Research Fields

Nuclear Waste Management

Energy > Nuclear Waste Management and Safety as well as Radiation Research - All Topics

Foto: Geo PET ©Copyright: HZDR/André Künzelmann Scientists around the globe continue to address the question of how safe nuclear waste repositories can be established. The high significance of this research was also specified in the Federal Government’s 6th Energy Research Program. The research conducted by the HZDR scientists is designed to protect people and the environment from the hazards associated with radioactivity entering into the bio and geosphere. In order to predict precisely the possible dispersion of radionuclides in the environment and at potential nuclear waste repository sites, researchers need to know much more about these highly complex processes.

For example, it is a particular challenge to improve the understanding and knowledge of the biologically influenced transportation of long-lived radionuclides in the geosphere and their behavior in such diverse biosystems as bacteria, plants or the human organism. This is the only way to avoid environmental hazards and health risks. The following questions are of primary interest in this context: What happens at the interface of bio- and geosystems? How do radionuclides behave in diverse biosystems? When do they enter the food chain? The scientists seek to answer these and other questions to meet their objective: Making better predictions on the safety of potential nuclear waste repository sites.

The quality of these predictions for nuclear waste repositories essentially depends on the availability of the necessary data. That is why the HZDR researchers are partners in the THEREDA project which fosters and promotes the creation of a comprehensive, quality-assured data bank for potential nuclear waste repository sites.

Objectives

Better understanding of the processes for the long-term safety analysis of nuclear repositories in deep geological formations
Developing new equipment systems to gain a better understanding of the processes for dispersing radionuclides in the bio- and geosystems at the molecular and cellular level
Determination of data for the long-term safety analysis of nuclear repositories

Press Releases

Involved HZDR institutes

Institute of Resource Ecology

Collaborations

THEREDA

Contacts

Publications

Hanke, M.; Dornbusch, D.; Tomm, E. et al.
Superstructure-dependent stability of DNA origami nanostructures in the presence of chaotropic denaturants
Nanoscale (2023) (10.1039/d3nr02045b)
Yin, J.-F.; Amidani, L.; Chen, J. et al.
Spatiotemporal Studies of Soluble Inorganic Nanostructures with X-rays and Neutrons
Angewandte Chemie - International Edition (2023) (10.1002/anie.202310953)
Dixon Wilkins, M. C.; Townsend, L. T.; Stennett, M. C. et al.
A multimodal X-ray spectroscopy investigation of uranium speciation in ThTi2O6 compounds with the brannerite structure
Scientific Reports 13(2023), 12776 (10.1038/s41598-023-38912-1)
Dewaele, A.; Amadon, B.; Bosak, A. et al.
Synthesis of Single Crystals of ε-Iron and Direct Measurements of Its Elastic Constants
Physical Review Letters 131(2023), 034101 (10.1103/PhysRevLett.131.034101)
Severin, T.; Karabtsova, V.; Börner, M. et al.
Synthesis, Structures and Photophysical Properties of Tetra- and Hexanuclear Zinc Complexes Supported by Tridentate Schiff Base Ligands
Chemistry 5(2023)2, 1028-1045 (10.3390/chemistry5020070)
Wagler, J.; Gericke, R.
Ge–Cu-Complexes Ph(pyO)Ge(μ²-pyO)₂CuCl and PhGe(μ²-pyO)₄CuCl - Representatives of Cu(I)→Ge(IV) and Cu(II)→Ge(IV) Dative Bond Systems
Molecules 28(2023)14, 5442 (10.3390/molecules28145442)
Koner, K.; Sadhukhan, A.; Karak, S. et al.
Bottom-Up Synthesis of Crystalline Covalent Organic Framework Nanosheets, Nanotubes, and Kippah Vesicles: An Odd–Even Effect Induction
Journal of the American Chemical Society 145(2023)26, 14475-14483 (10.1021/jacs.3c03831)
Arnold, F. M.; Ghasemifard, A.; Kuc, A. B. et al.
Relaxation effects in twisted bilayer molybdenum disulfide: structure, stability, and electronic properties
2D Materials 10(2023)4, 045010 (10.1088/2053-1583/aceb75)
Sucena, S. F.; Demirer, T. I.; Baitullina, A. et al.
Gold-based Coronands as Hosts for M3+ Metal ions: Ring Size Matters
Molecules 28(2023)14, 5421 (10.3390/molecules28145421)
Ruiz-Fresneda, M. A.; Schaefer, S.; Hübner, R. et al.
Exploring Antibacterial Activity and Bacterial-Mediated Allotropic Transition of Differentially Coated Selenium Nanoparticles
ACS Applied Materials and Interfaces 15(2023), 29958-29970 (10.1021/acsami.3c05100)
Zurita, C.; Tsushima, S.; Lorenzo Solari, P. et al.
Interaction between the transferrin protein and plutonium (and thorium), what’s new?
Chemistry - A European Journal (2023) (10.1002/chem.202300636)
Hilpmann, S.; Moll, H.; Drobot, B. et al.
Europium(III) as luminescence probe for interactions of a sulfate-reducing microorganism with potentially toxic metals
Ecotoxicology and Environmental Safety 264(2023), 115474 (10.1016/j.ecoenv.2023.115474)
Knuuti, T.; Tatomir, A.; Göbel, A. et al.
Capturing the state-of-knowledge in EURAD knowledge management
EPJ Nuclear Sciences & Technologies 8(2022), 37 (10.1051/epjn/2022030)
Gericke, R.; Bennett, M. A.; Privér, S. et al.
Formation of Heterobimetallic Complexes by Addition of d¹⁰-Metal Ions to [(Me₃P)_xM(2-C₆F₄PPh₂)₂] (x = 1, 2; M = Ni and Pt): A Synthetic and Computational Study of Metallophilic Interactions
Inorganic Chemistry 62(2023)23, 8846-8862 (10.1021/acs.inorgchem.3c00311)
Koch, T.; Fischer, C.; Schad, F. et al.
Quantification of surface changes and volume losses of selected rock types due to different cleaning processes
Environmental Earth Sciences 82(2023), 132 (10.1007/s12665-023-10776-8)
Heller, A.; Senwitz, C.; Foerstendorf, H. et al.
Europium(III) Meets Etidronic Acid (HEDP): a Coordination Study Combining Spectroscopic, Spectrometric, and Quantum Chemical Methods
Molecules 28(2023)11, 4469 (10.3390/molecules28114469)
Jha, G.; Heine, T.
Spin–orbit coupling corrections for the GFN-xTB method
Journal of Chemical Physics 158(2023)4, 044120 (10.1063/5.0129071)
Matulis, D.; Wadsö, L.; Fahmy, K.
Special Issue “Advances in Monitoring Metabolic Activities of Microorganisms by Calorimetry”
Microorganisms 11(2023)5, 1204 (10.3390/microorganisms11051204)
Opitz, L.; Hübner, R.; Shams Aldin Azzam, S. et al.
Investigations towards incorporation of Eu3+ and Cm3+ during ZrO2 crystallization in aqueous solution
Scientific Reports 13(2023), 12276 (10.1038/s41598-023-39143-0)
Pidchenko, I. N.; Christensen, J. N.; Kutzschbach, M. et al.
Deep anoxic aquifers could act as sinks for uranium through microbial-assisted mineral trapping
Communications Earth & Environment 4(2023), 128 (10.1038/s43247-023-00767-9)
Yang, L.; Zhang, Y.; Huang, Y. et al.
Promoting Oxygen Reduction Reaction on Carbon-based Materials by Selective Hydrogen Bonding
ChemSusChem (2023) (10.1002/cssc.202300082)
Panda, C.; Anny-Nzekwue, O.; Doyle, L. M. et al.
Evidence for a High-Valent Iron-Fluoride That Mediates Oxidative C(sp3)‐H Fluorination
JACS Au 3(2023), 919 (10.1021/jacsau.3c00021)
Klotzsche, M.; Vogel, M.; Sachs, S. et al.
How tobacco (Nicotiana tabacum) BY-2 cells cope with Eu(III) – A microspectroscopic study.
Analyst (2023) (10.1039/D3AN00741C)
Pingel, J. L.; Kulenkampff, J.; Jara-Heredia, D. et al.
In-situ flow visualization with Geo-Positron-Emission-Tomography in a granite fracture from Soultz-sous-Forêts, France
Geothermics 111(2023), 102705 (10.1016/j.geothermics.2023.102705)
Paulsen, C.; Maximilian Gerdes, J.; Svitlyk, V. et al.
Trimorphic TaCrP – A diffraction and 31P solid state NMR spectroscopic study
Zeitschrift für Kristallographie 238(2023)3-4, 105-117 (10.1515/zkri-2022-0070)
Heim, P.; Spedalotto, G.; Lovisari, M. et al.
Synthesis and Characterization of a Masked Terminal Nickel-Oxide Complex
Chemistry - A European Journal 29(2023)21, e202203840 (10.1002/chem.202203840)
Oertel, J.; Sachs, S.; Flemming, K. et al.
Distinct Effects of Chemical Toxicity and Radioactivity on Metabolic Heat of Cultured Cells Revealed by “Isotope-Editing”
Microorganisms 11(2023)3, 584 (10.3390/microorganisms11030584)
Takeyama, T.; Tsushima, S.; Takao, K.
Utility of redox-active ligands for reversible multi-electron transfer in uranyl(VI) complexes
Inorganic Chemistry Frontiers 10(2023)14, 4028-4044 (10.1039/D3QI00189J)
Jha, G.; Heine, T.
DFTB Parameters for the Periodic Table: Part III, Spin-Orbit Coupling
Journal of Chemical Theory and Computation 18(2022)7, 4472-4481 (10.1021/acs.jctc.2c00376)
Sporrer, L.; Zhou, G.; Wang, M. et al.
Near IR bandgap semiconducting 2D conjugated metal-organic framework with rhombic lattice and high mobility
Angewandte Chemie - International Edition 62(2023)25, e202300186 (10.1002/anie.202300186)
Heim, P.; Gericke, R.; Spedalotto, G. et al.
Aromatic and aliphatic hydrocarbon hydroxylation via a formally Ni(IV)=O oxidant
Dalton Transactions 52(2023), 2663-2671 (10.1039/D2DT03949D)
Missana, T.; Alonso, U.; Mayordomo, N. et al.
Analysis of Cadmium Retention Mechanisms by a Smectite Clay in the Presence of Carbonates
Toxics 11(2023)2, 130 (10.3390/toxics11020130)
Bianchetti, E.; Faria Oliveira, A.; Scheinost, A. et al.
Chemistry of the interaction and retention of TcVII and TcIV species at the Fe3O4(001) surface
Journal of Physical Chemistry C 127(2023)16, 7674-7682 (10.1021/acs.jpcc.3c00688)
Hao, H.; Adams, E.; Funke, S. et al.
Highly Altered State of Proton Transport in Acid Pools in Charged Reverse Micelles
Journal of the American Chemical Society 145(2023)3, 1826-1834 (10.1021/jacs.2c11331)
Yang, Y.; Korzhavyi, P.; Nikolaychuk, P. et al.
Tuning catalytic activity of Ni–Co nanoparticles synthesized by gamma-radiolytic reduction of acetate aqueous solutions
Advanced Materials Interfaces 10(2023)7, 202300038 (10.1002/admi.202300038)
Bok, F.; Moog, H. C.; Brendler, V.
The solubility of oxygen in water and saline solutions
Frontiers in Nuclear Engineering 2(2023), 1158109 (10.3389/fnuen.2023.1158109)
Han, S.-C.; Chang, E.; Bok, F. et al.
Application of Community Data to Surface Complexation Modeling Framework Development: Iron Oxide Protolysis
Journal of Colloid and Interface Science 648(2023), 1015-1024 (10.1016/j.jcis.2023.06.054)
Amidani, L.; Dumas, T.; Shuh, D. K. et al.
Oxygen K-edge X-ray Absorption Spectra of ThO2 and CeO2: experiment, interpretation and structural effects.
Journal of Physical Chemistry C 127(2023)6, 3077-3084 (10.1021/acs.jpcc.2c07771)
Caprani, R.; Martin, P.; Prieur, D. et al.
Fission products speciation in spent mixed oxide nuclear fuel: synthesis and characterisation of Pu-bearing SIMfuel
Journal of Nuclear Materials 585(2023), 154607 (10.1016/j.jnucmat.2023.154607)
Filimonova, O. N.; Wermeille, D.; Kvashnina, K.
The state of Ag in pyrrhotite: insights from X-ray absorption spectroscopy
ACS Earth and Space Chemistry (2023) (10.1021/acsearthspacechem.3c00002)
Seidel, A.; Gericke, R.; Brendler, E. et al.
Copper Complexes of Silicon Pyridine-2-olates RSi(pyO)₃ (R = Me, Ph, Bn, Allyl) and Ph₂Si(pyO)₂
Inorganics 11(2023)1, 2 (10.3390/inorganics11010002)
Freville, R.; Dewaele, A.; Bruzy, N. et al.
Comparison between mechanisms and microstructures of α − γ, γ − ϵ and α − ϵ − α phase transitions in iron
Physical Review B 107(2023), 104105 (10.1103/PhysRevB.107.104105)
Ritschel, T.; Stahl, Q.; Kusch, M. et al.
Stabilization mechanism of molecular orbital crystals in IrTe2
Communications Physics 5(2022), 325 (10.1038/s42005-022-01094-9)
Jo, Y.; Çevirim-Papaioannou, N.; Franke, K. et al.
Effect of ISA and chloride on the uptake of niobium(V) by hardened cement paste and C-S-H phases: quantitative description and mechanistic understanding
Cement and Concrete Research 172(2023), 107233 (10.1016/j.cemconres.2023.107233)
Yuan, T.; Yang, Y.; Ait-Mouheb, N. et al.
A comparative study on heterogeneity of clay rocks using pore‐scale diffusion simulations and experiments
Journal of Geophysical Research - Solid Earth 127(2022), e2022JB025428 (10.1029/2022JB025428)
Massonnet, M.; Claparede, L.; Martinez, J. et al.
Influence of sintering conditions on the structure and the redox speciation of homogenous (U,Ce)O2+δ ceramics : a synchrotron study
Inorganic Chemistry 62(2023)19, 7173-7185 (10.1021/acs.inorgchem.2c03945)
Lv, K.; Patzschke, M.; März, J. et al.
Selective crystallization of a highly radiation-resistant isonicotinic acid-based metal-organic framework as a primary actinide waste form
ACS Materials Letters 5(2023), 536-542 (10.1021/acsmaterialslett.2c01087)
Svitlyk, V.; Kuz’Min, M. D.; Mozharivskyj, Y. et al.
Investigation of the intrinsic magnetic properties of GdCo4B single crystal: determination of the magnetocrystalline anisotropy from the first-order magnetization processes
European Physical Journal Plus 138(2023), 388 (10.1140/epjp/s13360-023-03996-1)
Dettmann, S.; Huittinen, N. M.; Jahn, N. et al.
Influence of gluconate on the retention of Eu(III), Am(III), Th(IV), Pu(IV), and U(VI) by C-S-H (C/S = 0.8)
Frontiers in Nuclear Engineering 2(2023), 1124856 (10.3389/fnuen.2023.1124856)
Takeyama, T.; März, J.; Ono, R. et al.
Neptunyl(VI) Nitrate Coordination Polymer with Bis(2-pyrrolidone) Linkers Highlighting Crystallographic Analogy and Solubility Difference in Actinyl(VI) Nitrates
Inorganics 11(2023)3, 104-113 (10.3390/inorganics11030104)
Friedrich, S.; Sieber, C.; Drobot, B. et al.
Eu(III) and Cm(III) Complexation by the Aminocarboxylates NTA, EDTA, and EGTA Studied with NMR, TRLFS, and ITC – An Improved Approach to More Robust Thermodynamics
Molecules 28(2023)12, 4881 (10.3390/molecules28124881)
Qian, Y.; Scheinost, A.; Grangeon, S. et al.
Oxidation state and structure of Fe in nontronite: From oxidizing to reducing conditions
ACS Earth and Space Chemistry (2023) (10.1021/acsearthspacechem.3c00136)
Bazarkina, E.; Laskar, C.; Kokh, M. A. et al.
Contribution of X-ray Spectroscopy to Mineralogy: Exploring Platinum Using High-Energy Resolution Fluorescence Detection X-ray Absorption Spectroscopy, HERFD-XAS
Minerals 12(2022), 1602 (10.3390/min12121602)
Chen, C.; Yuan, T.; Lu, R. et al.
The influence of sedimentary heterogeneity on the diffusion of radionuclides in the sandy facies of Opalinus Clay at the field scale
Advances in Geosciences 58(2022), 77-85 (10.5194/adgeo-58-77-2022)
Laskar, C.; Bazarkina, E.; Kokh, M. et al.
Stability and structure of platinum sulfide complexes in hydrothermal fluids
Geochimica et Cosmochimica Acta 336(2022)1, 407-422 (10.1016/j.gca.2022.08.015)
Ceppatelli, M.; Scelta, D.; Serrano-Ruiz, M. et al.
High-Pressure and High-Temperature Chemistry of Phosphorus and Nitrogen: Synthesis and Characterization of α- and γ‑P3N5
Inorganic Chemistry 61(2022)12165 (10.1021/acs.inorgchem.2c01190)
Rosa, A. D.; Dewaele, A.; Garbarino, G. et al.
Martensitic fcc-hcp transformation pathway in solid krypton and xenon and its effect on their equations of state
Physical Review B 105(2022), 144103 (10.1103/PhysRevB.105.144103)
Murphy, G. L.; Gericke, R.; Gilson, S. et al.
Deconvoluting Cr States in Cr-Doped UO2 Nuclear Fuels via Bulk and Single Crystal Spectroscopic Studies
Nature Communications 14(2023), 2455 (10.1038/s41467-023-38109-0)
Schabernack, J.; Faria Oliveira, A.; Heine, T. et al.
Variability of radionuclide sorption efficiency on muscovite cleavage planes
Advanced Theory and Simulations 2300406(2023), 2300406 (10.1002/adts.202300406)
Ono, R.; Kazama, H.; März, J. et al.
Crystal Structures of Ce(IV) Nitrates with Bis(2-pyrrolidone) Linker Molecules Deposited from Aqueous Solutions with Different HNO3 Concentrations
Inorganic Chemistry 62(2023)1, 454-463 (10.1021/acs.inorgchem.2c03554)
Lippold, H.; Kahle, L.; Sonnendecker, C. et al.
Temporal and spatial evolution of enzymatic degradation of amorphous PET plastics
npj Materials Degradation 6(2022), 93 (10.1038/s41529-022-00305-6)
Johnstone, E. V.; Mayordomo, N.; Mausolf, E. J.
Discovery, nuclear properties, synthesis and applications of technetium-101
Communications Chemistry 5(2022), 131 (10.1038/s42004-022-00746-9)
Johnstone, E. V.; Mayordomo, N.; Mausolf, E. J.
Hybridised production of technetium-99m and technetium-101 with fluorine-18 on a low-energy biomedical cyclotron
EPJ Techniques and Instrumentation 10(2023)1, 1 (10.1140/epjti/s40485-023-00089-2)
Kvashnina, K.
Rare radioisotopes at the ready
Nature Chemistry 14(2022), 1337-1338 (10.1038/s41557-022-01086-w)
Seidel, A.; Weigel, M.; Ehrlich, L. et al.
Molecular Structures of the Silicon Pyridine-2-(thi)olates Me3Si(pyX), Me2Si(pyX)2 and Ph2Si(pyX)2 (py = 2-Pyridyl, X = O, S), and Their Intra- and Intermolecular Ligand Exchange in Solution
Crystals 12(2022)8, 1054-1054 (10.3390/cryst12081054)
Mitrofanov, A.; Berencén, Y.; Sadrollahi, E. et al.
Molecular engineering of naphthalene spacers in low-dimensional perovskites
Journal of Materials Chemistry C 11(2023), 5024 (10.1039/D3TC00132F)
Bag, S.; Sekhar Sasmal, H.; Pratap Chaudhary, S. et al.
Covalent Organic Framework Thin-film Photodetectors from Solution Processable Porous Nanospheres
Journal of the American Chemical Society 45(2023)3, 1649-1659 (10.1021/jacs.2c09838)
Ramzan, M. S.; Goodwin, Z. A. H.; Mostofi, A. A. et al.
Effect of Coulomb impurities on the electronic structure of magic angle twisted bilayer graphene
npj 2D Materials and Applications 7(2023), 49 (10.1038/s41699-023-00403-2)
Wozniak, T.; Asghar, U.-E.-H.; Paulo, E. F. J. et al.
Electronic and Excitonic Properties of MSi2Z4 Monolayers
Small 19(2023)19, 2206444 (10.1002/smll.202206444)
Nordenström, A.; Iakunkov, A.; Boulanger, N. et al.
Temperature dependent intercalation of molten 1-hexadecanol into Brodie graphite oxide
Carbon 203(2023), 770-784 (10.1016/j.carbon.2022.12.030)
Yuan, T.; Fischer, C.
The influence of sedimentary and diagenetic heterogeneity on the radionuclide diffusion in the sandy facies of the Opalinus Clay at the core scale
Applied Geochemistry 146(2022), 105478 (10.1016/j.apgeochem.2022.105478)
Fahmy, K.; Sakmar, T.
Interdisciplinary biophysical studies of membrane proteins bacteriorhodopsin and rhodopsin
Biophysical Reviews 15(2023), 111-125 (10.1007/s12551-022-01003-y)
Torres, K.; Kuc, A. B.; Maschio, L. et al.
Probing Defects and Spin-Phonon Coupling in CrSBr via Resonant Raman Scattering
Advanced Functional Materials 33(2023)12, 2211366 (10.1002/adfm.202211366)
Neumann, J.; Lessing, J.; Lee, S. S. et al.
Y(III) sorption at the orthoclase (001) surface measured by X-ray reflectivity
Environmental Science & Technology 57(2022)1, 266-276 (10.1021/acs.est.2c06703)
Stadler, J.; Vogel, M.; Steudtner, R. et al.
The Chemical Journey of Europium(III) through Winter Rye (Secale cereale L.) – Understanding through Mass Spectrometry and Chemical Microscopy
Chemosphere 313(2022), 137252 (10.1016/j.chemosphere.2022.137252)
Bezzina, J. P.; Neumann, J.; Brendler, V. et al.
Combining Batch Experiments and Spectroscopy for realistic Surface Complexation Modelling of the Sorption of Americium, Curium, and Europium onto Muscovite
Water Research 223(2022), 119032 (10.1016/j.watres.2022.119032)
Huang, W.; Wang, L.; Chen, J. et al.
Vibrio salinus sp. nov., a marine nitrogen-fixing bacterium isolated from the lagoon sediment of an islet inside an atoll in the western Pacific Ocean
Antonie van Leeuwenhoek 115(2022), 1203-1214 (10.1007/s10482-022-01768-y)
Zuniga-Puelles, E.; Cardoso-Gil, R.; Ozden, A. et al.
Low thermal conductivity in bournonite PbCuSbS3: A comprehensive study
Physical Review B 106(2022), 195201 (10.1103/PhysRevB.106.195201)
Alcalde, J.; Carbonell, R.; Pospiech, S. et al.
Preface: State of the art in mineral exploration
Solid Earth 13(2022), 1161-1168 (10.5194/se-13-1161-2022)
Stagg, O.; Morris, K.; Townsend, L. T. et al.
Sulfidation and Reoxidation of U(VI)-Incorporated Goethite: Implications for U Retention during Sub-Surface Redox Cycling
Environmental Science and Technology 56(2022)24, 17643-17652 (10.1021/acs.est.2c05314)
Lagrange, T.; Pan, Z.; Bártová, B. et al.
Uranium reduction by magnetite – mechanism of UO2 formation monitored by STEM, SAED and EELS
Microscopy and Microanalysis 28(2022)Suppl. 1, 2444-2446 (10.1017/S1431927622009370)
Fahmy, K.
Simple Growth–Metabolism Relations Are Revealed by Conserved Patterns of Heat Flow from Cultured Microorganisms
Microorganisms 10(2022), 1397 (10.3390/microorganisms10071397)
Hilpmann, S.; Roßberg, A.; Steudtner, R. et al.
Presence of uranium(V) during uranium(VI) reduction by Desulfosporosinus hippei DSM 8344T
Science of the Total Environment 875(2023), 162593 (10.1016/j.scitotenv.2023.162593)
Faria Oliveira, A.; Kuc, A. B.; Heine, T. et al.
Shedding light on the enigmatic TcO₂·xH₂O structure with density functional theory and EXAFS spectroscopy
Chemistry - A European Journal 28(2022)59, e202202235 (10.1002/chem.202202235)
Cametti, G.; Roos, D. P.; Churakov, S. V. et al.
Pbx(OH)y cluster formation in STI framework-type zeolites: anomalous thermal behaviour and increased thermal stability
Scientific Reports 12(2022), 15934 (10.1038/s41598-022-20317-1)
Rodriguez Hernandez, D. M.; Mayordomo, N.; Parra-Puerto, A. et al.
Exploring the Reduction Mechanism of ⁹⁹Tc(VII) in NaClO₄: A Spectro-Electrochimical Approach
Inorganic Chemistry 61(2022)26, 10159-10166 (10.1021/acs.inorgchem.2c01278)
Bollermann, T.; Yuan, T.; Kulenkampff, J. et al.
Pore network and solute flux pattern analysis towards improved predictability of diffusive transport in argillaceous host rocks
Chemical Geology 606(2022), 120997 (10.1016/j.chemgeo.2022.120997)
Bansal, D.; Kaden, P.; Patzschke, M. et al.
Comparative Analysis of Mononuclear 1:1 and 2:1 Tetravalent Actinide (U, Th, Np) Complexes: Crystal Structure, Spectroscopy, and Electrochemistry
Inorganic Chemistry 61(2022)27, 10509-10520 (10.1021/acs.inorgchem.2c01405)
Haldar, S.; Wang, M.; Bhauriyal, P. et al.
Porous Dithiine-Linked Covalent Organic Framework as a Dynamic Platform for Covalent Polysulfide Anchoring in Lithium–Sulfur Battery Cathodes
Journal of the American Chemical Society 144(2022)20, 9101-9112 (10.1021/jacs.2c02346)
Chen, G.; An, Y.; Liu, S. et al.
Highly accessible and dense surface single metal FeN4 active sites for promoting the oxygen reduction reaction
Energy & Environmental Science 15(2022)6, 2619-2628 (10.1039/d2ee00542e)
Gutenthaler, S. M.; Tsushima, S.; Steudtner, R. et al.
Lanmodulin peptides – unravelling the binding of the EF-Hand loop sequences stripped from the structural corset
Inorganic Chemistry Frontiers 9(2022)16, 4009-4021 (10.1039/d2qi00933a)
Arnold, F. M.; Liu, T.-J.; Kuc, A. B. et al.
Structure-imposed electronic topology in cove-edged graphene nanoribbons
Physical Review Letters 129(2022)21, 216401 (10.1103/PhysRevLett.129.216401)
Maria Dominic, A.; Wang, Z.; Kuc, A. B. et al.
Oxidation State Dependent Conjugation Controls Electrocatalytic Activity in a Two-Dimensional Di-Copper Metal–Organic Framework
Journal of Physical Chemistry C 127(2023), 7299-7307 (10.1021/acs.jpcc.2c08819)
Feig, M.; Carrillo-Cabrera, W.; Bobnar, M. et al.
Composition dependent polymorphism and superconductivity in Y3+x{Rh,Ir}4Ge13-x
Dalton Transactions 51(2022), 4734-4748 (10.1039/d2dt00167e)
Svitlyk, V.; Weiß, S.; Hennig, C.
Stability of doped zirconia under extreme conditions: towards long-term and secure storage of radioactive waste
Journal of the American Ceramic Society 105(2022), 7831-7839 (10.1111/jace.18735)
Ehrlich, L.; Gericke, R.; Brendler, E. et al.
P–Ru-Complexes with a Chelate-Bridge-Switch: A Comparison of 2-Picolyl and 2-Pyridyloxy Moieties as Bridging Ligands
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