Contact

Porträt Prof. Dr. Kvashnina, Kristina; FWOS

Prof. Dr. Kristina Kvashnina

Head of Department "Molecular Structures"
Responsible for the BM20 (ROBL) beamline at ESRF
k.kvashnina@hzdr.de
Phone: +33 476 88 2367

Publications

2024

  1. Jessat I., Foerstendorf H., Rossberg A., Scheinost A.C., Lützenkirchen J., Heim K., Stumpf T., Jordan N. - Unraveling the Np(V) sorption on ZrO2: A batch, spectroscopic and modeling combined approach, Journal of Hazardous Materials 461, 132168-1-132168-9(2024), https://doi.org/10.1016/j.jhazmat.2023.132168 
  2. A. Manceau, O. Mathon, K. A. Lomachenko, M. Rovezzi, K. O. Kvashnina, M.-C. Boiron, R. Brossier, and S. N. Steinmann, Revealing the Incorporation of Cerium in Fluorapatite, ACS Earth Sp. Chem. 8, 119 (2024), https://doi.org/10.1021/acsearthspacechem.3c00274

  3. H. Smith, L. T. Townsend, R. Mohun, J. F. W. Mosselmans, K. Kvashnina, N. C. Hyatt, and C. L. Corkhill, Fabrication, Defect Chemistry and Microstructure of Mn-Doped UO2, Sci. Rep. 14, 1656 (2024), https://doi.org/10.1038/s41598-023-50676-2

  4. Iakunkov A., Nordenström A., Boulanger N., Li G., Hennig C., Jørgensen M.R.V., Kantor I., Talyzin A.V. - Effect of chain length on swelling transitions of brodie graphite oxide in liquid 1‐alcohols, Advanced Materials Interfaces 11, 2300554-1-2300554-14(2024), https://doi.org/10.1002/admi.202300554
  5. Yin, J.; Amidani, L.; Chen, J.; Li, M.; Xue, B.; Lai, Y.; Kvashnina, K.; Nyman, M.; Yin, P. Spatiotemporal Studies of Soluble Inorganic Nanostructures with X‐rays and Neutrons. Angew. Chemie Int. Ed. 2024, 63 (1). https://doi.org/10.1002/anie.202310953

2023

1. Chakraborty, S., Banerjee, D., Scheinost, A.C., Grenèche, J.-M., Favre, F., Géhin, A. and Charlet, L., Assessing the reactivity of Fe(II) sorbed on smectite surface towards U(VI) reduction. Journal of Materials Research 38, 2752–2763 (2023), https://doi.org/10.1557/s43578-023-00998-8

2. Bulushev D.A., Golub F.S., Trubina S.V., Zvereva V.V., Gerasimov E.Y., Prosvirin I.P., Navlani-García M., Jena H.S. - Pd active sites on covalent triazine frameworks for catalytic hydrogen production from formic acid, ACS Applied Nano Materials 6, 13551-13560(2023), https://doi.org/10.1021/acsanm.3c02199

3. Caprani R., Martín P., Prieur D., Martinez J., Hunault M.O.J.Y., Lebreton F., Desagulier M.M., Aloin C., Picard L., Alibert M., Gabriel G., Signoret P., Clavier N. - Fission products speciation in nuclear fuel: Synthesis and characterisation of mixed oxide (U,Pu)O2 SIMfuel, Journal of Nuclear Materials 585, 154607-1-154607-14(2023), https://doi.org/10.1016/j.jnucmat.2023.154607

4. Dettmann S., Huittinen N.M., Jahn N., Kretzschmar J., Kumke M.U., Kutyma T., Lohmann J., Reich T., Schmeide K., Azzam S.S.A., Spittler L., Stietz J. - Influence of gluconate on the retention of Eu(III), Am(III), Th(IV), Pu(IV), and U(VI) by C-S-H (C/S = 0.8), Frontiers in Nuclear Engineering 2, 1124856-1-1124856-15(2023), https://doi.org/10.3389/fnuen.2023.1124856

5. Estevenon P., Amidani L., Bauters S., Tamain C., Bodensteiner M., Meurer F., Hennig C., Vaughan G., Dumas T., Kvashnina K.O. - From molecular oxo-hydroxo Ce clusters to crystalline CeO2, Chemistry of Materials 35, 1723-1734(2023), https://doi.org/10.1021/acs.chemmater.2c03456

6. Filimonova O.N., Trigub A.L., Shikina N.D., Nickolsky M.S., Tagirov B.R. - The state of Zr and Hf in chloride hydrothermal fluids from in situ X-ray absorption spectroscopy, Chemical Geology 641, 121787-1-121787-21(2023), https://doi.org/10.1016/j.chemgeo.2023.121787

7. Filimonova O.N., Wermeille D., Kvashnina K.O. - State of Ag in pyrrhotite: Insights from X-ray absorption spectroscopy
ACS Earth and Space Chemistry 7, 16448-1660(2023), https://doi.org/10.1021/acsearthspacechem.3c00002

8. Galakhov V.R., Udintseva M.S., Smirnov D.A., Makarova A.A., Kuepper K. - Spin states of cobalt ions in the bulk and on the surface of LaCoO3 probed by X-ray absorption, emission, and photoelectron spectra, JETP Letters 118, 185-190(2023), https://doi.org/10.1134/S0021364023601586

9. Gildenast H., Hempelmann G., Gruszien L., Englert U. - A rigid linker for site-selective coordination of transition metal cations: Combining an acetylacetone with a caged phosphine, Inorganic Chemistry 62, 3178-3185 (2023), https://doi.org/10.1021/acs.inorgchem.2c04101

10. Hilpmann S., Rossberg A., Steudtner R., Drobot B., Hübner R., Bok F., Prieur D., Bauters S., Kvashnina K.O., Stumpf T., Cherkouk A. - Presence of uranium(V) during uranium(VI) reduction by Desulfosporosinus hippei DSM 8344T, Science of the Total Environment 875, 162593-1-162593-13(2023), https://doi.org/10.1016/j.scitotenv.2023.162593

11. Lv K., Patzschke M., März J., Bazarkina E., Kvashnina K.O., Schmidt M. - Selective crystallization of a highly radiation- resistant isonicotinic acid-based metal-organic framework as a primary actinide waste form, ACS Materials Letters 5, 536-542(2023), https://doi.org/10.1021/acsmaterialslett.2c01087

12. Massonnet M., Claparede L., Martinez J., Martin P.M., Hunault M.O.J.Y., Prieur D., Mesbah A., Dacheux N., Clavier N. - Influence of sintering conditions on the structure and redox speciation of homogeneous (U,Ce)O2+δ ceramics: A synchrotron study, Inorganic Chemistry 62, 7173-7185(2023), https://doi.org/10.1021/acs.inorgchem.2c03945

13.Milasinovic V., Vukovic V., Krawczuk A., Molcanov K., Hennig C., Bodensteiner M. - The nature of π-hole interactions between iodide anions and quinoid rings in the crystalline state,  IUCrJ 10, 156-163(2023), https://doi.org/10.1107/S2052252523000052

14. Murphy G.L., Gericke R., Gilson S., Bazarkina E.F., Rossberg A., Kaden P., Thümmler R., Klinkenberg M., Henkes M., Kegler P., Svitlyk V., Marquardt J., Lender T., Hennig C., Kvashnina K.O., Huittinen N. - Deconvoluting Cr states in Cr-doped UO2 nuclear fuels via bulk and single crystal spectroscopic studies, Nature Communications 14, 2455-1-2455-11(2023), https://doi.org/10.1038/s41467-023-38109-0

15. Nordenström A., Iakunkov A., Boulanger N., Li G., Hennig C., Baburin I., Jørgensen M., Kantor I., Talyzin A.V. - Temperature dependent intercalation of molten 1-hexadecanol into Brodie graphite oxide, Carbon 203, 770-784(2023), https://doi.org/10.1016/j.carbon.2022.12.030

16. Paulsen C., Gerdes J.M., Svitlyk V., Reimann M.K., Rabenbauer A., Nilges T., Hansen M.R., Pöttgen R. - Trimorphic TaCrP – A diffraction and 31P solid state NMR spectroscopic study, Zeitschrift für Kristallographie - Crystalline Materials 238, 105-117(2023), https://doi.org/10.1515/zkri-2022-0070

17. Poliakova T., Krot A., Trigub A., Nevolin I., Averin A., Yapaskurt V., Vlasova I., Matveev P., Kalmykov S. - Uranium oxides structural transformation in human body liquids, Scientific Reports 13, 4088-1-4088-11(2023), https://doi.org/10.1038/s41598-023-31059-z

18. Qian Y., Scheinost A.C., Grangeon S., Grenèche J.M., Hoving A., Bourhis E., Maubec N., Churakov S.V., Fernandes M.M. - Oxidation state and structure of Fe in nontronite: From oxidizing to reducing conditions, ACS Earth and Space Chemistry 7, 1868-1881(2023), https://doi.org/10.1021/acsearthspacechem.3c00136

19. Romanchuk A.Y., Plakhova T.V., Konyukhova A.D., Smirnova A., Kozlov D.A., Novichkov D.A., Trigub A.L., Kalmykov S.N. - Oxidation and nanoparticle formation during Ce(III) sorption onto minerals, Environmental Science and Technology 57, 5243-5251(2023), https://doi.org/10.1021/acs.est.2c08921

20. Stietz J., Amayri S., Häussler V., Scholze R., Reich T. - The uptake of actinides by hardened cement paste in high-salinity pore water, Minerals 13, 1380-1-1380-14(2023), https://doi.org/10.3390/min13111380

21. Tagirov B.R., Filimonova O.N., Trigub A.L., Vikentyev I.V., Kovalchuk E.V., Nickolsky M.S., Shiryaev A.A., Reukov V.L., Chareev D.A. - The state of gold in phases of the Cu-Fe-S system: In situ X-ray absorption spectroscopy study, Geoscience Frontiers 14, 101533-1-101533-14(2023), https://doi.org/10.1016/j.gsf.2022.101533

22. Wilkins M.C.D., Townsend L.T., Stennett M.C., Kvashnina K.O., Corkhill C.L., Hyatt N.C. - A multimodal X-ray spectroscopy investigation of uranium speciation in ThTi2O6 compounds with the brannerite structure, Scientific Reports 13, 12776-1-12776-11(2023), https://doi.org/10.1038/s41598-023-38912-1

23. Yang Y., Korzhavyi P.A., Nikolaychuk P.A., Bazarkina E.F., Kvashnina K.O., Butorin S.M., Tarakina N.V., Soroka I.L. - Tuning catalytic activity of Ni-Co nanoparticles synthesized by gamma-radiolytic reduction of acetate aqueous solutions, Advanced Materials Interfaces 10, 2300038-1-2300038-13(2023), https://doi.org/10.1002/admi.202300038

24. Amidani, L., Dumas, T., Shuh, D.K., Butorin, S.M., Sahle, C.J., Longo, A. and Kvashnina, K.O., Oxygen K‑Edge X‑ray Absorption Spectra of ThO2 and CeO2: Experiment, Interpretation, and Structural Effects. J Phys Chem C 127, 3077-3084 (2023), https://doi.org/10.1021/acs.jpcc.2c07771

25. A Dewaele, B Amadon, A Bosak, V Svitlyk, F Occelli, Synthesis of Single Crystals of -Iron and Direct Measurements of Its Elastic Constants, Physical Review Letters 131 (3), 034101 (2023), https://doi.org/10.1103/PhysRevLett.131.034101

26. V Svitlyk, MD Kuz’min, Y Mozharivskyj, O Isnard, Investigation of the intrinsic magnetic properties of GdCo4B single crystal: determination of the magnetocrystalline anisotropy from the first-order magnetization process, The European Physical Journal Plus 138 (5), 388 (2023), https://doi.org/10.1140/epjp/s13360-023-03996-1

27. R Fréville, A Dewaele, N Bruzy, V Svitlyk, G Garbarino, Comparison between mechanisms and microstructures of a-y, y-e and a-e-a and phase transitions in iron, Physical Review B 107 (10), 104105(2023), https://doi.org/10.1103/PhysRevB.107.104105

28. Butorin, S. M.; Bauters, S.; Amidani, L.; Beck, A.; Rossberg, A.; Weiss, S.; Vitova, T.; Kvashnina, K. O.; Tougait, O.,  Effect of Carbon Content on Electronic Structure of Uranium Carbides. Sci. Rep., 13 (1), 20434 (2023), https://doi.org/10.1038/s41598-023-47579-7

29. Pidchenko, I. N.; Christensen, J. N.; Kutzschbach, M.; Ignatyev, K.; Puigdomenech, I.; Tullborg, E.-L.; Roberts, N. M. W.; Rasbury, E. T.; Northrup, P.; Tappero, R.; Kvashnina, K. O.; Schäfer, T.; Suzuki, Y.; Drake, H. Deep Anoxic Aquifers Could Act as Sinks for Uranium through Microbial-Assisted Mineral Trapping. Commun. Earth Environ., 4 (1), 128 (2023), https://doi.org/10.1038/s43247-023-00767-9

30. E. Bianchetti, A. F. Oliveira, A. C. Scheinost, C. Di Valentin, G. Seifert, Chemistry of the Interaction and Retention of TcVII and TcIV Species at the Fe3O4(001) Surface, J. Phys. Chem. C, 127, 16, 7674–7682 (2023), https://doi.org/10.1021/acs.jpcc.3c00688
 

2022

  1. Bes, R., Leinders, G. and Kvashnina, K.O. (2022) Application of Multi-Edge HERFD-XAS to Assess the Uranium Valence Electronic Structure in Potassium Uranate (KUO3). J. Synchrotron Rad. 29, 21-29. DOI  (open access)
  2. Bhandary, S., Belis, M., Kaczmarek, A.M. and Van Hecke, K. (2022) Photomechanical Motions in Organoboron-Based Phosphorescent Molecular Crystals Driven by a Crystal-State [2+2] Cycloaddition Reaction. Journal of the American Chemical Society 144, 22051−22058. DOI 
  3. Boulanger, N., Kuzenkova, A.S., Iakunkov, A., Nordenstrom, A., Romanchuk, A.Y., Trigub, A.L., Zasimov, P.V., Prodana, M., Enachescu, M., Bauters, S., Amidani, L., Kvashnina, K.O., Kalmykov, S.N. and Talyzin, A.V. (2022) High Surface Area "3D Graphene Oxide" for Enhanced Sorption of Radionuclides. Advanced Materials Interfaces 9. DOI  (open access)
  4. Brito, P., Paulinelli, B., de Oliveira, G.d.A. and Pinto, H.C. (2022) Length Microstructure and stress analyses in nano-structured alumina layers developed on Fe-Al single crystals. Materialia 22. DOI 
  5. Bulushev, D.A., Golub, F.S., Trubina, S.V., Zvereva, V.V., Bulusheva, L.G., Gerasimov, E.Y., Navlani-Garcia, M., Krot, A.D. and Jena, H.S. (2022) Single-Atom Pd Catalysts Supported on Covalent Triazine Frameworks for Hydrogen Production from Formic Acid. ACS Appl. Nano Mater. 5, 12887–12896. DOI 
  6. Butorin, S.M., Bauters, S., Amidani, L., Beck, A., Weiss, S., Vitova, T. and Tougait, O. (2022) X-ray spectroscopic study of chemical state in uranium carbides. J. Synchrotron Rad. 29, 295-302. DOI  (open access)
  7. Cametti, G., Roos, D.P., Prieur, D., Scheinost, A.C. and Churakov, S.V. (2022) Pbx(OH)y cluster formation and anomalous thermal behaviour in STI framework‑type zeolites. Sci.Rep. 12. DOI (open access)
  8. Carocci, E., Truche, L., Cathelineau, M., Caumon, M.C. and Bazarkina, E.F. (2022) Tungsten (VI) speciation in hydrothermal solutions up to 400 degrees C as revealed by in-situ Raman spectroscopy. Geochim. Cosmochim. Ac. 317, 306-324. DOI 
  9. Ceppatelli, M., Scelta, D., Serrano-Ruiz, M., Dziubek, K., Izquierdo-Ruiz, F., Recio, J.M., Garbarino, G., Svitlyk, V., Mezouar, M., Peruzzini, M. and Bini, R. (2022) High-Pressure and High-Temperature Chemistry of Phosphorus and Nitrogen: Synthesis and Characterization of α- and γ-P3N5. Inorg. Chem. 61, 12165-12180. DOI
  10. Ceppatelli, M., Scelta, D., Serrano-Ruiz, M., Dziubek, K., Morana, M., Svitlyk, V., Garbarino, G., Poreba, T., Mezouar, M., Peruzzini, M. and Bini, R. (2022) Single-Bonded Cubic AsN from High-Pressure and High-Temperature Chemical Reactivity of Arsenic and Nitrogen. Angewandte Chemie-International Edition 61, e202114191. DOI (open access)
  11. De Bona, E., Popa, K., Walter, O., Cologna, M., Hennig, C., Scheinost, A.C. and Prieur, D. (2022) Oxidation of Micro- and Nanograined UO2 Pellets by In Situ Synchrotron X-ray Diffraction. Inorg. Chem. 61, 1843-1850. DOI 
  12. Feig, M., Carrillo-Cabrera, W., Bobnar, M., Simon, P., Curfs, C., Levytskyi, V., Tsirlin, A.A., Leithe-Jasper, A. and Gumeniuk, R. (2022) Composition dependent polymorphism and superconductivity in Y3+x{Rh,Ir}4Ge13-x. Dalton Trans. 51, 4734-4748. DOI 
  13. Gerber, E., Romanchuk, A.Y., Weiss, S., Kuzenkova, A., Hynault, M., Bauters, S., Egorov, A., Butorin, S.M., Kalmykov, S.N. and Kvashnina, K.O. (2022) To form or not to form: PuO2 nanoparticles at acidic pH. Environmental Science Nano 9, 1509-1518. DOI (open access)
  14. Hanke, M., Dornbusch, D., Hadlich, C., Rossberg, A., Hansen, N., Grundmeier, G., Tsushima, S., Keller, A. and Fahmy, K. (2022) Anion-specific structure and stability of guanidinium-bound DNA origami. Computational and Structural Biotechnology Journal 20, 2611-2623. DOI 
  15. Huittinen, N., Virtanen, S., Rossberg, A., Eibl, M., Lönnrot, S. and Polly, R. (2022) A combined extended x–ray absorption fine structure spectroscopy and density functional theory study of americium vs. yttrium adsorption on corundum (α–Al2O3): Evidence for strong vs. weak site sorption. Minerals 12. DOI 
  16. Iakunkov, A., Nordenstrom, A., Boulanger, N., Hennig, C., Baburin, I. and Talyzin, A.V. (2022) Temperature-dependent swelling transitions in MXene Ti3C2Tx. Nanoscale 14, 10940-10949. DOI 
  17. Khabirova, S., Aleshin, G., Plakhova, T., Zubenko, A., Shchukina, A., Fedorova, O., Averin, A., Belova, E., Bazarkina, E., Kvashnina, K. and Kalmykov, S. (2022) CeO2-Azacrown Conjugate as a Nanoplatform for Combined Radiopharmaceuticals. Nanomaterials 12. DOI 
  18. Kohler, L., Patzschke, M., Bauters, S., Vitova, T., Butorin, S.M., Kvashnina, K.O., Schmidt, M., Stumpf, T. and Marz, J. (2022) Insights into the Electronic Structure of a U(IV) Amido and U(V) Imido Complex. Chem. Eur. J 28, online available DOI  (open access)
  19. Kvashnina, K. and Butorin, S.M. (2022) High-Energy Resolution X-Ray Spectroscopy at Actinide M4,5 and Ligand K Edges: What We Know, What We Want to Know, What We Can Know. Chem.Comm. 58, 327-343. DOI (open access)
  20. LaGrange, T., Pan, Z., Bártová, B., Butorin, S.M., Hyatt, N.C., Stennett, M.C., Kvashnina, K.O. and Bernier-Latmani, R. (2022) Uranium reduction by magnetite – mechanism of UO2 formation monitored by STEM, SAED and EELS. Microscopy and Microanalysis 28, 2444-2446. DOI
  21. Laskar, C., Bazarkina, E.F., Kokh, M.A., Hazemann, J.-L., Vuilleumier, R., Desmaele, E. and Pokrovski, G.S. (2022) Stability and structure of platinum sulfide complexes in hydrothermal fluids. Geochim. Cosmochim. Ac. 336, 407-422. DOI 
  22. Meurer, F., Dolomanov, O.V., Hennig, C., Peyerimhoff, N., Kleemiss, F., Puschmann, H. and Bodensteiner, M. (2022) Refinement of anomalous dispersion correction parameters in single-crystal structure determinations. IUCRJ 9, 604-609. DOI 
  23. Oliveira, A.F., Kuc, A., Heine, T., Abram, U. and Scheinost, A.C. (2022) Shedding light on the enigmatic TcO2·xH2O structure with density functional theory and EXAFS spectroscopy. Chem. Eur. J. 28, e202202235. DOI  cif-files (open access)
  24. Pokrovski, G.S., Desmaele, E., Laskar, C., Bazarkina, E.F., Testemale, D., Hazemann, J.L., Vuilleumier, R., Seitsonen, A.P., Ferlat, G. and Saitta, A.M. (2022) Gold speciation in hydrothermal fluids revealed by in situ high energy resolution X-ray absorption spectroscopy. American Mineralogist 107, 369-376. DOI 
  25. Poulain, A., Fernandez-Martinez, A., Greneche, J.-M., Prieur, D., Scheinost, A.C., Menguy, N., Bureau, S., Magnin, V., Findling, N., Drnec, J., Martens, I., Mirolo, M. and Charlet, L. (2022) Selenium nanowire formation by reacting selenate with magnetite. Environ. Sci. Technol., online available. DOI
  26. Romanchuk, A., Trigub, A., Plakhova, T., Kuzenkova, A., Svetogorov, R., Kvashnina, K. and Kalmykov, S. (2022) Effective coordination numbers from EXAFS: general approaches for lanthanide and actinide dioxides. J. Synchrotron Rad. 29, 288-294. DOI (open access)
  27. Rosa, A.D., Dewaele, A., Garbarino, G., Svitlyk, V., Morard, G., De Angelis, F., Krstulovic, M., Briggs, R., Irifune, T., Mathon, O. and Bouhifd, M.A. (2022) Martensitic fcc-hcp transformation pathway in solid krypton and xenon and its effect on their equations of state. Phys. Rev. B 105, 14. DOI 
  28. Scheinost, A.C. and Singh, B. (2022) Metal Oxides, Encyclopedia of Soils in the Environment, 2nd Edition. Elsevier, New York, online available. DOI 
  29. Smith, H., Townsend, L.T., Mohun, R., Cordara, T., Stennett, M.C., Mosselmans, J.F.W., Kvashnina, K. and Corkhill, C.L. (2022) Cr2+ solid solution in UO2 evidenced by advanced spectroscopy. Communications Chemistry 5. DOI (open access)
  30. Stagg, O., Morris, K., Townsend, L.T., Kvashnina, K.O., Baker, M.L., Dempsey, R.L., Abrahamsen-Mills, L. and Shaw, S. (2022) Sulfidation and Reoxidation of U(VI)-Incorporated Goethite: Implications for U Retention during Sub-Surface Redox Cycling. Environ. Sci. Technol. DOI 
  31. Svitlyk, V., Weiss, S. and Hennig, C. (2022) Immobilization of radiotoxic elements with Y-stabilized zirconia: The thorium case. Journal of the American Ceramic Society 105, 5975-5983. DOI (open access)
  32. Svitlyk, V., Weiss, S. and Hennig, C. (2022) Stability of doped zirconia under extreme conditions: Toward long-term and secure storage of radioactive waste. Journal of the American Ceramic Society 105, 7831-7839. DOI 
  33. Zasimov, P.V., Amidani, L., Retegan, M., Walter, O., Caciuffo, R. and Kvashnina, K.O. (2022) HERFD-XANES and RIXS study on the electronic structure of trivalent lanthanides across a series of isostructural compounds. Inorg. Chem. 61, 1817-1830. DOI 
  34. Zuñiga-Puelles, E., Cardoso-Gil, R., Özden, A., Bulut, N., Svitlyk, V., Himcinschi, C., Kortus, J. and Gumeniuk, R. (2022) Low thermal conductivity in bournonite PbCuSbS3: A comprehensive study. Phys. Rev. B 106. DOI 

2021

  1. Scheinost, A.C., Claussner, J., Exner, J., Feig, M., Findeisen, S., Hennig, C., Kvashnina, K.O., Naudet, D., Prieur, D., Rossberg, A., Schmidt, M., Qiu, C., Colomp, P., Cohen, C., Dettona, E., Dyadkin, V. and Stumpf, T. (2021) ROBL-II at ESRF: A synchrotron toolbox for actinide research. J. Synchrotron Rad. 28, 333-349. DOI (open access)
  2. Amidani, L., Vaughan, G.B.M., Plakhova, T.V., Romanchuk, A.Y., Gerber, E., Svetogorov, R., Weiss, S., Joly, Y., Kalmykov, S.N. and Kvashnina, K.O. (2020) The Application of HEXS and HERFD XANES for Accurate Structural Characterisation of Actinide Nanomaterials: The Case of ThO2. Chemistry-A European Journal 27, 252 –263. DOI (open access)
  3. Boersig, N., Scheinost, A.C., Schild, D. and Neumann, T. (2021) Mechanisms of selenium removal by partially oxidized magnetite nanoparticles for wastewater remediation. Appl. Geochem. 132. DOI
  4. De Bona, E., Balice, L., Cognini, L., Holzhaeuser, M., Popa, K., Walter, O., Cologna, M., Prieur, D., Wiss, T. and Baldinozzi, G. (2021) Single-step, high pressure, and two-step spark plasma sintering of UO2 nanopowders. J. Eur. Ceram. Soc. 41, 3655-3663. DOI (open access)
  5. Cametti, G., Scheinost, A.C. and Churakov, S.V. (2021) Cd2+ incorporation in small-pore LEV/ERI intergrown zeolites: A multi-methodological study. Micropor Mesopor Mat, 313, 110835. DOI
  6. Estevenon, P., Dumas, T., Solari, P.L., Welcomme, E., Szenknect, S., Mesbah, A., Kvashnina, K.O., Moisy, P., Poinssot, C. and Dacheux, N. (2021) Formation of plutonium(iv) silicate species in very alkaline reactive media. Dalton Trans., online available. DOI
  7. Feig, M., Akselrud, L., Motylenko, M., Bobnar, M., Wagler, J., Kvashnina, K.O., Levytskyi, V., Rafaja, D., Leithe-Jasper, A. and Gumeniuk, R. (2021) Valence fluctuations in the 3D + 3 modulated Yb3Co4Ge13 Remeika phase. Dalton Trans., online available. DOI
  8. Flipo, S., Rosner, H., Bobnar, M., Kvashnina, K.O., Leithe-Jasper, A. and Gumeniuk, R. (2021) Thermoelectricity and electronic properties of Y1-xCexCrB4. Phys. Rev. B 103, 195121. DOI
  9. Gerber, E., Romanchuk, A.Y., Weiss, S., Bauters, S., Schacherl, B., Vitova, T., Hübner, R., Shams Aldin Azzam, S., Detollenaere, D., Banerjee, D., Butorin, S.M., Kalmykov, S.N. and Kvashnina, K. (2021) Insight into the structure-property relationship of UO2 nanoparticles. Inorganic Chemistry Frontiers 8, 1102-1110. DOI (open access)
  10. Grote, L., Zito, C.A., Frank, K., Dippel, A.-C., Reisbeck, P., Pitala, K., Kvashnina, K.O., Bauters, S., Detlefs, B., Ivashko, O., Pandit, P., Rebber, M., Harouna-Mayer, S.Y., Nickel, B. and Koziej, D. (2021) X-ray studies bridge the molecular and macro length scales during the emergence of CoO assemblies. Nature Communications 12. DOI
  11. Kolomiets, A.V., Paukov, M., Valenta, J., Chatterjee, B., Andreev, A.V., Kvashnina, K.O., Wilhelm, F., Rogalev, A., Drozdenko, D., Minarik, P., Kolorenc, J., Richter, M., Prchal, J. and Havela, L. (2021) 5f states in UGa2 probed by x-ray spectroscopies. Phys. Rev. B 104., online available. DOI
  12. Krawczyk-Bärsch, E., Scheinost, A.C., Rossberg, A., Müller, K., Bok, F., Hallbeck, L., Lehrich, J. and Schmeide, K. (2021) Uranium and neptunium retention mechanisms in Gallionella ferruginea/ferrihydrite systems for remediation purposes. Environmental Science and Pollution Research 28, 18342-18353. DOI (open access)
  13. Kretzschmar, J., Tsushima, S., Lucks, C., Jäckel, E., Meyer, R., Steudtner, R., Müller, K., Rossberg, A., Schmeide, K. and Brendler, V. (2021) Dimeric and Trimeric Uranyl(VI)−Citrate Complexes in Aqueous Solution. Inorg. Chem. 60, 7998–8010. DOI
  14. Kuippers, G., Morris, K., Townsend, L.T., Bots, P., Kvashnina, K., Bryan, N.D. and Lloyd, J.R. (2021) Biomineralization of Uranium-Phosphates Fueled by Microbial Degradation of Isosaccharinic Acid (ISA). Environ. Sci. Technol. 55, 4597-4606. DOI
  15. Kvashnina, K. and Butorin, S.M. (2021) High-Energy Resolution X-Ray Spectroscopy at Actinide M4,5 and Ligand K Edges: What We Know, What We Want to Know, What We Can Know. Chemical Communications, online available. DOI (open access)
  16. Levytskyi, V., Wagler, J., Hennig, C., Feig, M., Weigel, T., Leithe-Jasper, A., Meyer, D.C. and Gumeniuk, R. (2021) Sc3Ir4Si13+x and Sc4Ir7Ge6 - the perovskite-related crystal structures. Zeitschrift Fur Kristallographie-Crystalline Materials 236, 313-323. DOI
  17. Maiwald, M.M., Müller, K., Heim, K., Rothe, J., Dardenne, K., Rossberg, A., Koke, C., Trumm, M., Skerencak-Frech, A. and Panak, P.J. (2021) Complexation of Np(V) with the Dicarboxylates, Malonate, and Succinate: Complex Stoichiometry, Thermodynamic Data, and Structural Information. Inorg. Chem., online available. DOI
  18. Mayordomo, N., Rodríguez, D.M., Rossberg, A., Foerstendorf, H., Heim, K., Brendler, V. and Müller, K. (2021) Analysis of technetium immobilization and its molecular retention mechanisms by Fe(II)-Al(III)-Cl layered double hydroxide. Chemical Engineering Journal 408, 127265. DOI
  19. Prieur, D., Vigier, J.-F., Popa, K., Walter, O., Dieste, O., Varga, Z., Beck, A., Vitova, T., Scheinost, A.C. and Martin, P.M. (2021) Charge Distribution in U1-xCexO2+y Nanoparticles. Inorg. Chem. 60, 14550-14556. DOI
  20. Prieur, D., Desagulier, M.-M., Neuville, D.R., Gueneau, C., Epifano, E., Dardenne, K., Rothe, J. and Martin, P. (2021) A spectroscopic hike in the U-O phase diagram. J. Synchrotron Rad. 28, 1684-1691. DOI (open access)
  21. Roos, D.P., Scheinost, A.C., Churakov, S.V., Nagashima, M. and Cametti, G. (2021) On the nature of Pb species in Pb-exchanged zeolite stellerite (STI): A combined experimental and theoretical study. Micropor. Mesopor. Mat. 327, 111444. DOI
  22. Schmeide, K., Rossberg, A., Bok, F., Azzam, S.S.A., Weiss, S. and Scheinost, A.C. (2021) Technetium immobilization by chukanovite and its oxidative transformation products: Neural network analysis of EXAFS spectra. Sci. Total. Environ. 770, 145334. DOI (open access)
  23. Shiryaev, A.A., Trigub, A.L., Voronina, E.N., Kvashnina, K.O. and Bukhovets, V.L. (2021) Behavior of implanted Xe, Kr and Ar in nanodiamonds and thin graphene stacks: experiment and modeling. Phys. Chem. Chem. Phys., online available. DOI
  24. Suksi, J., Tullborg, E.-L., Pidchenko, I., Krall, L., Sandström, B., Kaksonen, K., Vitova, T., Kvashnina, K.O. and Göttlicher, J. (2021) Uranium remobilisation in anoxic deep rock-groundwater system in response to late Quaternary climate changes – Results from Forsmark, Sweden. Chem. Geo. 584,120551. DOI
  25. Wilkins, M.C.D., Mottram, L.M., Maddrell, E.R., Stennett, M.C., Corkhill, C.L., Kvashnina, K.O. and Hyatt, N.C. (2021) Synthesis, Characterization, and Crystal Structure of Dominant Uranium(V) Brannerites in the UTi2–xAlxO6 System. Inorg. Chem., online available. DOI
  26. Zhang, J., Wenzel, M., Schnaars, K., Hennersdorf, F., Schwedtmann, K., März, J., Rossberg, A., Kaden, P., Kraus, F., Stumpf, T. and Weigand, J.J. (2021) Coordination of Trivalent Lanthanum and Cerium, and Tetravalent Cerium and Actinides (An = Th(IV), U(IV), Np(IV)) by a 4-Phosphoryl 1H-Pyrazol-5-olate Ligand in Solution and the Solid State. Dalton Trans. 50, 3550-3558. DOI

2020

  1. Bauters, S., Scheinost, A.C., Schmeide, K., Weiss, S., Dardenne, K., Rothe, J., Mayordomo, N., Steudtner, R., Stumpf, T., Abram, U., Butorin, S.M. and Kvashnina, K.O. (2020) Signatures of technetium oxidation states: A new approach. Chemical Communications 56, 9608-9611. DOI (open access)
  2. Belskaya, O.B., Zaikovskii, V.I., Gulyaeva, T.I., Talsi, V.P., Trubina, S.V., Kvashnina, K.O., Nizovskii, A.I., Kalinkin, A.V., Bukhtiyarov, V.I. and Likholobov, V.A. (2020) The effect of Pd(II) chloride complexes anchoring on the formation and properties of Pd/MgAlOx catalysts. Journal of Catalysis 391, 109-118. DOI
  3. Bloesser, A., Kurz, H., Timm, J., Wittkamp, F., Simon, C., Hayama, S., Weber, B., Apfel, U.P. and Marschall, R. (2020) Tailoring the Size, Inversion Parameter, and Absorption of Phase-Pure Magnetic MgFe2O4 Nanoparticles for Photocatalytic Degradations. ACS Appl. Nano Mater. 3, 11587-11599. DOI
  4. Bonato, L., Virot, M., Dumas, T., Mesbah, A., Dalodière, E., Blanco, O.D., Wiss, T., Goff, X.L., Odorico, M., Prieur, D., Rossberg, A., Venault, L., Dacheux, N., Moisy, P. and Nikitenko, S.I. (2020) Probing the local structure of nanoscale actinide oxides: A comparison between PuO2 and ThO2 nanoparticles rules out PuO2+x hypothesis. Nanoscale Advances 2, 214-224. DOI (open access)
  5. Boulanger, N., Kuzenkova, A.S., Iakunkov, A., Romanchuk, A.Y., Trigub, A.L., Egorov, A.V., Bauters, S., Amidani, L., Retegan, M., Kvashnina, K.O., Kalmykov, S.N. and Talyzin, A.V. (2020) Enhanced Sorption of Radionuclides by Defect-Rich Graphene Oxide. ACS Applied Materials & Interfaces 12, 45122-45135. DOI (open access)
  6. Cametti, G., Scheinost, A.C. and Churakov, S.V. (2020) Structural Evolution of Ag-LEV Zeolite upon Heating: An In Situ Single-Crystal X-ray Diffraction (SC-XRD) and X-ray Absorption Spectroscopy (XAS) Study. ACS Omega 49, 31774-31783. DOI (open access)
  7. Eibl, M., Shaw, S., Prieur, D., Rossberg, A., Wilding, M.C., Hennig, C., Morris, K., Rothe, J., Stumpf, T. and Huittinen, N. (2020) Understanding the local structure of Eu3+- and Y3+-stabilized zirconia: insights from luminescence and X-ray absorption spectroscopic investigations. J. Mater. Sci. 55, 10095-10120. DOI
  8. Epifano, E., Vauchy, R., Lebreton, R.Lauwerier, F., Joly, A., Scheinost, A., Guéneau, C., Valot, C. and Martin, P.M. (2020) On the O-rich domain of the U-Am-O phase diagram. J. Nucl. Mater. 531, 151986. DOI
  9. Epifano, E., Prieur, D., Martin, P.M., Guéneau, C., Dardenne, K., Rothe, J., Vitova, T., Dieste, O., Wiss, T., Konings, R.J.M. and Manara, D. (2020) Melting behaviour of uranium-americium mixed oxides under different atmospheres. J. Chem. Thermodyn. 140, 105896. DOI
  10. Epifano, E., Vauchy, R., Lebreton, F., Joly, A., Gueneau, C., Valot, C. and Martin, P.M. (2020) Behaviour of (U,Am)O-2 in oxidizing conditions: a high-temperature XRD study. J. Nucl. Mater. 531, 11. DOI
  11. Feig, M., Akselrud, L., Schnelle, W., Dyadkin, V., Chernyshov, D., Ormeci, A., Simon, P., Leithe-Jasper, A. and Gumeniuk, R. (2020) Crystal structure, chemical bonding, and electrical and thermal transport in Sc5Rh6Sn18. Dalton Trans. 49, 6832-6841. DOI
  12. Feig, M., Baenitz, M., Bobnar, M., Luders, K., Naumann, M., Schnelle, W., Medvediev, S., Ranjith, K.M., Hassinger, E., Weigel, T., Meyer, D.C., Leithe-Jasper, A., Kortus, J. and Gumeniuk, R. (2020) Anisotropic superconductivity and quantum oscillations in the layered dichalcogenide TaSnS2. Phys. Rev. B 102, 10. DOI (open access)
  13. Gerber, E., Romanchuk, A.Y., Pidchenko, I., Amidani, L., Rossberg, A., Hennig, C., Vaughan, G.B.M., Trigub, A., Egorova, T., Bauters, S., Plakhova, T., Hunault, M.O.J.Y., Weiss, S., Butorin, S.M., Scheinost, A.C., Kalmykov, S.N. and Kvashnina, K.O. (2020) The missing pieces of the PuO2 nanoparticle puzzle. Nanoscale 12, 18039-18048. DOI (open access)
  14. Kéri, A., Dahn, R., Marques Fernandes, M., Scheinost, A.C., Krack, M. and Churakov, S.V. (2020) Iron adsorption on clays inferred from atomistic simulations and XAS studies. Environ. Sci. Technol. 54, 11886-11893. DOI
  15. Kieffer, J., Valls, V., Blanc, N. and Hennig, C. (2020) New tools for calibrating diffraction setups. J. Synchrotron Rad. 27, 558-566. DOI (open access)
  16. Knaus, J., Sommer, M., Duchstein, P., Gumeniuk, R., Akselrud, L., Sturm, S., Auffermann, G., Hennig, C., Zahn, D., Hulliger, J. and Sturm, E.V. (2020) Polar Structure Formation in Solid Solution of Strontium-Substituted Fluorapatite-Gelatin Composites: From Structural and Morphogenetic Aspects to Pyroelectric Properties. Chem Mater 32, 8619-8632. DOI
  17. Kuzenkova, A.S., Romanchuk, A.Y., Trigub, A.L., Maslakov, K.I., Egorov, A.V., Amidani, L., Kittrell, C., Kvashnina, K.O., Tour, J.M., Talyzin, A.V. and Kalmykov, S.N. (2020) New insights into the mechanism of graphene oxide and radionuclide interaction. Carbon 158, 291-302. DOI
  18. Leinders, G., Bes, R., Kvashnina, K.O. and Verwerft, M. (2020) Local structure in U(IV) and U(V) environments: The case of U3O7 . Inorg. Chem. 59, 4576-4587. DOI (open access)
  19. Pan, Z., Bartova, B., LaGrange, T., Butorin, S.M., Hyatt, N.C., Stennett, M.C., Kvashnina, K.O. and Bernier-Latmani, R. (2020) Nanoscale mechanism of UO2 formation through uranium reduction by magnetite. Nature Communications 11. DOI (open access)
  20. Pidchenko, I., Bauters, S., Sinenko, I., Hempel, S., Amidani, L., Detollenaere, D., Vinze, L., Banerjee, D., van Silfhout, R., Kalmykov, S.N., Goettlicher, J., Baker, R.J. and Kvashnina, K.O. (2020) A multi-technique study of altered granitic rock from the Krunkelbach Valley uranium deposit, Southern Germany. RSC Advances 10, 25529-25539. DOI (open access)
  21. Pidchenko, I., Maerz, J., Hunault, M.O.J.Y., Bauters, S., Butorin, S.M. and Kvashnina, K.O. (2020) Synthesis, Structural, and Electronic Properties of K4Puv102(CO3)3(co: An Environmentally Relevant Plutonium Carbonate Complex. Inorg. Chem. 59, 11889-11893. DOI
  22. Prieur, D., Bonani, W., Popa, K., Walter, O., Kriegsman, K.W., Engelhard, M.H., Guo, X., Eloirdi, R., Gouder, T., Beck, A., Vitova, T., Scheinost, A.C., Kvashnina, K. and Martin, P. (2020) Size dependence of lattice parameter and electronic structure in CeO2 nanoparticles. Inorg. Chem. 59, 5760−5767 DOI (open access)
  23. Rodriguez, D.M., Mayordomo, N., Scheinost, A.C., Schild, D., Brendler, V., Müller, K. and Stumpf, T. (2020) New insights into 99Tc(VII) removal by pyrite: a spectroscopic approach. Environ. Sci. Technol. 54, 2678-2687. DOI
  24. Sichevych, O., Flipo, S., Ormeci, A., Bobnar, M., Akselrud, L., Prots, Y., Burkhardt, U., Gumeniuk, R., Leithe-Jasper, A. and Grin, Y. (2020) Crystal Structure and Physical Properties of the Cage Compound Hf2B2-2 delta Ir5+delta. Inorg. Chem. 59, 14280-14289. DOI
  25. Sotnikov, A.V., Bakovets, V.V., Korotaev, E.V., Trubina, S.V. and Zaikovskii, V.I. (2020) Short- and long-range disorders in misfit layered compounds (MS)(1.2+q)NbS2 with the solid solution subsystem (MS) = (GdxDy1-xS). Materials Research Bulletin 131. DOI
  26. Trigub, A.L., Trofimov, N.D., Tagirov, B.R., Nickolsky, M.S. and Kvashnina, K.O. (2020) Probing the Local Atomic Structure of In and Cu in Sphalerite by XAS Spectroscopy Enhanced by Reverse Monte Carlo Algorithm. Minerals 10. DOI (open access)
  27. Trofimov, N.D., Trigub, A.L., Tagirov, B.R., Filimonova, O.N., Evstigneeva, P.V., Chareev, D.A., Kvashnina, K.O. and Nickolsky, M.S. (2020) The State of Trace Elements (In, Cu, Ag) in Sphalerite Studied by X-Ray Absorption Spectroscopy of Synthetic Minerals. Minerals 10, 640. DOI (open access)
  28. Wyzga, P., Carrillo-Cabrera, W., Akselrud, L., Veremchuk, I., Wagler, J., Hennig, C., Tsirlin, A.A., Leithe-Jasper, A., Kroke, E. and Gumeniuk, R. (2020) Crystal structure, phase transition and properties of indium(III) sulfide. Dalton Trans. 49, 15903-15913. DOI
  29. Wyzga, P., Veremchuk, I., Bobnar, M., Hennig, C., Leithe-Jasper, A. and Gumeniuk, R. (2020) Ternary MIn2S4 (M = Mn, Fe, Co, Ni) thiospinels – Crystal structure and thermoelectric properties. J. Inorgan. Gen. Chem. 646, 1-9. DOI