Publications Repository - Helmholtz-Zentrum Dresden-Rossendorf

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39295 Publications

Flash lamp annealing with millisecond pulses for ultra-shallow boron profiles in silicon

Gebel, T.; Voelskow, M.; Skorupa, W.; Mannino, G.; Privitera, V.; Priolo, F.; Napolitani, E.; Carnera, A.

In this paper we report on recent results obtained from flash lamp annealing (FLA) for the formation of ultra-shallow junctions. Si (100) wafers were implanted at ultra-low energy (500eV) with boron to a fluence of 1015 ions/cm2. FLA was carried out at temperatures of 1100 and 1200°C with a soak time of 20ms. For comparison conventional rapid thermal annealing (RTA) was performed at 1100°C and 1200°C. The boron diffusion and the dopant activation were investigated by secondary ion mass spectroscopy (SIMS) and spreading resistance profiling (SRP). The activated doses after FLA were as high as 20% of the implanted dose and confined in a layer of 60 nm. The sheet resistances were comparable to those after RTA treatment.

Keywords: shallow junctions; flash lamp annealing (FLA); rapid thermal annealing (RTA); spike anneal

  • Nuclear Instruments and Methods B 186 (2002) 287-290
  • Lecture (Conference)
    E-MRS Spring Meeting 2001, 04.-08.06.2001, Strasbourg (France)

Publ.-Id: 4337

Antimony implanted in silicon-a thin layer reference material for surface analysis

Ecker, K. H.; Berger, A.; Grötzschel, R.; Persson, L.; Wätjen, U.

A reference material has been produced which can be used for the calibration of surface - and near-surface analytical methods.

Keywords: Certified reference material; RBS; Instrumental neutron activation analysis

  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms Volumes 175-177 (2001)797

Publ.-Id: 4336

Determination of parameters for channeling of protons in SiC polytypes in the backscattering geometry

Kokkoris, M.; Kossionides, S.; Vlastou, R.; Aslanoglou, X. A.; Grötzschel, R.; Nsouli, B.; Kuznetsov, A.; Petrovic, S.; Paradellis, T.

Energy spectra of protons channeling along the (0001) axis of several SiC polytype crystals, (namely 4H, 6H, 15R, 21R) in the energy region Ep=1.7-2.5 MeV, in the backscattering geometry, were taken and analyzed. Computer simulations based on the assumption that the dechanneling of protons follows an exponential law are in very good agreement with the measured spectra. The obtained results for the two crucial channeling parameters, ?, the mean channeling distance, and, a, the ratio of the stopping powers in the aligned and random mode are compared for the different structures and an attempt is made to explain the occuring similarities as well as the differences, in order to evaluate the use of SiC polytypes as substrates in implantations and thin film depositions. An attempt is also made to correlate the results from the present work to the ones obtained in the past for simpler crystallographic structures, namely Si <100> and Si <111>, as well as more complex ones, such as SiO2 (c-axis).

Keywords: Backscattering; Channeling; Nuclear resonance; SiC crystal; Protons; Polytype

  • Nuclear Instruments and Methodes in Physics Research B 184 (2001) 319-326

Publ.-Id: 4335

Phase transformations in nitrogen-implanted iron layers

Jagielski, J.; Kopcewicz, M.; Matz, W.; Grötzschel, R.; Thomé, L.

Phase transformations in implanted iron may strongly depend on the sample thickness. The effect essentially relies on lower impurity concentration required for given phase transformation in thin films when compared with thick layers or bulk samples.

Keywords: Ion implantation; Phase formation; thin films

  • Nuclear Instruments and Methodes in Physics Research B 175-177 (2001) 448-452

Publ.-Id: 4334

RBS and HIRBS Studies of Nanostructured AgSiO2 Sol-Gel Thin Coatings

Kokkoris, M.; Trapalis, C. C.; Kossionides, S.; Vlastou, R.; Nsouli, B.; Grötzschel, R.; Spartalis, S.; Kordas, G.; Paradellis, T.

In the present work, composite AgSiO2 thin coatings, containing metal nanoparticles, were prepared on glass substrates by the sol-gel route. The coatings were thermally treated in oxidative and reductive conditions up to 500oC for metal nanoparticle formation. The coating structure and the nanoparticle formation were studied by Atomic Force Microscopy (AFM) and Rutherford Backscattering Spectroscopy (RBS) techniques. In the case of RBS, 1.4 MeV 4He+ ions were used for all samples, and low energy 16O and 12C ions in selected ones (Heavy Ion RBS), in order to improve the depth resolution for the profiling of the metal component. The antibacterial activity against Escherichia Coli is examined by antibacterial-drop test. The coatings exhibited a high antibacterial activity, which was enhanced with the increase of the metal concentration and was reduced with the increase of the particle size of the metal nanoparticles. The possible correlation between the layer interdiffusion after the thermal treatment and the antibacterial activity is examined and analyzed. Although further studies are required, RBS and HIRBS seem to be excellent tools for the quality control in the production of sol-gel thin coatings.

Keywords: RBS; HIRBS; Sol-Gel; Antibacterial; XRD; Thin coatings

  • Lecture (Conference)
    ECAART-7 Conference, 21st - 25th August 2001, Guildford, UK

Publ.-Id: 4333

Post Test Calculation with CFX-4 of the OECD/CSNI International Standard Problem Nr. 43

Höhne, T.

The need of the experimental support for validation of the computational tools to be applied to analyze the mixing of diluted slugs has been recognized in various countries. The test series for the International Standard Problem ISP-43 provides a platform for experiences to be applied to the simulation of a well-defined test series. Test A of the UM2x4 loop test facility was calculated with the CFD Code CFX-4.3. The results show qualitatively good agreement with the experimental data. The structure of the flow field and the form of the propagating temperature perturbation front are well modeled by the CFD code. However, deviations occur at local positions. Comparative calculations with and without taking into account buoyancy have shown, that buoyancy effects are noticeable, but the mixing is mainly momentum controlled.

Keywords: Boron Dilution; Pressurized Water Reactor

  • Lecture (Conference)
    ICONE 10-22722, Tenth International Conference on Nuclear Engineering Hyatt Regency Crystal City, Arlington, Virginia, USA, April 14-18, 2002, CD-ROM
  • Contribution to proceedings
    ICONE 10-22722, Tenth International Conference on Nuclear Engineering Hyatt Regency Crystal City, Arlington, Virginia, USA, April 14-18, 2002, CD-ROM

Publ.-Id: 4332

Die Mehrzweck-Thermohydraulikversuchsanlage TOPFLOW des Forschungszentrums Rossendorf e.V. - Aufbau, Ziele und Perspektiven

Schaffrath, A.; Krüssenberg, A.-K.; Weiß, F.-P.; Prasser, H.-M.

Am Institut fuer Sicherheitsforschung des Forschungszentrums Rossendorf e.V. wird die Mehrzweck-Thermohydraulikversuchsanlage TOPFLOW zur Untersuchung stationaerer und transienter Phaenomene in Zweiphasenstroemungen sowie zur Entwicklung und Validierung der in Computational Fluid-Dynamic Codes enthaltenen Modelle aufgebaut. Im Detail sind Experimente zu den Themen

  • transiente zweiphasige Stroemungen in vertikalen, horizontalen und beliebig geneigten Rohrleitungen sowie in reaktortypischen Geometrien,
  • Sieden in grossen Behaeltern und Wasserpools,
  • Erprobung passiver Komponenten und Sicherheitssysteme
  • Kondensation in horizontalen Rohren in Ab- und Anwesenheit von nichtkondensierbaren Gasen.
  • Atomwirtschaft-Atomtechnik 47 (2002), Nr. 6, S. 383-388

Publ.-Id: 4331

Synthesis of nano-sized SiC precipitates in Si by simultaneous dual beam implantation of C+ and Si+ ions

Kögler, R.; Eichhorn, F.; Kaschny, J.; Mücklich, A.; Reuther, H.; Skorupa, W.; Serre, C.; Perez-Rodriguez, A.

Nanometer-sized SiC precipitates were in-situ synthesized in Si by simultaneous implantation of two ion beams, of C+ and Si+ ions. The results of simultaneous dual beam implantation were compared with those of sequential dual beam ion implantation and of single beam C+ ion implantation. Remarkable differences were observed regarding the content and the crystal perfection of SiC precipitates as well as the defect structure of the Si substrate. The SiC precipitation during dual beam synthesis was found to depend on the ion energy of the second beam and on the implantation mode, simultaneous or sequential. For suitable implantation conditions the simultaneous dual beam synthesis can improve the in-situ SiC formation in comparison to the single beam synthesis. A higher density of the SiC precipitates with better crystal perfection was observed whereas their size was not changed. The second ion beam enables to shift the dynamic equilibrium of constructive and destructive processes for the SiC formation.
A model is proposed assuming that SiC precipitation preferentially proceeds in regions with vacancy defects. The implantation process itself creates vacancy-dominated and also interstitial-dominated regions. The balance of the local point defect composition is shifted under the second ion beam. In this way the conditions for SiC precipitation can be modified.

Keywords: Ion implantation; material synthesis; nanocluster; Si; SiC

  • Applied Physics A 76 (2003) 827-835

Publ.-Id: 4330

Structure and magnetic phase transformation in metastable Fe-Cr alloys induced by ion irradiation

Wieser, E.; Reuther, H.; Prokert, F.; Gorbunov, A.; Tselev, A.; Pompe, W.; Levin, A. A.; Meyer, D. C.; Paufler, P.

Unusual metastable paramagnetic phases have been observed in Fe-Cr thin films fabricated by pulsed laser deposition. In the present paper, X-ray diffraction and Mössbauer spectroscopy have been applied to follow the structural and magnetic phase transformation in these alloys induced by ion irradiation. The projected range of the chosen implantation energies of 40 keV for Cr and 25 keV for Ne lies in the center of the about 40 nm thick films. It has been found that the critical dose for the transformation to the more stable body-centered cubic (b.c.c.) structure depends on the initial phase of the film and the ion mass. The initial body-centered tetragonal phase which forms in the alloys with low Cr content (~30 at.%) can be completely transformed in the b.c.c. phase already by a dose of 5x1015 Cr/cm2 whereas the primitive orthorombic phase at roughly equiatomic Fe-Cr alloys is about 4 times more resistant against ion bombardment. One needs to apply a five times higher Ne-ion dose to induce the same transformation as by the Cr bombardment. The observed effects are discussed comparing the radiation damage caused by the different ions and the grade of affinity of the initial phase to the b.c.c. one.

Keywords: Fe-Cr alloys; ion irradiation; crystallographic phase transformation; magnetic phase transformation

  • Journal Applied Physics 92 (2002) 572-577

Publ.-Id: 4326

Structural investigation and wear resistance of submicron TiN coatings obtained by a hybride plasma immersion ion implantation process

Günzel, R.; Shevshenko, N.; Matz, W.; Mücklich, A.; Celis, J. P.

The ever increasing demands for high precision machining and increased cutting performance, in terms of cutting speed and lifetime, require wear resistant tools of large dimensional accuracy that have very sharp cutting edges. All these requirements can not be fulfilled by the classic PVD and CVD technologies because they result in rather thick overlay coatings.
In this report, first experiments are presented on a hybride plasma immersed ion implantation process (PIII) for depositing thin TiN coatings on hardened and annealed high speed steel or cemented carbides. The layers were produced using a dc-cathodic arc source with a titanium cathode and a nitrogen feed gas. As the cathodic arc generates additional to the metal plasma, a large amount of liquid metal droplets, the plasma was guided to the samples through a 900 magnetic bending field avoiding the deposition of droplets on the samples. The obtained layer thickness was below 1 µm for deposition times of 2 min.
To improve the adhesion of the deposited layers on the substrate materials, sputter cleaning by energetic ions was used during the initial phase of the process. Negative high voltage pulses in the range from zero to 5 kV have been applied to the samples during the deposition. The effect of the energy of these ions on the coating structure was also investigated by SEM, TEM and XRD. Mechanical and functional properties were investigated by hardness measurements and fretting wear tests respectively. Finally cutting performance tests of PIII-treated drills were performed, revealing that a 0.8µm thick TiN PIII-coating increased the lifetime of the drills by a factor of 2.5.

Keywords: cutting tools; coatings; ion implantation; PIII; TiN

  • Surf. Coat. Techn. 142-144 (2001) 978-983

Publ.-Id: 4323

Tiefenselektive Phasenanalyse der a-FeSi2-Bildung nach Beschuß von ß-FeSi2 mittels DCEMS, XPS und AES

Walterfang, M.; Keune, W.; Reiche, R.; Oswald, S.; Dobler, M.; Reuther, H.

Tiefenselektive Phasenanalyse der a-FeSi2-Bildung nach Beschuß von ß-FeSi2 mittels DCEMS, XPS und AES

  • Lecture (Conference)
    65. Physikertagung, Hamburg, 26.-30.3.2001

Publ.-Id: 4322

Improvement of Tribological Properties of Ti6Al4V by Nitrogen Plasma Immersion Ion Implantation

Ueda, M.; Silva, M. M.; Otani, C.; Reuther, H.; Yatsuzuka, M.; Lepienski, C. M.; Berni, L. A.

Improvement of Tribological Properties of Ti6Al4V by Nitrogen Plasma Immersion Ion Implantation

  • Lecture (Conference)
    International conference on Frontiers of Surface Engineering 2001, Nagoya, Japan, 28. October to 1. November 2001

Publ.-Id: 4321

Nitrogen Plasma Ion Implantation of Al5052 Alloy

Ueda, M.; Reuther, H.; Dias, F. G.; Rangel, E. C.; Cruz, N. C.

Nitrogen Plasma Ion Implantation of Al5052 Alloy

  • Lecture (Conference)
    International conference on Frontiers of Surface Engineering 2001, Nagoya, Japan, 28. October to 1. November 2001

Publ.-Id: 4319

Determination of the hyperfine parameters of iron silicides by angle dependent conversion electron Mössbauer spectroscopy on single crystals

Reuther, H.; Behr, G.

Iron silicides are of growing interest because of their interesting properties in reference to potential applications in thermoelectrics, photovoltaics and optoelectronics. For phase analysis by Mössbauer spectroscopy on bulk material or on thin layers, the knowledge of their hyperfine parameters is necessary.
In the present study, the Mössbauer spectra of single crystals of various silicides e-FeSi, ß-FeSi2 and a-FeSi2 are collected by conversion electron Mössbauer spectroscopy at room temperature. Measurements were performed at different angles between the propagation direction of the exciting g-radiation and the crystal axis of the single crystals.
The Mössbauer spectrum of the monosilicide consists of two lines while those of the disilicides consist of four lines. In the latter two cases, an unambiguous assignment of the lines to two quadrupole doublets could be performed. The hyperfine parameters including the signs of the quadrupole splittings are determined with high accuracy. Moreover, the direction of the main axis of the electric field gradient in regard to the crystal orientation was determined.
The results are compared with those obtained at powder or thin layer samples in the past. Differences and coincidences are discussed.

  • Lecture (Conference)
    International Conference on the Applications of the Mössbauer Effect, Oxford, England, 2.-7. Sept. 2001

Publ.-Id: 4314

Spin-density enhancement in the presurface zone of chromium

Dubiel, S. M.; Cieslak, J.; Zukrowski, J.; Reuther, H.

Spin-density enhancement in the presurface zone of chromium

  • Lecture (Conference)
    International Conference on the Applications of the Mössbauer Effect, Oxford, England, 2.-7. Sept. 2001

Publ.-Id: 4313

Depth analysis of buried iron disilicide formation by Fe ion implantation into Si

Walterfang, M.; Kruijer, S.; Keune, W.; Dobler, M.; Reuther, H.

Depth analysis of buried iron disilicide formation by Fe ion implantation into Si was performed by DCEMS.

  • Poster
    International Conference on the Applications of the Mössbauer Effect, Oxford, England, 2.-7. Sept. 2001

Publ.-Id: 4312

The effect of chlorite dissolution on the sorption behavior of U(VI)

Krawczyk-Bärsch, E.; Arnold, T.; Brandt, F.; Bosbach, D.; Bernhard, G.

In the Western Erzgebirge in Germany the abandoned uranium mines are mostly related to the rock phyllite. Currently, many of these mines are being flooded. The flood water is contaminated with uranium and penetrates the phyllite through cracks and fissures. The contact of the flood water with the rock leads to dissolution processes. One of the major components in this phyllite is an iron-rich chlorite. Chlorites are 2:1 sheet silicates, with an octahedral sheet sandwiched between two tetrahedral sheets. In contact with water chlorites tend to dissolve leading to a loss of octahedral layer cations, i.e. Al3+ with Mg2+, Fe2+ and Fe3+ substitutions. During the dissolution the chlorites are progressively degenerating to vermiculite and secondary iron minerals. In previous studies these secondary iron minerals have been determined as a poorly-crystalline iron oxide hydroxide, like ferrihydrite, which has a significant influence on the uranium migration behavior.
In flow-through experiments the kinetics of the U(VI) uptake on chlorite were studied to show the sorption behavior of U(VI) during the dissolution of chlorite within the phyllite of the abandoned uranium mines. These flow-through experiments were carried out under oxic conditions and at room temperature, using a NaClO4-solution with an ionic strength of 0.1 M and a pH of 7. An UO2(ClO4)2 solution was added to reach an initial U(VI) concentration of 1*10-6 M. The dissolution rates calculated for Al, Mg and Si are decreasing during the first hours of the experiment. Due to the precipitation of iron oxide hydroxides in a pH-range > 5 the released Fe cations have not been determined in the reacted solution. The dissolution rate of Fe is for this reason remaining low during the experiment. The formed secondary iron minerals are responsible for the remarkable high uptake of U(VI) on chlorite. In the first 24 h period of the experiment 72 % of the totally uranium was sorbed. In the following hours the relative amount of the sorbed uranium decreases, since most of available sorption sites of the chlorite and of the secondarily formed iron oxide hydroxides were already occupied. Additional sorption of U(VI) out of solution on the solid chlorite during the flow-through experiment is therefore decreasing. Conclusively, the chlorite within the phyllite is retarding under oxic conditions most of the U(VI) during the flooding, due to the dissolution of chlorite and the subsequent precipitation of iron oxide hydroxides.

  • Lecture (Conference)
    Uranium Mining and Hydrology UMH III, Freiberg 2002, 15.-21.9. Uranium in the Aquatic Environment, 425-430, Springer Verlag, 2002

Publ.-Id: 4311

Investigation of gypsum dissolution under saturated and unsaturated water conditions

Kuechler, R.; Noack, K.; Zorn, T.

Batch and column experiments were carried out to study the dissolution of gypsum by water under saturated and unsaturated conditions. The experimental results were verified by calculations. Comparing the dissolution in batch and column experiments, which were performed with a water flow velocity of 0.015 cm/h, one has to conclude that under unsaturated conditions only the
very small portion of 2.2 percent of the grain surface is chemically reactive. Experiments and calculation show that the gypsum release in the column is mainly determined by the flow velocity.

Keywords: Pollutant transport; Unsaturated soil; Gypsum dissolution; Transport modelling

  • Ecological Modelling 176(2004), 1-14

Publ.-Id: 4310

Infiltration water dating from tritium measurements in mining dumps: methodic specifics and case study

Mibus, J.; Szymczak, P.; Hebert, D.

Mine waste dumps and industrial tailings often emit toxic substances like sulfuric acid, heavy metals, or radionuclides over seepage discharge. An important parameter to characterize these transfer processes is the mean residence time tm of the infiltration water usually determined from tritium measurements. Conventional models assume a constant reservoir size (aquifer thickness) and to a great extent stationary hydraulics.
Emerging dumps, in contrast, exhibit a more or less continuously increasing thickness during deposition. The infiltration water is partly or even completely consumed to build up a static reservoir of adhesive water in the initial dry pores. The water percolation begins not until the field capacity is reached. This deceleration depends on deposit rates, recharge rates and cap-illary capacity and increases the portion of older components in the effluent waters compared to model assumptions.
In a case study a time series of effluent waters from a mining dump of Kupferschiefer mining in the south-eastern Harz-foreland was analyzed for ³H. The interpretation using the linear model revealed contradictions between residence time of infiltration waters and life span of the dump.
For the case of the linear model a proposal is made to modify the residence time distribution function. The

  • Poster
    Uranium Mining and Hydrogeology, Freiberg 2002, 15.-21.9.
  • Contribution to external collection
    Uranium Mining and Hydrogeology, Freiberg 2002, 15.-21.9.

Publ.-Id: 4308

From KD to Surface Complexation Models: Present State of Actinide Data Supply

Brendler, V.; Arnold, T.; Richter, A.; Bernhard, G.; Fanghänel, T.

Almost all risk assessment studies related to uranium mining and milling legacies rely on the wide-spread but simplistic KD concept of distribution coefficients, which subsumes all relevant physico-chemical phenomena into only one parameter. To overcome the resulting limitations, more realistic chemical speciation patterns are needed, including complex formation, heterogeneous phase equilibria and surface complexation. Following this strategy, the paper presents a digitized version of a thermodynamic sorption database as required for the parametrization of Surface Complexation Models (SCM). It is mineral-specific and hence also suitable for additive models of more complex solid phases such as rocks or soils. All major electrostatic variants of SCM are integrated. Also the concept of strong and weak binding sites, and the 1-pK approach is applicable. Surface species include ternary ones.
Data records comprise of mineral properties, specific surface areas, surface binding site concentrations and protolysis constants, sorption ligand information, and surface complexation reactions, all coupled to an extensive bibliography. Based on them, a detailed picture about the distribution of actinide SCM data amongst minerals, SCM subtypes and ligands is presented. Derived from that and focused on uranium, critical data gaps are identified, existing parameter sets are evaluated, and consistency tests are performed. Final goal is the establishment of recommended reference data sets.
Only few of the surface complexes proposed in the literature (mostly resulting just from best-fit considerations) are actually validated by spectroscopic evidence. If such information is available it is stored in the database and used for data evaluation.
Originally implemented as a stand-alone relational database under MS Access on a PC, the database RES³T (Rossendorf Expert System for Surface and Sorption Thermodynamics) is now connected to the WWW and accessible through common web browser interfaces.

  • Lecture (Conference)
    Uranium Mining and Hydrogeology III, Freiberg 2002, 15.-21.9.

Publ.-Id: 4307

Uranium speciation in plants

Günther, A.; Bernhard, G.; Geipel, G.; Rossberg, A.; Reich, T.

The chemical characterization of the radionuclide species is essential for a reliable assessment of the migration of radionuclides and heavy metals into the geological and biological environment on the load pathway soil - plant - animal - human. Only a few is known about the speciation of uranium in plants. Therefore we investigate the change of speciation during the transfer of uranium from initial solution into plant.
Various plants (lupins, dandelion e.g.) were grown in an agricultural test field and in the laboratory on contaminated soils (up to concentration of 1g U/kg soil) and as hydroponics in the uranium containing solutions (uranium concentration: 10-5 M - 10-2 M, pH: 3 - 8). For the study of the chemical speciation in the initial solution (pore water and hydroponic solution) and in plant samples we use the Time-Resolved Laser-Induced Fluorescence Spectroscopy, the X-Ray-Absorption Spectroscopy and the Scanning Electron Microscopy. Differences between the uranium speciation in the initial solutions and the speciation in the plant could be detected spectroscopically. The chemical speciation of the uranium seems to be identical in the roots, shoot axes and leaves. It is independent of the growing conditions (soil culture or hydroponic) and the type of the plant. Spectroscopic results show the formation of uranyl phosphato complexes as the main species in plants.

  • Lecture (Conference)
    Uranium Mining and Hydrogeologie UMH II, 15.9.-21.9.02, Freiberg Proceedings, Uranium in the Aquatic Environment, Springer Verlag 2002, p 513-520

Publ.-Id: 4306

Formation of secondary Fe-oxyhydroxide phases during the dissolution of chlorite effect on uranium sorption

Krawczyk-Bärsch, E.; Arnold, T.; Reuther, H.; Brandt, F.; Bosbach, D.; Bernhard, G.

The formation of Fe-colloids resulting from the chemical weathering of chlorite (Mg5.5Al2.48Fe2+3.02Fe3+0.94)(Si5.33Al2.66)O20 was studied in batch experiments. The chemistry of the detected colloids was determined by SEM/EDS measurements on separated agglomerated colloids fixed on filter membranes. The results show that the Fe-colloids exist as aqueous colloids as well as sorbed colloids forming iron coatings on the chlorite platelets. It was also observed that the newly-formed Fe-colloids are preferentially attached to the {hk0} edge surfaces and only to a minor extent as isolated Fe-colloids to the {001} basal plane surfaces. The average surface coverage of sorbed Fe-colloids on the {hk0} edge surfaces was found to be 0,276 žm2 of sorbed Fe-colloids per 1 žm2 of {hk0} chlorite surface, i.e. 27,6 % of the {hk0} surfaces is covered with adsorbed Fe-colloids. This value is significantly higher than the surface coverage found on the {001} basal plane surfaces. Here, the average surface coverage of Fe-colloids on the {001} basal plane surfaces was determined to be 0,030 žm2 of sorbed Fe-colloids per 1 žm2 of {001} chlorite surface, i.e. 3,0 % of the {001} surface area is covered with sorbed Fe-colloids. This shows that there are nine times more Fe-colloids adsorbed onto the edge surfaces than on the basal plane surfaces.
The detected colloids were, based on their chemistry, their spherical character and small particles sizes, identified as ferrihydrite. In addition, Mössbauer spectroscopy measurements were used to quantify the increase of ferric iron which formed during the batch experiment. This detected increase in ferric iron in the chlorite from 14.0 to 15.3 % š 1% was attributed to the formation of ferrihydrite.
The assumption that the edge surfaces of sheet silicates show a much higher affinity for adsorption reactions was so far not conclusively proven. However, the results of this study clearly show that colloid adsorption on the sheet silicate chlorite preferentially takes place on the {hk0} edge surfaces indicating that the edge surfaces of sheet silicates are by far more reactive in regard to sorption reactions than the distinctively less reactive {001} basal plane surfaces. In addition, the influence of Fe-phases as weathering products on sorption processes in nature is discussed.

Keywords: chlorite; colloids; ferrihydrite; chemical weathering; coating

  • Applied Geochemistry, 19(2004)9, 1403-1412, DOI:10.1016/j.apgeochem.2004.01.017

Publ.-Id: 4305

Der NOKO-Versuchsstand der Forschungszentrum Jülich (FZR) GmbH - Rückblick auf 7 Jahre experimentelle Untersuchungen zur Erhöhung der Sicherheit von Leichtwasserreaktoren

Hicken, E. F.; Schaffrath, A.; Fethke, M.; Jaegers, H.

Es ist ein Zeichen einer guten Sicherheitskultur, wenn Hersteller, Betreiber und Gutachter gleichermassen das Sicherheitsniveau von Kernkraftwerken stetig anheben wollen. Derzeit bietet sich die Gelegenheit, ueber fruehere, aktuelle und zukuenftige Konzepte nachzudenken. Ziel ist es, zukuenftige Anlagen zu optimieren, durch Systemvereinfachungen die Uebersichtlichkeit zu erhoehen und somit ihre Zuverlaessigkeit zu verbessern. Ferner sollen Effektivitaet und Wirtschaftlichkeit gesteigert werden. Hierzu wird seit Mitte der 90er Jahre an verschiedenen Stellen weltweit die Effektivitaet und das Betriebsverhalten passiver Sicherheitssysteme untersucht.
Im Beitrag wird auf die Geschichte des NOKO-Versuchsstandes zurueckgeblickt. Ferner werden ausgewaehlte Hoehpunkte der experimentellen Untersuchungen (u. a. der experimentelle Nachweis der thermohydraulischen Wirksamkeit des Notkondensators, des Gebaeudekondensators sowie des passiven Impulsgebers) beschrieben.

Keywords: NOKO-Versuchsstand; Notkondensator; Gebaeudekondensator; Passiver Impulsgeber

  • Atomwirtschaft-Atomtechnik 47 (2002), Nr. 5, S. 343-348

Publ.-Id: 4304

Sorption of Uranium(VI) onto Schwertmannite - EXAFS Investigations

Walter, M.; Arnold, T.; Funke, H.; Reich, T.; Bernhard, G.

The ferric oxide schwertmannite is commonly formed in acid mine drainage waters (pH-range from 2.8 to 4.5) in the presence of high sulfate concentrations. Because of its large specific surface area its may influence the migration of uranium(VI) by sorption processes. The aim of this study were structural informations for uranium(VI) surface complexes given by Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy. We include Goethite in our investigations as a reference to compare and interpret the schwertmannite data.

Samples for EXAFS analysis were prepared under N2 atmosphere using 200 mg of schwertmannite or goethite with initial uranium(VI) concentrations of 1x10-5 (pH 6.5) to 5x10-5 M (pH 4.2). The ionic strength was adjusted using 0.01 M Na2SO4 or NaClO4 respectively. EXAFS spectra were recorded at room temperature in fluorescence mode at the Rossendorf beamline (ROBL) at the ESRF in Grenoble. The measured EXAFS oscillations were fitted using EXAFSPAK procedure. The theoretical phase shifts and backscattering amplitudes were calculated with FEFF8.

All distances of the equatorial oxygens are about 2.37 Å. These are significantly shorter than typical values of 2.41 Å for the aquatic UO2 2+ ion, which indicates strong interactions. An iron backscatterer is clearly found for uranium(VI) sorbed onto goethite at pH 4.2 and 6.5 in sulfate-rich solution as well as for schwertmannite at pH 4.2 in perchloric solution. Such a uranium - iron distance indicates a bidentate inner sphere complexation. In contrast, the EXAFS of uranium(VI) sorbed onto schwertmannite at pH 4.2 in sulfate-rich solutions shows only a sulfur backscatterer at a distance of 3.66 Å, indicating the formation of a ternary surface complex.

  • Lecture (Conference)
    Uranium Mining and Hydrogeology UMH III, Freiberg , 15.9.-21.9. 2002, Proceedings: Uranium in the Aquatic Environment, 395-398, Springer Verlag, 2002
  • Contribution to external collection
    Uranium Mining and Hydrogeology UMH III, Freiberg , 15.9.-21.9. 2002, Proceedings: Uranium in the Aquatic Environment, 395-398, Springer Verlag, 2002

Publ.-Id: 4303

Atomic scale simulation of the stress relief in tetrahedral amorphous carbon

Belov, A.

Tetrahedral amorphous carbon (ta-C) is an amorphous form of carbon with a high content of sp3 bonded atoms, which can be deposited as thin films by energetic carbon ions or neutral atoms. As-grown ta-C films possess a high level of intrinsic compressive stresses (~10 GPa) inhibiting the use of this very promising material. The stress is due to a specific growth mechanism (subplantation), resulting from a competition between the densification of subsurface layers by incoming ions and the thermally activated diffusion of subplanted atoms to the surface. In agreement with experiment, we demonstrate using atomic scale simulation that low-temperature annealing can induce a considerable stress reduction in as-grown ta-C with minor
changes in its atomic structure and density. Simulating annealing by means of empirical molecular-dynamics with the interatomic Brenner potential for carbon and realistic boundary conditions, the dependence of the residual stress on the annealing temperature was investigated. It is found that a complete stress relief in ta-C is not accompanied by a change in the short-range order. The average atomic coordination remains nearly constant up to 1400 K. The stress relaxation mechanism discussed involves only structural optimization within the sp3 bonded constituent of ta-C and does not require clustering of sp2 bonded atoms.

Keywords: tetrahedral amorhous carbon; intrinsic stress; simulated annealing; molecular-dynamics

  • Poster
    E-MRS 2002 Spring Meeting, June 18-21, 2002, Strasbourg (France), Symposium A: Atomic Scale Materials Design

Publ.-Id: 4288

Complex Formation of Uranium(VI) with Glucose-1-Phosphate

Koban, A.; Geipel, G.; Bernhard, G.; Fanghänel, T.

The uptake of heavy metals into plants is commonly quantified by the soil-plant transfer factor. Up to now little is known about the chemical speciation of actinides in plants. To compare the obtained spectroscopic data of uranium complexes in plants with model compounds, we investigate the complexation of uranium with relevant bioligands of various functionalities. A very important class of ligands are phosphate esters, which serve as phosphate group and energy transmitters as well as energy storage mediums in biological systems.
Therefore, in our study we present the results of uranium complexation with glucose-1-phosphate (G1P) obtained by time-resolved laser-induced fluorescence spectroscopy (TRLFS) and potentiometric titration. The TRLFS-experiments were performed at a fixed uranyl concentration (10-5 M) as a function of the ligand concentrations (10-5 to 10-3 M) in a pH range from 2 to 4.5. The potentiometric titrations were performed at fixed uranyl (10-4 M) and ligand (10-3 M) concentrations in a pH range from 3 to 10.
The TRLFS-measurements show a decrease in the fluorescence intensities with increasing ligand concentrations, and no shift of the emission bands. The TRLFS spectra indicate the presence of only one species with fluorescence properties. This species has a lifetime of 1.50 µs and was identified as the free uranyl ion. Therefore we conclude that the complexed uranyl glucose phosphate species shows no fluorescence.
From quantitative evaluation of the TRLFS spectra we conclude, that 1:1 uranyl glucose phosphate species UO2(G1P) has formed. The complex formation constant was calculated to be log beta=5.60.
The results of the potentiometric titration show the same type of complex with a stability constant of log beta=5.37.

  • Poster
    Uranium Mining and Hydrogeology Conference Freiberg UMH III 15.09.-21.09.2002. Uranium in the Aquatic Environment (Proceedings of the UMH III), 537-540, Springer Verlag 2002.
  • Contribution to proceedings
    Uranium Mining and Hydrogeology Conference Freiberg UMH III 15.09.-21.09.2002. Uranium in the Aquatic Environment (Proceedings of the UMH III), 537-540, Springer Verlag 2002.

Publ.-Id: 4287

Atomistic study of ion beam deposition conditions for hard amorphous carbon

Belov, A.; Jäger, H.-U.

The influence of deposition conditions on the sp3 content, intrinsic stress, and elastic modulus in hard amorphous carbon (a-C) films was studied at the atomic scale. Simulation of ion beam deposition of carbon films was performed by the molecular-dynamics method with a modified analytical hydrocarbon potential of Brenner. Deposition of films with a thickness of up to 10 nm was computed for ion energies E = 10-80 eV, and for substrate temperatures ranging from 100 to 900 K. The dependence of the sp3 content and the intrinsic stress on substrate temperature was found to be in qualitative agreement with experiment. At low substrate temperatures and low ion energies, the sp3 fraction increases with ion energy, giving at E > 30 eV a highly sp3 bonded tetrahedral amorphous carbon (ta-C) with a high level of intrinsic compressive stress. This trend also remains at room emperature, however with lower values of sp3 content, whereas at T > 200 °C a transition to graphite-like a-C with dominating sp2 bonding was found.

Keywords: tetrahedral amorphous carbon; hard amorphous carbon fims; intrinsic stress; ion beam deposition; computer simulation; molecular-dynamics

  • Poster
    E-MRS 2002 Spring Meeting, June 18-21, 2002, Strasbourg (France), Symposium A: Atomic Scale Materials Design

Publ.-Id: 4286

A model of the thermochemical polishing of CVD diamond films on transition metals with emphasis on steel

Weima, J. A.; Fahrner, W. R.; von Borany, J.; Job, R.

A model of thermochemical polishing, namely the conversion of diamond into non-diamond carbon at elevated temperatures and the subsequent dissolution of the non-diamond carbon into a transition metal polishing plate is investigated. Equations of the conversion rate k1, the dissolution rate k2, the diffusion constant of carbon in steel D, and the concentration profile of carbon in steel N(x,t)are derived. The rate constants are calculated for four diamond films polished at varying temperatures. Elastic recoil detection analysis (ERDA) measured carbon depth profiles in steel agree well with theoretical calculations. However, the calculated value of D = 1,16 x 10-14 cm2/s is far below the value of D = 1,19 x 10-7 cm2/s for gamma-iron. The discrepancy between the two values is related to oxygen-enhanced segregation of carbon in the near surface region of steel and to the incorporation of elements which act as trap centers of carbon in steel.

  • Journal of the Electrochemical Society

Publ.-Id: 4285

Thermochromatographic oxidation studies of plutonium dioxide

Hübener, S.; Fanghänel, T.

The volatility of plutonium oxides in the O2-H2O(g)/SiO2(s) system has been studied by thermochromatography in the temperature range 1475 to 600 K. Oxides of uranium and neptunium have been studied for comparison. Oxide samples containing 1015 - 1016 actinide atoms were heated in the starting position of the thermochromatographic silica columns. Mixtures of helium, oxygen and water vapor were applied as reactive mobile gas phase. Resulting from thermochromatography the volatile actinide species are deposited in the column downstream, thus creating inner chromatograms along a temperature gradient. At the end of each experiment the actinide chromatograms were measured by alpha spectrometry.
Plutonium was found to be volatile in humid oxygen at temperatures above 1250 K. The Pu volatility is lower than that of uranium, but higher as one would expect for stable Pu(IV) which is nonvolatile under the applied experimental conditions. The Pu volatility is assigned to PuO2(OH)2(g). The experimental results give further evidence that water can oxidize plutonium dioxide.

Keywords: actinides; oxides; plutonium; oxidation state

  • Lecture (Conference)
    Rare Earth Research Conference, Davis, California, July 13-18, 2002, Abstracts

Publ.-Id: 4284

A novel technetium-99m radioligand for the 5-HT1A receptor derived from desmethyl-WAY-100635 (DWAY)

Heimbold, I.; Drews, A.; Syhre, R.; Kretzschmar, M.; Pietzsch, H.-J.; Johannsen, B.

This paper reports the synthesis, biological evaluation and in vitro autoradiography of a new technetium-99m radioligand with high affinity for the 5-HT1A receptor. The neutral complex combines an N2S2 diamine dithiol (DADT) ligand as complexing moiety for oxotechnetium(V) and a 2-(1-piperazino)phenol via a 6-carbon alkyl chain, derived from desmethyl-WAY-100635 (DWAY). The complex displays an IC50 value for the 5-HT1A receptor of 1.29 nM against the selective 5-HT1A agonist [3H]8-OH-DPAT, a moderate selectivity towards the alpha1-adrenergic receptor (IC50 of 8.1 nM against [3H]prazosin) and a good selectivity for the D2 receptor (IC50 of 192 nM against [3H]spiperone) and the 5-HT2A receptor (IC50 of 922 nM against [3H]ketanserin). Biodistribution studies in rats show an initial brain uptake of 0.65%±0.07% ID 2.5 min p.i. In vitro autoradiographic studies of the 99mTc complex in rat brains indicate a strong specific accumulation of the radioactivity in 5-HT1A receptor-rich brain regions.

Keywords: 5-HT1A receptor; technetium-99m; 99mTc receptor ligand; DWAY analogue; radioligand

  • European Journal of Nuclear Medicine 29 (2002) 82-87

Publ.-Id: 4283

Separation of Uranium from Aqueous Solution by Textile Bound Calixarenes

Schmeide, K.; Geipel, G.; Keil, D.; Jansen, K.; Praschak, D.; Heise, K.-H.; Bernhard, G.

The remediation of former uranium mining and milling sites of Saxony and Thuringia requires the purification of uranium contaminated seepage and mine waters. The separation of uranium(VI) from aqueous solution by calixarenes by means of solvent extraction is described in the literature (e.g., [1,2]). Calixarenes are macrocyclic molecules formed by 4, 6 or 8 parasubstituted phenolic units linked by methylene bridges ortho to the OH functions. Thus, molecules of various ring sizes are formed. The substitution of calix[6]arenes on the hydroxyl group by carboxylic and hydroxamic groups, respectively, leads to ligands that are able to bind uranium(VI) selectively.
The present work represents an innovative method for the separation of uranium(VI) from aqueous solution using uranophile calix[6]arenes that are fixed on textile substrates such as polyester fabric. For this, the calix[6]arenes are statistically functionalized by spacer groups (n-alkyl groups) that enable their fixation onto polyester fabric.
The complex formation of the textile bound calixarenes, e.g., carboxymethoxy-p-mono-nonyl-penta-tert-butyl-calix[6]arene, and their selectivity towards uranium(VI) ions is studied as a function of pH value, ionic strength and competing ions by means of batch experiments. Time-resolved laser-induced fluorescence spectroscopy (TRLFS) is used to determine complex formation constants. The reaction mechanisms are discussed. As competing ions, Na+, Ca2+, Mg2+ and Fe3+ as well as SO4 2- are studied, that occur typically in mine waters. Furthermore, the reversibility of the uranium binding is evaluated. The results are compared with those obtained for the corresponding non-fixed calixarenes [3].
The new technique for the remediation of uranium contaminated waters is also applicable for lower contamination levels ([UO2 2+] < 1x10-6 M) and is especially suitable for smaller remediation objects. The applicability of this separation principle to further actinides is expected.

[1] Shinkai, S., Koreishi, H., Ueda, K., Arimura, T., Manabe, O.: Molecular Design of Calixarene-Based Uranophiles which Exhibit Remarkably High Stability and Selectivity. J. Am. Chem. Soc. 109, 6371 (1987).
[2] Nagasaki, T., Shinkai, S.: Synthesis and Solvent Extraction Studies of Novel Calixarene-based Uranophiles Bearing Hydroxamic Groups. J. Chem. Soc., Perkin Trans. 2 (7), 1063 (1991).
[3] Schmeide, K., Barz, B., Heise, K.H., Bernhard, G., Gloe, K.: Solvent Extraction of Uranium(VI) by Calix[6]arene. In: FZR-318, Annual Report 2000 (Th. Fanghänel, ed.). Forschungszentrum Rossendorf, Institute of Radiochemistry, Rossendorf 2001, p. 17.

Keywords: Uranium; calixaren; textile bound calixaren; extraction; remediation; complex formation; TRLFS

  • Lecture (Conference)
    International Conference Uranium Mining and Hydrogeology III and the International Mine Water Association Symposium, Freiberg, 15.-21.09.2002

Publ.-Id: 4282

Entwicklung und Relaxation mechanischer Spannungen in Bornitrid-Schichten

Fitz, C.

  • Open Access Logo Wissenschaftlich-Technische Berichte / Forschungszentrum Rossendorf; FZR-337 Januar 2002
    ISSN: 1437-322X


Publ.-Id: 4281

Colloid-borne Uranium in Mine Waters

Zänker, H.; Richter, W.; Hüttig, G.; Moll, H.

There is ample evidence from groundwaters, river waters, lakes or seawater that colloids influence the transport behavior of contaminants such as As, Pb, Cu, Zn, actinides, fission products, hydrophobic organics etc. Little efforts have been made to elucidate the role of colloids in mine waters. We studied mine waters of very different nature for their colloid-chemistry.
Very stable Fe(III) oxyhydroxy sulfate colloids were found in acid rock drainage (oxic acidic pore waters, pH < 3). The particle size was < 5 nm, the colloid concentration reached the g/l range. Mineralogically, the particles were a mixture of hydronium jarosite and schwertmannite. As and Pb showed a high tendency to adsorb onto these particles. Quite a different type of colloids was found in the oxic "bulk waters" of mines as for instance in tunnel waters (near-neutral pH). The particles were composed of oxyhydroxides of Fe(III) and Al, the particle size was 100 to 300 nm, the particle concentration was about 1 mg/l, the colloids were unstable, i.e. they tended to aggregate. Important colloid-borne contaminants were As, Cu, Zn, Pb, Po. Uranium(VI) adsorption is normally supressed due to the formation of uranyl carbonato complexes in such "bulk waters". The flooding of mines can be regarded as the dilution of acidic pore waters to form "bulk waters". Huge amounts of iron(III) particles with a size of 100 to 300 nm are formed under such conditions. The adsorption of trace elements rises drastically when the pH reaches the near-neutral region. Uranyl adsorption to the iron(III) particles is neither supressed by acidity nor by uranyl carbonate complexation in the pH region 4 to 6. Therefore most of the uranium(VI) is colloid-borne in waters of the transition type; scavenging, colloid aggregation and sedimentation can result in the immobilization of uranium in such waters ("natural attenuation").

Keywords: Uranium; colloids; oxyhydroxides; oxyhydroxy sulfates; iron; aluminum

  • Lecture (Conference)
    International Conference on Uranium Mining and Hydrology (UMH III). Freiberg, 15.09.-21.09.2002

Publ.-Id: 4280

Scavenging and immobilization of trace contaminants by colloids in the waters of abandoned ore mines

Zänker, H.; Richter, W.; Hüttig, G.

Inorganic colloids in mine waters are able to influence trace heavy metal transport. In oxic waters they mainly result from the formation of oxyhydroxides and oxyhydroxy sulfates of Fe(III) and Al due to the oxidation of Fe2+ and the hydrolysis of Fe3+ and Al3+. However, the colloid inventories and the colloid properties depend on the mine wa-ter type. Acidic pore waters (pH < 3) contain large amounts (g/l range) of relatively stable ultrafine (< 5 nm) iron(III) oxyhydroxy sulfate particles which most probably consist of a mixture of hydronium jaro-site (HFe3(SO4)2(OH)6) and schwertmannite (Fe8O8(OH)6SO4). Arse-nic and lead tend to be adsorbed onto these colloids. Waters of higher pH (pH > 4) contain smaller amounts (mg/l range) of Fe- and Al-rich colloids of 100 to 300 nm that are unstable. They carry elements such as As, Pb, Zn, Cu, Po, Th, Ac. These trace heavy metals can be scavenged by the colloids and can be immobilized due to colloid coagulation and sedimentation ("natural attenuation"). In the pH range from 4 to 6 (flooding waters) also U(VI) is adsorbed onto the colloidal particles since their adsorption is neither prevented by high acidity nor by the formation of uranyl carbonato complexes. Also U(VI) can be scavenged and immobilized in this pH range. However, in "bulk wa-ters" of pH > 6 such as tunnel waters the adsorption of U(VI) to the colloids is normally prevented by carbonate complexation

Keywords: Colloids; mine waters; iron; aluminum; uranium

  • European Materials Research Society (E-MRS) 2002 Spring Meeting, Symposium C: Colloid 2002. Strasbourg (France), June 18 - 21, 2002.
  • Colloids and Surfaces A: Physicochemical and Engineering Aspects 217 (2003) 21-31

Publ.-Id: 4279

Analyses of the OECD Main Steam Line Break Benchmark with the Codes DYN3D and ATHLET

Grundmann, U.; Kliem, S.

The OECD Main Steam Line Break (MSLB) Benchmark was defined to validate the thermal-hydraulic system codes coupled with three-dimensional neutron kinetic codes. The reference problem is a MSLB in a pressurized water reactor (PWR) at end of cycle (EOC). The analyses were performed with the three-dimensional core model DYN3D, the thermal-hydraulic system code ATHLET and the coupled code DYN3D/ATHLET. The results of the DYN3D and ATHLET simulations based on the specification are compared with the results of other participants in the final OECD reports. The effect of the thermal-hydraulic nodalisation of the core, i.e. the number of coolant channels, and the influence of the coolant mixing inside the pressure vessel are studied in the paper. Calculations with a reduced number of coolant channels are performed often in coupled calculations for saving
computational time. Results of a 25-channel model were compared with the 177-channel calculation (1 channel/assembly). The results for global parameters like nuclear power show only small differences for the two models, however the prediction of local parameters such as maximum fuel temperatures requires a detailed thermal-hydraulic modeling. The effect of different coolant mixing within the reactor pressure vessel is investigated. It is shown that the influence of coolant mixing mitigates the accident
consequences when three-dimensional neutron kinetics is applied. In case of point kinetics, coolant mixing leads to an opposite effect. To profit from the three-dimensional core model, a realistic description of the coolant mixing in the coupled codes is a topic of further investigations.

Keywords: coupled neutron kinetics/thermal-hydraulics codes; main steam line break analyses; coolant mixing

  • Nuclear Technology 142(2003) 146-153

Publ.-Id: 4278

Balakovo-3 Ex-vessel Exercise: Analysis of Calculation Results Intercomparison and Comparison with Reference Data

Borodkin, G.; Böhmer, B.; Konheiser, J.; Manturov, G.; Polke, E.; Brodkin, E.; Jegorov, A.; Zaritsky, S.

Ex-vessel neutron dosimetry at NPP with VVER was used for validation of 3D absolute neutron fluence calculations. As second step of the VVER-1000 Balakovo-3 Ex-vessel Exercise, an analysis of calculational results has been performed. The reference experimental data - End-Of-Irradiation activities AEOI - were used as criteria of validation. The purpose of the research was to perform an intercomparison of independent calculational results and comparison with reference data of the full-scale VVER-1000 ex-vessel experiment. New and improved results of calculations analysed in the paper were run with codes and applied libraries DORT/BUGLE-96, DORT/EURLIB-6, DORT/ABBN-93 (and ABBN-93 modifications), TRAMO/ENDF/B-VI, MCNP/ENDF/B-VI. Calculated pure 3D or 3D synthesis multigroup neutron fluence rates in positions of experimental capsules provided by every calculator were used as basic calculational information. As first step of their comparative analysis a study was done of the used calculation input data prepared on the base of the same reactor information. For example, a difference of neutron source model details may be a reason of some discrepancy of results obtained by similar calculational procedures. Aspects of the influence of different dosimetry cross sections and local power history on the calculation of AEOI from calculated spectra were investigated. The analysed dosimetry cross section libraries were IRDF-90v2, JENDL-D99, RRDF-98 and ENDF/B-VI based BUGLE-96 responses. Final C/E values were based on AEOI. The C/E values for threshold dosimetry reactions 237Np(n,f), 93Nb(n,n'), 238U(n,f), 58Ni(n,p), 54Fe(n,p), 46Ti(n,p) and 63Cu(n,a), which are widely used in reactor pressure vessel dosimetry for fast neutron fluence evaluation, showed on the whole the expected agreement (better 20 %). It was found that the C/E data for the Balakovo-3 exercise in application to the 237Np(n,f) and 93Nb(n,n') reactions may be improved in case of using JENDL-D99 library. Another new aspect of the Balakovo-3 research is an analysis and intercomparison of calculational and experimental results for (n,g) dosimetry reactions. Different type (n,g) detectors were irradiated in cadmium. The obtained reaction rates characterize the distribution of epithermal neutrons. A comparison of the reaction rates, for example, for reactions 93Nb(n,g), 69Co(n,g) and 103Ag(n,g) in case of DORT/BUGLE-96 calculations has shown a coincidence of experiment and calculation data within ± 11 %. For one ex-vessel position where bare (n,g) detectors were irradiated thermal neutron parameters were evaluated and compared.

  • Lecture (Conference)
    11th International Symposium on Reactor Dosimetry, August 18-23, 2002 in Brussels, Belgium, Proceedings by World Scientific Publ., ISBN 981-238-448-0, p. 665-673
  • Contribution to proceedings
    11th International Symposium on Reactor Dosimetry, August 18-23, 2002 in Brussels, Belgium, Proceedings by World Scientific Publ., ISBN 981-238-448-0, p. 665-673

Publ.-Id: 4277

Complexation of uranium (VI) by three eco-types of Acidithiobacillus ferrooxidans studied using time-resolved laser-induced fluorescence spectroscopy and infrared spectroscopy

Merroun, M.; Geipel, G.; Nicolai, R.; Heise, K.-H.; Selenska-Pobell, S.

Time-resolved laser-induced fluorescence spectroscopy (TRLFS) was used to study the properties of uranium complexes (emission spectra and fluorescence lifetimes) formed by the cells of the three recently described eco-types of Acidithiobacillus ferrooxidans. The results demonstrated that these complexes have different lifetimes which increase in the same order as the capability of the strains to accumulate uranium. The complexes built by the cells of the eco-type II were the strongest, whereas, those of the eco-types I and III were significantly weaker. The emission spectra of all A. ferrooxidans complexes were almost identical to those of the uranyl organic phosphate compounds. The latter funding was confirmed by infrared spectroscopic analysis.

Keywords: TRLFS; IRS; uranium; Acidithiobacillus ferrooxidans eco-types

  • Biometals 16, 331-339 (2003)

Publ.-Id: 4275

Column experiments with heap material of Kupferschiefer mining and thermodynamic interpretation

Mibus, J.

Material of a mine waste dump of Kupferschiefer mining was investigated in column and equilibrium experiments in closed vessels over 64 days and 90 days, respectively. The de-ployed solids are composed of silicate phases, calcite, dolomite, gypsum, and a few percent of residual sulfides, already indicating a depletion of the karstifyable material and in particular a dedolomitization. The development of the solution composition at the columns outflow is characterized by a steady increase of alkalinity with a striking transient maximum, succeed-ing draw back and equilibration. In connection with an increasing mole fraction of magnesium in solution this phenomenon is interpreted as consequence of dedolomitization and depicted in abinary solubility diagram according to Lippmann (1980). In calcium rich pore waters (due to gypsum dissolution) dolomite dissolves incongruently precipitating calcite. Such compli-cated reaction paths are usually not identified by "crude" batch experiments. Moreover it could be shown that the formation of preferred flow paths may even affect the solution com-position in particular cases. In these experiments an estimation of transport parameters was not yet carried out, but is planned for the future to apply reactive transport codes for model-ing these processes.

  • FZKA scientific report 6721, 55-60
  • Poster
    Workshop on Modelling of Coupled Transport Reaction Processes TrePro 2002, 20.-21.03.2002, Karlsruhe, Deutschland

Publ.-Id: 4274

ANISN-DORT-ROZ-MCNP-TRAMO Neutron-Gamma Flux Intercomparison Exercise for a Simple Testing Model

Böhmer, B.; Borodkin, G.; Brodkin, E.; Egorov, A.; Konheiser, J.; Kozhevnikov, S.; Manturov, G.; Voloschenko, A.; Zaritsky, S.

The ability of transport codes ANISN, DORT, ROZ-6, MCNP and TRAMO, as well as nuclear data libraries BUGLE-96, ABBN-93, VITAMIN-B6 and ENDF/B-6 to deliver consistent gamma and neutron flux results was tested in calculation of an one-dimensional cylindrical model consisting of a homogeneous core and an outer zone with a single material. Model variants with H2O, Fe, Cr and Ni in the outer zones were investigated. The results are compared with MCNP-ENDF/B-6 results. Discrepancies are discussed. The specified test model is proposed as a computational benchmark for testing calculation codes and data libraries.

Keywords: Coupled neutron-gamma transport calculations; neutron data libraries; Monte Carlo Codes; discrete ordinate codes; calculational benchmark

  • Poster
    11th International Symposium on Reactor Dosimetry, 18 -23 August 2002 in Brussels, Belgium, Proceedings by World Scientific Publ., ISBN 981-238-448-0, p. 572-579
  • Lecture (Conference)
    13th Seminar on Algorithms and Codes for Neutronics Calculations of Nuclear Reactors, 26-29 October 2002, Obninsk, Rußland
  • Contribution to proceedings
    11th International Symposium on Reactor Dosimetry, 18 -23 August 2002 in Brussels, Belgium, Proceedings by World Scientific Publ., ISBN 981-238-448-0, p. 572-579

Publ.-Id: 4273

Neutron and Gamma Fluence and Radiation Damage Parameters of Ex-core Components of Russian and German Light Water Reactors

Böhmer, B.; Borodkin, G.; Konheiser, J.; Noack, K.; Polke, E.; Rogov, A.; Vladimirov, P.

Radiation embrittlement of pressure vessel steel in mixed neutron-gamma fields is mostly determined by neutrons, but in some cases also by gamma-radiation. Depending on the reactor type, gamma radiation can influence evaluations of lead factors of surveillance specimens, effect the interpretation of results of irradiation experiments and finally, it can result in changed pressure vessel lifetime evaluations. This work aims to facilitate for some reactor types the evaluation of the importance of gamma radiation for embrittlement studies. Absolute neutron and gamma fluence spectra had been calculated for two core loading variants of the Russian PWR type VVER-1000, for a German PWR of Konvoi-Type and for a German BWR. Based on the calculated spectra several fluence integrals and radiation damage parameters were derived for the region of the midplane azimuthal flux maximum for different radial positions between the core and the biological shield, particularly, the inner and outer PV walls, the ¼ PV thickness and the surveillance positions. The relative contributions of gamma radiation to the sums of gamma and neutron contributions are of special interest. As damage parameters the displacements per atom of iron are given separately for neutrons and gammas as well as some rough estimations of the numbers of freely migrating defects. To get some notion about the uncertainty of the obtained dpa, the calculations were performed using different dpa cross section evaluations. Additionally, gamma produced dpa were calculated by means of the Monte Carlo code EGS.
Another parameter of practical interest for pressure vessel dosimetry, the contribution of photofission to the total number fissions, was calculated for the detector reactions 237Np(n,f) and 238U(n,f).
Most of the calculations were performed using a 3D synthesis of 2D/1D-flux distributions obtained by the DORT code with the BUGLE-96 library. To increase the reliability of the evaluations some of the calculations were repeated by different laboratories. For two reactors the influence of the group approximation on the calculation results was investigated by parallel calculations with the continuous energy Monte Carlo code MCNP using nuclear data from the library ENDF/B-VI.
The results were compared and the reasons of found discrepancies were discussed.

  • Lecture (Conference)
    11th International Symposium on Reactor Dosimetry, 18 -23 August 2002 in Brussels, Belgium, Proceedings by World Scientific Publ., ISBN 981-238-448-0, p. 286-294
  • Contribution to proceedings
    11th International Symposium on Reactor Dosimetry, 18 -23 August 2002 in Brussels, Belgium, Proceedings by World Scientific Publ., ISBN 981-238-448-0, p. 286-294

Publ.-Id: 4272

TOPFLOW - A new multipurpose thermalhydraulic test facility for the investigation of steady state and transient two phase flow phenomena

Schaffrath, A.; Weiß, F.-P.

The Forschungszentrum Rossendorf (FZR) e.V. is building a new large-scale test facility for thermal hydraulic single effect tests, named TOPFLOW. The acronym stands for Transient Two Phase Flow Test Facility. It will mainly be used for the investigation of generic and applied steady state and transient two phase flow phenomena in power- and process industries. Main research activities are the investigation of:

· transient flow regimes in horizontal, vertical and inclined tubes,
· the dynamic behaviour of interphase areas in gas-liquid flows,
· critical mass flows and oscillations during depressurization of chemical reactors,
· natural convection in large pools with local heating,
· natural convection in parallel channels and feed pipes and
· condensation phenomena (e.g. in emergency and isolation condensers, WWER steam generators).
It is FZR strategy to use TOPFLOW as a central experimental basis for the nuclear competence centre, rejoining FZR, the Technical University of Dresden (TUD) and the University of Applied Sciences Zittau-Görlitz (HTW) and to offer it to working groups throughout Europe. They will be invited to come to Rossendorf with their ideas and to perform their experiments here making use of the parameters (power, water and steam mass flow, pressure range, measuring instrumentation) and the multipurpose character of the test facility.

Keywords: TOPFLOW; two-phase flow; test facility

  • Lecture (Conference)
    NUSIM 2002 (11. Meeting of Nuclear Specialists from Slovakia, Czech and Germany), 13.-15.03.2002, Dresden

Publ.-Id: 4270

A small and compact AMS facility for tritium depth profiling

Friedrich, M.; Pilz, W.; Glugla, M.; Bekris, N.; Kiisk, M.; Liechtenstein, V.

Depth profiling measurements of tritium at carbon samples have been performed during the past seven years at the AMS facility installed at the Rossendorf 3 MV tandetron. The samples have been cut from the inner wall of the fusion experiments ASDEX-upgrade/Garching and JET/Culham. The increasing amounts of tritium inside the samples from JET have been required a dedicated AMS facility to prevent any contamination of the versatile 3 MV tandetron. On base of an air-insulated 100 kV tandem accelerator equipped with a gas stripper a small dedicated AMS facility for tritium depth profiling was installed, tested and used for routinely measurements. After successful tests of diamond-like carbon (DLC) stripper foils at this accelerator a small and compact SF6-insulated 100 kV tandem accelerator with a DLC-stripper has been installed at the AMS facility. Results measured with the different tandem accelerators are presented.

Keywords: Tritium; Fusion; Mass Spectrometry; Electrostatic Accelerators

  • Contribution to proceedings
    PRAMANA-journal of physics, Vol. 59, No. 6 (2002) 1053. Proccedings of the 9th International Conference on Heavy Ion Accelerator Technology, New Delhi, India, January 14-18, 2002.

Publ.-Id: 4269

Kinetische Modellierung von PET-Studien des Neurokinin1-Rezeptors im menschlichen Hirn

Hinz, R.

(kein Abstrakt)

  • Lecture (others)
    Universität Leipzig Klinik und Poliklinik für Nuklearmedizin Institut für Interdisziplinäre Isotopenforschung 20. Dezember 2001

Publ.-Id: 4268

Kinetic Modelling of Neurokinin-1 Receptor Studies in Human Brain

Hinz, R.

(no abstract available)

  • Lecture (others)
    PET Methodology Seminar, Imaging Research Solutions Limited, London, UK 14 December 2001

Publ.-Id: 4267

Kinetic Modelling of NK1 Receptor Studies in Human Brain

Hinz, R.

(no abstract available)

  • Lecture (others)
    National Institutes of Health, Positron Emission Tomography Department Bethesda, Maryland, USA, November 2, 2001

Publ.-Id: 4266

Gamma and Neutron Spectra Investigations in Iron-Water Benchmark Configurations for the Verification of Monte Carlo Calculations in Reactor Material Dosimetry

Böhmer, B.; Grantz, M.; Hansen, W.; Hinke, D.; Konheiser, J.; Mehner, H.-C.; Noack, K.; Schneider, R.; Stephan, I.; Unholzer, S.

In order to validate Monte Carlo calculations for coupled neutron/gamma problems in reactor dosimetry an experimental benchmark programme at two low power reactors was started to measure both, neutron and gamma flux spectra behind and inside of transmission modules consisting of variable iron and water slabs. The comparison of the first series of experiments with MCNP calculations is presented.

Keywords: reactor dosimetry; neutron spectrometry; gamma spectrometry; reactor pressure vessel; steel embrittlemen; coupled neutron; gamma fluence calculations; benchmark

  • Lecture (Conference)
    Jahrestagung Kerntechnik 2002, Stuttgart, 14.-16. Mai 2002, Proceedings pp. 511-514
  • Contribution to proceedings
    Jahrestagung Kerntechnik 2002, Stuttgart, 14.-16. Mai 2002, Proceedings pp. 511-514

Publ.-Id: 4265

Detection and Characterization of ultrafine Fe-As-Pb colloids in acid rock drainage solution from an ore mine

Zänker, H.; Moll, H.; Richter, W.; Brendler, V.; Hennig, C.; Reich, T.; Kluge, A.; Hüttig, G.

The processes of sulfide oxidation, water acidification and water mineralization in abandoned ore mines is closely associated with the existence of gangue fissures in the host rock that contain clay minerals and finely-divided sulfide ores. These fis-sures release highly mineralized, red-colored acid rock drainage (ARD) solutions which can easily be collected from pools in front of the fissures. ARD solution from an abandoned Zn-Pb-Ag mine at Freiberg, Germany, (pH 2.7, sulfate concentration 411 mmol/l, Fe concentration 93,5 mmol/l) was investigated by photon correlation spec-troscopy, centrifugation, filtration, ultrafiltration, scanning electron microscopy, ICP-MS, AAS, ion chromatography, TOC analysis, and X-ray absorption fine structure (EXAFS) spectroscopy. The question was if this ARD solution contains colloidal par-ticles of the lower nanometer range or if it is particle-free after the common filtration through a 450-nm filter. We found that the solution contains a small amount (about 20 mg/l) of submicron particles of about 100 nm in size. However, the major colloidal component was shown to be a population of ultrafine particles of less than 5 nm. The concentration of these particles is about 1 g/l. They consist of Fe, As and Pb com-pounds. According to EXAFS spectroscopy, the most probable mineralogical compo-sition of these particles is a mixture of hydronium jarosite (HFe3(SO4)2(OH)6) and schwertmannite (ideally Fe8O8(OH)6SO4). We also observed the formation of a rela-tively coarse precipitate of a similar mineralogy in the colloidal solution over a time span of months. The ultrafine colloids are obviously an intermediate in the formation process of the long-term precipitate. The arsenic is probably bound onto the ultrafine colloidal particles as a bidentate binuclear arsenate surface complex (inner-sphere complex). However, the transformation of the colloids to the more aggregated long-term precipitate leads to the incorporation of the arsenic into the interior of the iron hydroxy sulfate structures. The mechanism of this incorporation could be the substi-tution of arsenate for sulfate in the jarosite structure and/or the formation of very small scorodite clusters as occlusions within the oxyhydroxysulfate structures. The lead might occur as anglesite (PbSO4).

Keywords: colloids; ultrafiltration; EXAFS; acid rock drainage; jarosite; schwertmannite; arsenate

  • Lecture (Conference)
    XXVII General Assembly of the European Geophysical Society. Nice, France, 21 - 26 April 2002

Publ.-Id: 4260

Synthesis and structural characterization of two cis-dioxorhenium(V) ReO2[SN][P] mixed-ligand complexes

Bouziotis, P.; Papagiannopoulou, D.; Pirmettis, I.; Pelecanou, M.; Raptopoulou, C. P.; Stassinopoulou, C. I.; Terzis, A.; Friebe, M.; Spies, H.; Papadopoulos, M.; Chiotellis, E.

Two novel five-coordinate cis-dioxorhenium(V) complexes of the general formula ReO2[R2NCH2CH2S][PPh3] (R2N=Et2N, complex 1 and R2N=(o-CH3O-C6H4N(CH2CH2)2N, complex 2) have been synthesized by reacting ReOCl3(PPh3)2 with the respective bidentate ligands R2NCH2CH2SH. The complexes have been characterized by elemental analysis, IR, NMR spectroscopies and X-ray crystallography. X-ray crystallographic studies showed that the coordination geometry around rhenium is distorted trigonal bipyramidal. the basal plane is defined by the two doubly bonded oxygen atoms and the sulfur of the bidentate ligand, while the nitrogen of the ligand and the phosphorus occupy the apical positions.

Keywords: Crystal structures; Rhenium complexes; Dioxo complexes

  • Inorganica Chimica Acta 320 (2001) 174-177

Publ.-Id: 4259

Simulation of two surge line break experiments at the PMK-2 Test Facility using the code ATHLET

Schäfer, F.; Krepper, E.; Prasser, H.-M.; Szabados, L.; Ezsöl, G.

Results of two surge line break experiments, which were conducted at the PMK-2 test facility, are presented. The thermo-hydraulic computer code ATHLET, which was developed by GRS (Gesellschaft für Anlagen- und Reaktorsicherheit) mbH, was used for post-test calculations. The experiments simulate a break of the pressurizer surge line in the hot leg of a VVER-440-type reactor with different injection modes from the ECC systems. The main phenomena of the experiments are discussed and in case of selected events a more detailed interpretation with help of the measured void fraction, obtained with a special measurement device, is given. The results of the experiments and the ATHLET calculations are compared. In both experiments natural circulation instabilities could be observed. The physical mechanisms of the instabilities are discussed and it could be shown, that ATHLET can calculate the instabilities in good agreement with the experimental data.

Keywords: Thermo-hydraulics; Simulations; Instabilities; ATHLET

  • Lecture (Conference)
    Annual Meeting on Nuclear Technology, May 14-16, 2002, Stuttgart, Germany
  • Contribution to proceedings
    Annual Meeting on Nuclear Technology, May 14-16, 2002, Stuttgart, Germany

Publ.-Id: 4258

Experimental analysis of crossflow in the reactor core geometry.

Kliem, M.

A new method for the thermal-hydraulic calculations in the reactor core using a porous media approach is presented in this paper.
The Core Crossflow Experimental Facility (CCEF) was built for the validation of this method.
The comparison of the calculations using this method with the experimental data from CCEF are also presented.

Keywords: reactor core; crossflow; CCEF

  • Lecture (Conference)
    Annual Meeting on Nuclear Technology 2002, Stuttgart, Germany, May 14-16, 2002 Proceedings pp. 55-58
  • Contribution to proceedings
    Annual Meeting on Nuclear Technology 2002, Stuttgart, Germany, May 14-16, 2002 Proceedings pp. 55-58

Publ.-Id: 4257

High-spin structure of the spherical nucleus 90Y

Rainovski, G.; Schwengner, R.; Schilling, K. D.; Wagner, A.; Jungclaus, A.; Galindo, E.; Thelen, O.; Napoli, D. R.; Ur, C.; de Angelis, G.; Axiotis, M.; Gadea, A.; Marginean, N.; Martinez, T.; Kröll, T.

High-spin states in 90Y were populated in the 82Se(11B,3n)
reaction at a beam energy of 37 MeV. Gamma rays were detected with the spectrometer GASP. The level scheme of 90Y was extended up to J^\pi = (18^+) at 9.6 MeV. Mean lifetimes of four levels were determined using the Doppler-shift-attenuation method. The structure of 90Y was
interpreted in terms of the shell model. The calculations were performed in the model space \pi(0f_{5/2},1p_{3/2},1p_{1/2},0g_{9/2})
\nu(1p_{1/2},0g_{9/2},1d_{5/2}) and in an extended space including the \nu(0g_{7/2})$ orbital as well. The calculations in the extended model space reveal a correspondence between states in ^{90}Y and ^{89}Y. Moreover, a combination of the predicted states with J^\pi \geq 14^(+) can be found
that reproduces the large B(M1) values of up to about 1 W.u.

Keywords: Nuclear structure; In-beam gamma-ray spectroscopy; Shell model

  • Physical Review C, Vol. 65, 044327

Publ.-Id: 4256

Synthetic Humic Acids A Useful Tool to Study the Interaction of Humic Acids with Actinides in the Environment

Sachs, S.; Schmeide, K.; Heise, K.-H.; Bernhard, G.

The present work gives a detailed overview about our motivation for the synthesis of humic acid model substances. Exemplary for one synthetic humic acid (type M42), which is synthesized from xylose, glutamic acid and water [1], the synthesis, 14C-labeling ([14C]M42) and modification (M42-PB) of humic acids are described. We will discuss the characterization of these synthetic humic acids in comparison to natural humic acids from the literature as well as to natural humic acid Kranichsee [2]. This humic acid was isolated from surface water of the mountain bog "Kleiner Kranichsee" (Johanngeorgenstadt, Western Saxony, Germany) applying standard isolation techniques for humic acids.
The application of synthetic humic acid model substances will be presented with two examples. First, we will demonstrate the use of humic acid type M42 and humic acid type M42 with blocked phenolic and other blocked acidic OH groups (M42-PB) as model substances for the investigation of the neptunium(V) complexation by humic acids.
Secondly, we will discuss the application of 14C-labeled synthetic humic acid type M42 in batch and column experiments. The intend of these investigations is to improve the knowledge about the influence of humic acids on the mobilization or immobilization of actinides under natural conditions.
In addition to humic acid-like melanoidins, we synthesize humic acid model substances with distinct redox functionalities. Applying these model substances, detailed investigations with regard to the redox behavior of humic acids as well as to the redox stability of actinide humate complexes can be performed. In the present work we will give an brief overview about the synthesis, characterization and application of humic acids with pronounced redox functionalities.

[1] S. Pompe (Sachs), M. Bubner, K. Schmeide, K.H. Heise, G. Bernhard, H. Nitsche, 'Influence of Humic Acids on the Migration Behavior of Radioactive and Non-radioactive Substances under Conditions Close to Nature. Synthesis, Radiometric Determination of Functional Groups, Complexation', Report FZR-290, Rossendorf, 2000.
[2] K. Schmeide, H. Zänker, K.H. Heise, H. Nitsche, in Report FZKA 6124, G. Buckau (ed.), Karlsruhe, 1998, p. 161.

Keywords: Humic Acid; Synthesis; Modification; Labeling; Characterization; Complexation; Actinides; Neptunium; Migration

  • Lecture (Conference)
    20th Anniversary Conference of the International Humic Substances Society, July 21-26, 2002, Northeastern University Boston, Massachusetts, USA

Publ.-Id: 4255

Studies on interactions of actinides with organic ligands using femtosecond-laser-induced spectroscopy

Geipel, G.; Bernhard, G.; Fanghänel, T.

Polyelectrolytic organic macromolecules, like humic substances, are important complexing agents towards actinide metal ions. Due to these properties humic substances are possible carriers for the migration of actinides in the environment. The study of the high molecular compounds is very complex. Therefore the investigation of simple model ligands would give a more detailed description of the binding behavior of humic substances. Especially the different bonding of carboxylic and phenolic group and the discrimination between them is of interest to get more detailed information about the complex formation. The various hydroxy benzoic acids allow the investigation of these differences.
To study the complex formation of actinides with such organic ligands we used the new, recently developed tool of femtosecond laser-induced time-resolved fluorescence spectroscopy. The method uses the fluorescence properties of organic ligands with p-electron systems and their change by interaction with metal ions to study the complex formation of these systems.
The method was validated by study of the deprotonation of 2,3 dihydroxybenzoic acid. Within the error limits a very good agreement of the third protonation constant was found.
The studies of the complex formation of uranium(VI) with 2,3 dihydroxybenzoic acid in the pH range from 3.0 to 4.5 showed an one to one complex. The dependence of the complex formation on pH leads to the conclusion that besides the carboxylic group one of the two phenolic OH-groups contributes to the complex formation. The formation constant was determined to be log K(I=0.1M) = - 3.02 ± 0.09.
Studies of the complex formation in the system neptunium(V)-2,3 dihydroxybenzoic acid showed a completely different behavior. At low pH values also an one to one complex formation was found. This complex formation was not dependent on pH. That means complexes with the deprotonated carboxylic group were formed.
The formation constant was determined to be log K(I=0.1M) = 0.11 ± 0.04. With increasing pH the complex reaction changes. An intermediate complex can be observed by its own fluorescence properties. At pH values higher then six an one to two complex will be formed. The complex formation constants and the stoichiometry of the complex reaction will presented.

  • Lecture (Conference)
    14th Radiochemical Conference, Marianzke Lazne, 14-19. April 2002

Publ.-Id: 4254

Inner-sphere, outer-sphere and ternary surface complexes: a TRLFS study of the sorption process of Eu(III) onto smectite and kaolinite

Stumpf, T.; Bauer, A.; Coppin, F.; Fanghänel, T.; Kim, I.

Summary. The surface sorption process of Eu(III) onto smectite and kaolinite was investigated by time-resolved laser fluorescence spectroscopy (TRLFS) in the trace concentration range. The experiments were performed in 0.025 M and 0.45 M NaClO4. The sorption process of Eu(III) onto smectite was obtained by TRLFS under atmospheric conditions and in absence of CO2. The pH was varied between 3.5 and 9 at a fixed metal ion concentration of 3.3x10-6 mol/L Eu(III). At low pH (< 4) the metal ion keeps its complete hydration sphere indicating outer-sphere complexation. With increasing pH the formation of an inner-sphere Eu(III) surface complex was observed. The differences in the spectra and the fluorescence emission lifetimes of the surface sorbed Eu(III) in presence and absence of carbonate indicate the formation of ternary clay/Eu(III)/carbonate complexes. The different europium/clay surface complexes were characterized by their fluorescence emission spectra (5D0®7F1/5D0®7F2 intensity ratio) and their fluorescence emission lifetime.

  • Radiochimica Acta

Publ.-Id: 4253

Analyse der Schädigung eines Druckbehälters in Simulationsexperimenten von nuklearen Kernschmelzunfällen

Böhmert, J.; Müller, G.; Willschütz, H.-G.; Sehgal, B. R.

Das Verhalten eines Reaktordruckbehälters bei Kernschmelzunfällen ist von hoher sicherheitstechnischer Bedeutung für die Beherrschung derartiger Störfälle. An der Königlich-Technischen Hochschule Stockholm werden in einem umfangreichen Programm (FOREVER - Failure Of REactor VEssel Retention) die Verformung und das Versagenverhalten des Druckbehälters unter der thermischen Belastung einer oxidischen Schmelze untersucht. Die Experimente werden begleitet durch Finite-Element-Modell-Vorausrechnungen und durch metallografische Nachuntersuchungen. Die Gefügeänderungen geben Hinweise auf die aufgetretenen Maximaltemperaturen und Temperaturgradienten, auf die Wechselwirkungen mit der Schmelze und der umgebenden Atmosphäre sowie auf den Versagensmechanismus. Am Beispiel eines FOREVER-Experimentes werden die Ergebnisse der Nachtestuntersuchungen mit den FE-Modellrechnungen verglichen. Die metallografischen Befunde bestätigen die FEM-Vorausrechnungen.

  • Lecture (Conference)
    DGM-Tagung Werkstoffprüfung 2001, Bad Nauheim, 6. - 7. 12. 2001

Publ.-Id: 4252

Separation Control On A NACA 0015 Hydrofoil Using Lorentz Forces

Weier, T.; Gerbeth, G.; Mutschke, G.; Lielausis, O.; Lammers, G.

The use of electromagnetic forces to control the flow of electrically
conducting fluids is mostly associated with highly conducting liquids
like liquid metals and semiconductor melts. Only recently,
Electro-magnetic Flow Control for fluids of low electrical
conductivity like seawater has gained increasing interest. Most of the
published experimental and numerical work in this emerging field is
dedicated to skin friction reduction in turbulent boundary layers.

The present paper is focused on utilizing the accelerating effect of a
streamwise Lorentz force to prevent flow separation at the suction
side of a NACA 0015 hydrofoil. While the basic effects of
separation suppression and circulation enhancement have been
shown in [1], we will concentrate on the comparison of the
experimental results with such of separation control by steady
blowing. For this purpose, the Lorentz force strength will be given in
terms of an electromagnetic momentum coefficient C_EMHD, describing
the ratio of the total electromagnetic force imposed on the flow to
the product of dynamic pressure and wing area. Force measurements in
the Reynolds number range 2.9 10E4 < Re < 3.7 10E5, obtained with 3
different hydrofoils will be used to give a first approximation of the
maximum lift gain in dependence upon Reynolds number and Lorentz
force. Again, the electromagnetic momentum coefficient seems to be an
acceptable correlation factor to describe the control effect of the
Lorentz force in different flow configurations.

  • Lecture (Conference)
    12th European Drag Reduction Meeting, 18-20 April 2002, Herning, Denmark

Publ.-Id: 4251

Die kolloidalen Bestandteile von Lettenwasser (Acid Rock Drainage) aus der Himmelfahrt Fundgrube in Freiberg/Sa.

Zänker, H.; Moll, H.; Richter, W.; Brendler, V.; Hennig, C.; Reich, T.; Kluge, A.; Hüttig, G.

Es wurde gezeigt, daß das Lettenwasser eine kleine Menge (ca. 20 mg/l) an Submicronpartiklen von etwa 100 nm Größe enthält. Die kolloidale Hauptkomponente sind jedoch ultrafeine Partikel einer Größe von weniger als 5 nm. Sie weisen eine Konzentration von ca. 1 g/l auf. Diese Partikel bestehen wahrscheinlich aus einem Gemisch von H-Jarosit und Schwertmannit und sind ein Zwischenprodukt bei der Ausscheidung gröberkristalliner Präzipitate. Außerdem tragen sie Arsen und Blei. Das As ist offensichtlich als Arsenat-Oberflächenkomplex an die ultrafeinen Partikel gebunden. Bei der Ausscheidung von gröberkristallinen Fe-Oxyhydroxisulfatpräzipitaten scheint dann auch Arsenateinbau in das Innere der Oxyhydroxisulfatstrukturen eine Rolle zu spielen.

Keywords: Acid Rock Drainage; Kolloide; Eisenoxyhydroxysulfate; Arsenat

  • Lecture (Conference)
    Jahrestagung der Wasserchemischen Gesellschaft, Eichstätt/Altmühltal, 6.-8. Mai 2002

Publ.-Id: 4245

Acceptance and count rate estimates for experiments on subthreshold Phi meson production in central collisions of C + C at 2 AGeV

Kotte, R.; Kämpfer, B.

Monte-Carlo estimates of the subthreshold Phi meson production are performed for the reaction 12C + 12C at 2 AGeV assuming the Phi's to be emitted isotropically and distributed thermally in the center-of-mass system of the colliding nuclei. Different scenarios involving the detector installations FOPI and HADES at SIS/GSI are considered to determine the expected yields of Phi(1020) mesons identified via the K+K- and e+e- decay channels.

Keywords: PACS. 25.75.-q; 25.75.Dw

  • Open Access Logo Wissenschaftlich-Technische Berichte / Forschungszentrum Rossendorf; FZR-339 Januar 2002
    ISSN: 1437-322X


Publ.-Id: 4244

phi puzzle in heavy-ion collisions at 2 AGeV: how many K^- from phi decays?

Kämpfer, B.; Kotte, R.; Hartnack, C.; Aichelin, J.

The preliminary experimental data on phi production in the reaction Ni(1.93 AGeV) + Ni point to a puzzling high phi yield which can not be reproduced with present transport codes. We survey the experimental situation and present prospects for dedicated measurements of the phi multiplicities with the $K^+ K^-$ and $e^+ e^-$ channels at HADES and FOPI.

Keywords: Haevy-ion collisions; kaon production; phi mesons

  • J.Phys.G28:2035-2040,2002 arXiv: nucl-th/0112040

Publ.-Id: 4243

Ion Induced Formation of Regular Nanostructures on Amorphous GaSb Surfaces

Facsko, S.; Bobek, T.; Kurz, H.; Dekorsy, T.; Kyrsta, R.; Cremer, R.

Crystalline and amorphous GaSb surfaces are compared concerning their response
to sputter erosion with low-energy Ar$^+$-ions under normal incidence. We show
that the formation of regular nanostructures on GaSb is basically independent
on whether the initial material is crystalline or amorphous. The similarity in
the temporal and spatial evolution demonstrates that the dynamics of the
morphology evolution is entirely controlled by a thin amorphous
nonstoichiometric surface layer.

Keywords: self organization; ion induced surface modification; quantum dots; nanotechnology

  • Applied Physics Letters 80 (2002) 130-132

Publ.-Id: 4242

Two crossovers in the pseudogap regime of YBa$_2$Cu$_3$O$_{7-x}$ superconductors observed by ultrafast spectroscopy

Misochko, O. V.; Georgiev, N.; Dekorsy, T.; Helm, M.

We have investigated the temperature dependence of the optical reflectivity on
a femtosecond scale in a near-optimally doped YBa$_2$Cu$_3$O$_{7-x}$
superconductor. The combined study of the lattice and carrier dynamics at
temperatures above T$_c$ allows us to identify two crossover temperatures in
the normal state giving evidence for an inhomogeneity of the pseudogap regime.
These crossovers exhibit a clear hysteresis behavior depending on the direction
of temperature change. The carrier and lattice dynamics within the crossover
regimes show distinct differences from and similarities to the superconducting
state, which may help in choosing between the competing theories for the
pseudogap state.

Keywords: HTSC; coherent phonons; pseudogap; femtosecond spectroscopy

  • Physical Review Letters 89 (2002) 067002-067005

Publ.-Id: 4241

Prophylaxis of restenosis with 186Re-labeled stents in a rabbit model

Tepe, G.; Dinkelborg, L. M.; Brehme, U.; Muschick, P.; Noll, B.; Dietrich, T.; Greschniok, A.; Baumbach, A.; Claussen, C. D.; Duda, S. H.


Intraluminal beta-irradiation has been shown to decrease neointimal proliferation after angioplasty in experimental models. The purpose of this study was to test the technical feasibility and biological effects of 186Re-labeled stents.

Methods and results:

Thirty-four New Zealand White rabbits were fed a 0.5% cholesterol diet before balloon angioplasty and insertion of Palmaz stents in the infrarenal aorta. The animals were killed 7 weeks after stent implantation. Two of 34 animals died prematurely (aortic leak, pneumonia). Control stents (n=7) were compared with 186Re stents (2.6 MBq [n=6], 8.1 MBq [n=5], 16 MBq [n=6], and 25.3 MBq [n=8]). Stent application was successful in all cases. No thrombus occlusion was observed. After 7 weeks, neointima formation was 2.2±0.2 mm2 in the control group. In the treatment groups, a dose-dependent neointima reduction was detectable (0.5±0.5 mm2 [2.6 MBq], 0.4±0.4 mm2 [8.1 MBq], and 0 mm2 [16.0 MBq, 25.3 MBq]). No induction of neointimal formation was observed at the edges of the stents. Radiation resulted in delayed reendothelialization.


186Re stents were capable of reducing neointima formation in a dose-dependent fashion. 186Re stents did not cause late thrombosis or neointimal induction at the stent margins in the observation period of 7 weeks.

Keywords: atherosclerosis; angioplasty; hypertension; restenosis; radioisotopes; stents

  • Circulation 104 (2001) 480-485

Publ.-Id: 4240

Magnetic and collective rotation in 79Br

Schwengner, R.; Dönau, F.; Servene, T.; Schnare, H.; Reif, J.; Winter, G.; Käubler, L.; Prade, H.; Skoda, S.; Eberth, J.; Thomas, H. G.; Becker, F.; Fiedler, B.; Freund, S.; Kasemann, S.; Steinhardt, T.; Thelen, O.; Härtlein, T.; Ender, C.; Köck, F.; Reiter, P.; Schwalm, D.

Excited states of the nucleus 79Br were investigated via the reaction
76Ge(7Li,4n) at 35 MeV. Coincidence data of emitted gamma rays
were measured with an arrangement of six EUROBALL CLUSTER detectors.
The E2 bands built on the 9/2+ and 3/2- states were extended up to
J = 37/2 at E \approx 8.8 MeV. The M1 band starting with a 15/2-
state at 2.6 MeV was extended to J = (29/2) at E = 6.4 MeV. Cross-over
E2 transitions within this band were observed for the first time. Mean
lifetimes of 17 levels were deduced using the Doppler-shift-attenuation method.
The M1 band can be described within theTilted-Axis-Cranking model on the
basis of the tilted three-quasiparticle configuration
pi(g9/2) nu (g9/2) nu (fp) which has a triaxial shape. This band
appears as a mixed case including contributions of both, magnetic and
collective rotation.

Keywords: Nuclear spectroscopy; Cluster detectors; Magnetic and collective rotation; Tilted-axis cranking model

  • Physical Review C, Vol. 65, 044326

Publ.-Id: 4239

On parabolic potential profile in ion sheaths

Mukherjee, S.

Parabolic potential profiles are commonly used in ion sheaths as it simplifies the mathematical formulation and is observed in limited experimental observations, where measurement uncertainties justify it. However, before using the parabolic potential profile assumption in all cases, there are other factors that needs to be concerned. The article highlights these factors for collisionless and collisional ion sheaths.

Keywords: parabolic potential profile; ion sheath; ion matrix

  • PHYS SCRIPTA 66 (2): 165-167 AUG 2002

Publ.-Id: 4238

Fluid-Structure Interaction Experiments at the Cold Water Hammer Test Facility (CWHTF) of the FZ-Rossendorf

Altstadt, E.; Carl, H.; Weiß, R.

In existing NPPs water hammers can occur in case of an inflow of sub-cooled water into pipes or other parts of the equipment, which are filled with steam or steam-water mixture. They also may appear as the consequence of valve closing or opening actions or of breaks in pipelines, with single phase or two-phase flow. The influence of the fluid-structure interaction on the magnitude of the loads on pipe walls and support structures is not yet completely understood. The lack of experimental data obtained at well defined geometric boundary conditions is a significant obstacle for the validation of codes which consider fluid-structure interaction. Furthermore, up to now the feedback from structural deformations to the fluid mechanics is not fully implemented in existing calculation software codes. Therefore, at FZR a cold water hammer test facility (CWHTF) was designed and built up.

Keywords: fluid-structure interaction; waterhammer

  • Lecture (Conference)
    Jahrestagung Kerntechnik 2002, Stuttgart, Tagungsband S. 59-64, May 14-16, 2002
  • Contribution to proceedings
    Jahrestagung Kerntechnik 2002, Stuttgart, Tagungsband S. 59-64, May 14-16, 2002

Publ.-Id: 4237

The influence of the N=50 neutron-core on dipole excitations in 87Rb

Käubler, L.; Schilling, K. D.; Schwengner, R.; Dönau, F.; Grosse, E.; Belic, D.; von Brentano, P.; Bubner, M.; Fransen, C.; Grinberg, M.; Kneissl, U.; Kohstall, C.; Linnemann, A.; Matschinsky, P.; Nord, A.; Pietralla, N.; Pitz, H. H.; Scheck, M.; Stedile, F.; Werner, V.

Dipole excitations in the semimagic N=50 nucleus ^{87}Rb were investigated at the Stuttgart Dynamitron
facility using bremsstrahlung with an endpoint energy of 4.0 MeV. The widths Gamma or the reduced excitation probabilities B(Pi 1)uparrow of 19 states were determined for the first time. The magnetic dipole excitations
are well reproduced in the framework of the shell model, however, these calculations cannot describe the observed electric dipole excitations.The 1/2^+ state at 3060 keV is proposedto be the weak coupling of an f_{5/2} proton hole to the 3^- octupole vibrational state in the N=50 core ^{88}Sr. The relatively strong E1 transition from that state to the ground state is explained as mainly the neutron h_{11/2} \rightarrow g_{9/2} transition. The breakup of the N=50 core and neutron excitations into the h_{11/2} shell are essential to describe electric dipole excitations, but neutron-core excitations do not play an important role for the structure of magnetic dipole excitations.

  • Physical Review C, Vol. 65, 054315

Publ.-Id: 4233

Analysis and insights about FE-Calculations of the EC-Forever-Experiments

Willschütz, H.-G.; Altstadt, E.; Weiß, F.-P.; Sehgal, B. R.

To get an improved understanding and knowledge of the melt pool convection and the vessel creep and possible failure processes and modes occurring during the late phase of a core melt down accident the FOREVER-experiments are currently underway at the Division of Nuclear Power Safety of the Royal Institute of Technology Stockholm. These experiments are simulating the behaviour of the lower head of the RPV under the thermal loads of a convecting melt pool with decay heating, and under the pressure loads that the vessel experiences in a depressurization scenario.
Due to the multi axial creep deformation of the vessel with a non-uniform temperature field these experiments are on the one hand an excellent source of data to validate numerical creep models which are developed on the basis of uniaxial creep tests. On the other hand the results of pre-test calculations can be used to optimize the experimental procedure and can help to make on-site decisions during the experiment.
Therefore a Finite Element model is developed based on a multi-purpose code. After post-test calculations for the FOREVER-C2 experiment, pre-test calculations for the forthcoming experiments are performed. Additionally metallographic post test investigations of the experiments are conducted to improve the numerical damage model and to adjust the correlation between the metallographic observations and the calculated damage. Taking into account both - experimental and numerical results - gives a good opportunity to improve the simulation and understanding of real accident scenarios.
After analysing the calculations, it seems to be advantageous to introduce a vessel support which can unburden the vessel from a part of the mechanical load and, therefore, avoid the vessel failure or at least prolong the time to failure. This can be a possible accident mitigation strategy. Additionally, it is possible to install an absolutely passive automatic control device to initiate the flooding of the reactor pit to ensure external vessel cooling in the event of a core melt down.

Keywords: Scaled Core Melt Down Experiments; FEM Calculations; Advanced Creep Modelling; Metallographic Investigations; Vessel Support as Accident Mitigation Measure

  • Lecture (Conference)
    10th International Conference on Nuclear Engineering, Arlington, VA, USA, April 14-18, 2002, Proceedings on CD-ROM, Paper No. 22262
  • Contribution to proceedings
    10th International Conference on Nuclear Engineering, Arlington, VA, USA, April 14-18, 2002, Proceedings on CD-ROM, Paper No. 22262

Publ.-Id: 4232

Scaled vessel failure experiment analysis and investigation of a possible vessel support

Willschütz, H.-G.; Altstadt, E.; Weiß, F.-P.; Sehgal, B. R.

Scaled coupled melt pool convection and vessel creep failure experiments are being performed in the FOREVER program at the Royal Institute of Technology, Stockholm. These experiments are simulating the lower head of a pressurized reactor vessel under the thermal load of a melt pool with internal heat sources [1]. Due to the multi axial creep deformation of the three-dimensional vessel with a highly non-uniform temperature field these experiments offer an excellent opportunity to validate numerical creep models. A Finite Element model is developed and using the Computational Fluid Dynamic module, the melt pool convection is simulated and the temperature field within the vessel wall is evaluated. The transient structural mechanical calculations are then performed applying a new creep modeling procedure. Additionally, the material damage is evaluated considering the creep deformation as well as the prompt plasticity [2, 3].
Pre- and post-test calculations of at least 4 FOREVER experiments have been performed successfully [4]. Taking into account both - experimental and numerical results - gives a good opportunity to improve the simulation and understanding of real accident scenarios.
After analyzing the calculations, it seems to be advantageous to introduce a vessel support which can unburden the vessel from a part of the mechanical load and, therefore, avoid the vessel failure or at least prolong the time to failure. This can be a possible accident mitigation strategy. Additionally, it is possible to install an absolutely passive automatic control device to initiate the flooding of the reactor pit to ensure external vessel cooling in the event of a core melt down.

Keywords: LWR scaled vessel failure experiments; FE-simulation; vessel support as accident mitigation strategy

  • Lecture (Conference)
    Jahrestagung Kerntechnik 2002, Stuttgart, May 14-16, 2002, Tagungsband S. 173-178
  • Contribution to proceedings
    Jahrestagung Kerntechnik 2002, Stuttgart, May 14-16, 2002, Tagungsband S. 173-178

Publ.-Id: 4231

First measurement of beta-decay properties of the proton drip-line nucleus 60Ga

Mazzocchi, C.; Janas, Z.; Döring, J.; Axiotis, M.; Batist, L.; Borcea, R.; Cano-Ott, D.; Caurier, E.; de Angelis, G.; Farnea, E.; Fassbender, A.; Gadea, A.; Grawe, H.; Jungclaus, A.; Kapica, M.; Kirchner, R.; Kurcewicz, J.; Lenzi, S.; Mart'Inez, T.; Mukha, I.; N'Acher, E.; Napoli, D. R.; Roeckl, E.; Rubio, B.; Schwengner, R.; Tain, J. L.; Ur, C. A.

By using the fusion-evaporation reaction 28Si(36Ar,p3n) and spectroscopy of beta-delayed gamma rays and charged particles on mass-separated sources, beta-decay properties of the neutron-deficient isotope 60Ga were studied for the first time. The half-life of 60Ga was determined to be 70(15) ms, and, based on gamma-gamma coincidences, the isobaric-analogue state in 60Zn was identified at 4851.9(7) keV. A semiempirical proton separation energy value of 40(70) keV was deduced for 60Ga. The experimental results on half-life, mass excess, proton separation energy, and structure of the 60Zn daughter states are discussed in comparison with various model predictions, including large scale shell model calculations.

Keywords: Properties of nuclei; nuclear energy levels; Beta decay; 21. Shell model

  • European Physical Journal A 12, 269-277 (2001)

Publ.-Id: 4230

Vacancy-type defects in 6H-SiC caused by N+ and Al+ high fluence co-implantation

Anwand, W.; Brauer, G.; Skorupa, W.

6H-SiC n-type wafers were implanted with Al+ and N+ ions in two steps: first N+ double implantation (65 keV, 5x1016 cm-2 , 120 keV, 1.3x1017 cm-2 ) followed by Al+ double implantation (100 keV, 5x1016 cm-2 and 160 keV, 1.3x1017 cm-2 ). The implantation was carried out at a substrate temperature of 800 0C in order to avoid amorphisation. In this way a buried SiC1-x(AlN)x layer could be created. Variable-energy positron Doppler broadening measurements were performed at room temperature using a magnetic transport beam system in order to characterize the vacancy-type defects created by ion implantation. Depth profiles could be evaluated from the measured Doppler broadening profiles. The defect distribution and the defect size after the complete co-implantation are discussed and the contribution of the different implantation steps to the evolution of this defect structure is shown.

Keywords: 6H-SiC; N+ and Al+ co-implantation; vacancy-type defects; slow positron spectroscopy

  • Applied Surface Science 194 (2002) 131-135
  • Poster
    9th International Workshop on Slow Positron Beam Techniques for Solids and Surfaces, Dresden, Germany, September 16-22, 2001

Publ.-Id: 4229

The influence of substrate temperature on the evolution of ion implantation induced defects in epitaxial 6H-SiC

Anwand, W.; Brauer, G.; Wirth, H.; Skorupa, W.; Coleman, P. G.

An epitaxial n-type 6H-SiC layer has been fourfold implanted with Al+ ions at temperatures ranging from room temperature to 1200 oC in order to create a buried p-doped layer from 200 nm to 600 nm below the surface. The defects induced by the ion implantation at different temperatures have been investigated by Slow Positron Implantation Spectroscopy. Higher substrate temperatures were found to lead to a significant reduction in the depth of the damage. However, this is accompanied by the formation of vacancy clusters of sizes up to seven Si-C divacancies. Only at 1200 ºC does the vacancy agglomeration disappear in the implanted region, and larger agglomerates are formed immediately below the surface. Furnace annealing at 1650 ºC was found to be insufficient to remove all damage.

Keywords: epitaxial 6H-SiC; Al implantation; vacancy-type defects; slow positron spectroscopy

  • Applied Surface Science 194 (2002) 127-130
  • Poster
    9th International Workshop on Slow Positron Beam Techniques for Solids and Surfaces, Dresden, Germany, September 16-22, 2001

Publ.-Id: 4228

Investigation of ion implantation induced damage in the carbon and silicon sublattices of 6H-SiC

Zolnai, Z.; Khánh, N. Q.; Szilágyi, E.; Kótai, E.; Ster, A.; Posselt, M.; Lohner, T.; Gyulai, J.

Single crystal 6H-SiC samples were irradiated at room temperature with 200 keV Al+ ions at fluences ranging from 3.5x1013 to 2.8x1014 ion/cm2. Depth profiles of crystal defects both in the C and Si sublattices were measured by Backscattering Spectrometry combined with channeling technique (BS/C) at 3550 keV 4He+ ion beam energy along the <0001> axial channeling direction. Damage in the carbon sublattice was found to be higher than in the silicon one. Moreover, C/Si damage ratio decreased with increasing fluence. The crystal defect profiles can be well simulated both by full-cascade SRIM and Crystal-TRIM programs. Effective displacement energies for carbon and silicon sublattices in the applied fluence range of Al implantation were determined by comparing SRIM simulations to BS/C results.

Keywords: Silicon carbide; Ion implantation; Backscattering Spectrometry; Defects

  • Lecture (Conference)
    12th European Conf. on Diamond, Diamond-Like Materials, Carbon Nanotubes, Nitrides and Silicon Carbide, September 2-7, 2001, Budapest, Hungary
  • Diamond and Related Materials 11 (2002) 1239-1242

Publ.-Id: 4227

Einfluss von Wasserstoff auf die Zähigkeit von Reaktordruckbehälterstählen

Uhlemann, M.; Böhmert, J.; Müller, G.

Niedriglegierte ferritische Stähle gelten ebenso wie die hochlegierten austentischen Stähle als anfällig gegen Wasserstoffversprödung. Im Kernreaktor können Korrosion oder Radiolyse zur Bildung von atomaren Wasserstoff an der inneren Oberfläche des Reaktordruckbehälters und folglich zur Wasserstoffaufnahme während des Reaktorbetriebes führen. Der Beitrag stellt Ergebnisse zum Wasserstoffdiffusionsverhalten, zur Wasserstofflöslichkeit und zum Einfluss des Wasserstoffs auf die mechanischen Eigenschaften vor. Sie wurden an unbestrahlten Druckbehälterstählen unterschiedlicher Art gewonnen und beziehen sich auf solche Bedingungen, die denen im DWR nahe kommen.

  • Lecture (Conference)
    Jahrestagung Kerntechnik 2002, Tagungsbericht, 14.-16.05.2002, Stuttgart, S. 609
  • Contribution to proceedings
    Jahrestagung Kerntechnik 2002, Tagungsbericht, 14.-16.05.2002, Stuttgart, S. 609

Publ.-Id: 4226

ROCOM experiments on the influence of density differences on the coolant mixing inside the reactor pressure vessel of a PWR

Kliem, S.; Prasser, H.-M.; Grunwald, G.; Rohde, U.; Höhne, T.; Weiß, F.-P.

During emergency core cooling (ECC) injection into the cold leg of a PWR an incomplete mixing of the injected water with the natural circulation flow in the loop takes place. Due to the higher density of the ECC water a streak of cold water is flowing downwards the downcomer. This causes thermal loads on the reactor pressure vessel wall. Furthermore, the core behaviour is determined by the resulting parameter distributions at the core inlet.
An experimental study was carried out at the ROCOM test facility, a fluid dynamic model of a German type PWR (KONVOI 1300 MWe) in the scale of 1:5. Natural circulation conditions in one loop were approximated by running the corresponding pump at low rotation speed by means of a frequency transformer system. The higher density of the injected water was simulated by adding sugar. The evolution of the spatial distribution of the ECC water was measured by tracering with sodium chloride. Conductivity distributions reflecting the share of ECC water present at given time and location were measured by electrode mesh sensors, one close to the reactor inlet nozzle (16 x 16 measuring points), two sensors in the upper and lower part of the downcomer (2D grids of 4 radial and 64 angular measuring positions) and one sensor at the core entrance (inlets of each of 193 fuel elements).
The paper presents visualisations of the streak effect in the downcomer. The transition from momentum driven flow in the downcomer to a density driven regime was identified (critical Froude number). In the experiments the relative density difference was varied between 0 and 10 % and the loop flow rate between 0 and 15 % of the nominal. The streak effect is more pronounced at higher density differences.

  • Lecture (Conference)
    Annual Meeting on Nuclear Technology 2002, Stuttgart, Germany, May 14-16, 2002 Proceedings pp. 65-69
  • Contribution to proceedings
    Annual Meeting on Nuclear Technology 2002, Stuttgart, Germany, May 14-16, 2002 Proceedings pp. 65-69

Publ.-Id: 4225

Syntheses and first crystal structures of rhenium complexes derived from omega-functionalized fatty acids as model compounds of technetium tracers for myocardial metabolism imaging

Jung, C. M.; Kraus, W.; Leibnitz, P.; Pietzsch, H.-J.; Kropp, J.; Spies, H.

In an attempt to develop new technetium-based radiopharmaceuticals for the non-invasive diagnosis of myocardial metabolism, we have synthesized three examples of novel metal-containing fatty acid derivatives according to the '3+1' mixed-ligand and the Schiff Base/tricarbonyl design. The chelates contain the metal core in the oxidation states +5 and +1 respectively, and were attached to the ending position of a fatty acid chain. The complex formation was accomplished by ligand exchange reactions using three different rhenium precursors, whereas the inactive rhenium metal was utilized as surrogate of the technetium radionuclide. The molecular structures of the fatty acid complexes 7, 10 and 14 were determined by single-crystal X-ray diffraction analyses and show impressively a general problem in technetium tracer research, namely the significant structural alterations of bioactive molecules by coordination even to small-sized metal chelates.

Keywords: rhenium; technetium; fatty acid; drug research, radiopharmaceuticals

  • European Journal of Inorganic Chemistry (2002) 1219-1225

Publ.-Id: 4224

Linear three-dimensional instability of a magnetically driven flow

Grants, I.; Gerbeth, G.

The instability of a rotating magnetic field driven liquid metal flow in a finite cylinder with respect to infinitesimal azimuthally periodic
perturbations is studied numerically. This instability is observed to set in prior to its axisymmetric counterpart with relatively low frequency at diameter-to-height ratios between 0.5 and 2. The both, axisymmetric and three-dimensional instabilities have similar characteristic features. The instability originates in the cross-section of the horizontal and vertical rotating boundary layers and excites inertial waves in the inviscid core.

  • Journal of Fluid Mechanics (2002), vol. 463, pp. 229-239

Publ.-Id: 4223

Targeting of human gamma-glutamyltransferase with mAb 138H11 in a new renal cell carcinoma mouse model

Zimmermann, J.; Sachsinger, J.; Ivancevic, V.; Künstler, J.-U.; Michael, R.; Knoll, K.; Reszka, R.; Seifert, S.; Krause, H.; Munz, D. L.; Heicappell, R.; Fischer, P.

Renal cell carcinoma (RCC) belongs to the 12 most frequent tumors in Germany. Its incidence increases worldwide. 30% to 40% of patients already have metastases when the tumor is diagnosed and further 50% develop metastases after tumor resection. Radiotherapy or chemotherapy have no therapeutic effect against RCC. Systematic therapy of RCC with immunostimulatory cytokines is limited by dose due to serious side effects. A tumor targeting antibody offers the possibility to achieve efficient local doses of cytotoxic or immunostimulating reagents within the tumor without high systemic burden.

Our approach is to treat metastatic RCC with immunoactive agents coupled to our mAb 138H11 specific for human GGT (gamma-glutamyltransferase) which has the ability to target human clear cell and papillary RCC. In extracorporeal transfusion experiments with human RCC-bearing kidney 99m-Tc-labeled 138H11 was enriched up to 20-fold in the tumor. Treatment of nude mice bearing human RCC xenografts with a highly cytotoxic drug (Calicheamicin theta) conjugated to mAb 138H11 led to a significant shrinkage of tumor mass (Cancer Res. 2000, 60, 6089-6094). However, these nude mice are not useful for evaluating ADCC of naked 138H11 or immunoactive conjugates.

For creating a syngeneic immunocompetent mouse model bearing a tumor sensitive to mAb 138H11, we stably transfected the murine RCC RENCA cell line with the human GGT-gene. FACS-analyses revealed that transfected cells were positive for mAb 138H11, in contrast to wild type cells. The transfected cells were growing s.c. in Balb/c Mice without signs of rejection by the host. The mice showed a higher uptake of 99m-Tc-labeled 138H11 in the GGT positive RENCA tumors compared to the wild type tumors.

  • Abstract in refereed journal
    Immunobiology 204 (2001) 308-309
  • Poster
    32nd Annual Meeting of the German Society of Immunology, September 2001

Publ.-Id: 4222

EXAFS Analyses in Radiopharmaceutical Research: Stability Studies of Technetium(I) Carbonyl Complexes in Solution

Seifert, S.; Künstler, J.-U.; Gupta, A.; Funke, H.; Reich, T.; Hennig, C.; Roßberg, A.; Pietzsch, H.-J.; Alberto, R.; Johannsen, B.

Nowadays, the majority of radiopharmaceuticals used in routine nuclear medicine imaging procedures are 99mTc labelled compounds, and intensive research is in progress to design new 99mTc radiopharmaceuticals. Investigation of Tc and Re carbonyl chemistry has led to an organometallic M(I) aqua ion, M(CO)3(H2O)3]+
(M = Tc, Re), as a precursor for the preparation of complexes containing the small [M(CO)3]+ moiety. Tc(I) and Re(I) tricarbonyl complexes represent a new and promising approach to low-valent, non-polar and inert compounds. Complexes with N-donor or S-donor chelating ligands coordinated to the M(I) tricarbonyl moiety with high stability in aqueous solution may serve in the design of radiopharmaceuticals [1, 2].

The aim of this work was to investigate the stability of a model Tc(I) dithioether-tricarbonyl complex, Tc1, in aqueous solution and to estimate structural
parameters for the dissolved compounds. Owing to the extremely small concentration of the radionuclide present in the radiopharmaceutical preparation (10­6 ­ 10­8 M), XAS studies as well as most other chemical investigations employ the long-lived isotope 99Tc (K-edge at 21.044 keV). We found that the complex Tc1 is reversibly transformed into the complex Tc1a in aqueous solution (Figure 24).

Fig. 24: Reversible transformation of the complex Tc1 in aqueous solution.

Chemical investigations were performed both at the 99Tc and 99mTc levels. The change of charge of the complexes was determined by electrophoresis. Mass-spectrometric analyses and EXAFS measurements confirmed the composition of the compounds. EXAFS analyses were carried out at BM20 (Rossendorf CRG beamline, ROBL) [3]. 99Tc solutions of Tc1 and Tc1a were prepared by dissolving solid Tc1 in water/methanol and adding chloride or Ag+, respectively. With an excess of sodium chloride the equilibrium (Figure 24) is on the side of the Tc1 complex. If chloride is removed from the equilibrium by precipitation as AgCl, Tc1a is the species in solution. To obtain a satisfactory evaluation of the EXAFS spectra and the Fourier transforms, single-scattering paths including the C, O and S/Cl coordination shells and multiple-scattering paths to model the oxygen atom of the carbonyl group were taken into account (Figure 25). The estimated atomic distances are 1.92 Å (Tc­C), 2.49 Å (Tc­S or Tc­Cl), 2.19 Å (Tc­Oaq) and 3.06 Å (Tc­OCO). The coordination numbers agree with the molecular structure represented in Figure 24. EXAFS analysis of Tc1a shows the same structural parameters for the C, S/Cl and CO coordination shells as Tc1 except that the coordination number for the S/Cl coordination shell is lowered by approximately one. In addition, the detection of 1.2 ± 0.3 oxygen atoms at 2.19 Å proves the substitution of chlorine by water. This can be seen in Figure 25 as a reduction of the magnitude of the second peak in the Fourier transform since electron back-scattering from the oxygen atom is weaker than from the chlorine atom.

Fig. 25: Tc K-edge k3-weighted EXAFS spectra and the corresponding Fourier transforms of Tc1 and Tc1a (solid line: experimental data, dotted line: fit), transmission mode, sample concentration 3.5 x 10-2 M, sample thickness 1 cm, room temperature.

EXAFS analyses were successfully used to determine structural parameters of Tc(I) tricarbonyl complexes in solution. In connection with chromatographic,
electrophoretic and mass-spectrometric methods, it was found that Tc(I) tricarbonyl complexes containing a bidentate thioether ligand are able to react with water by
exchange of chlorine.

[1] R. Alberto et al., Coordination Chem. Rev., 190-192, 901 (1999).
[2] H.-J. Pietzsch et al., Bioconj. Chem., 11, 414 (2000).
[3] W. Matz et al., J. Synchrotron Rad., 6, 1076 (...

  • Contribution to external collection
    ESRF Highlights 2000 (2001) 22-23

Publ.-Id: 4221

Anordnung zur quantitativen Bildrekonstruktion

Hoppe, D.; Christen, M.

Die Erfindung betrifft Materialuntersuchungen mit Hilfe der Tomographie.
Der Erfindung liegt die Aufgabe zugrunde, auch dann eine quantitative Bildrekonstruktion durchführen zu können, wenn im zu untersuchenden Objekt kein Gebiet bekannter Absorption vorhanden ist.

  • Patent
    DE 101 44 261 A1 - 10. April 2003
  • Patent
    DE 101 44 261 B4 - 20. Dezember 2007

Publ.-Id: 4220

Schichtmaterial für optische Informationsträger und Lichtmasken sowie ein Verfahren zur Herstellung des Schichtmaterials

Teichert, J.; Bischoff, L.; Tsvetkovam, T.

Der Erfindung liegt die Aufgabe zugrunde, ein neues Schichtmaterial für optische Informationsträger und Lichtmasken sowie ähnlich gelagerte Anwendungen vorzuschlagen. Außerdem wird ein einfaches Verfahren zur lokalen Veränderung der optischen Absorption in diesem Schichtmaterial angegeben, mit dem Strukturgrößen erreichbar sind, wie sie die fortgeschrittene Halbleiterindustrie fordert.
Das Schichtmaterial besteht aus amorphem, hydroxierten Siliciumkarbid der Form a-SiC:H, die Schichtbereiche hoher optischer Absorption enthalten Metallatome, vorzugsweise Gallium oder Zinn.

  • Patent
    Patentanmeldung Az 101 43 616.5
  • Patent
    DE 101 43 616 A 1

Publ.-Id: 4219

Biomaterial und Verfahren zu dessen Herstellung

Pham, M. T.; Maitz, M. F.

Die Erfindung betrifft ein Biomaterial und ein Verfahren zu dessen Herstellung. Potentielle Anwendungen sind medizinische Implantologie, Gewebezüchtung, Biotechnologie und Pharmazeutik.
Der Erfindung liegt die Aufgabe zugrunde, ein Biomaterial für Anwendungen in medizinischer Implantologie, Gewebezüchtung, Biotechnologie und Pharmazeutik zu schaffen, das eine gute Strukturbildung und Haftfestigkeit aufweist sowie die zellbiologischen Aspekte berücksichtigt.
Der Erfindung obliegt auch die Aufgabe, ein einfaches und anwendungswirksames Verfahren zur Herstellung des genannten Biomaterials vorzuschlagen.

  • Patent
    Patentanmeldung Az 101 43 410.3
  • Patent
    DE 101 43 410 A 1

Publ.-Id: 4218

Radioaktiv markierte 3-O-Methyl-6-halogen-L-DOPA- Verbindung, (3-O-Methyl-6-halogen-L-4-hydroxyphenylalanin, 3-(2-Halogen-4-hydroxy-5-methoxy-phenyl)-2-amino-propansäure) und deren Verwendung zur Diagnose und Therapie von Tumoren sowie ein Verfahren zu ihrer Herstellung

Füchtner, F.; Bergmann, R.; Steinbach, J.; Wunderlich, G.; Bredow, J.

Aufgabe der Erfindung ist es Substanzen vorzuschlagen, die zur Diagnose und Therapie von Tumoren in der Nuklearmedizin geeignet sind und ein Verfahren zur Herstellung der Substanzen anzugeben.

  • Patent
    DE 101 27 835 A 1

Publ.-Id: 4217

Verfahren und Schaltungsanordnung zur Regelung von Extremwerten

Herbrand, F.

Der Erfindung liegt die Aufgabe zugrunde, ein Verfahren und eine Schaltungsanordnung vorzuschlagen, mit denen der Extremwert einer Größe, oft als Gütegröße bezeichnet, auch bei sehr kleinen Stellbewegungen zu finden und zu halten ist und bei denen der Suchverlust durch die Suchbewegungen konstant gehalten werden kann.

  • Patent
    Patentanmeldung Az 101 27 878.0
  • Patent
    DE 101 27 878 A1
  • Patent
    EP 1 267 228 A2

Publ.-Id: 4216

Verfahren zur Behandlung heteroepitaktischer Halbleiterschichten auf Siliziumsubstraten

Gebel, T.; Heera, V.; Panknin, D.; Skorupa, W.; Voelskow, M.; Eickhoff, M.

Die Erfindung betrifft ein Verfahren zur Behandlung heteroepitaktisch auf Siliziumsubstraten abgeschiedener Halbleiterschichten. Die Erfindung soll insbesondere für die Herstellung elektronischer Bauelemente eingesetzt werden.

  • Patent
    Patentanmeldung Az 101 27 073.9
  • Patent
    DE 101 27 197 A1
  • Patent
    EP 1 263 030 A2

Publ.-Id: 4215

Verfahren zur Behandlung heteroepitaktischer Halbleiterschichten auf Silicon-on-insulator(SOI)-Substraten

Gebel, T.; Heera, V.; Panknin, D.; Skorupa, W.; Voelskow, M.; Eickhoff, M.

Die Erfindung betrifft ein Verfahren zur Behandlung heteroepitaktisch auf SOI-Substraten abgeschiedener Halbleiterschichten. Die Erfindung soll insbesondere für die Herstellung elektronischer Bauelemente eingesetzt werden.

  • Patent
    Patentanmeldung Az 101 27 074.7
  • Patent
    DE 101 27 074 A 1

Publ.-Id: 4214

Anordnung zur tomographischen Bildrekonstruktion

Hoppe, D.

Der Erfindung liegt die Aufgabe zugrunde, dass bei Auftreten von Fluid-Gas-Gemischen (2-Phasen-Gemischen) für das Rekonstruktionsobjektbild die Fehler verringert oder vermieden werden.

  • Patent
    Patentanmeldung Az 101 21 998.9
  • Patent
    DE 101 21 998 A1
  • Patent
    DE 101 21 998 B4

Publ.-Id: 4213

Anordnung zur messtechnischen Erfassung einer Projektion des Strahlungsabsorptionsvermögens eines periodisch veränderlichen Messobjekts

Prasser, H.-M.; Zschau, J.

Die Anwendung ist insbesondere als tomographische Anordnung zur Erzeugung von Schnittbildern von Objekten gegeben, deren Gestalt beziehungsweise Zusammensetzung schnellen Änderungen unterworfen ist, und zwar für den Fall, dass die Änderungen sich zeitlich periodisch wiederholen.
Aufgabe der Erfindung ist es, eine Anordnung vorzuschlagen, die auch bei Objekten, deren Gestalt beziehungsweise Zusammensetzung schnellen, sich periodisch wiederholenden Änderungen unterworfen sind, die Ermittlung von Projektionen gestattet, die einen Momentanzustand oder eine Abfolge von Momentanzuständen der periodisch veränderlichen Verteilung des Absorptionsverhaltens repräsentieren und aus denen sich die Verteilungen selbst rekonstruieren lassen und die dabei mit einer kontinuierlich Strahlung aussendenden Gammaquelle auskommt.

  • Patent
    Patentanmeldung Az 101 17 569.8
  • Patent
    DE 101 17 569 C1
  • Patent
    WO 02/080772 A1

Publ.-Id: 4212

Structure and evolution of electric dipole strength in 204,206,208 Pb below the neutron emission threshold

Enders, J.; von Brentano, P.; Eberth, J.; Fitzler, A.; Fransen, C.; Herzberg, R.-D.; Kaiser, H.; Käubler, L.; von Neumann-Cosel, P.; Pietralla, N.; Ponomarev, V. Y.; Prade, H.; Richter, A.; Schnare, H.; Schwengner, R.; Skoda, S.; Thomas, H. G.; Tiesler, H.; Weisshaar, D.; Wiedenhöver, I.

Not available

  • Physics Letters B 486 (2000) 279-285

Publ.-Id: 4210

Experimental Investigation of the Emergency Condenser of the SWR1000

Schaffrath, A.; Hicken, E. F.; Prasser, H.-M.; Palavecino, C.

The experimental investigations of the emergency condenser of the SWR1000 done at Forschungszentrum Jülich is described in detail. After the description of the emergency condenser operation mode and the NOKO Test facility the performance and the evaluation of several bundle tests are presented. From the bundle tests a thermal and a hydraulic condition are developed. Single tube test results are remarked at the end of the presentation.

  • Lecture (others)
    Centro Atomico Bariloche, Argentinien, 28.11.-04.12.2001

Publ.-Id: 4209

Modeling of Condensation inside Horizontal Tubes

Schaffrath, A.; Krüssenberg, A.-K.; Alt, S.

In the presentation the modeling of condensation inside horizontal tubes is described. The differences between condensation in vertical tubes and in horizontal tubes is explained in detail. The development of the improvement KONWAR for the German thermohydraulic program system ATHLET is decribed in detail. Afterwards the validation of this improvement with the two different experiments NOKO (Forschungszentrum Jülich GmbH) and HORUS (Universität Zittau/Görlitz) is presented.

  • Lecture (others)
    Centro Atomico Bariloche, Argentinien, 28.11.-04.12.2001

Publ.-Id: 4208

Investigation of Two Phase Flow in Vertical Pipes

Schaffrath, A.; Krüssenberg, A.-K.; Prasser, H.-M.

In the presentation a description of the investigations concerning flowmaps for vertical pipes done at the institute of safety research are given. That means, the test facility MTLOOP of the institute with its measurement techniques and the test matrix is described in detail. From these experiments a new criterium for the bubble to slug flow transition is presented. Afterwards, the comparison of this criterium to existing flow maps is done.

  • Lecture (others)
    Centro Atomico Bariloche, Argentinien, 28.11.-04.12.2001

Publ.-Id: 4207

TOPFLOW - a new multipurpose test facility for the investigation of transient two phase flows

Schaffrath, A.; Krüssenberg, A.-K.; Weiß, F.-P.; Prasser, H.-M.

In the presentation a description of the new multipurpose thermohydraulic test facility TOPFLOW is given including the construction phase and the main working fields. Then, after the details about flow diagram and facility loayout as well as the building layout the chosen documentatin form via internet and intranet is presented. Ideas concerning possible CAREM system tests in TOPFLOW are summarized, too.

  • Lecture (others)
    Centro Atomico Bariloche, Argentinien, 26.11.-04.12.2001

Publ.-Id: 4206

Spectroscopy of 44,46Ti with the Binary Reaction Spectrometer and Euroball

Thummerer, S.; Gebauer, B.; Bohlen, H. G.; von Oertzen, W.; Bazzacco, D.; Lenzi, S. M.; Algora, A.; de Angelis, G.; Gadea, A.; Napoli, D. R.; Borcan, C.; Dönau, F.; Käubler, L.; Schnare, H.; Schwengner, R.; Peter, I.; Beck, C.; Bhattacharya, C.; Rousseau, M.; Noucier, R.; Lisle, J.

Not available

  • Physica Scripta T 88 (2000) 114

Publ.-Id: 4205

Magnetic rotation in the A = 80 region: M1 bands in heavy Rb isotopes

Schwengner, R.; Schnare, H.; Frauendorf, S.; Dönau, F.; Käubler, L.; Prade, H.; Grosse, E.; Jungclaus, A.; Lieb, K. P.; Lingk, C.; Skoda, S.; Eberth, J.; de Angelis, G.; Gadea, A.; Farnea, E.; Napoli, D. R.; Ur, C. A.; Lo Bianco, G.

We have studied the isotopes 82Rb45, 83Rb46, and 84Rb47 to search for magnetic rotation which is predicted in the tilted-axis cranking model for a certain mass region around A = 80. Excited states in these nuclei were populated via the reaction 11B + 76Ge with E = 50 MeV at the XTU tandem accelerator of the LNL Legnaro. Based on a -coincidence experiment using the spectrometer GASP we have found magnetic dipole bands in each studied nuclide. The regular M1 bands observed in the odd-odd nuclei 82Rb and 84Rb include B(M1)/B(E2) ratios decreasing smoothly with increasing spin in a range of 13-≤Jπ≤16-. These bands are interpreted in the tilted-axis cranking model on the basis of four-quasiparticle configurations of the type π(fp) πg9/2 2 vg9/2. This is the first evidence of magnetic rotation in the A ≈ 80 region. In contrast, the M1 sequences in the odd-even nucleus 83Rb are not regular, and the B(M1)/B(E2) ratios show a pronounced staggering.

Keywords: in-beam gamma-spectroscopy; magnetic dipole bands

Publ.-Id: 4204

Three-quasiparticle excitations in $^{77}$Br

Döring, J.; Funke, L.; Schwengner, R.; Winter, G.

Not available

  • Physical Review C 48 (1993) 2524-2547

Publ.-Id: 4203

Quadrupole moments of high-spin isomers: Test of the tilted-axis cranking model

Balabanski, D. L.; Vyvey, K.; Neyens, G.; Almehed, D.; Blaha, P.; Borremans, D.; Chmel, S.; Coulier, N.; Coussement, R.; de Clercq, W.; Frauendorf, S.; Georgiev, G.; Hubel, H.; Lepine-Szily, A.; Mineva, M.; Nenoff, N.; Pancholi, S.; Rossbach, D.; Schwengner, R.; Teughels, S.; Walker, P.

We report the results of recent measurements of the spectroscopic quadrupole moments of high-spin isomers. For the K-pi = 35/2(-) five-quasiparticle isomer in W-179 we measured Q(B) =4.00 ((+0.83)(-1.06)) eb. It corresponds to a smaller deformation compaxed to the ground states of the W isotopes and is in disagreement with the current theoretical predictions. We also measuredthe quadrupole moment of the I-pi = 11(-) isomer in Pb-196, Q(s) = (-)3.41(66) eb. It has the same proton (s(1/2)(-2)h(9)/(2)i(13/2)) configuration as the one suggested for the 11 = 16(-) magneticbandhead which allows to deduce the quadrupole moment of the 16(-) state as Q(s) = -0.316(97) eb. This small value proves the near sphericity of the bandhead.

  • Acta Physica Polonica B 32 (2001) 2655

Publ.-Id: 4202

Synthesis and biological evaluation of technetium(III) mixed-ligand complexes with high affinity for the cerebral 5-HT1A receptor and the alpha1-adrenergic receptor

Drews, A.; Pietzsch, H.-J.; Syhre, R.; Seifert, S.; Varnäs, K.; Hall, H.; Halldin, C.; Kraus, W.; Karlsson, P.; Johnsson, C.; Spies, H.; Johannsen, B.

Tc(III) and Re(III) complexes [M(NS3)(CNR)] (M = Re, 99mTc, NS3 = 2,2',2''-nitrilotris(ethanethiol), CNR = functionalized isocyanide bearing a derivative of WAY 100635) have been synthesized and characterized. Re was used as Tc surrogate for chemical characterization and in vitro receptor-binding studies. For two representatives subnanomolar affinities for the 5-HT1A as well as for the alpha1-adrenergic receptor were reached. Biodistribution studies in rats of the 99mTc complexes showed brain uptakes between 0.3 and 0.5 % ID/organ (5 min p.i.). In vitro autoradiography of one 99mTc representative in sections of post mortem human brain indicate its accumulation in 5-HT1A receptor-rich brain regions. However, addition of the specific 5-HT1A receptor agonist 8-OH-DPAT as well as the alpha1-adrenoceptor antagonist prazosin could not substantially block this tracer accumulation. A preliminary SPET study in a monkey showed negligible brain uptake.

  • Nuclear Medicine and Biology 29 (2002) 389-398

Publ.-Id: 4201

Kühlmittelvermischung in Druckwasserreaktoren Teil 1: Möglichkeiten geschlossener analytischer Lösungen und Simulation der Vermischung mit CFX-4

Grunwald, G.; Höhne, T.; Prasser, H.-M.; Rohde, U.

Ziel des Vorhabens war die analytische und numerische Simulation der Kühlmittelvermischung im Ringraum und unteren Plenum von Druckwasserreaktoren. Generell ist die Kühlmittelvermischung relevant für zwei große Störfallgruppen - Borsäureverdünnungsstörfälle und Kaltwassertransienten. Zur Untersuchung der Vermischungsphänomene aus diesen Störfallszenarien wurde die Rossendorfer Versuchsanlage ROCOM konzipiert, die ein 1:5 skaliertes Plexiglasmodell des DWR Konvoi darstellt, in dem auch Geschwindigkeitsmessungen mit Hilfe von LDA-Technik möglich sind. Konstruktion, Errichtung und meßtechnische Ausstattung von ROCOM erfolgten in einem 2. Teil des Vorhabens. Im Vorfeld der Errichtung des ROCOM-Versuchsstandes wurden mit Hilfe des dreidimensionalen Strömungsberechnungsprogrammes CFX-4 Skalierungseffekte untersucht. Die Vergleichsrechnungen belegten, daß eine 1:5 Skalierung ausreichend ist. Nach dem Aufbau des Versuchsstandes und der Inbetriebnahme im 2. Teil des Vorhabens wurden die Vorausberechnungen anhand von experimentellen Ergebnissen bestätigt. Es wurde weiterhin ein Verfahren zur vereinfachten analytischen 2D-Beschreibung des Strömungsfeldes im Ringraum von Druckwasserreaktoren aufgestellt. Es beruht auf der Potentialtheorie, wobei Quellen an den Kühlmitteleintrittspositionen und Wirbel unter Beachtung der Randbedingungen der typischen Ringspaltgeometrie von DWR überlagert wurden. Der Schwerpunkt des Projektes lag jedoch in der numerischen Simulation der Kühlmittelvermischung unterschiedlicher Reaktoranlagen mit CFX-4 und der Validierung des Rechenprogramms anhand von Vermischungsexperimenten. Dabei wurden sowohl stationäre Schleifendurchsätze bei Nominalbetrieb und Teilschleifenbetrieb bzw. transiente Strömungsbedingungen der Reaktortypen DWR Konvoi und WWER-440 untersucht. Die Ergebnisse der CFX-4 Rechnungen im Vergleich mit den Leitfähigkeits- bzw. LDA-Messungen sind im Abschlußbericht dokumentiert. Grundlage für diesen Abschlußbericht ist eine Promotionsarbeit von T. Höhne zum gleichnamigen Thema im Rahmen des Kompetenzerhaltungsprogrammes Kerntechnik.

  • Open Access Logo Wissenschaftlich-Technische Berichte / Forschungszentrum Rossendorf; FZR-335 Oktober 2001
    ISSN: 1437-322X


Publ.-Id: 4200

Jahresbericht 2. Halbjahr 1999/2000 Forschungszentrum Rossendorf

Ottow, S.

  • Open Access Logo Wissenschaftlich-Technische Berichte / Forschungszentrum Rossendorf; FZR-327 August 2001
    ISSN: 1437-322X


Publ.-Id: 4199

Group-IV Nanocluster Formation by Ion Beam Synthesis

Skorupa, W.; Rebohle, L.; Gebel, T.

A short review of our investigations devoted to the use of ion beam synthesized nanoclusters for silicon based light emission and nonvolatile memory effects is presented. Blue-violet light emission is demonstrated basing on Ge-implanted silicon dioxide layers thermally grown on silicon substrates. This version of silicon-based light emission relies on Ge-related defects in the amorphous -Si-O-Si- network. The photo (PL) - and electroluminescence (EL) is excited by a singlett S0-S1 transition of neutral oxygen vacancy and by electron injection from the silicon substrate into the silicon dioxide layer, respectively. Whereas the PL excitation is a well-known mechanism, for the case of electroluminescence an interpretation was performed for the first time in the course of our studies. It is found that the most probable way to excite luminescence centers is the impact excitation by hot electrons. Whereas the injection is explained by trap assisted tunneling of electrons from the substrate into the oxide, the electrons will be transported via traps or in the SiO2 conduction band. The application of the silicon-based light emitting devices for an optocoupler arrangement are described. Another application of nanoclusters is basing on the investigation of thin Si-implanted silicon dioxide layers for nonvolatile memory applications. First promising results demonstrated that the observed programming window can reach several volts and the devices exhibit excellent retention behavior. A 256k-nv-SRAM is demonstrated showing a programming window >1V for write pulses of 12V/8ms.

Keywords: ion implantation; ion beam synthesis; silicon dioxide; silicon; germanium; tin; charge trapping; photoluminescence; electroluminescence; integrated optocoupler; nonvolatile memory device

  • Applied Physics A Volume 76(2003)1049-1059

Publ.-Id: 4198

Pages: [1.] [2.] [3.] [4.] [5.] [6.] [7.] [8.] [9.] [10.] [11.] [12.] [13.] [14.] [15.] [16.] [17.] [18.] [19.] [20.] [21.] [22.] [23.] [24.] [25.] [26.] [27.] [28.] [29.] [30.] [31.] [32.] [33.] [34.] [35.] [36.] [37.] [38.] [39.] [40.] [41.] [42.] [43.] [44.] [45.] [46.] [47.] [48.] [49.] [50.] [51.] [52.] [53.] [54.] [55.] [56.] [57.] [58.] [59.] [60.] [61.] [62.] [63.] [64.] [65.] [66.] [67.] [68.] [69.] [70.] [71.] [72.] [73.] [74.] [75.] [76.] [77.] [78.] [79.] [80.] [81.] [82.] [83.] [84.] [85.] [86.] [87.] [88.] [89.] [90.] [91.] [92.] [93.] [94.] [95.] [96.] [97.] [98.] [99.] [100.] [101.] [102.] [103.] [104.] [105.] [106.] [107.] [108.] [109.] [110.] [111.] [112.] [113.] [114.] [115.] [116.] [117.] [118.] [119.] [120.] [121.] [122.] [123.] [124.] [125.] [126.] [127.] [128.] [129.] [130.] [131.] [132.] [133.] [134.] [135.] [136.] [137.] [138.] [139.] [140.] [141.] [142.] [143.] [144.] [145.] [146.] [147.] [148.] [149.] [150.] [151.] [152.] [153.] [154.] [155.] [156.] [157.] [158.] [159.] [160.] [161.] [162.] [163.] [164.] [165.] [166.] [167.] [168.] [169.] [170.] [171.] [172.] [173.] [174.] [175.] [176.] [177.] [178.] [179.] [180.] [181.] [182.] [183.] [184.] [185.] [186.] [187.] [188.] [189.] [190.] [191.] [192.] [193.] [194.] [195.] [196.] [197.] [198.] [199.] [200.] [201.] [202.] [203.] [204.] [205.] [206.] [207.] [208.] [209.] [210.] [211.] [212.] [213.] [214.] [215.] [216.] [217.] [218.] [219.] [220.] [221.] [222.] [223.] [224.] [225.] [226.] [227.] [228.] [229.] [230.] [231.] [232.] [233.] [234.] [235.] [236.] [237.] [238.] [239.] [240.] [241.] [242.] [243.] [244.] [245.] [246.] [247.] [248.] [249.] [250.] [251.] [252.] [253.] [254.] [255.] [256.] [257.] [258.] [259.] [260.] [261.] [262.] [263.] [264.] [265.] [266.] [267.] [268.] [269.] [270.] [271.] [272.] [273.] [274.] [275.] [276.] [277.] [278.] [279.] [280.] [281.] [282.] [283.] [284.] [285.] [286.] [287.] [288.] [289.] [290.] [291.] [292.] [293.] [294.] [295.] [296.] [297.] [298.] [299.] [300.] [301.] [302.] [303.] [304.] [305.] [306.] [307.] [308.] [309.] [310.] [311.] [312.] [313.] [314.] [315.] [316.] [317.] [318.] [319.] [320.] [321.] [322.] [323.] [324.] [325.] [326.] [327.] [328.] [329.] [330.]