walls was investigated. The following solidification phenomena were observed during the experiments: columnar growth at the walls, nucleation and growth of equiaxed crystals in the bulk, chimney-formation in the mushy layer as well as the remelting of columnar and equiaxed dendrites.
Keywords: equiaxed solidification, double diffusive convection, dual phase velocimetry, PTV, PIV
  • Lecture (Conference)
    SP17, Solidification Processing 2017, 25.-28.07.2017, Beaumont Estate, Old Windsor, United Kingdom
  • Contribution to proceedings
    SP17, Solidification Processing 2017, 25.-28.07.2017, Beaumont Estate, Old Windsor, United Kingdom
    Proceedings of the 6th Decennial International Conference on Solidification Processing, London: BCAST, Brunel University London, 978-1-908549-29-7, 350-353


Publ.-Id: 26185 - Permalink

Combined experimental and numerical analysis of a bubbly liquid metal flow
Krull, B.; Strumpf, E.; Keplinger, O.; Shevchenko, N.; Fröhlich, J.; Eckert, S.; Gerbeth, G.;
The paper proposes a combined experimental and numerical procedure for the investigation of bubbly liquid-metal flows. It describes the application to a model configuration consisting of a recirculating GaInSn flow driven by an argon bubble chain. The experimental methods involve X-ray measurements to detect the bubbles and UDV measurements to gain velocity information about the liquid metal. The chosen numerical method is an immersed boundary method extended to deformable bubbles. The model configuration includes typical phenomena occurring in industrial applications and allows insight into the physics of bubbly liquid-metal flows. It constitutes an attractive test case for assessing further experimental and numerical methods.
Keywords: Bubbly liquid-metal flows, Xray radiography, UDV, GaInSn

Publ.-Id: 26184 - Permalink

Development of an 18F-radioligand for in vivo monocarboxylate transporter 1 (MCT1) tumor imaging with PET
Sadeghzadeh, M.; Brust, P.; Fischer, S.; Moldovan, R.-P.;
Impressive developments in the areas of imaging technology and imaging tracers have strengthened preclinical imaging studies on the “hallmarks of cancer” to provide fundamentals for translation to the clinic. Until today, many positron emission tomography (PET) based molecular biomarkers have been used with that regard [1]. Particularly, significant effort has been dedicated to the development and validation of PET biomarkers for tumor cell proliferation and metabolism. Monocarboxylate transporter 1 (MCT1) is an integral plasma membrane protein which bidirectionally transports lactate and ketone bodies along a concentration gradient and is highly expressed in non-hypoxic regions of human colon, breast, head and neck, lung and other tumors. Accordingly, MCT1 inhibitors are regarded to be of potential clinical use [2]. Since there is no selective PET tracer available based on this class of compounds the aim of this project is the development an 18F-labelled radioligand for in vivo imaging of MCT1-overexpressing brain tumors.
Keywords: Fluorine-18 radioligand, Positron Emission Tomography (PET) imaging, Monocarboxylate transporter 1 (MCT1), Brain Tumor
  • Poster
    Network Meeting of the Alexander von Humboldt Foundation, 18.-20.10.2017, Bielefeld, Germany

Publ.-Id: 26183 - Permalink

Comparison of robust optimized proton planning strategies for dose escalation in pancreatic cancer
Stefanowicz, S.; Zschaeck, S.; Rehm, M.; Jakobi, A.; Stützer, K.; Troost, E. G. C.;
Purpose or Objective
In patients with locally advanced unresectable pancreatic cancer, neoadjuvant or primary radiochemotherapy (RCT) are alternative treatment options. Today, treatment outcome after RCT is poor, in part due to radiosensitive organs at risk (OARs) limiting the prescribed dose to the target volume. Proton beam techniques enable delivering high radiation doses to the target volume while sparing OARs. In this in-silico feasibility study, we assessed different strategies for dose escalation to 66Gy(RBE) using a simultaneous integrated boost technique and robust multi-field optimized intensity modulated (rMFO-IMPT) pencil beam scanned protons and evaluated their robustness.

Material and Methods
For each of six pancreatic cancer patients, four different rMFO-IMPT plans were optimized on free-breathing treatment planning CTs using the RayStation treatment planning system (V5.99, RaySearch Laboratories AB, Sweden). These planning strategies consisted of equally-weighted beams: (S1) two posterior oblique (PO) beams, (S2) lateral right beam and left PO beam, (S3) two PO beams plus right non-coplanar beam, and (S4) three non-coplanar beams. At least 95% of 66Gy(RBE) in 30 fractions was prescribed to 95% of the boost volume (GTV), and 51Gy(RBE) was prescribed to 95% of the CTV (GTV with margin and elective volume). A dose fall-off range of 10 mm around the GTV was preset, and setup and range uncertainty parameters of 3 mm and of 3.5% for GTV and CTV coverage were chosen, respectively. The OAR dose constraints adhered to local guidelines and QUANTEC. For each patient and planning strategy, conformity and homogeneity index (CI, HI) of target doses as well as doses to GTV, CTV, and OARs were calculated. Together with additional robustness evaluations of the worst-case scenarios (±3 mm, ±3.5%) the best planning strategy for dose escalation was sought for.

All nominal plans reached the prescribed dose to the GTV and CTV (Fig. 1a). The CI of all planning strategies was similar (mean CI: 0.6-0.7) even though S3 and S4 were more homogeneous. In some patients, S1 was associated with excess dose to the kidneys (Fig. 1b). Radiation doses (D2%, V45Gy) to the duodenum exceeded the constraints since that OAR was next to or within the target volume, while for the remaining gastrointestinal organs radiation doses were similar for the different strategies and within preset limits (Fig. 1c, d). Overall, S3 and S4 showed the best dose distribution for all OARs. Robustness evaluation of all plans revealed that in total only 38% of the D95% values (S1: 31%, S2: 31%, S3: 39%, S4: 51%) in the worst-case scenarios fulfilled the dose requirement for the GTV leading to an insufficient robustness. Conversely, more than 90% of the D95% values to the CTV were robust against uncertainties, with S3 being most robust (97%).

Disregarding the inter- and intra-fractional organ motion, dose escalation is possible using robust MFO-IMPT plans with three beams, of which at least one non-conformal.
Keywords: Robust planning

Publ.-Id: 26182 - Permalink

Aliovalent cation substitution in UO2: Electronic and local struc-tures of U1-yLayO2±x solid solutions
Prieur, D.ORC; Martel, L.; Vigier, J.-F.; Scheinost, A. C.; Kvashnina, K. O.; Somers, J.; Martin, P. M.
For nuclear fuel related applications, the oxygen stoichiometry of mixed oxides U1-yMyO2±x is an essential property as it af-fects the fuel properties and may endanger the safe operation of nuclear reactors. A careful review of the open literature indicates that this parameter is difficult to assess properly and that the nature of the defects, i.e. oxygen vacancies or UV, in aliovalent cation – doped UO2 is still subject to controversy. To confirm the formation of UV, we have investigated the room temperature stable U1-yLayO2±x phase using several experimental methods (e.g. XRD, XANES and NMR) confirmed by theo-retical calculations. This paper presents the experimental proof of UV and its effect we identified in both electronic and local structure. We observe that UV is formed in quasi equimolar proportion as LaIII in U1-yLayO2±x (y=0.06; 0.11; 0.22) solid solu-tions. The fluorite structure is maintained despite the cationic substitution but the local structure is affected as variations of the interatomic distances are found. Therefore, we provide here the definitive proof that the substitution of UIV with LaIII is not accommodated by the creation of O vacancies as has often been assumed. The UO2 fluorite structure compensates the incorporation of an aliovalent cation by the formation of UV in quasi equimolar proportions
Keywords: UO2, Lanthanum, XANES, EXAFS, NMS


Publ.-Id: 26181 - Permalink

Inter-center variability in CT-to-SPR conversion in particle therapy: Survey-based evaluation
Taasti, V.; Bäumer, C.; Dahlgren, C.; Deisher, A.; Ellerbrock, M.; Free, J.; Gora, J.; Kozera, A.; Lomax, T.; de Marzi, L.; Molinelli, S.; Teo, K.; Wohlfahrt, P.; Peetersen, J.; Muren, L.; Hansen, D.; Richter, C.;
To assess the inter-center variability of the conversion between CT number and particle stopping power ratio (SPR), a survey-based evaluation was carried out in the framework of the European Particle Therapy Network (EPTN). The conversion is applied to treatment planning CTs to finally derive the proton range in patients. Currently, CT scan protocols for treatment planning are not standardized in image acquisition and reconstruction parameters. Hence, the CT-to-SPR conversion (Hounsfield look-up table, HLUT), depending on the former parameters, has to be defined by each center individually. Aiming to access the current status of inter-center differences, this investigation is a first step towards better standardization of CT-based SPR derivation.
A questionnaire was sent out to particle therapy centers involved in the EPTN and a few centers in the United States. The questionnaire asked for details on CT scanners, acquisition and reconstruction parameters, the calibration and definition of the HLUT, as well as body-region specific HLUT selection. It was also assessed whether the influence of beam hardening (BH) on the HLUT was investigated and if an experimental validation of the HLUT was performed. Furthermore, different future techniques were rated regarding their potential to improve range prediction accuracy.
Twelve centers completed the survey (10 in Europe, 2 in the US). Scan parameters, especially reconstruction kernel and beam hardening correction, as well as the HLUT generation varied widely between centers. Eight of the twelve centers applied a stoichiometric calibration method, while three defined the HLUT entirely based on tissue substitutes, and one center used a combination of both. All facilities performed a piecewise linear fit to convert CT numbers into SPRs, but the number of line segments used varied from 2 to 11 (Table 1). Nine centers had investigated the influence of BH, and seven of them had evaluated the size dependence of their conversion. All except one center had validated their HLUT experimentally, but the validation schemes varied widely. A few things were though found to be common for most centers: 1) CT scans were most commonly acquired at 120 kVp, 2) all centers individually customized their CT-to-SPR conversion, and 3) dual energy CT was seen as a promising technique to reduce CT-related uncertainties (Figure 1).
In general, a large inter-center variability in implementation of CT scans, image reconstruction and especially in CT-to-SPR conversion was found. The benefit of a future standardization is obvious: It would reduce the time-intensive site-specific efforts as well as variations in treatment quality. Due to the interdependency of multiple parameters, no conclusion can be drawn on the derived SPR accuracy and its inter-center variability. As a next step within the EPTN, an inter-center comparison of CT-based SPR prediction accuracy will be performed with a ground-truth phantom.
Keywords: proton therapy, Stopping power ratio, CT, HLUT
  • Lecture (Conference)
    ESTRO 37, 20.-24.04.2018, Barcelona, España
  • Poster
    57th Annual Meeting of the Particle Therapy Co-Operative Group (PTCOG), 21.-26.05.2018, Cincinnati, USA
  • Open Access LogoAbstract in refereed journal
    Radiotherapy and Oncology 127(2018), S533-S534
    DOI: 10.1016/S0167-8140(18)31279-9

Publ.-Id: 26180 - Permalink

Spin-wave reciprocity in the presence of Néel walls
Körber, L.ORC; Wagner, K.; Kákay, A.ORC; Schultheiß, H.ORC
The reciprocity of spin-wave propagation in 180° Néel walls and surrounding domains is studied. For this, the dispersion relation, phase fronts and spin-wave intensities are analyzed via micromagnetic simulations. Despite the in-plane curling of the magnetization, the domain wall itself acts as a reciprocal channel, whereas non-reciprocal spin-wave propagation is found within the domains. Since the spin-wave localization depends on the selected frequency, this may allow to control the degree of propagation asymmetry.
Keywords: Nanomagnetics, spin waves, domain wall, reciprocity, micromagnetics


Publ.-Id: 26179 - Permalink

Laboratory-scale X-ray absorption spectroscopy approach for actinide research: Experiment at the uranium L3-edge
Bes, R.; Ahopelto, T.; Honkanen, A.-P.; Huotari, S.; Leinders, G.; Pakarinen, J.; Kvashnina, K. O.;
We report the first proof of principle of an efficient and cost-effective bentchtop alternatives to synchrotron radiation beamlines to perform at laboratory scale Xray Absorption Spectroscopy (XAS) at the U L3-edge in transmission mode. We find excellent agreement with synchrotron-based studies for concentrated samples, in reasonable acquisition time, for UO2, KUO3 and b-UO3 samples. The approach described here already constitutes an inexpensive answer to the XAS beamline over-subscription in the field of actinide’s research for state of the art experiments.
Moreover, our results opens the door to many future applications in the field of actinide’s research, including f-electron chemistry, environmental chemistry and nuclear energy physico-chemistry such as advanced nuclear fuel and long term
nuclear waste disposal.


  • Secondary publication expected

Publ.-Id: 26178 - Permalink

New insight in the uranium valence state determination in UyNd1-yO2-x
Bes, R.; Kvashnina, K.; Rossberg, A.; Dotavio, G.; Desgranges, L.; Pontillon, Y.; Solari, P. L.; Butorin, S. M.; Martin, P.;
The charge compensation mechanisms in UyNd1-yO2-x and its consequence on the overall O stoichiometry (or O/M ratio where M=Nd+U) have been studied through the uranium valence state mixture evolution as a function of Nd content up to y=0.62 by means of high energy resolution fluorescence detection X-ray absorption spectroscopy (HERFD-XAS) at the U M4-edge. Our results clearly demonstrate the formation of U5+ at low Nd content (y < 0.15). Upon increasing the Nd content, oxygen vacancies and the formation of U6+ appear as competing mechanisms for intermediate Nd concentrations, leading to the co-existence of U4+/U5+/U6+ mixed valence and an overall hypostoichiometry (O/M < 2.00). Finally, the formation of U6+ associated with strongly distorted U local environment is observed for high Nd concentrations (y=0.62), leading to an overall hyperstoichiometry (O/M < 2.00)


  • Secondary publication expected

Publ.-Id: 26177 - Permalink

Electronic structure studies of bismuth compounds by high energy resolution X-ray spectroscopy and ab-initio calculations
Mistonov, A. A.; Chumakov, A. P.; Ermakov, R. P.; Iskhakova, L. D.; Zakharova, A. V.; Chumakova, A. V.; Kvashnina, K. O.;
Bismuth-based compounds are widely used as superconductors, catalysts and material for optical devices. Its properties and possibilities to control it are determined by the electronic structure and local environment of Bi-centres. Although x-ray spectroscopy is a powerful method to reveal the crystal and electronic structures, the results obtained so far were limited by the energy resolution of the experimental data. Here we report, for the first time, x-ray absorption near edge structure (XANES) data, recorded in high energy resolution uorescence detection (HERFD) mode at the Bi LIII and LI edges for the number of bismuth compounds. Experimental data are analyzed by ab initio calculations, using finite difference method (FDMNES) code for metallic Bi, Bi2O3, BiPO4, Bi4(GeO4)3 and NaBiO3 compounds. It is shown, that oxidation state as well as Bi-ligand bonds length determines the exact position of the absorption edge. Additionally, the strong Bi p-d orbital mixing is observed. The obtained results can be used as an input for the further electronic structure investigations of the bismuth compounds, in different chemical states.


  • Secondary publication expected

Publ.-Id: 26176 - Permalink

Investigating spin-transfer torques induced by thermal gradients on magnetic tunnel junctions using microcavity ferromagnetic resonance
Cansever, H.; Fowley, C.; Narkovic, R.; Lenz, K.; Kowalska, E.; Yildirim, O.; Aleksandrov, Y.; Lindner, J.; Fassbender, J.; Deac, A. M.;
Similar to electrical currents flowing through magnetic multilayers [1], it has been predicted that thermal gradients applied across the spacer of a spin-valve or a magnetic tunnel junction may induce pure spin currents and generate ‘thermal’ spin-transfer torques (T-STTs) large enough to induce magnetization dynamics [2-3]. Nevertheless, providing detailed experimental studies in this direction has so far proved elusive, due to difficulties in generating sufficiently large thermal gradients for such effects to be observed. Here, we describe a different approach, which focuses on observing and quantifying spin-transfer torques induced by thermal gradients in magnetic multilayers by means of ferromagnetic resonance (FMR) response under open circuit conditions. The FMR response is measured using specially designed planar microresonators, which generate ac fields perpendicular to the plane of the layers [4]. Such microresonators, with loop diameters of 10 and 20 μm were optimized at a fixed frequency of 14 GHz. Magnetic multilayers with different compositions were patterned using electron-beam lithography into micron-sized pillars with different cross-sections. Microresonators were fabricated using UV lithography such that the magnetic device lies in the center of the loop. An example is shown in Fig 1. For laser heating, we used a diode laser with 51 mW power (5-10 μm focus in diameter). Fig 2 shows a set of FMR measurements performed on an 8x10 μm elliptical shape Py/Cu/Py magnetic multilayer under laser heating, with different laser powers. A clear change is observed at higher than 30 mW laser power, with the FMR line exhibiting changes in resonance field and linewidth. These changes likely arise from a combination of the induced TSTT and the heating of the whole device. The results are analyzed by means of conventional FMR modeling and the thermal gradients are estimated from COMSOL simulations.This project is funded by DFG Priority Programme SPP 1538 Spincaloritronics (SpinCat) and supported by the Nanofabrication Facilities at Ion Beam Center.
Keywords: thermal spin transfer torque, microresonator, ferromagnetic resonance, magnetic tunnel junction.
  • Lecture (Conference)
    Magnetism and Magnetic Materials MMM 2017, 06.-10.11.2017, Pittsburgh, PA, USA

Publ.-Id: 26175 - Permalink

Decoupling the two roles of Ga droplets in the self-catalyzed growth of GaAs nanowires on SiOx/Si(111) substrates
Tauchnitz, T.ORC; Nurmamytov, T.; Hübner, R.; Engler, M.ORC; Facsko, S.; Schneider, H.; Helm, M.; Dimakis, E.ORC
Liquid Ga droplets play a double role in the self-catalyzed growth of GaAs nanowires on Si(111) substrates covered with a native SiOx layer: they induce the formation of nano-sized holes in SiOx and then drive the uniaxial nanowire growth directly onto the underlying Si. The independent control of the two mechanisms is a prerequisite for mastering the growth of nanowires, but it is challenging in a conventional growth procedure where they both take place under the same droplets. To that end, we have developed an in situ procedure where the Ga droplets used for the formation of SiOx holes are removed before new Ga droplets drive the growth of GaAs nanowires. In that way, it was made possible to study the interaction between Ga droplets and SiOx, to create holes in SiOx with controlled number density and size and, finally, to grow GaAs nanowires only within those holes. Our results show unprecedented control of the nanowire nucleation with unique possibilities: (1) deliberate control of the number density of nanowires within three orders of magnitude (106-109 cm-2) without patterning the substrate and without changing the growth conditions, (2) highly synchronous nucleation events and, thus, exceptionally narrow nanowire length distributions (standard deviation < 1 % for 3 mm long nanowires), (3) high yield of vertical nanowires up to 80 % (against GaAs islands), (4) highly reproducible results, and (5) independent control of the nanowire diameter from the number density. We anticipate that our methodology could be also exploited for different materials or other types of nanostructures.

Publ.-Id: 26174 - Permalink

AER Working Group D on VVER Safety Analysis – Report of the 2017 Meeting
Kliem, S.ORC
The AER Working Group D on VVER reactor safety analysis held its 26th meeting in Erlan-gen, Germany, during the period 10-11 May, 2017. The meeting was hosted by AREVA Germany and was held in conjunction with the 11th workshop on the OECD Benchmark for Uncertainty Analysis in Best-Estimate Modelling (UAM) for Design, Operation and Safety Analysis of LWRs. Altogether 11 participants attended the meeting of the working group D, all 11 from AER member organizations. The co-ordinator of the working group, Mr. S. Kliem, served as chairman of the meeting.
The meeting started with a general information exchange about the recent activities in the participating organizations.
The given presentations and the discussions can be attributed to the following topics:
• Safety analyses methods and results
• Code development and benchmarking
• Future activities
A list of the participants and a list of the handouts distributed at the meeting are attached to the report. The corresponding PDF-files of the handouts can be obtained from the chairman.
  • Contribution to proceedings
    27th Symposium of AER on VVER Reactor Physics and Reactor Safety, 17.-20.10.2017, München, Deutschland
    Proceedings of the 27th Symposium of AER on VVER Reactor Physics and Reactor Safety, Budapest, 9789637351280, 11-18
  • Lecture (Conference)
    27th Symposium of AER on VVER Reactor Physics and Reactor Safety, 17.-20.10.2017, München, Deutschland

Publ.-Id: 26173 - Permalink

Production of Amphiphilic Hydroxamate Siderophores Marinobactins by Marinobacter sp. DS40M6 for Bioflotation Process
Schrader, S.; Kutschke, S.; Rudolph, M.; Pollmann, K.;
Marinobacter sp. DS40M6 produces the siderophores marinobactins, which are amphiphilic and contain hydroxamate functional groups responsible for a strong complexation of iron(III). First tests about growth and production conditions showed on the one hand a high rate for both growth of bacteria and siderophore production at 25°C. The pH value, on the other hand, demonstrated a contrary effect, thus the optimal pH 7.0 for growth was not the most efficient pH value for siderophore production.

Publ.-Id: 26172 - Permalink

Bioflotation with amphiphilic siderophores
Schrader, S.; Kutschke, S.; Pollmann, K.; Rudolph, M.;
Siderophores are small organic molecules with a high affinity for binding Fe(III) and the ability to form strong complexes. They are produced by microorganisms (aerobic bacteria and fungi) and some plants to equalize the low bioavailability of iron in their environment.
The biotechnological production of siderophores offers the application in very different fields. For example, they are used as medicine against iron or heavy metal poisoning. Other applications are their utilization for the extraction, recovery and treating of iron as well as other elements, that also can be bound by siderophores. In addition, their application in froth flotation processes could be an attractive novel approach. Molecules produced by the chemical industry with functional groups like hydroxamates have been already applied successfully in this processing method. It can be suggested that siderophores carrying the same functional groups should also work well as collectors. Particularly the group of amphiphilic siderophores that have both hydrophilic and hydrophobic areas are very interesting. The natural hydrophobic property of these chelating agents could avoid additional chemicals and further working steps for making the target mineral particles hydrophobic for an efficient flotation process.
The main advantage of using biotechnology for the production of siderophores is the wide natural diversity of the structures. A lot of microorganisms and their produced siderophores have already been identified and analyzed in detail. So there is an enormous variety of different molecules available. The aim of this study is to test for the first time, whether it is possible to use siderophores in flotation processes. In addition optimized processes for both the biotechnological production and the froth flotation have to be developed. This presupposes also the investigation and characterization of the binding properties during these procedures.
  • Lecture (Conference)
    Mineral Engineering Conference 2017, 20.-23.09.2017, Wisła, Poland

Publ.-Id: 26171 - Permalink

Bioflotation – Kombination der Biotechnologie mit dem klassischen Prozess der Flotation
Schrader, S.; Kutschke, S.; Pollmann, K.; Rudolph, M.;
Die Idee der Verknüpfung von Biotechnologie mit der Aufbereitung von Mineralien wurde auf den Gebieten Bioleaching von Metallen und Bioremediation mineralischer Abfälle bereits eingehend untersucht. Ein neues Interessensgebiet ist nun die Kombination von Biotechnologie mit dem klassischen Prozess der Flotation.
  • Poster
    Tagung Aufbereitung und Recycling, 08.-09.11.2017, Freiberg, Deutschland

Publ.-Id: 26170 - Permalink

Production of amphiphilic hydroxamate siderophore marinobactin by Marinobacter sp. DS40M6 for bioflotation process
Schrader, S.; Kutschke, S.; Rudolph, M.; Pollmann, K.;
Siderophores are small biomolecules (400-1500 Da) with the ability to form strong complexes with Fe(III) and other metals. A wide range of siderophore structures are already well-known.
The biotechnological production of these organic compounds with bacteria enables them to be used for extracting and recycling metals.
The application of siderophores in traditional froth flotation process enables the development of a sustained bioflotation.
Keywords: siderophores; marinobactin; bioflotation
  • Poster
    22. International Biohydrometallurgy Symposium 2017, 24.-27.09.2017, Freiberg, Deutschland

Publ.-Id: 26169 - Permalink

Variability in crystal surface reactivity: A critical constraint for reactive transport modeling
Fischer, C.;
Reactive transport modeling of fluid-solid interactions relies on (i) contrasts in fluid flow velocity and (ii) variability of surface reactivity. The first point is based on data from, e.g., PET and µCT techniques. The second point, however, is usually addressed by simple kinetic data only. Thus, it neglects information about the intrinsic variability of crystal surface reactivity that often results in a rate range of 2-3 orders of magnitude (1). Such variability is however an important constraint for the evolution of surface roughness and porosity pattern in crystalline matter (2). Here, we highlight important sources of the intrinsic variability of crystal surface reactivity and their impact on surface reaction rates. Rate maps (3) and rate spectra (4) provide critical information about the spatial and temporal variability of surface reactivity that is required to predict the evolution of porosity pattern in crystalline matter (5).

1. Luttge A, Arvidson RS, & Fischer C (2013) A Stochastic Treatment of Crystal Dissolution Kinetics. Elements 9(3):183-188.
2. Fischer C, Kurganskaya I, Schäfer T, & Luttge A (2014) Variability of Crystal Surface Reactivity: What do we know? (Review Article). Applied Geochemistry 43:132-157.
3. Fischer C & Luttge A (2017) Beyond the conventional understanding of water–rock reactivity. Earth and Planetary Science Letters 457:100-105.
4. Fischer C, Arvidson RS, & Luttge A (2012) How predictable are dissolution rates of crystalline material? Geochimica et Cosmochimica Acta 98:177-185.
5. Michaelis M, Fischer C, Colombi Ciacchi L, & Luttge A (2017) Variability of Zinc Oxide Dissolution Rates. Environmental Science & Technology 51(8):4297-4305.
  • Poster
    Reactive Transport in the Earth and Environmental Sciences in the 21st Century, 02.-05.10.2017, Amboise, Frankreich

Publ.-Id: 26168 - Permalink

Manipulation of antiferromagnetic domain distribution in Mn2Au by ultrahigh magnetic fields and by strain
Sapozhnik, A. A.; Abrudan, R.; Skourski, Y.; Jourdan, M.; Zabel, H.; Kläui, M.; Elmers, H. J.;
Evidence for a spin reorientation in antiferromagnetic (AFM) Mn2Au thin films induced by high magnetic fields as well as by the application of in-plane mechanical stress is provided. The AFM domain population in the samples was investigated by resonant X-ray Magnetic Linear Dichroism (XMLD) measurements at the L3 edge of Mn using a variable linear polarization of the incident photon beam. As grown samples show no XMLD signal due to averaging over a random AFM domain distribution. After the exposure to a 70 T in-plane magnetic field a clear XMLD signal indicating the generation of a preferential AFM domain orientation is obtained. The same type of XMLD signal is observed when the thin films are strained, demonstrating the feasibility of AFM Domain manipulation by magnetic fields and stress in Mn2Au.

Publ.-Id: 26167 - Permalink

Magnetic structure in a U(Ru0.92Rh0.08)2Si2 single crystal studied by neutron diffraction in static magnetic fields up to 24 T
Prokes, K.; Bartkowiak, M.; Rivin, O.; Prokhnenko, O.; Förster, T.; Gerischer, S.; Wahle, R.; Huang, Y.-K.; Mydosh, J. A.;
We report a high-field-induced magnetic phase in a single crystal of U(Ru0.92Rh0.08)2Si2. Our neutron study, combined with high-field magnetization, shows that the magnetic phase above the first metamagnetic transition at μ0H = 21.6 T has an uncompensated commensurate antiferromagnetic structure with a propagation vector Q2 = (2/3 0 0) possessing two single-Q domains. U moments of 1.45(9)μB directed along the c axis are arranged in an up-up-down sequence propagating along the a axis, in agreement with bulk measurements. The U magnetic form factor at high fields is consistent with both the U3+ and U4+ types. The low-field short-range order that emerges from pure URu2Si2 due to Rh doping is initially strengthened by the field but disappears in the field-induced phase. The tetragonal symmetry is preserved across the transition, but the a-axis lattice parameter increases already at low fields. Our results are in agreement with an itinerant electron model with 5f states forming bands pinned in the vicinity of the Fermi surface that is significantly reconstructed by the applied magnetic field.

Publ.-Id: 26166 - Permalink

Magnetic field induced tunneling and relaxation between orthogonal configurations in solids and molecular systems
Averkiev, N. S.; Bersuker, I. B.; Gudkov, V. V.; Zhevstovskikh, I. V.; Baryshnikov, K. A.; Sarychev, M. N.; Zherlitsyn, S.; Yasin, S.; Korostelin, Y. V.;
We report the effect of magnetic field induced quantum tunneling and relaxation transitions between orthogonal configurations in polyatomic systems where no tunneling is expected. Typical situations of this kind occur in molecular systems and local centers in crystals in ground and excited electronic T states, subject to the T⊗e problem of the Jahn-Teller effect, where the wave functions of the three tetragonally distorted configurations are orthogonal. A detailed microscopic theory of this effect shows how the magnetic field violates the orthogonality between the latter allowing for tunneling and relaxations, which decrease in strong fields due to the induced decoherence. The novel effect is demonstrated experimentally as a big, sharp peak in ultrasound attenuation by Cr2+ centers in ZnSe:Cr2+ in the magnetic field B = 0.15 T at the temperature below 8 K. It may influence a variety of magnetic, electronic, and photonic properties of any system in an electronic T state.

Publ.-Id: 26165 - Permalink

Neutron imaging of froth structure and particle motion
Heitkam, S.; Rudolph, M.; Lappan, T.; Sarma, M.; Eckert, S.; Trtik, P.; Lehmann, E.; Vontobel, P.; Eckert, K.ORC
This article reports on the simultaneous measurement of foam structure and attached particles employing neutron imaging. An aqueous foam sample is placed in the NEUTRA beamline at PSI, enabling a spatial resolution of less than 200 micron to be achieved at a frame rate of more than 1 Hz. A forced drainage setup allows the liquid content of the foam to be controlled. The averaged attenuation of the neutrons is demonstrated to yield the liquid fraction of the foam. Hydrophobized gadolinium particles with a diameter of 200 microns are added to the foam. Using two surfactants, different levels of hydrophobicity are achieved. Depending on the drainage flow and the hydrophobicity, the particles are washed out of the foam at different rates. An avalanche-like motion of particle clusters is observed. Neutron radiography is demonstrated to yield unique insights into the unsteady froth flotation process.
Keywords: Neutron imaging, Flotation, Froth, Particle Tracking


  • Secondary publication expected

Publ.-Id: 26164 - Permalink

Coarsening evolution of dendritic sidearms: from synchrotron experiments to quantitative modeling
Neumann-Heyme, H.; Shevchenko, N.; Lei, Z.; Eckert, K.ORC; Keplinger, O.; Grenzer, J.; Beckermann, C.; Eckert, S.
The local dynamics of dendritic sidearms during coarsening are studied by combining in-situ radiography observations with numerical and analytical models. A flat sample of a Ga-In alloy is partially solidified and then held isothermally in a vertical temperature gradient. The evolving dendritic microstructure is visualized using synchrotron X-ray imaging at the BM20 (ROBL) beamline at ESRF, France. During the coarsening stage, the temporal evolution of the geometrical features of sidebranches is captured by automated image processing. This data is used to quantify the dynamics of two basic evolution mechanisms for sidebranches: retraction and pinch-off. The universal dynamics of sidearm necks during pinch-off are exploited to determine the product of liquid diffusivity and capillarity length, Dd_0, as a parameter that is crucial in the calibration of quantitative models. By employing an idealized phase-field model for the evolution of a single sidebranch, the behavior of selected sidebranches is reproduced from the experiments in a consistent way.
Keywords: Dendritic solidification; microstructure; coarsening; sidearm detachment; X-ray radiography; phase-field model; material properties


  • Secondary publication expected

Publ.-Id: 26163 - Permalink

Structural and thermodynamic investigation of AnIVLI(O)HOPO(Article)
Aupiais, J.; Younes, A.; Moisy, P.; Hennig, C.; Rossberg, A.; Brunel, B.; Kerbaa, M.; Vidaud, C.; Den Auwer, C.;
For the first time, capillary electrophoresis coupled with inductively coupled plasma mass spectrometry has been used to determine the stability constants of PuIV with the multidentate hydroxypyridinonate chelating agents 3,4,3-LI(1,2-HOPO) and 5-LIO(Me-3,2-HOPO) in 0.1 M NaNO3 solution, pcH = 1.395 at 25 °C through competition with the NTA ligand. The limiting electrophoretic mobility was found to be zero for AnIV[5-LIO(Me-3,2-HOPO)] and slightly positive for AnIV[3,4,3-LI(1,2-HOPO)] (AnIV = Th, Pu). They were respectively assigned to the formation of the 1:2 neutral species An[5-LIO(Me-3,2-HOPO)]2 and a mixture of the neutral species AnIV[3,4,3-LI(1,2-HOPO)] and its protonated form AnIVH[3,4,3-LI(1,2-HOPO)]+. The corresponding stability constants of ThIV with both chelators were evaluated through the same experiments for the sake of comparison. The stability of both PuIV-HOPOs was about ten orders of magnitude better than that of the equivalent ThIV complexes. To complement these thermodynamic data, structural parameters of Pu[3,4,3-LI(1,2-HOPO)] and Th[3,4,3-LI(1,2-HOPO)] complexes in solution have been derived from EXAFS experiments and compared to previously reported crystallographic structures.

Publ.-Id: 26162 - Permalink

Calibration of scintillation screens for ultrashort electron bunch detection
Kurz, T.; Couperus, J. P.ORC; Krämer, J. M.; Ding, H.; Kuschel, S.; Köhler, A.; Zarini, O.; Hollatz, D.; Schinkel, D.; D‘Arcy, R.; Schwinkendorf, J. P.; Irman, A.; Schramm, U.; Karsch, S.
This work reports on the calibration of scintillating screens for diagnoses of high-charge density electron beams origination from laser plasma accelerators (LPA). Our setup at the conventional ELBE accelerator is cross-calibrated with an integrating current transformer (ICT) and allows for calibration over a large charge density range, thus enabling the study both the linear and non-linear scintillating screen response, as well as long-term stability tests of the screens. In contrast to previous works, the calibration presented here is performed under conditions with a close mimic to real experimental LPA conditions.
A linear response of the scintillator to the applied electron charge was found, followed by a saturation process starting in the range of nC/mm^2. Mimicking a 1-Hz LPA, long–term stability tests showed a significant decrease of the scintillation efficiency over time.
Finally, we present a method where a LED-based constant light source provides an easy method for absolute calibration of charge diagnostic systems at LPAs. This method eliminates many potential error sources existing in currently used methods and enables the transfer of absolute charge calibrations between laboratories.
  • Poster
    3rd European Advanced Accelerator Concepts Workshop, 24.-30.09.2017, Isola d'Elba, Italy

Publ.-Id: 26161 - Permalink

Demonstration of a beam loaded nanocoulomb-class laser wakefield accelerator
Couperus, J. P.ORC; Pausch, R.; Köhler, A.; Zarini, O.; Krämer, J. M.; Kurz, T.; Garten, M.; Huebl, A.; Gebhardt, R.; Helbig, U.; Bock, S.; Zeil, K.; Debus, A.; Bussmann, M.; Schramm, U.; Irman, A.
Laser-plasma wakefield acceleration is capable of producing quasi-monoenergetic electron beams reaching into the GeV range with few-femtoseconds bunch duration. Scaling the charge to the nanocoulomb range would yield hundreds of kiloamperes peak-current and stimulate the next generation of radiation sources covering high-field THz, high-brightness X-ray and γ-ray sources, compact FELs and laboratory-size beam-driven plasma accelerators. Laser-plasma accelerators generating such high currents operate in the beam loading regime where the accelerating field is strongly modified by the self-fields of the injected bunch, improving the final beam quality if appropriately controlled. Here we experimentally investigate the effects of beam loading at the theoretically predicted limit by loading unprecedented charges of about 0.5 nC within a mono-energetic peak into the first plasma cavity. As the energy balance is reached, the final energy spread is minimized. We show that the beam quality is maintained up to an estimated peak-current of 50 kA, an order of magnitude larger than in state-of-the-art conventional and laser-plasma accelerators.
  • Lecture (Conference)
    3rd European Advanced Accelerator Concepts Workshop, 24.-30.09.2017, Isola d'Elba, Italy
  • Lecture (Conference)
    Conference on High Intensity Laser and attosecond science in Israel (CHILI), 11.-13.12.2017, Tel-Aviv, Israel

Publ.-Id: 26160 - Permalink

Research on the chemistry of f-elements at HZDR - A general overview of the division Chemistry of the f-Elements
Ikeda-Ohno, A.ORC
Established in June 2014, the division Chemistry of the f-Elements at the Institute of Resource Ecology (IRE) is conducting research on the fundamental physics/chemistry of f-elements, i.e. actinides and lanthanides. This presentation intends to provide a general overview of the recent research activities in the division, in order to possible research overlapping between HZDR-IRE and CEA-Marcoule for future collaborations.
Keywords: actinides, f-elements, coordination, chemistry
  • Lecture (others)
    Internal colloquium, 05.10.2017, CEA-Marcoule, France

Publ.-Id: 26159 - Permalink

Drone-borne hyperspectral monitoring of acid mine drainage. An example from the Sokolov lignite district.
Jackisch, R.; Lorenz, S.; Zimmermann, R.; Möckel, R.; Gloaguen, R.;
This contributions aims to demonstrate the potential of unmanned aerial systems (UAS) to monitor areas affected by Acid mine drainage (AMD). The investigated area covers a recultivated tailing, which is and part of the Sokolov coalmine district in the Czech Republic. A high abundance of AMD minerals occurs in a confined space of the selected test site, which AMD minerals in high abundances can signal potential environmental predicament. The deposited mine waste material contains pyrite and itsthe consecutive weathering products, mainly iron hydroxides and oxides, which affect the natural pH values of the Earth’s surface. While previous research done in this area relies on satellite and air-borne data, our approach focuses on lightweight drone systems providing ground readiness within hours and, thus,, enabling rapid field campaigns. High spatial image resolutions and and precise target determination are additional advantages of UAS-based mapping. During April to September 2016, in total four field and flight campaigns were conducted. For validation, the waste heap was probed in-situ for pH, X-ray fluorescence (XRF) and, reflectance spectrometry. and sSampling points were surveyed by a differential GNSS global navigation satellite systems. Ground truth was achieved by collecting samples that were characterized for pH, X-ray diffraction and XRF in laboratory conditions. Sampling points were surveyed by a differential GNSS global navigation satellite systems. Hyperspectral data were processed and corrected for atmospheric, topographic and illumination effects. High-resolution point clouds and digital elevation models were built from drone-borne RGB data using Structure-from-Motion. The supervised classification of hyperspectral image (HSI) data suggests the presence of jarosite and goethite -, minerals associated with the acidic environmental conditions (pH range = 2.3 – 2.8 in situ). We identified specific iron absorption bands in the UAS-HS data, and was confirmed with ground-truth spectroscopy. The distribution of in-situ pH data supports the UAS-based mineral classification results. Evaluation of the applied methods highlights the drone surveying as a fast, non-invasive, inexpensive technique for multi-temporal environmental monitoring of the post-mining landscape.
Keywords: Hyperspectral; Remote sensing; unmanned aerial system; Acid mine drainage; Iron minerals; Image classification, Sokolov, post-mining

Publ.-Id: 26158 - Permalink

Ion Beam Induced Surface Modification of ta-C Thin Films
Berova, M.; Sandulov, M.; Tsvetkova, T.; Kitova, S.; Bischoff, L.; Boettger, R.;
Thin film samples (d ~ 40 nm) of tetrahedral amorphous carbon (ta-C), deposited by filtered cathodic vacuum arc, were implanted with Ga+ at ion energy E = 20 keV and ion fluences D = 3E14 - 3E15 cm-2 and N+ with the same energy and ion fluence D = 3 E14 cm-2. The Ga+ ion beam induced surface structural modification of the implanted material, displayed by formation of new phase at non-equilibrium condition, which could be accompanied by considerable changes in the optical properties of the ta-C films. The N+ implantation also results in modification of the surface structure. The induced structural modification of the implanted material results in a considerable change of its topography and optical properties. Nanoscale topography and structural properties characterisation of the Ga+ and N+ implanted films were performed using atomic spectroscopy analysis. The observed considerable surface structural properties modification in the case of the higher fluence Ga+ implanted samples results from the relatively high concentration of introduced Ga+ atoms, which is of the order of those for the host element.
Keywords: carbon, ion implantation, atomic force microscopy

Publ.-Id: 26157 - Permalink

Visualization of gas-liquid multiphase pseudo-slug flow using Wire-Mesh Sensor
Kesana, N. R.; Parsi, M.; Vieira, R. E.; Azzopardi, B.; Schleicher, E.; Mclaury, B. S.; Shirazi, S. A.; Hampel, U.;
Intermittent two-phase flows are commonly encountered in the petroleum industry. Much attention has been focused by several researchers on intermittent flows existing at low superficial gas velocities (<10 m/s). There is limited work performed on intermittent structures persisting at higher superficial gas velocities (pseudo-slug flows). In the present experimental study, a conductivity-based Wire-Mesh Sensor (WMS) was used to visualize and characterize pseudo-slug flow. Experiments were performed in a 76.2 mm horizontal pipe with air and water as the working fluids at atmospheric conditions. The superficial gas and liquid velocities ranged from 9 m/s to 35 m/s and 0.45 m/s to 0.76 m/s, respectively. A 16 × 16 WMS was placed 17 m away from the pipe inlet to measure spatio-temporal void-fraction distribution. The WMS data acquisition frequency was set to 10 kHz. From the void-fraction time series data, the periodic pseudo-slug structures were visualized. The visualization suggested that unlike slug flow where the liquid structures fill the pipe cross-section, the pseudo-slugs were extremely aerated structures (high gas-liquid mixing) formed due to the gas penetration into the liquid slug body. This paper also presents the measurements of important hydrodynamic characteristics such as cross-sectional averaged void-fraction time series and mean void fraction. The effect of liquid viscosity on the visualized structures is also presented.
Keywords: Flow visualization Intermittent multiphase flows Pseudo-slug flow Slug flow Wire-mesh sensor

Publ.-Id: 26156 - Permalink

Fission and other fast neutron induced reactions investigated at nELBE
Beyer, R.ORC; Junghans, A. R.; Dietz, M.; Kögler, T.; Schwengner, R.; Urlaß, S.; Wagner, A.
The nELBE neutron time-of-flight facility provides neutrons in the energy range from about 10 keV up to 10 MeV with an intensity of about 10⁴ n/s/cm². The combination of the superconducting electron accelerator ELBE and a compact liquid lead neutron production target delivers neutron bunches within a time spread of a few picoseconds and a repetition rate of 100 to 400 kHz (cw) enabling high resolution time-of-flight measurement even with flight paths of only 5 to 11 meters. At nELBE different types of fast neutron induced nuclear reactions can be and have been investigated, ranging from total neutron cross section measurement over elastic and inelastic scattering to neutron induced fission. E.g. the neutron induced fission cross section of Pu-242 has been measured in the range from 0.5 to 10 MeV relative to U-235(n,fis) using two fission ionization chambers. A statistical uncertainty down to 1.1 % and systematic uncertainty of about 2.7 % was reached.
Keywords: nELBE, neutron time-of-flight, transmission, inelastic scattering, fission
  • Poster
    LANL FIESTA Fission School & Workshop, 17.-22.09.2017, Santa Fe, New Mexico, USA

Publ.-Id: 26155 - Permalink

Fission measurements at nELBE
Beyer, R.ORC; Dietz, M.; Junghans, A. R.; Kögler, T.; Schwengner, R.; Urlaß, S.
The nELBE neutron time-of-flight facility provides neutrons in the energy range from about 10 keV up to 10 MeV with an intensity of about 104 n/s/cm2. The combination of the superconducting electron accelerator ELBE and a compact liquid lead neutron productiontarget delivers neutron bunches within a time spread of a few picoseconds and a repetition rate of 100 to 400 kHz (cw) enabling high resolution time-of-flight measurement even with flight paths of only 5 to 11 meters. At nELBE different types of fast neutron induced nuclear reactions can be and have been investigated, ranging from total neutron cross section measurement over elastic and inelastic scattering to neutron induced fission. E.g. the neutron induced fission cross section of 242Pu has been measured in the range from 0.5 to 10 MeV relative to 235U(n,f) using two fission ionization chambers. A statistical uncertainty down to 1.1% and systematic uncertainty of about 2.7% was reached.
Keywords: nELBE, neutron time-of-flight, fission
  • Invited lecture (Conferences)
    LANL FIESTA Fission School & Workshop, 17.-22.09.2017, Santa Fe, New Mexico, USA

Publ.-Id: 26154 - Permalink

Magnetic field induced strong valley polarization in the three-dimensional topological semimetal LaBi
Kumar, N.; Shekhar, C.; Klotz, J.; Wosnitza, J.; Felser, C.;
LaBi is a three-dimensional rocksalt-type material with a surprisingly quasi-two-dimensional electronic structure. It exhibits excellent electronic properties such as the existence of nontrivial Dirac cones, extremely large magnetoresistance, and high charge-carrier mobility. The cigar-shaped electron valleys make the charge transport highly anisotropic when the magnetic field is varied from one crystallographic axis to another. We show that the electrons can be polarized effectively in these electron valleys under a rotating magnetic field. We achieved a polarization of 60% at 2 K despite the coexistence of three-dimensional hole pockets. The valley polarization in LaBi is compared to the sister compound LaSb where it is found to be smaller. The performance of LaBi is comparable to the highly efficient bismuth.

Publ.-Id: 26153 - Permalink

Charge Density Waves in Graphite: Towards the Magnetic Ultraquantum Limit
Arnold, F.; Isidori, A.; Kampert, E.; Yager, B.; Eschrig, M.; Saunders, J.;
Graphite is a model system for the study of three-dimensional electrons and holes in the magnetic quantum limit, in which the charges are confined to the lowest Landau levels.We report magneto-transport measurements in pulsed magnetic fields up to 60 T, which resolve the collapse of two charge density wave states in two, electron and hole, Landau levels at 52.3 and 54.2 T, respectively. We report evidence for a commensurate charge density wave at 47.1 T in the electron Landau level, and discuss the likely nature of the density wave instabilities over the full field range. The theoretical modeling of our results predicts that the ultraquantum limit is entered above 73.5 T. This state is an insulator, and we discuss its correspondence to the “metallic” state reported earlier.We propose that this (interaction-induced) insulating phase supports surface states that carry no charge or spin within the planes, but does, however, support charge transport out of plane.

Publ.-Id: 26152 - Permalink

Magnetic field induced phase transitions and phase diagrams of multiferroic Mn0.95Co0.05WO4 with cycloidal spin structure
Urcelay-Olabarria, I.; Ressouche, E.; Wang, Z.; Skourski, Y.; Ivanov, V. Y.; Popov, Y. F.; Vorobev, G. P.; Balbashov, A. M.; Qureshi, N.; Garcia-Munoz, J. L.; Skumryev, V.; Mukhin, A. A.;
Slightly Co-doped MnWO4 at the lowest 5% Co concentration, for which the multiferroic cycloidal phase becomes a ground state, has been studied in magnetic fields up to 60 T by bulk magnetic and electric polarization measurements along different crystallographic directions. The field induced magnetic transitions up to 12 T and the ways they proceed were tracked also by single-crystal neutron diffraction, and the relevant field induced magnetic structures were identified and refined. The complete magnetoelectric phase diagrams for magnetic fields along distinct directions in relation to the cycloidal spin structure have been constructed for magnetic field values exceeding those necessary to induce a spin-flip transition into the paramagnetic state. Their common feature is the existence of nonpolar sinusoidal phases identified by the disappearance of the electric polarization in a field regime slightly below the spin-flip transition. At lower magnetic fields either continuous or abrupt field induced reorientations of the cycloidal magnetic structures were observed, respectively, for a field direction along the crystallographic b axis or along the easy magnetic axis, and the different character of those transitions has been attributed to specific features in the magnetic anisotropy.

Publ.-Id: 26151 - Permalink

Influence of MOCVD Growth Pressure on Magnetoresistance of Nanostructured La-Ca-Mn-O Films Used for Magnetic Field Sensors
Zurauskiene, N.; Pavilonis, D.; Klimantavicius, J.; Balevicius, S.; Stankevic, V.; Kersulis, S.; Plausinaitiene, V.; Abrutis, A.; Lukose, R.; Skapas, M.; Juskenas, R.; Knasiene, B.; Naujalis, E.; Law, J. M.;
The results of structure and magnetoresistance (MR) of nanostructured La1−xCaxMnyO3 (LCMO) films, grown at different gas pressure (from 3 to 7 Torr) by pulse injection metal–organic chemical vapor deposition (MOCVD) technique, are presented. The MR was investigated in pulsed magnetic fields up to 60 T in the temperature range 1.5–294 K. The results were analyzed from the perspective of using these films for magnetic field sensors operating at low temperatures. It was demonstrated that with the increase of Ar + O2 gas pressure, the surface morphology of the films becomes rougher and grain size increases. Also, the ratio of Mn/(La + Ca) increases with the increase of the pressure. Large MR of the films was observed in a wide temperature range below the ferromagnetic–paramagnetic phase transition. It was shown that at cryogenic temperatures, the films grown at gas pressure of 3 Torr have higher sensitivity in lower magnetic field range (<10 T), while in high magnetic fields (20–60 T), the properties of films grown at higher gas pressure 5–7 Torr are favored. The obtained results allow evaluating the influence of MOCVD growth pressure on MR and sensitivity to the magnetic field of LCMO manganites used for pulsed magnetic field sensors.

Publ.-Id: 26150 - Permalink

Structural and Magnetic Properties of the Trirutile-type 1D-Heisenberg Anti-Ferromagnet CuTa2O6
Golubev, A.; Dinnebier, R. E.; Schulz, A.; Kremer, R. K.; Langbein, H.; Senyshyn, A.; Law, J. M.; Hansen, T. C.; Koo, H.-J.; Whangbo, M.-H.;
We prepared trirutile-type polycrystalline samples of CuTa2O6 by low-temperature decomposition of a Cu−Ta−oxalate precursor. Diffraction studies at room temperature identified a slight monoclinic distortion of the hitherto surmised tetragonal trirutile crystal structure. Detailed high-temperature X-ray and neutron powder diffraction investigations as well as Raman scattering spectroscopy revealed a structural phase transition at 503(3) K from the monoclinic structure to the tetragonal trirutile structure. GGA+U density functional calculations of the spin-exchange parameters as well as magnetic susceptibility and isothermal magnetization measurements reveal that CuTa2O6 is a new 1D Heisenberg magnet with predominant anti-ferromagnetic nearest-neighbor intrachain spin-exchange interaction of ∼50 K. Interchain exchange is a factor of ∼5 smaller. Heat capacity and low-temperature high-intensity neutron powder diffraction studies could not detect long-range order down to 0.45 K.

Publ.-Id: 26149 - Permalink

Coordination polymer (CP) networks and molecular complexes of tetravalent actinides (Th, U, Np) with aromatic polycarboxylate ligands or polyoxometalate (POM) species
Loiseau, T.ORC; Martin, N. P.; Volkringer, C.; Duval, S.; März, J.; Ikeda-Ohno, A.ORC
Coordination polymers are built up from the association of metallic centers with organic (e.g. O- or N-donor) ligands. In the particular case of actinides (An), precedent studies have reported mainly the synthesis of such solid networks bearing U(VI) or Th(IV), while trans-uranium elements have been much less studied due to their high radiotoxicity and limited amount of the material source. Among the possible oxidation states of An, the tetravalent state has been investigated most actively and large polyoxo clusters have been isolated for U or Pu. In contrast, there are very few data concerning Np(IV) compounds. The knowledge of the formation of such polynuclear An(IV) species could be of significant importance for the fate of An in contaminated soils containing O-donor ligands, such as humic acids, or other organic pollutants (e.g. phthalates).
In the present communication, we firstly present the formation of several series of uranyl-organic frameworks associated to poly-carboxylate linkers, by following the pH variation parameter of the reaction medium, related to the hydrolysis rate. This strategy was then applied to actinides(IV), which are known to exhibit a strong affinity for hydrolysis reaction in order to form inorganic entities with high nuclearities. In a first approach, the control of water content in reaction media containing organic solvent will be investigated in different chemical systems with Th(IV) and U(IV) in the presence of dicarboxylic acids molecules (typically terephthalic acid), and was then extended to Np(IV) for some cases. The structural descriptions of the different coordination polymers will point out the nuclearity variation of the inorganic bricks from mononuclear [AnO9] up to hexanuclear entities [An6O8]. The particular case of the poly-oxo cluster [An38] will be discussed, and its formation will be described with U(IV) and Np(IV) in different solvents. The crystallization of the crystallization of U(IV) and Np(IV) with various aromatic polycarboxylate ligands was then considered in water medium and crystal structures of coordination networks with phtalate and mellitate have been analyzed. The last point deals with the isolation and crystallization of polynuclear clusters of actinides (Th(IV)/U(IV)) embedded within large anionic polytungstate moieties ([SiW9O34], [AsW9O33]). Trinuclear, tetranuclear and hexanuclear motifs bearing actinides(IV) have thus been identified in this system.
Keywords: Actinides, tetravalent, coordination polymers, carboxylates, polyoxo-metalate, metal-organic frameworks
  • Invited lecture (Conferences)
    American Chemical Society Annual Meeting, 22.-28.03.2018, New Orleans, USA

Publ.-Id: 26148 - Permalink

QMOM methods for bubbly flows –potentials for simulation of pumps
Hasse, C.; Salenbauch, S.; Pollack, M.; Oertel, R.; Li, D.; Schlegel, F.; Lucas, D.;
The temporal and spatial development of a particle size distribution, e.g. in a bubbly flow, can be described with the so-called Population Balance Equation. It represents a continuity statement for the number density of particles in a flow. The presentation contains a comparison of two prominent approaches for solving the population balance equation, i.e. the family of Quadrature-based Moment Methods and the Method of Classes.
Keywords: Population Balance Modeling, Quadrature-based Method of Moments, Class Methods, Pumps
  • Lecture (others)
    VDMA AK-Mehrphasenströmung, 26.09.2017, Frankfurt, Deutschland

Publ.-Id: 26147 - Permalink

Negative Longitudinal Magnetoresistance from the Anomalous N = 0 Landau Level in Topological Materials
Assaf, B. A.; Phuphachong, T.; Kampert, E.; Volobuev, P. S.; Mandal, P. S.; Sanchez-Barriga, J.; Rader, O.; Bauer, G.; Springholz, G.; de Vaulchier, L. A.; Guldner, Y.;
Negative longitudinal magnetoresistance (NLMR) is shown to occur in topological materials in the extreme quantum limit, when a magnetic field is applied parallel to the excitation current. We perform pulsed and dc field measurements on Pb1−xSnxSe epilayers where the topological state can be chemically tuned. The NLMR is observed in the topological state, but is suppressed and becomes positive when the system becomes trivial. In a topological material, the lowest N = 0 conduction Landau level disperses down in energy as a function of increasing magnetic field, while the N = 0 valence Landau level disperses upwards. This anomalous behavior is shown to be responsible for the observed NLMR. Our work provides an explanation of the outstanding question of NLMR in topological insulators and establishes this effect as a possible hallmark of bulk conduction in topological matter.

Publ.-Id: 26146 - Permalink

Interplay between localization and magnetism in (Ga,Mn)As and (In,Mn)As
Yuan, Y.; Xu, C.; Hübner, R.; Jakiela, R.; Böttger, R.; Helm, M.; Sawicki, M.; Dietl, T.; Zhou, S.;
Ion implantation of Mn combined with pulsed laser melting is employed to obtain two representative compounds of dilute ferromagnetic semiconductors (DFSs): Ga1−xMnxAs and In1−xMnxAs. In contrast to films deposited by the widely used molecular beam epitaxy, neither Mn interstitials nor As antisites are present in samples prepared by the method employed here. Under these conditions the influence of localization on the hole-mediated ferromagnetism is examined in two DFSs with a differing strength of p-d coupling. On the insulating side of the transition, ferromagnetic signatures persist to higher temperatures in In1−xMnxAs compared to Ga1−xMnxAs with the same Mn concentration x. This substantiates theoretical suggestions that stronger p-d coupling results in an enhanced contribution to localization, which reduces hole-mediated ferromagnetism. Furthermore, the findings support strongly the heterogeneous model of electronic states at the localization boundary and point to the crucial role of weakly localized holes in mediating efficient spin-spin interactions even on the insulator side of the metal-insulator transition.

Publ.-Id: 26145 - Permalink

ASTEC model development for the severe accident progression in a generic AP1000-LIKE
Albright, L.; Wilhelm, P.; Jevremovic, T.;
Improvements in light water reactor (LWR) technologies in recent decades have led to the development of advanced LWRs, currently under construction, soon to join the international fleet of nuclear power plants (NPPs). Enhanced safety capabilities have been achieved in advanced LWRs through the utilization of passive safety systems and design improvements. The progression of severe accidents in advanced LWRs is not well described in the current open literature. To date severe accident analyses performed on the Westinghouse AP1000 have focused on evaluating the performance of the AP1000 safety systems in the prevention of severe accidents, with little focus on characterizing the progression of core degradation to identify the timing of key events such as core uncovery, relocation of corium to the lower plenum, and lower head failure.

An initial, generic model of an AP1000-LIKE reactor has been developed in the severe accident integral code ASTEC to characterize the progression of severe accidents in the AP1000-LIKE model and identify the representation of important physical phenomena and key events of core degradation progression. To evaluate the progression of severe accidents in the AP1000 an accident scenario without accident management measures (AMM), and a complete loss of primary flow is designed and simulated using the developed ASTEC model. The preliminary code results showed the applicability of the model to simulate severe accident scenarios. Without AMM, it is determined that reactor pressure vessel failure occurs nearly four hours after the start of the transient; after the loss of primary coolant flow, a large amount of hydrogen is produced (~800 kg), and a large mass of molten material forms (~150 tons) and relocates to the lower plenum. Future efforts will focus on developing a full plant model for a generic AP1000 and further characterizing the progression of severe accidents.
Keywords: Severe Accidents, Westinghouse AP1000, ASTEC
  • Lecture (Conference)
    IAEA Technical Meeting on the Status and Evaluation of Severe Accident Simulation Codes for Water Cooled Reactors (I3-TM-54660), 09.-12.10.2017, Vienna, Austria

Publ.-Id: 26144 - Permalink

Molecular and Crystal Structures of Uranyl Nitrate Coordination Polymers with Double-headed 2-Pyrrolidone Derivatives
Kazama, H.; Tsushima, S.; Ikeda, Y.; Takao, K.;
Double-headed 2-pyrrolidone derivatives (DHNRP) were designed and synthesized as bridging ligands for efficient and selective separation of UO22+ from HNO3 solution by precipitation. The building blocks, UO2(NO3)2 and DHNRP, were successfully connected to form an infinite 1D coordination polymer. Solubility of [UO2(NO3)2(DHNRP)]n is no longer correlated to hydrophobicity of the ligand, but is exclusively governed by ligand symmetry and packing efficiency. The newly designed DHNRP family can be used to establish a new spent nuclear fuel reprocessing scheme.

Publ.-Id: 26143 - Permalink

Interaction of NpO2+ with Cl– in NaCaCl-type solutions at ionic strength of 6M: Effect of presence of Ca ion on interaction
Nagasakia, S.; Saito, T.; Tsushima, S.; Goguen, J.; Yang, T.;
The interaction of NpO2+ with Cl– was studied using visible–near-infrared spectroscopy in NaClCaCl2NaClO4, NaClNaClO4, and CaCl2NaClO4 solutions with ionic strength (I) of 6M. The spectra of NpO2+ around 980 nm varied with Cl– concentration in the NaClCaCl2NaClO4 and NaClNaClO4 solutions at [Cl–] ≥ 3.5M, but not in the CaCl2NaClO4 solution. Assuming the 1:1 interaction between NpO2+ and Cl–, the apparent equilibrium constants at I = 6M were evaluated. The presence of Ca2+ was found to destabilize overall interaction between NpO2+ and Cl–. The observations were consistent with the density functional theory calculation.
Keywords: Cl–, Density Functional Theory Calculation, Equilibrium Constants, Ionic Strength, NpO2+, Presence of Ca2+
  • Open Access LogoContribution to proceedings
    37th Annual Conference of the Canadian Nuclear Society and 41st Annual CNS/CNA Student Conference, 04.-07.06.2017, Niagara Falls, Canada
    DOI: 10.1016/

Publ.-Id: 26142 - Permalink

Geostatistical simulation of compositional data in the presence of several geological domains
Talebi, H.; Tolosana-Delgado, R.; Lo, J.; Mueller, U.;
This paper proposes a methodology for geostatistical simulation of compositional data in presence of several geological domains: After applying statistical analysis and compositionally compliant contact analysis on the data set, geological domains with the same compositional characteristics are merged. Plurigaussian simulation (PGS) is utilized to generate multiple numerical models of the remaining domains, with the aim of assessing the uncertainty in the domain boundaries and improving the geological controls in the characterization of compositional attributes. The resulting conditional realisations of geological domains are used to derive the posterior probabilities of occurrence of the domains over the deposit. The compositional data set is classified by geological domain and for each class realisations are generated across the target grid of the resource. The final mineral resource model is obtained by weighting the simulated mineral compositions associated with the different domains by the probabilities of occurrence of each domain. This approach accounts for the uncertainty in the geology of the ore body and spatial variability of mineral composition.

The approach is illustrated through an application to a nickel-cobalt laterite deposit located in Western Australia. A set of 8818 samples is considered in order to provide the conditioning data. Four rock types (Ferruginous, Smectite, Saprolite, and Ultramafic) are considered to define compositionally homogeneous domains. Three major (Fe, Al, and Mg) and two target (Ni and Co) elements are the variables of interest in this study. Since the data are compositional a filler variable is introduced to achieve closure and to retain the intuitive relation between each component and the mass of its associated element.
  • Lecture (Conference)
    Annual Conference of the International Association for Mathematical Geosciences, 04.-07.09.2017, Fremantle, Perth, Australia

Publ.-Id: 26141 - Permalink

Geochemical Interactions of Plutonium with Opalinus Clay Studied by Spatially Resolved Synchrotron Radiation Techniques
Kaplan, U.; Amayri, S.; Drebert, J.; Rossberg, A.; Grolimund, D.; Reich, T.;
Plutonium plays an important role within nuclear waste materials because of its long half-life and high radiotoxicity. The aim of this study was to investigate with high spatial resolution the reactivity of the more oxidized forms of Pu(V,VI) within Opalinus Clay (OPA) rock, a heterogeneous, natural argillaceous rock considered as a potential repository host. A combination of synchrotron based X-ray microprobe and bulk techniques was used to study the spatial distribution and molecular speciation of Pu within OPA after diffusion and sorption processes. Microscopic chemical images revealed a pronounced impact of geochemical heterogeneities concerning the reactivity of the natural barrier material. Spatially resolved X-ray absorption spectroscopy documented a reduction of the highly soluble Pu(V,VI) to the less mobile Pu(IV) within the argillaceous rock material, while bulk investigations showed second-shell scattering contributions, indicating an inner-sphere sorption of Pu on OPA components. Microdiffraction imaging identified the clay mineral kaolinite to play a key role in the immobilization of the reduced Pu. The findings provide strong evidence that reduction and immobilization do not occur as linked processes on a single reactive phase but as decoupled, subsequent, and spatially separated reactions involving different phases of the OPA.
Keywords: Plutonium opalinus clay sorption XAS ROBL


Publ.-Id: 26140 - Permalink

Zur Mineralogie von Vulkaniten im Bereich des Kemmlitzer Porphyrs (Oschatz Formation, Nordwestsächsisches Becken)
Götze, J.; Lessig, F.; Möckel, R.; Georgi, U.;
Mineralogische und geochemische Untersuchungen an Proben des Kemmlitzer Porphyrs sowie von Lithophysen (Hochtemperatur- Kristallisationsdomänen) im entsprechenden Verbreitungsgebiet wurden durchgeführt, um eine mineralogisch-petrographische Charakteristik dieser vulkanischen Bildungen und deren Zuordnung zu möglichen Muttergesteinen zu ermöglichen. Phasenanalytische Untersuchungen (Röntgendiffraktometrie, Mikroskopie, Kathodolumineszenz - KL) erbrachten eine monotone Mineralzusammensetzung, die von Quarz und den beiden Kalifeldspatphasen Sanidin und Orthoklas dominiert ist. Anhand der geochemischen Charakteristika (RFA) lassen sich die untersuchten Vulkanite als Rhyolithe einstufen. Das Vorkommen von hypidiomorphen Quarzphänokristen, z.T. mit Resorptionserscheinungen, gut erhaltenen Kalifeldspäten sowie das Fehlen von Glas-Shards und Fiamme (Bimsfetzen) deuten darauf hin, dass es sich bei den vulkanischen Ablagerungen im Untersuchungsgebiet um Laven und keine Pyroklastite (Ignimbrite) handelt.
Aus den deutlichen Übereinstimmungen hinsichtlich mineralogischer Zusammensetzung, chemischer Charakteristik und textureller Ausbildung kann geschlussfolgert werden, dass alle untersuchten Proben einem vulkanischen Ereignis (Kemmlitzer Porphyr) zuzuordnen sind. Auftretende Unterschiede sind im Wesentlichen auf sekundäre Alterationen zurückzuführen. Das übereinstimmende Erscheinungsbild der Phänokristen sowie deren KL-Eigenschaften deuten auf eine Herkunft aus einer gemeinsamen Schmelze hin. Obwohl die mineralogischen, geochemischen und texturellen Ähnlichkeiten von Lithophysen und Kemmlitzer Porphyr auffällig sind, konnten bisher im massiven, porphyrisch ausgebildeten Vulkanit keine sphärolithischen Bildungen nachgewiesen werden. Randliche Anhaftungen von Pechsteinrelikten an den Lithophysen verschiedener Vorkommen lassen dagegen vielmehr auf eine Bildung im Bereich einer glasigen Fazies schließen.

Mineralogical and geochemical investigations of the Kemmlitz porphyry and lithophysae (high-temperature crystallization domains) in the associated area were carried out to get information concerning mineralogical-petrographical characteristics of these volcanic formations and their relation to possible parent rocks. An integrated analytical study by X-ray diffraction, microscopy and cathodoluminescence (CL) revealed a monotonic mineral composition dominated by quartz, sanidine and orthoclase. The rocks can be classified as rhyolite based on the chemical composition (XRF). The predominance of hypidiomorphic quartz phenocrysts, partially with resorption features, well preserved K-feldspar as well as the lack of glass shards and fiamme indicate that the volcanic rocks derive from lava flows and are not related to ignimbrites.
The investigated samples can probably be related to the same volcanic event (Kemmlitz porphyry) because of the similarities in mineral composition, chemical characteristics and texture. Detected variations mainly result from secondary alteration processes. The consistent appearance of phenocrysts and their CL characteristics indicate the origin from a common melt source. Despite these mineralogical, chemical and textural similarities between the Kemmlitz porphyry and the lithophysae, no spherulithic aggregates have been found within the massive porphyric volcanics. Marginal relics of pitchstone on some of the lithophysae instead indicate their formation in a glassy facies.
Keywords: Porphyr, Mineralogie, Nordwestsachsen
  • Contribution to external collection
    in: Veröffentlichungen des Museums für Naturkunde Chemnitz, Chemnitz: Museum für Naturkunde, 2017, 133-150

Publ.-Id: 26139 - Permalink

Measurements of neutron scattering angular distributions with a new scintillator setup
Pirovano, E.; Beyer, R.; Junghans, A. R.; Nolte, R.; Nyman, M.; Plompen, A.;
A new experimental setup for the measurement of neutron scattering cross sections and angular distributions is currently being developed at the neutron time-of-flight facility GELINA, at the JRC-Geel. Up to 32 liquid organic scintillators are employed for the detection of neutrons scattered from a sample of the investigated material. The differential cross section is measured at eight different angles, and the angleintegrated cross section is obtained from the differential data by numerical integration. Two experiments for the study of scattering on iron were carried out, one at GELINA and the other at nELBE (HZDR). The first results for the angular distributions of elastic scattering in the neutron energy range from 2 to 6MeV are here presented and compared with evaluations from the major nuclear data libraries.
Keywords: nELBE, GELINA, neutron, angular distribution
Related publications
Cross section and neutron angular distribution … (Id 28211) has used this publication of HZDR-primary research data


Publ.-Id: 26138 - Permalink

Measuring at relevant concentrations – radiolabeling as a versatile tool in nanosafety research
Schymura, S.; Hildebrand, H.; Franke, K.;
The employment of radiotracers is a versatile tool for the detection of nano-particulate materials in complex systems such as environmental samples or organisms. With the increasing usage of nanoparticles in applications outside of research laboratories, a careful risk assessment of their release into the environment becomes mandatory. However, the monitoring of nanoparticles in such complex natural systems as soil, natural waters, plants, sewage sludge, etc. is nearly impossible using conventional methods, especially at environmentally relevant concentrations. This obstacle can be overcome by radiolabeling, which may be of crucial value in enabling such research.
We have developed various methods of introducing radiotracers into some of the most common nanoparticles, such as Ag, carbon, SiO2, CeO2 and TiO2 nanoparticles. The labeling techniques are the synthesis of the nanoparticles using radioactive starting materials, the binding of the radiotracer to the nanoparticles, the activation of the nanoparticles using proton irradiation, the recoil labeling utilizing the recoil of a nuclear reaction to implant a radiotracer into the nanoparticle, and the in-diffusion of radiotracers into the nanoparticles at elevated temperatures. Using these methods we have produced [105/110mAg]Ag, [124/125/131I]CNTs, [48V]TiO2, [139Ce]CeO2, [7Be]MWCNT, [7Be]SiO2, [44/45Ti]TiO2, etc.. The methods are adaptable for a wide range of other nanoparticles. The so-labelled nanoparticles can be detected at minimal concentrations well in the ng/L range even with a background of the same element and without complicated sample preparations necessary.
Using our methods one can radiolabel commercial nanoparticle samples for sensitive detection in environmentally relevant trace concentrations. The labeled particles have been successfully used in release studies, environmental mobility studies, fate studies in waste water treatment and plant uptake studies.
  • Poster
    Scientific Stakeholder Meeting on Nanomaterials in the Environment, 10.-11.10.2017, Dessau, Deutschland
  • Invited lecture (Conferences)
    Scientific Stakeholder Meeting on Nanomaterials in the Environment, 10.-11.10.2017, Dessau, Deutschland

Publ.-Id: 26137 - Permalink

NANOSUPPE - Behavior of engineered nanoparticles in the pathway wastewater - sewage sludge - plant using the examples TiO2, CeO2, MWCNT and quantum dots
Schymura, S.; Fricke, T.; Hildebrand, H.; Neugebauer, M.; Franke, K.;
The Project NanoSuppe is concerned with the behavior of nanoparticles along the pathway wastewater – sewage sludge – plant as this is one of the main expected paths in the life cycle of manufactured nanomaterials (MNMs) and marks the possible preliminary end of life of a MNM when it is removed from contaminated wastewater, as well as the potential reintroduction into the human food chain by the use of contaminated sewage sludge as fertilizer. Hence, work was conducted concerning the fate of MNMs in wastewater treatment plants by means of model WWTPs in the lab. Furthermore, environmental mobility studies concerning colloidal stability of MNMs in natural waters and their interaction with soil and sewage sludge were conducted by means of batch and column experiments. As a last step the uptake of MNMs by plants was investigated from hydroponic media as well as soil/sewage sludge matrices.
As a rather unique feature the used MNMs (TiO2, CeO2, MWCNTs and quantum dots) were radiolabeled to enable their sensitive detection at environmentally relevant concentrations in the complex matrices involved.
  • Invited lecture (Conferences)
    Scientific Steakholder Meeting, 10.-11.10.2017, Dessau, Deutschland
  • Invited lecture (Conferences)
    Scientific Steakholder Meeting, 10.-11.10.2017, Dessau, Deutschland

Publ.-Id: 26136 - Permalink

Studies towards the development of a PET radiotracer for imaging of the P2Y1 receptors in the brain: synthesis, 18F-labeling and preliminary biological evaluation
Moldovan, R.-P.; Wenzel, B.; Teodoro, R.; Neumann, W.; Dukic-Stefanovic, S.; Deuther-Conrad, W.; Hey-Hawkins, E.; Krügel, U.; Brust, P.;
Purine nucleotides such as ATP and ADP are important extracellular signaling molecules in almost all tissues activating various subtypes of purinoreceptors. In the brain, the P2Y1 receptor (P2Y1R) subtype mediates trophic functions like differentiation and proliferation, and modulates fast synaptic transmission, both suggested to be affected in diseases of the central nervous system. Research on P2Y1R is limited because suitable brain-penetrating P2Y1R-selective tracers are not yet available. Here, we describe the first efforts to develop an 18F-labeled PET tracer based on the structure of the highly affine and selective, non-nucleotidic P2Y1R allosteric modulator 1-(2-[2-(tert-butyl)phenoxy]pyridin-3-yl)-3-[4-(trifluoromethoxy)phenyl]urea (7). A small series of fluorinated compounds was developed by systematic modification of the p-(trifluoromethoxy)phenyl, the urea and the 2-pyridyl subunits of the lead compound 7. Additionally, the p-(trifluoromethoxy)phenyl subunit was substituted by carborane, a boron-rich cluster with potential applicability in boron neutron capture therapy (BNCT). By functional assays, the new fluorinated derivative 1-{2-[2-(tert-butyl)phenoxy]pyridin-3-yl}-3-[4-(2-fluoroethyl)phenyl]urea (18) was identified with a high P2Y1R antagonistic potency (IC50 = 10 nM). Compound [18F]18 was radiosynthesized by using tetra-n-butyl ammonium [18F]fluoride with high radiochemical purity, radiochemical yield and molar activities. Investigation of brain homogenates using hydrophilic interaction chromatography (HILIC) revealed [18F]fluoride as major radiometabolite. Although [18F]18 showed fast in vivo metabolization, the high potency and unique allosteric binding mode makes this class of compounds interesting for further optimizations and investigation of the theranostic potential as PET tracer and BNCT agent.
Keywords: Purine P2Y1 receptors Positron emission tomography Brain PET tracers Radiometabolites Micellar chromatography Hydrophilic interaction chromatography


  • Secondary publication expected from 01.03.2020

Publ.-Id: 26135 - Permalink

P1513 - Procedure and apparatus for measuring a d.c. magnetic field based on magnetostrictive effect in magnetic wires
Bali, R.; Kolesar, V.; Vazquez, M.;
The present invention relates to a procedure for measuring a d.c. magnetic field by means of a cylindrical device formed by a magnetostrictive core. A d.c. magnetic field is applied and the mechanical deformation on the device caused by the magnetic field is measured and compared with the obtained measurements from previous calibrations to estimate magnetic field intensity values. The invention also relates to an apparatus for measuring a d.c. magnetic field by means of the indicated procedure. The apparatus comprises:
- a cylindrical sensor element and an abutment/fixing element, such that the cylindrical sensor element experiences mechanical deformation when exposed to the d.c. magnetic field,
- a deformation sensing device configured for detecting the mechanical deformation of the cylindrical sensor element, and
- a processing unit configured for determining the intensity of the d.c. magnetic field based on the detected mechanical deformation of the cylindrical sensor element.
  • Patent
    EP3171189 - Offentlegung: 24.05.2017

Publ.-Id: 26134 - Permalink

Radiolabeling - an appropriate tool to study the environmental fate of engineered nanoparticles
Franke, K.; Schymura, S.; Hildebrand, H.;
To study the environmental fate of nanoparticles it requires versatile tools for detection of nano-particulate materials in complex systems such as soil, sewage sludge or organisms within a wide range of concentration. Challenging are the environmentally relevant low concentrations of nanoparticles and the presence of background concentrations of the respective elements. The radiolabeling of nanoparticles offers an excellent and robust method to enable nanoparticle detection in these complex media down to the ng/L range. Even online in-situ tracing and visualization techniques are accessible to obtain spatio - temporal process information.

Depending on the nature of the nanoparticle and the process of interest different methods for the radiolabeling of nanoparticles can be applied, like the synthesis of the nanoparticles using radioactive starting materials, the binding of the radiotracer to the nanoparticles, the activation of the nanoparticles using proton irradiation, the recoil labeling utilizing the recoil of a nuclear reaction to implant a radiotracer into the nanoparticle, and the in-diffusion of radiotracers into the nanoparticles.

For our recent studies we produced [44Ti]TiO2, [45Ti]TiO2, [48V]TiO2, [64Cu]CuS, [64Cu]SiO2, [65Zn]CdSe/ZnS, [105Ag]Ag, [110mAg]Ag, [124I]CNTs, [125I]CNTs, [131I]CNTs, [7Be]MWCNT, [139Ce]CeO2 and [194Au]Pt nanoparticles. Due to the choice of the used radionuclide (half-life, decay-mode) and the activity concentrations it was possible to enable different detection methods and time scales for the investigations. All these methods go along with a careful characterization of the radiolabeled nanoparticles in respect of the radiolabeling stability and nanoparticle properties.

The radiolabeled nanoparticles have been successfully used in comprehensive environmental studies, like release studies, environmental mobility studies, fate studies in waste water treatment and plant uptake studies.
  • Invited lecture (Conferences)
    NanoSafety 2017, 11.-13.10.2017, Saarbrücken, Deutschland

Publ.-Id: 26133 - Permalink

P1601 - Verfahren und Vorrichtung
Hoffmann, A.; Speck, O.;
Gemäß verschiedenen Ausführungsformen kann ein Verfahren (100) Folgendes aufweisen: Erzeugen (101) eines Magnetfeldes in einem Bestrahlungsbereich; Bestrahlen (103) des Bestrahlungsbereichs mittels eines Partikelstrahls, welcher spinpolarisierte Partikel aufweist; Erfassen (105) einer Anregung der spinpolarisierten Partikel, welche durch das Magnetfeld bewirkt wird; und Ermitteln (107) einer räumlichen Charakteristik des Partikelstrahls auf Grundlage der Anregung.
  • Patent
    DE102016100638 - Offenlegung: 20.07.2017, Nachanmeldungen: WO

Publ.-Id: 26132 - Permalink

P1602 - Tomographievorrichtung
Barthel, F.; Hampel, U.; Bieberle, A.;
Die Erfindung betrifft eine Tomographievorrichtung mit Mitteln zum Erzeugen eines Elektronenstrahls; einer Ablenkvorrichtung zum Ablenken des Elektronenstrahls; einem Target; einer Steuervorrichtung zur Steuerung der Ablenkvorrichtung mittels Steuerungsdaten derart, dass der Elektronenstrahl an einem Auftreffpunkt auf das Target auftrifft und der Auftreffpunkt entlang mehrerer, in unterschiedlichen Ebenen verlaufender Bahnen geführt wird, wobei an dem Auftreffpunkt Röntgenstrahlung entsteht; und mehreren Röntgendetektoren zum Erfassen der Röntgenstrahlung, wobei jeder der Röntgendetektoren ein sich über alle Ebenen hinweg erstreckendes Detektorelement mit Szintillatormaterial und einen Lichtdetektor zum Erfassen von Szintillationslicht und Erzeugen eines Detektorsignals aufweist; wobei jedes der Detektorsignale basierend auf den Steuerungsdaten derjenigen Ebene zugeordnet wird, in der sich der Auftreffpunkt des Elektronenstrahls auf dem Target während der Erzeugung des Detektorsignals befindet.
  • Patent
    DE102016101787 - Offenlegung 03.08.2017, Nachanmeldungen: WO

Publ.-Id: 26131 - Permalink

P1609 - THz-Antenne und Vorrichtung zum Senden und/oder Empfangen von THz-Strahlung
Singh, A.; Winnerl, S.; Schneider, H.; Helm, M.;
Die Erfindung betrifft eine THz-Antenne und Vorrichtung zum Senden und/oder Empfangen von THz-Strahlung, wobei die THz-Antenne mehrere streifenförmige Elektroden und mehrere streifenförmige Gegenelektroden aufweist, die unter Ausbildung einer periodischen Elektrodenanordnung abwechselnd und parallel zueinander angeordnet sind, wobei jeweils eine Elektrode und eine Gegenelektrode ein Elektrodenpaar definieren, wobei die Elektrode und die Gegenelektrode jedes der Elektrodenpaare mittels photoleitfähigen Materials miteinander verbunden sind, und wobei die Elektroden und die Gegenelektroden mit einer konstanten Breite derart ausgebildet sind, dass die Elektroden eine größere Breite aufweisen als die Gegenelektroden.
  • Patent
    DE102016116900 - Erteilung: 02.08.2017, Nachanmeldungen: WO

Publ.-Id: 26130 - Permalink

Two Point Correlation Measurements in Liquid Metal Duct Flows using Ultrasound Phased Arrays
Mäder, K.; Räbiger, D.; Nauber, R.; Büttner, L.; Eckert, S.; Czarske, J.;
A key to improvements of industrial processes involving liquid metals like continuous steel casting is a good knowledge of the interaction between time-varying magnetic fields and conductive fluids. For investigations in this area, model experiments using low-melting liquid metals are conducted, which require suitable instrumentation for opaque media. Ultrasound Doppler velocimetry allows to measure the flow structures and thus to obtain turbulence statistics. For MHD experiments investigating small-scale and turbulent flows, a spatial resolution in the low millimeter range is required.
However, state of the art systems using arrays of unfocused single transducers are limited in their resolution by the divergence of the far field ultrasound beam. In addition, thus systems allow only one dimensional measurements along the propagation direction of the ultrasound beam. Thus interesting quantities in some experiments like turbulence statistics in the axial direction in duct flows can not be measured.
Using our novel phased array ultrasound Doppler velocimeter (PAUDV), the duct flow of an opaque liquid under the influence of an magnetic field can be studied. The measurement system combines the ultrasound Doppler velocimetry with the phased array technique, which allows to adaptively shape the sound field. Using its possibility to drive phased arrays with up to 256 individual channels simultaneously, the ultrasound beam is dynamically focussed in the measurement area, which increases the spatial resolution. In addition, the cross beam technique is used to enable two component measurements using a single acoustical access. This allows to measure turbulence statistics in the main flow direction of a fluid duct with only one ultrasound array on the duct wall.
Keywords: Ultrasound Phased arrays, flow measurements, liquid metals, duct flows
  • Lecture (Conference)
    16th European Turbulence Conference, 21.-24.08.2017, Stockholm, Sweden

Publ.-Id: 26128 - Permalink

Controlled ion beam hyperdoping of silicon nanowires
Berencén, Y.; Prucnal, S.; Wang, M.; Hübner, R.; Böttger, R.; Glaser, M.; Schönherr, T.; Möller, W.; Georgiev, Y. M.; Rebohle, L.; Erbe, A.; Lugstein, A.; Zhou, S.; Helm, M.; Skorupa, W.;
The hyperdoping of semiconductors consists of introducing dopant concentrations far above the equilibrium solubility limits. This results in a broadening of dopant energy levels into an impurity or intermediate band. We have recently demonstrated that hyperdoping bulk Si with Se shows promise for Si-based short-wavelength infrared photodetectors [1]. Lately, silicon nanowires (NWs) have gained increasing importance as building blocks for nanodevices like field-effect transistors, light emitting devices and photovoltaic cells [2, 3]. Therefore, the comparison between hyperdoping Si nanowires and bulk Si is a common issue to be examined, which comes along with the transition from a bulk material to semiconductor NWs.
In this work, we report on non-equilibrium processing for controlled hyperdoping of Si/SiO2 core/shell nanowires previously synthesized by the vapor-liquid-solid method. Our approach is based on Se implantation of the upper half of NWs followed by millisecond flash lamp annealing, which allows for a bottom-up template-assisted recrystallization of the amorphized parts of the NWs via explosive solid-phase epitaxy. The Se-hyperdoped Si NWs are successfully recrystallized and accommodate Se concentrations as high as 1021 cm-3. As a proof of device concept, a single Se-hyperdoped NW-based IR photoconductor is shown. In this way, the combination of ion implantation and flash lamp annealing as a promising nanoscale hyperdoping technology is successfully established.
[1] Y. Berencén, S. Prucnal, Fang Liu, I. Skorupa, R. Hübner, L. Rebohle, S. Zhou, H. Schneider, M. Helm, and W. Skorupa, “Room-temperature short-wavelength infrared Si photodetector,” Sci. Rep. 7, 43688 (2017).
[2] B. Tian, T. Cohen-Karni, Q. Qing, X. Duan, P. Xie and C.M. Lieber, “Three-dimensional, flexible nanoscale field-effect transistors as localized bioprobes,” Science 329, 831 (2010).
[3] T. J. Kempa, B. Tian, D.R. Kim, J. Hu, X. Zheng and C.M. Lieber, “Single and tandem axial p-i-n nanowire photovoltaic devices,” Nano Lett. 8, 3456 (2008).
Keywords: Hyperdoping, Si nanowires, ion implantation, flash lamp annealing, impurity band, sub bandgap photoresponse
  • Lecture (Conference)
    E-MRS 2017 Fall Meeting (European-Materials Research Society), Symposium S: Materials- nanoelectronics & nanophotonics, 18.09.2017, Warsaw, Poland

Publ.-Id: 26127 - Permalink

Development of highly potent phosphodiesterase 2A (PDE2A) inhibitors: Synthesis and in vitro evaluation of novel fluorinated tricyclic compounds
Ritawidya, R.; Scheunemann, M.; Brust, P.;
Phosphodiesterases (PDEs) play an important role in degrading the cyclic nucleotide second messengers, cAMP and cGMP. They are involved in many biological processes such as neurological, immune or inflammatory disorders, cancer, and heart diseases [1]. One of the PDEs, PDE2A, is found highly expressed in distinct areas of the brain but also in certain types of cancer [1]. Our goal was to synthesize novel fluorinated tricyclic compounds (FT) derivatives which could potentially be used as radioligands for PDE2A imaging of above-mentioned diseases via Positron Emission Tomography (PET). A key intermediate (compound 5 in the respective poster) was prepared in 4 steps, starting from aniline. Afterwards, two-step Suzuki coupling reaction, as well as bromination [2,3] were employed to introduce different moieties in C-1 and C-8 position of 5 to afford three FT derivatives, so-called FT1, FT2, and FT3. They were successfully prepared in 6-8 % overall yield (7-10 steps). The inhibitory potential of these FT derivatives towards PDE2A3 and other subtypes of PDEs was estimated. The affinity and selectivity of FT1 (82.9 % inhibition of PDE2A3 at 10 nM) was much higher than that of FT2 and FT3 (8.52 % and 13.2 % inhibition, respectively). The IC50 value of FT1 was 3.33 nM. It shows selectivity against PDE1A3, 3A, 4A1, 5A1, 6AB, 7A, 8A1, 9A1, 10A1, and 11A1. It is suggested that FT1 if radiolabeled with the PET radionuclide 18F could be a promising PDE2A imaging agent. Further studies to determine the suitability of FT1 as PET candidate are still needed.
Keywords: PDE2A, Benzoimidazotriazine, PET tracer
  • Poster
    Biotechnology Symposium, 05.10.2017, Leipzig, Deutschland

Publ.-Id: 26126 - Permalink

Dynamo action generated by a precession driven flow in a cylindrical container
Giesecke, A.; Vogt, T.; Gundrum, T.; Stefani, F.;
Since many years precession is regarded as an alternative flow driving mechanism that may account, e.g., for remarkable features of the ancient lunar magnetic field or as a complementary power source for the geodynamo. Precessional forcing is also of great interest from the experimental point of view because it represents a natural forcing mechanism that allows an efficient driving of conducting fluid flows on the laboratory scale without making use of propellers or pumps. Within the project DRESDYN (DREsden Sodium facility for DYNamo and thermohydraulic studies) a dynamo experiment is under development at Helmholtz-Zentrum Dresden-Rossendorf in which a precession driven flow of liquid sodium with a magnetic Reynolds number of up to Rm=700 will be used to drive dynamo action.

Our present study addresses preparative numerical simulations and flow measurements at a small model experiment running with water. In dependence of precession ratio and Reynolds number the resulting hydrodynamic flow patterns and amplitudes provide the essential ingredients for kinematic dynamo models that are used to estimate whether the particular flow is able to drive a dynamo. In the strongly non-linear regime the flow essentially consists of standing inertial waves. Most remarkable feature is the resonant-like occurrence of a stationary axisymmetric mode which emerges around a precession ratio Ωp/Ωc = 0.1. Kinematic dynamo models applying the time-averaged flow field from the hydrodynamic simulations exhibit dynamo action at a critical magnetic Reynolds number of Rmc=430 which is well within the range that will be achieved in the planned large scale sodium experiment.
Keywords: Dynamo, DRESDYN
  • Poster
    Dynamos and planetary flows today (PHR2017), 16.-17.11.2017, London, Great Britain

Publ.-Id: 26124 - Permalink

Engineering and modifying two-dimensional materials by electron beams
Zhao, X.; Kotakoski, J.; Meyer, J. C.; Sutter, E.; Sutter, P.; Krasheninnikov, A. V.ORC; Kaiser, U.; Zhou, W.
Electron-beam (e-beam) irradiation damage is often regarded as a severe limitation to atomic-scale study of two-dimensional (2D) materials using electron microscopy techniques. However, energy transferred from the e-beam can also provide a way to modify 2D materials via defect engineering when the interaction of the beam with the sample is precisely controlled. In this article, we discuss the atomic geometry, formation mechanism, and properties of several types of structural defects, ranging from zero-dimensional point defects to extended domains, induced by an e-beam in a few representative 2D materials, including graphene, hexagonal boron nitride, transition-metal dichalcogenides, and phosphorene. We show that atomic as well as line defects and even novel nanostructures can be created and manipulated in 2D materials by an e-beam in a controllable manner. Phase transitions can also be induced. The e-beam in a (scanning) transmission electron microscope not only resolves the intrinsic atomic structure of materials with defects, but also provides new opportunities to modify the structure with subnanometer precision.
Keywords: TEM, graphene


Publ.-Id: 26123 - Permalink

Towards diluted magnetism in TaAs
Liu, Yu; Li, Z.; Guo, L.; Chen, X.; Yuan, Y.; Xu, C.; Hübner, R.; Akhmadaliev, S.; Krasheninnikov, A. V.; N'Diaye, A. T.; Arenholz, E.; Helm, M.; Zhou, S.ORC
Magnetism in Weyl semimetals is desired to investigate the interaction between the magnetic moments and Weyl fermions, e.g., to explore anomalous quantum Hall phenomena. Here we demonstrate that proton irradiation is an effective tool to induce ferromagnetism in the Weyl semimetal TaAs. The intrinsic magnetism is observed with a transition temperature above room temperature. The magnetic moments from d states are found to be localized around Ta atoms. Further, the first-principles calculations indicate that the d states localized on the nearest-neighbor Ta atoms of As vacancy sites are responsible for the observed magnetic moments and the long-ranged magnetic order. The results show the feasibility of inducing ferromagnetism in Weyl semimetals so that they may facilitate the applications of this material in spintronics.


Publ.-Id: 26122 - Permalink

Substitutional carbon doping of free-standing and Ru-supported BN sheets: A first-principles study
Berseneva, N.; Komsa, H.-P.; Vierimaa, V.; Björkman, T.; Fan, Z.; Harju, A.; Todorovic, M.; Krasheninnikov, A. V.ORC; Nieminen, R. M.
The development of spatially homogeneous mixed structures with boron (B), nitrogen (N) and carbon (C) atoms arranged in a honeycomb lattice is highly desirable, as they open the possibility of creating stable two-dimensional materials with tunable band gaps. However, at least in the free-standing form, the mixed BCN system is energetically driven towards phase segregation to graphene and hexagonal BN. It is possible to overcome the segregation when BCN material is grown on a particular metal substrate, for example Ru(0 0 0 1), but the stabilization mechanism is still unknown. With the use of density-functional theory we study the energetics of BN/Ru slabs, with different types of con gurations of C substitutional defects introduced to the h-BN overlayer. The results are compared to the energetics of free- standing BCN materials. We found that the substrate facilitates the C substitution process in the h-BN overlayer. Thus, more homogeneous BCN material can be grown, overcoming the segregation into graphene and h-BN. In addition, we investigate the electronic and transport gaps in free-standing BCN structures, and assess their mechanical properties and stability. The band gap in mixed BCN free-standing material depends on the concentration of the constituent elements and ranges from zero in pristine graphene to nearly 5 eV in free-standing h-BN. This makes BCN attractive for application in modern electronics.
Keywords: graphene, doping, first-principles calculations


Publ.-Id: 26121 - Permalink

Ionization and reflux dependence of magnetic instability generation and probing inside laser-irradiated solid thin foils
Huang, L. G.; Schlenvoigt, H.-P.; Takabe, H.; Cowan, T. E.;
When an intense laser accelerated electron beam, with large current density on the order of 10^12 A/cm^2, enters a solid density plasma, it is well-known to be subject to a number of different types of instabilities that cause it to filament. In this work, we investigate the transport instability of a fast electron beam that is imprinted on the self-generated magnetic filaments inside the solid density plasmas using particle-in-cell simulations. By varying collisional ionization models, our simulations show that the atomic ionization process is crucial to determine the structure of the magnetic filaments. We further attribute the generation of bulk magnetic filaments to Weibel-like instability mechanism caused by counter-propagating hot forward-bulk return current streams and counterpropagating hot forward-reflux current streams. It is found that the magnetic fields in the filament channels near the rear surface are around one order of magnitude higher than those near the front surface of the thin solid target. This asymmetry is likely induced by the very different properties of bulk electron stream and hot reflux electron stream in terms of density and velocity distribution. Finally, we propose to probe the magnetic fields inside the solid density plasmas by X-Ray polarimetry via Faraday rotation using X-Ray free electron lasers (XFELs). The synthetic simulations show that XFELs are capable to detect the magnetic fields from relativistic laser-solid interactions.
Keywords: Laser plasma interactions, Weibel instability,XFEL,Faraday rotation

Publ.-Id: 26120 - Permalink

Reactive transport modelling based on actual parameters obtained from GeoPET analysis of column experiments
Karimzadeh, L.; Schymura, S.; Kulenkampff, J.; Franke, K.; Eichelbaum, S.; Lippmann-Pipke, J.; Fischer, C.;

GeoPET is the application of positron emission tomography (PET) for direct, non-destructive, quantitative spatiotemporal measurement and visualization of fluid transport in natural geological media on drill-core scale [1-5]. Here, we present new results that focus on reactive transport simulations on a drill core sample in 4D (3D+t) by using velocity fields (vx, vy, vz) obtained from GeoPET measurements of a fractured rock sample.
A mechanically induced fracture was obtained during a geomechanical shear test in a calciferous sandstone drill core sampled from the Permian Kupferschiefer ore formation (Rudna mine, Poland). Column leaching experiments using the core sample (D = 6 cm, L = 10 cm) were carried out in a plexiglas reaction cell in the laboratory at atmospheric pressure. The leaching solutions were injected with constant flow rate of 1 mL/h in three stages: First, a moderately hard synthetic fresh water (pH = 8.5) was used as inflow solution for 22 days in order to remove the salts minerals. Second, an acidic solution with pH of 1.5 (H2SO4) was injected to reduce the carbonat content within another 23 days. In stage three, 0.17 mol/L concentrated ferric iron was added to the acidic inflow solution (pH 1.5, H2SO4) for 20 days in order to dissolve mainly the Cu-sulfid minerals and increase the copper recovery from sample. The tracer transport in the sample was monitored by PET technique and the velocity fields derived by using an image analysing algorithm. The velocity fields then imported in the COMSOL Multyphisics to simulate and calibrate the fluidflow. Three dimensional modeling by means of iCP 1.3[6] (an interface coupling of the finite element based code COMSOL Multiphysics® with the geochemical code PhreeqC[7]) was performed to predict the leaching process and solute transport through the core sample by using kinetic mineral dissolution and precipitation data (BRGM database). The reactive transport model results are compared and refined by using the laboratory column leaching experiments.
Keywords: Reactive transport modeling, GeoPET, Column leaching experiment
  • Poster
    Reactive Transport in the Earth and Environmental Sciences in the 21st Century, 02.-06.10.2017, Amboise, France

Publ.-Id: 26119 - Permalink

Scaling EUV and X-ray Thomson sources to optical free-electron laser operation with Traveling-Wave Thomson-Scattering
Steiniger, K.; Albach, D.; Debus, A.; Loeser, M.; Pausch, R.; Roeser, F.; Schramm, U.; Siebold, M.; Bussmann, M.;
Traveling-Wave Thomson-Scattering (TWTS) allows for the realization of ultra-compact, inherently synchronized and highly brilliant light sources by providing optical undulators with hundreds to thousands of undulator periods from high-power, pulse-front tilted lasers pulses.

With TWTS the realization of optical free-electron lasers (OFELs) as well as incoherent radiation sources with orders of magnitude higher photon yields than classic head-on Thomson sources becomes possible with state-of-the-art technology in electron accelerators and laser systems.

The talk will show how pulse-front tilted, petawatt class laser pulses and relativistic electrons work together in a side-scattering geometry, where laser end electron propagation direction of motion enclose an angle, to realize long but compact optical undulators with centimeter to meter-scale interaction distances at sub-millimeter undulator periods. Example setups of TWTS OFELs emitting ultraviolet radiation are presented which are realizable today with existing technology for electron accelerators and laser systems. Especially the ultra-low emittance of laser wakefield accelerated electron bunches can be exploited to compensate for their one percent level energy spreads. Further an experimental setup is presented to generate the tilted TWTS laser pulses. This setup strategy provides dispersion compensation, required due to angular dispersion of the laser pulse, and is especially relevant when building compact, high-yield hard X-ray TWTS sources in large interaction angle setups.
Keywords: Optical free-electron laser, traveling wave, thomson scattering, vuv, euv, x-ray, laser dispersion control
  • Lecture (Conference)
    SPIE Optics + Optoelectronics, 24.-27.04.2017, Prague, Czech Republic

Publ.-Id: 26118 - Permalink

Design of optical setups for high-yield optical undulators in the Traveling-Wave Thomson-Scattering geometry
Steiniger, K.; Debus, A.; Albach, D.; Loeser, M.; Pausch, R.; Roeser, F.; Schramm, U.; Siebold, M.; Bussmann, M.;
Traveling-Wave Thomson-Scattering (TWTS) can realize ultra-compact, inherently synchronized and highly brilliant light sources from the ultraviolet to the hard X-ray range. In TWTS ultrashort laser pulses and relativistic electron bunches are utilized in a side-scattering geometry where laser pulse and electron bunch direction of motion enclose an interaction angle. Thereby the laser electric field provides the undulator field in which electrons oscillate and emit radiation during interaction. By employing tilted laser pulses TWTS ensures continuous overlap of laser and electrons while these traverse the laser cross-sectional area. Tilting the laser pulse-front compensates the spatial separation of electrons and laser at begin and end of the interaction originating from their different propagation directions. Combining laser pulse-front tilt and side-scattering in TWTS enables interaction over hundreds to thousands of optical undulator periods, enough to allow for optical free-electron laser (OFEL) operation since microbunching of the electron bunch and thus coherent radiation amplification can be achieved.
After shortly introducing the TWTS scattering geometry, the design of optical setups to generate the tilted TWTS laser pulses is presented in the talk. This setup strategy provides dispersion compensation, required due to angular dispersion of the laser pulse, and is especially relevant when building compact, high-yield hard X-ray TWTS sources in large interaction angle setups. Determining parameters of the setup is illustrated in an example of an ultraviolet TWTS OFEL and an outlook is given on the design of hard X-ray TWTS sources.
Keywords: Traveling wave, thomson scattering, laser dispersion control, x-ray source
  • Lecture (Conference)
    DPG Frühjahrstagung Dresden, 19.-24.03.2017, Dresden, Deutschland

Publ.-Id: 26116 - Permalink

IAEA CRP benchmark of ROCOM PTS test case for the use of CFD in reactor design using ANSYS CFX
Höhne, T.;
Over the last 15 years, considerable effort has been expended in assembling the available information on the use of CFD in the nuclear reactor safety field. Typical application areas here are heterogeneous mixing and heat transfer in complex geometries, buoyancy-induced natural and mixed convection, etc., with specific reference to NRS accident scenarios such as Pressurized Thermal Shock (PTS), boron dilution, hydrogen build-up in containments, thermal fatigue and thermal striping issues, etc. The development, verification and validation of CFD codes in respect to NPP design necessitates further work on the complex physical modelling processes involved, and on the development of efficient numerical schemes needed to solve the basic equations. Therefore, a set of ROCOM CFD-grade test data were made available to set up an IAEA benchmark, relating to Pressurized Thermal Shock (PTS) scenarios. The benchmark deals with the injection of the relatively cold Emergency Core Cooling (ECC) water which can induce buoyancy-driven stratification. Data obtained from the PTS experiment were compared with predictions obtained from the CFD software ANSYS CFX.

The results of the experiment and of the numerical calculations show that mixing is dominated by buoyancy effects: at higher mass flow rates (close to nominal conditions) the injected slug propagates in the circumferential direction around the core barrel. Buoyancy effects reduce this propagation. The ECC water falls in an almost vertical path and reaches the lower down-comer sen¬sor directly below the inlet nozzle. Therefore, density effects play an important role during natural convection with ECC injection in PWRs. CFD was able to predict well the observed flow patterns and mixing phenomena.
  • Lecture (Conference)
    Fourth Research Coordination Meeting on the Application of Computational Fluid Dynamics Codes for Nuclear Power Plant Design, 08.11.2017, Wien, Österreich

Publ.-Id: 26114 - Permalink

Ex-situ doping and Ohmic contact formation with low contact resistance on MBE grown GeSn on Si
Prucnal, S.; Augel, L.; Schulze, J.; Fischer, I. A.; Berencén, Y.; Hübner, R.; Böttger, R.; Rebohle, L.; Skorupa, W.; Wang, M.; Voelskow, M.; Helm, M.; Zhou, S.;
GeSn with quasi-direct band gap is one of the most promising semiconductor materials for light emitters integrated with CMOS technology. The equilibrium solid solubility limit (SSL) of Sn in Ge is in the range of 0.5 % and the predicted theoretical Sn concentration needed for the direct band gap formation is above 5 %. This means that GeSn with direct band gap is metastable and any related material process cannot be thermal equilibrium. Here we propose to utilize strongly non-equilibrium processing i.e. ion implantation followed by millisecond range flash lamp annealing (FLA), for doping and the formation of Ohmic contacts with low contact resistance on Ge0.95Sn0.05. The effective carrier concentration in P+ implanted Ge0.95Sn0.05 layer followed by FLA for 3 ms is above 5×10^19cm-3 with a specific contact resistance rc=4×10^-6Ωcm2. NiGe for Ohmic contact is made by Ni diffusion into GeSn during a single 3 ms long flash pulse. TEM images reveal that NiGe is polycrystalline but with an atomically sharp interface between the metal contact and GeSn. The influence of non-equilibrium processing (ion implantation and FLA) on the optical, electrical and microstructural properties of the GeSn layer grown by MBE on Si will be discussed in details.
Keywords: GeSn, MBE, doping, flash lamp annealing
  • Poster
    EMRS Fall Meeting 2017, 18.-21.09.2017, Warsaw, Poland

Publ.-Id: 26113 - Permalink

Strategies for high doping of Ge
Prucnal, S.;
One of the main obstacles towards wide application of Ge in nanoelectronics is the lack of an efficient doping method for the fabrication of heavily doped Ge layers with well controlled junction depth. In fact, n-type doping of Ge is a key bottleneck in the realization of advanced negative-channel metal-oxide-semiconductor (NMOS) devices. Here an overview of different doping techniques will be presented. Special attention will be focused on the use of ion implantation followed by flash-lamp (FLA) annealing for the fabrication of heavily doped Ge. In contrast to conventional annealing procedures, rear-side FLA leads to full recrystallization of Ge and dopant activation independently of pre-treatment. The maximum carrier concentration is well above 10^20 cm-3 for n-type and above 10^21 for p-type doping. The recrystallization mechanism and the dopant distribution during rear-side FLA are discussed in detail. In this work, we report on the strong mid-IR plasmon absorption from heavily P-doped Ge thin films and superconductivity in Ga and Al doped Ge obtained by non-equilibrium thermal processing. The mid-IR plasmon spectral response at room temperature from those samples was characterized by means of Fourier transform infrared spectroscopy. It is proven that the position of the plasmonic resonance frequency signal can be tuned as a function of the P concentration.
Keywords: Ge, flash lamp annealing, doping
  • Invited lecture (Conferences)
    EMRS Fall Meeting 2017, 18.-21.09.2017, Warsaw, Poland

Publ.-Id: 26112 - Permalink

Influence of Nickel Catalyst Morphology on Layer-Exchange-Based Carbon Crystallisation of Ni/a-C Bilayers
Janke, D.; Hulman, M.; Wenisch, R.; Gemming, S.; Rafaja, D.; Krause, M.;
Metal-induced crystallisation with layer exchange is applied on Ni/C bilayer stacks deposited by three PVD techniques on SiO2. The layer stacks were deposited at room temperature by either ion beam sputtering, direct current magnetron sputtering or high-power impulse magnetron sputtering. The influence of the Ni morphology on the layer exchange degree aLE and the resulting graphitic ordering is studied by atomic force microscopy, Rutherford backscattering spectrometry and Raman spectroscopy. The initial RMS roughness of the Ni top layer varied with the deposition technique by a factor of 20, from 0.3 to 6.1 nm.
After annealing in UHV at up to 700°C, layer exchange was observed for all samples. Still, the layer exchange degree was affected by the roughness of the initial bilayer stack. The highest value of 96% was achieved for magnetron-sputtered samples, what is by ~35% higher than for the initially roughest Ni surfaces. Raman spectroscopy showed the formation of graphitic carbon, characterised by a strong 2D line, for all three bilayer stacks. The degree of graphitic ordering increased with decreasing Ni surface roughness.
Keywords: Metal-induced crystallisation of amorphous carbon, Layer exchange, Rutherford Backscattering Spectrometry, Raman spectroscopy

Publ.-Id: 26111 - Permalink

An Eulerian-Eulerian Computational Fluid Dynamic Approach to Predict the Boiling Process with New Developed Sub Models
Ding, W.; Krepper, E.; Hampel, U.;
Time averaged Eulerian multiphase approaches and the heat flux partitioning method is popular to be applied in the computational fluid dynamic simulations of wall boiling especially in the forced convective boiling. In such CFD simulations, many submodels for the bubble dynamics and the implementation of the bubble dynamics into the global models are particularly important. In order to get accurate bubble dynamics, a single bubble model for nucleate boiling based on the known microlayer theory was developed. The single bubble model consideres the dynamic bubble geometry, contact angle and bubble inclination angle in flow boiling at different time periods. The model is able to show the dependency of bubble departure diameter (lift off diameter) and frequency on the different physical quantities such as heat flux, liquid properties, sub-cooling temperature, design of channel (diameter, length), mass flow rate and so on. The implementation of this developed single bubble model requires an update of the conventional nucleation site activation and heat partitioning models in time averaged Eulerian multiphase approaches. The new activation approach considers a distribution of cavity sizes and their influence on the activation temperature. The dynamics of the bubbles generated from different size cavities at the same position differ from each other. The updated heat partitioning model assumes the heat flux at the evaporative area always as constant and equal to the known feed heat flux when the boiling system is in the steady state. With help of the multiple size group (MUSIG) model and a breakup and coalesce model, the time averaged Eulerian approach could simulate the bubble size distribution in a heated pipe. With the necessary calibration of the nucleation site density the comparisons between the calculation results and the Bartolomej’s experiments demonstrate the accuracy of this approach.
Keywords: Forced convective boiling, Eulerian multi-phase approach, microlayer, cavity group activation, heat partitioning
  • Contribution to proceedings
    17th International Topical Meeting on Nuclear Reactor Thermal hydaulics, 04.-08.09.2017, Xi'an, China
    17th International Topical Meeting on Nuclear Reactor Thermal hydaulics

Publ.-Id: 26110 - Permalink

A hypothesis of near critical heat flux (CHF-) based on minimum waiting time
Ding, W.; Krepper, E.; Hampel, U.;
Boiling is a very efficient heat transfer mechanism with a large heat transfer coefficient and it is widely found in industrial systems. However, boiling heat transfer is limited by the critical heat flux (CHF), also termed as boiling crisis, which may lower efficiency and jeopardize safety of heat transfer systems. The latter is of particular importance for the safe operation of nuclear light water reactors. A clear understanding of the basic mechanisms leading to CHF is still lacking. In this paper a new model for the quantitative prediction of the initiation of critical heat flux is derived from the bubble dynamics and heat fluxes in nucleate boiling. It incorporates effects of mutual bubble interaction and shear stress from bulk flow. The model was successfully validated with available experimental data from literature for both pool boiling and forced convective boiling and with that it can be very widely applied, both as a stand-alone model for heat transfer system design as well as a sub-model in computational fluid dynamics (CFD).
Keywords: Critical heat flux (CHF), boiling heat transfer, pool boiling, forced convective boiling, cavity activation
  • Contribution to proceedings
    17th International Topical Meeting on Nuclear Reactor Thermal Hydraulics, 04.-08.09.2017, Xi'an, China
    17th International Topical Meeting on Nuclear Reactor Thermal Hydraulics

Publ.-Id: 26109 - Permalink

Bulk anaylsis of extraterrestrial samples using INAA at the research reactor FRM II
Li, X.; Leister, N.; Lierse Von Gostomski, C.; Merchel, S.; Gurlit, S.; Muszynski, A.; Szyszko, M.; Bischoff, A.;
Within the framework of a TUM-Kolleg Project between the TU München and the Otto-von-Taube-Gymnasium Gauting three ordinary chondrites from Germany (Cloppenburg [1], Oldenburg (Bissel), Benthullen), three HEDs from Oman and North-West-Africa (Dhofar 1675, NWA 2690, NWA 2698), one lunar and one martian Meteorite (NWA 7986, NWA 4925) were analyzed by instrumental neutron actication analysis (INAA). In Germany the FRM II is currently the most intensive neutron source offering different irradiation facilities and high and pure thermal neutron flux for INAA. In total, 45 elements including many REEs could be determined. A clear difference between chondrites and achondrites could be observed according to the element compositions. The high Ba-concentration in all samples is probably a result of weathering [2].
The martian meterorite has a high concentration of Fe (17.2%) compared to other achondrites. The moon sample has higher concentrations of REEs, but is apparently not a rock with a KREEP-signature.
[1] Storz, J. et al., this meeting. [2] Stelzner, T. et al., (1999) MAPS 34, 787-794.
Keywords: AMS, meteorite, REE, INAA, ICP-MS
  • Poster
    Paneth-Kolloquium, 10.-13.10.2017, Nördlingen, Deutschland

Publ.-Id: 26108 - Permalink

Photochemical Reduction of Non-fluorescent Tris(carbonato)uranyl(VI) Complex
Takao, K.; Tsushima, S.ORC
A uranyl ion usually shows characteristic green emission and photochemical reactions under UV irradiation, while tris(carbonato)uranyl(VI) complex is known to be exceptionally inert because of strong quenching through the bound carbonates. In this study, we report that tris(carbonato)uranyl(VI) was immediately reduced to the corresponding uranyl(V) species under presence of tetrahydroborate and UV irradiation.
  • Lecture (Conference)
    The 67th Conference of Japan Society of Coordination Chemistry, 16.-18.09.2017, Sapporo, Japan

Publ.-Id: 26106 - Permalink

Computational study on the interaction between Eu(III) and calmodulin
Tsushima, S.ORC; Mochizuki, Y.; Komeiji, Y.; Takao, K.
there is no abstract
  • Lecture (Conference)
    Atomic Energy Society of Japan 2017 Fall Meeting, 13.-15.09.2017, Sapporo, Japan

Publ.-Id: 26105 - Permalink

Theoretical study on Calmodulin binding with Ca(II) and Eu(III) ions
Tsushima, S.ORC; Mochizuki, Y.; Komeiji, Y.; Okuwaki, K.; Abe, T.; Mori, H.; Tanaka, S.
there is no abstract
  • Lecture (Conference)
    The 78th Japan Society of Applied Physics Meeting, 05.-08.09.2017, Fukuoka, Japan

Publ.-Id: 26104 - Permalink

Cloppenburg (H4-5) – first results of a new find
Storz, J.; Bischoff, A.; Degering, D.; Ebert, S.; Heinlein, D.; Jull, T.; Kontul, I.; Li., X.; Merchel, S.; Oberst, J.; Ott, U.; Pack, A.; Peters, S.; Petö, M. K.; Rugel, G.;
The Cloppenburg meteorite of 141 g was found March 15, 2017 by the facility manager of a school while collecting rocks for the school garden. The rock with a mean density of (3.33 ± 0.03) g/cm3 is a brecciated H-group ordinary chondrite (H4-5) with mean olivine and low-Ca pyroxene of Fa18.5±0.3 and Fs16.4±0.6, respectively. The breccia containing shock veins is weakly shocked (S3) and heavily weathered (W3). The occurrence of vivianite, the oxygen isotopes, and the Ba-enrichment (by INAA) indicate strong weathering in a very wet environment. Radionuclide data evaluation is still ongoing: Accelerator mass spectrometry (AMS) of 14C, will reveal the terrestrial age. An upper limit of the terrestrial age is yet set by low-level gamma-spectrometry in the Felsenkeller underground lab. No 22Na (t1/2=2.6 a) nor 44Ti (t1/2=59 a) could been detected within a counting time of 27 days, whereas 26Al (t1/2=0.7 Ma) was clearly identified. AMS of 10Be (t1/2=1.4 Ma) of ~18 dpm/kg confirms the high cosmic ray exposure age (CRE age) of (7.5 ± 0.4) Ma from noble gas mass spectrometry.
Keywords: AMS, cosmogenic nuclide, mass spectrometry, gamma-spectrometry, INAA
  • Poster
    Paneth-Kolloquium, 11.-13.10.2017, Nördlingen, Deutschland

Publ.-Id: 26103 - Permalink

Investigation of bioreactors by instrumented flow-following sensor particles
Reinecke, S.; Hampel, U.;
Instrumented flow-following sensor particles have been developed for investigation of hydrodynamic and biochemical processes chemical reactors and bioreactors, where standard measurement techniques are not applicable. The sensor particles allow autonomous long-term measurement of spatially distributed process parameters in the chemically and mechanically harsh environments of agitated industrial vessels. Each sensor particle comprises of an on-board measurement electronics that logs the signals of the embedded sensors. A buoyancy control unit enables automated taring to achieve neutral buoyancy of the sensor particles. Moreover, controlled floating of the sensor particles is possible to expose them for recovery from the fluid surface. The paper presents exemplary results from tests in an air-water column reactor, a pilot biogas digester and a waste water treatment plant.
Keywords: sensor particle, autonomous sensor, flow follower, hydrodynamics, bioreactor
  • Contribution to proceedings
    Sensor 2017, 30.05.-01.06.2017, Nürnberg, Deutschland
  • Lecture (Conference)
    Sensor 2017, 30.05.-01.06.2017, Nürnberg, Deutschland

Publ.-Id: 26102 - Permalink

The 2017 Magnetism Roadmap
Sander, D.; Valenzuela, S. O.; Makarov, D.; Marrows, C. H.; Fullerton, E. E.; Fischer, P.; McCord, J.; Vavassori, P.; Mangin, S.; Pirro, P.; Hillebrands, B.; Kent, A. D.; Jungwirth, T.; Gutfleisch, O.; Kim, C. G.; Berger, A.;
Building upon the success and relevance of the 2014 Magnetism Roadmap, this 2017 Magnetism Roadmap edition follows a similar general layout, even if its focus is naturally shifted, and a different group of experts and, thus, viewpoints are being collected and presented. More importantly, key developments have changed the research landscape in very relevant ways, so that a novel view onto some of the most crucial developments is warranted, and thus, this 2017 Magnetism Roadmap article is a timely endeavour. The change in landscape is hereby not exclusively scientific, but also reflects the magnetism related industrial application portfolio. Specifically, Hard Disk Drive technology, which still dominates digital storage and will continue to do so for many years, if not decades, has now limited its footprint in the scientific and research community, whereas significantly growing interest in magnetism and magnetic materials in relation to energy applications is noticeable, and other technological fields are emerging as well. Also, more and more work is occurring in which complex topologies of magnetically ordered states are being explored, hereby aiming at a technological utilization of the very theoretical concepts that were recognised by the 2016 Nobel Prize in Physics. Given this somewhat shifted scenario, it seemed appropriate to select topics for this roadmap article that represent the three core pillars of magnetism, namely magnetic materials, magnetic phenomena and associated characterization techniques, as well as applications of magnetism. While many of the contributions in this Roadmap have clearly overlapping relevance in all three fields, their relative focus is mostly associated to one of the three pillars. In this way, the interconnecting roles of having suitable magnetic materials, understanding (and being able to characterize) the underlying physics of their behaviour and utilizing them for applications and devices is well illustrated, thus giving an accurate snapshot of the world of magnetism in 2017. The article consists of 14 sections, each written by an expert in the field and addressing a specific subject on two pages. Evidently, the depth at which each contribution can describe the subject matter is limited and a full review of their statuses, advances, challenges and perspectives cannot be fully accomplished. Also, magnetism, as a vibrant research field, is too diverse, so a number of areas will not be adequately represented here, leaving space for further roadmap editions in the future. However, this 2017 Magnetism Roadmap article can provide a frame that will enable the reader to judge where each subject and magnetism research field stands overall today and which directions it might take in the foreseeable future. The first material focused pillar of the 2017 Magnetism Roadmap contains five articles, which address the questions of atomic scale confinement, 2D, curved and topological magnetic materials, as well as materials exhibiting unconventional magnetic phase transitions. The second pillar also has five contributions, which are devoted to advances in magnetic characterization, magneto-optics and magneto-plasmonics, ultrafast magnetization dynamics and magnonic transport. The final and application focused pillar has four contributions, which present non-volatile memory technology, antiferromagnetic spintronics, as well as magnet technology for energy and bio-related applications. As a whole, the 2017 Magnetism Roadmap article, just as with its 2014 predecessor, is intended to act as a reference point and guideline for emerging research directions in modern magnetism.
Keywords: magnetism, roadmap, magnetic materials, magneto-optics, spintronics, magnonics, magnetic memory

Publ.-Id: 26101 - Permalink

Mesoscale Dzyaloshinskii-Moriya interaction: geometrical tailoring of the magnetochirality
Volkov, O. M.; Sheka, D. D.; Kravchuk, V. P.; Gaididei, Y.; Rößler, U. K.; Faßbender, J.; Makarov, D.;
Crystals with broken inversion symmetry can host fundamentally appealing and technologically relevant periodical or localized chiral magnetic textures. The type of the texture as well as its magnetochiral properties are determined by the intrinsic Dzyaloshinskii-Moriya interaction (DMI), which is a material property and can hardly be changed. Here we put forth a method to create new artificial chiral nanoscale objects with tunable magnetochiral properties from standard magnetic materials by using geometrical manipulations. We introduce a mesoscale Dzyaloshinskii-Moriya interaction that combines the intrinsic spin-orbit- and extrinsic curvature-driven DMI terms and depends both on the material and geometrical parameters. The vector of the mesoscale DMI determines magnetochiral properties of any curved magnetic system with broken inversion symmetry. The strength and orientation of this vector can be changed by properly choosing the geometry. For a specific example of nanosized magnetic helix, the same material system with different geometrical parameters can acquire one of three zero-temperature magnetic phases, namely, phase with a quasitangential magnetization state, phase with a periodical state and one intermediate phase with a periodical domain wall state. The difference between equilibrium magnetization states for magnetic nanohelices with opposite geometrical chiralities put forth on a new simple measuring method of the DMI constant. Our approach paves the way towards the realization of a new class of nanoscale spintronic and spinorbitronic devices with the geometrically tunable magnetochirality.
Keywords: curvilinear magnetism, curved magnetic nanowires, micromagnetism

Publ.-Id: 26100 - Permalink

Magnetic coupling phenomena in curved nanomagnets
Makarov, D.;
Magnetic curvilinear objects possess new fundamental properties originating from the curvature-driven effects, leading to magnetochiral effects and topologically induced magnetization patterns. Recently, it was theoretically predicted that these effects come from the exchange-induced curvilinear interactions like anisotropy-like and chiral-like parts [R. Streubel et al., Magnetism in curved geometries (topical review), Journal of Physics D: Applied Physics 49 p. 363001 (2016)]. These recent developments ranging from theoretical predictions over fabrication of three-dimensionally curved magnetic thin films, hollow cylinders or wires, to their characterization using integral means as well as the development of advanced tomography approaches are in the focus of this talk.
Keywords: curved magnetic thin films, curvilinear magnetism
  • Invited lecture (Conferences)
    Magnetic Coupling in Nanostructured Materials, 23.-25.10.2017, Rome, Italy

Publ.-Id: 26098 - Permalink

Spintronics of thin film granular antiferromagnets
Makarov, D.;
Antiferromagnets have the potential to revolutionize spintronics due to their inherently magnetic-field stable magnetic order and high-frequency operation. There are already great advances in the field especially when bulk antiferromagnets are considered. The application potential of antiferromagnets can be explored in full only if they will be prepared in the way to be compatible with a conventional microelectronic processing. This necessarily requires the use of (i) thin film antiferromagnets and (ii) discovery of methods to address the order parameter and its modifications all-electrically.
With respect to the first challenge it is necessary to understand modifications of the magnetic properties and magneto-electric responses of thin film antiferromagnets with respect to their bulk counterparts. Typically, thin films possess grainy morphology. Hence, to determine their application potential, questions regarding the change of the intergranular exchange, criticality behavior and switching of the order parameter need to be answered. This topic I will illustrate on the specific example of thin film magnetoelectric collinear antiferromagnet α-Cr2O3 studied using zero-offset Hall magnetometry and NV microscopy [1].
To address the second challenge it is required to develop transport-based techniques to harness the responses of thin film antiferromagnets. This task is difficult as minute uncompensated surface magnetization of antiferromagnets needs to be detected, which imposes strict requirements to the sensitivity of the method. I will outline our developments of zero-offset anomalous Hall magnetometry [2] applied to study the physics of conventional metallic IrMn and insulating magnetoelectric Cr2O3 antiferromagnets.
The fundamental understanding of the magnetic microstructure of magnetoelectric α-Cr2O3 thin films and the possibility to read-out its antiferromagnetic order parameter all-electrically enabled the entirely new recording concept where a magnetoelectric memory cell can be addressed without using a ferromagnet. With this approach, we opened an appealing field of purely antiferromagnetic magnetoelectric random access memory (AF-MERAM) [1]. The key performance parameters of the Cr2O3 based AF-MERAM will be highlighted.

[1] T. Kosub, M. Kopte, R. Hühne, P. Appel, B. Shields, P. Maletinsky, R. Hübner, M. O. Liedke, J. Fassbender, O. G. Schmidt, and D. Makarov, “Purely antiferromagnetic magnetoelectric random access memory”. Nature Communications 8, 13985 (2017).
[2] T. Kosub, M. Kopte, F. Radu, O. G. Schmidt, and D. Makarov, “All-Electric access to the magnetic-field-invariant magnetization of antiferromagnets”. Phys. Rev. Lett. 115, 097201 (2015).
Keywords: antiferromagnetic spintronics, magnetoelectric Memory
  • Invited lecture (Conferences)
    Workshop on antiferromagnetic spintronics, 25.-27.10.2017, Grenoble, France

Publ.-Id: 26097 - Permalink

Electronic proprioception
Makarov, D.;
Augmented reality gadgets are becoming common for our information intensive society assisting us to acquire and process the data. Although impressive in the realization and demonstrations, the obvious drawback of the state-of-the-art augmented and virtual reality devices relying on optical detection systems is their bulkiness, energy inefficiency and the stringent requirement for an operator to be at the line of sight of the device.
We envision that prospective augmented reality systems will strongly benefit from the recent developments in compliant on-skin electronics. The fabrication of highly conformable gadgets requires the realization of the electronic replica of the exteroceptive sensory system of humans as well as calls for the acquiring new perception skills beyond those prescribed by the evolution. The first crucial step towards the realization of this vision was accomplished with the development of interactive magnetosensitive skins [1-4].
Here, we present the first on-skin gadgets, which replicate our natural proprioceptive sensory ability of detecting the motion. Relying on this magnetically enabled electronic proprioception, we visualize the bodily motion and demonstrate the touchless manipulation of virtual objects for augmented reality systems. Those highly conformable interactive devices possess great potential to extend the portfolio of tasks, which can be performed in virtual or augmented reality. The integration of gadgets in imperceptible electronic skins will open not only exciting possibilities for business or gaming industry but is also beneficial for safety and security applications, where the somatic manipulation of objects, e.g. turning regulation knobs located in a restricted environment is undesirable or even prohibited.

1. M. Melzer et al., Nature Commun. 6, 6080 (2015).
2. M. Melzer et al., Adv. Mater. 27, 1274 (2015).
3. N. Münzenrieder et al., Adv. Electron. Mater. 2, 1600188 (2016).
4. D. Makarov et al., Appl. Phys. Rev. 3, 011101 (2016).
Keywords: magnetic field sensors, flexible electronics
  • Invited lecture (Conferences)
    NanoBioSensor Conference, 04.-05.09.2017, Dresden, Germany

Publ.-Id: 26096 - Permalink

H-T phase diagram of solid oxygen
Nomura, T.; Matsuda, Y. H.; Kobayashi, T. C.;
The comprehensive magnetic field–temperature (H-T) phase diagram of solid oxygen including the θ phase is discussed in the context of the ultrahigh-field measurement and the magnetocaloric effect (MCE) measurement. The problems originating from the short duration of the pulse field, nonequilibrium conditions and MCEs, are pointed out and dealt with. The obtained phase diagram manifests the entropy relation between the phases as Sθ ∼ Sα < Sβ << Sγ

Publ.-Id: 26095 - Permalink

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